Your expanded list of values in att.placement is very helpful: this was one of the things I found particularly unclear when I was starting out with TEI.
One thing I don’t see there is an equivalent to EpiDoc’s ‘overstrike’, indicating that something has been written or carved over whatever was there before (which may or may not be decipherable). I assume that ‘inline’ is not referring to this, which I would take as indicating, for example, that a character had been squeezed between two others. I'm not sure what this should be called; 'superimposed' is one example in the Guidelines that isn't specific to a particular medium.
It could also be helpful to have a 'centre' or 'textblock' value (though there might be a better solution that I am missing here). For instance, if one is using this list to roughly record the position of an annotation on a page, what would one do if it was placed somewhere in the middle of the page (e.g. on a page with relatively little text, such as a title page or verso)?
I also wonder about the definition of 'margin' as 'in the outer margin', whereas the Guidelines give it as 'in the margin (left, right, or both)'. The TEI Simple additions pinpoint the ambiguity precisely, but on the other hand I can see them leading to inconsistency, with some people using 'margin-left' and 'margin-right' and others 'margin' – and then what if you wanted to say that something was in the inner margin?