diff --git a/Sources/SpectroEDX/Fit/Continuum.swift b/Sources/SpectroEDX/Fit/Continuum.swift
index 3942e90..2671ee7 100644
--- a/Sources/SpectroEDX/Fit/Continuum.swift
+++ b/Sources/SpectroEDX/Fit/Continuum.swift
@@ -29,7 +29,7 @@
 //  the model has no nonlinear parameter: n_0 + 1 and n_1 + 1 coefficients, 10 + 6 = 16 by default, all
 //  linear and non-negative.
 //
-//  THE STEP SEEN THROUGH THE DETECTOR (opt-in `ContinuumEdgeStep.broadened`): a detector records the incoming spectrum
+//  THE STEP SEEN THROUGH THE DETECTOR (`ContinuumEdgeStep.broadened`, the default since the generators were blurred): a detector records the incoming spectrum
 //  convolved with its resolution, so a measured edge is a Gaussian-blurred step (about 75 eV FWHM at 1.56 keV for 128 eV at
 //  Mn K-alpha), never a jump between two channels. The broadened form weights segment s by
 //      w_s(E) = Phi((E - a_s) / sigma(a_s)) - Phi((E - b_s) / sigma(b_s)),
@@ -42,8 +42,11 @@
 //  Measured: on a pure Al wedge (Titan 200 kV, Super-X; Snelson, Collins, MacArthur, University of Leeds, doi 10.5518/1826,
 //  CC BY 4.0) the sharp step made the model fall 351 counts more than the data between the channels at 1.559 and 1.564 keV,
 //  left the data 1677 counts above the model in 1.53-1.65 keV and the model 39 % above the data in 1.65-2.2 keV; broadened:
-//  42 counts, 907 counts and 19 %. `.sharp` (the default) is the earlier form, value for value: the kit's registered
-//  synthetic generators plant an unbroadened step, so making `.broadened` the default re-measures those results first.
+//  42 counts, 907 counts and 19 %. `.sharp` (opt-in) is the earlier form, value for value: the cut at the edge channel. The kit's
+//  synthetic generators blur their continuum with the detector resolution (tools/edx-sim/detector_blur.py), as a detector does, and
+//  the registered synthetic results were re-measured under `.broadened` when it became the default.
+//  The remaining data excess on that wedge at 1.56-1.65 keV is the Al K-beta line, not the continuum: eXSpy's table ties it at
+//  0.0132 of K-alpha; fitted free it reads 0.028 there (NIST EPQ 0.0315). The quantification fit keeps eXSpy's weight (parity).
 //
 //  The Al K edge energy 1.5596 keV is the standard tabulated value (X-ray Data Booklet, Table 1-1).
 //  The Si K edge (1.839 keV, a detector dead-layer step) is NOT in the default: add it to `edges` to test it, or model the step
@@ -91,14 +94,14 @@ public nonisolated struct ContinuumForm: Sendable, Equatable {
     /// roll-off is modelled and P_s only carries what epsilon does not. nil: the round-1 form. The model is generic
     /// (`DetectorEfficiency`), not a measured Super-X calibration.
     package var efficiency: (any DetectorEfficiency)?
-    /// How the step at each edge is drawn: sharp at the edge channel (default) or broadened by the detector resolution.
+    /// How the step at each edge is drawn: broadened by the detector resolution (default) or sharp at the edge channel.
     package var edgeStep: ContinuumEdgeStep
 
     package static let alKEdge = FitPolicy.alKEdgeKeV
 
     package init(beamEnergy: Double, edges: [Double] = [ContinuumForm.alKEdge], orders: [Int] = [9, 5],
                  nonNegative: Bool = true, efficiency: (any DetectorEfficiency)? = nil,
-                 edgeStep: ContinuumEdgeStep = .sharp) {
+                 edgeStep: ContinuumEdgeStep = .broadened) {
         precondition(orders.count == edges.count + 1, "ContinuumForm needs one order per segment")
         precondition(zip(edges, edges.dropFirst()).allSatisfy { $0 < $1 }, "edges ascend")
         self.beamEnergy = beamEnergy; self.edges = edges; self.orders = orders; self.nonNegative = nonNegative
@@ -216,15 +219,15 @@ public nonisolated struct ContinuumForm: Sendable, Equatable {
     public static let weakLineBiasNote =
         "a weak line next to Al K\u{03B1} reads low by \u{2248} 300 counts per pooled spectrum on synthetic data "
         + "(cause: the Al K\u{03B1} incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); "
-        + "unmeasured on real data. Weak-line bias measured on synthetic data: \u{0394} = \u{2212}295 \u{00B1} 31 counts at 900 planted Mg K\u{03B1} "
-        + "(generator A, no tail: continuum\u{2013}line projection) and \u{2212}310 \u{00B1} 23 at 882 (generator S); "
-        + "\u{2212}402 \u{00B1} 33 at 3000 (A) and \u{2212}310 \u{00B1} 23 at 2899 (S)"
+        + "unmeasured on real data. Weak-line bias measured on synthetic data: \u{0394} = \u{2212}270 \u{00B1} 31 counts at 900 planted Mg K\u{03B1} "
+        + "(generator A, no tail: continuum\u{2013}line projection) and \u{2212}272 \u{00B1} 23 at 882 (generator S); "
+        + "\u{2212}325 \u{00B1} 38 at 3000 (A) and \u{2212}226 \u{00B1} 22 at 2899 (S)"
 }
 
 /// How the continuum's step at an absorption edge is drawn (`FitPolicy.continuumEdgeStep`).
 public nonisolated enum ContinuumEdgeStep: String, Sendable, Codable, Equatable {
-    /// Seen through the detector: each segment weighted by the detector's Gaussian step at its edges.
+    /// Seen through the detector: each segment weighted by the detector's Gaussian step at its edges (the default).
     case broadened
-    /// A jump between the two channels either side of the edge (the default).
+    /// A jump between the two channels either side of the edge: the form before `.broadened` was the default, value for value.
     case sharp
 }
diff --git a/Sources/SpectroEDX/Quant/QuantificationPolicy.swift b/Sources/SpectroEDX/Quant/QuantificationPolicy.swift
index 04af535..ed59b63 100644
--- a/Sources/SpectroEDX/Quant/QuantificationPolicy.swift
+++ b/Sources/SpectroEDX/Quant/QuantificationPolicy.swift
@@ -73,10 +73,10 @@ public nonisolated struct FitPolicy: Sendable, Equatable, Codable {
     public var continuumEdges: [Double]
     /// Bernstein basis with non-negative coefficients (the continuum cannot go negative). False: free-sign monomials.
     public var continuumNonNegative: Bool
-    /// How the continuum steps at each edge. Default `.sharp`, the form the registered synthetic results were measured with.
-    /// `.broadened` blurs the step by the detector resolution, as a measured edge is: on a pure Al spectrum (Titan, Super-X) the
-    /// sharp step left the model 39 % above the data in 1.65-2.2 keV, the broadened one 19 %; on a synthetic Al film with a
-    /// broadened edge a weak Si K-alpha read -38.7 % sharp and -25.4 % broadened.
+    /// How the continuum steps at each edge. Default `.broadened`: the step blurred by the detector resolution, as a measured edge
+    /// is. On a pure Al spectrum (Titan, Super-X) the sharp step left the model 39 % above the data in 1.65-2.2 keV, the broadened
+    /// one 19 %; on a synthetic Al film with a broadened edge a weak Si K-alpha read -38.7 % sharp and -25.4 % broadened.
+    /// `.sharp` is the form before `.broadened` became the default, value for value; a stored policy without the field reads it.
     public var continuumEdgeStep: ContinuumEdgeStep
     /// A detector efficiency multiplying the whole continuum form (its low-energy roll-off modelled instead of absorbed in the
     /// polynomial). Default nil: the Kramers-only form.
@@ -116,7 +116,7 @@ public nonisolated struct FitPolicy: Sendable, Equatable, Codable {
                 irls: IRLSSettings = IRLSSettings(), escapeRatioWarning: Double = 0.05,
                 axisRefinement: AxisRefinementSettings = AxisRefinementSettings(),
                 lineTail: LineTail? = nil, sumPeaks: SumPeakRule = .whenSignificant, sumPeakSignificance: Double = 3,
-                continuumEdgeStep: ContinuumEdgeStep = .sharp, continuumDeadLayer: ContinuumDeadLayer? = nil) {
+                continuumEdgeStep: ContinuumEdgeStep = .broadened, continuumDeadLayer: ContinuumDeadLayer? = nil) {
         self.continuumDeadLayer = continuumDeadLayer
         self.fitFromKeV = fitFromKeV; self.defaultUpperLimitKeV = defaultUpperLimitKeV
         self.continuumOrders = continuumOrders; self.continuumEdges = continuumEdges
@@ -127,7 +127,8 @@ public nonisolated struct FitPolicy: Sendable, Equatable, Codable {
         self.continuumEdgeStep = continuumEdgeStep
     }
 
-    /// The fit before sum peaks were the default (one Gaussian per line, no sum peaks): exSpy's line model.
+    /// The fit before sum peaks were the default (one Gaussian per line, no sum peaks): exSpy's line model. Its continuum is the
+    /// default one (exSpy's polynomial has no edge at all), broadened step included.
     public static let exspyEquivalent = FitPolicy(sumPeaks: .off)
 
     private enum CodingKeys: String, CodingKey {
@@ -136,8 +137,8 @@ public nonisolated struct FitPolicy: Sendable, Equatable, Codable {
              continuumDeadLayer
     }
 
-    /// The synthesized encoding, except that `continuumEdgeStep` is written only when it is not the default, so the default
-    /// policy's canonical JSON stays byte for byte what it was before the field existed.
+    /// The synthesized encoding in a fixed key order. Every field with a value is written, `continuumEdgeStep` and `sumPeaks`
+    /// included; a stored policy without them reads the form it was run with (see `init(from:)`).
     public func encode(to encoder: any Encoder) throws {
         var c = encoder.container(keyedBy: CodingKeys.self)
         try c.encode(fitFromKeV, forKey: .fitFromKeV)
@@ -154,7 +155,7 @@ public nonisolated struct FitPolicy: Sendable, Equatable, Codable {
         try c.encode(axisRefinement, forKey: .axisRefinement)
         try c.encode(sumPeaks, forKey: .sumPeaks)
         try c.encode(sumPeakSignificance, forKey: .sumPeakSignificance)
-        if continuumEdgeStep != .sharp { try c.encode(continuumEdgeStep, forKey: .continuumEdgeStep) }
+        try c.encode(continuumEdgeStep, forKey: .continuumEdgeStep)
         try c.encodeIfPresent(continuumDeadLayer, forKey: .continuumDeadLayer)
     }
 
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.arrays.f64 b/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.arrays.f64
index 9caca37..da36aad 100644
Binary files a/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.arrays.f64 and b/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.arrays.f64 differ
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.txt b/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.txt
index f79335d..7a2c21f 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.txt
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/demo-edx-tiny-dm4.txt
@@ -391,26 +391,26 @@ whole.quantification.method.fitToKeV = nil
 whole.quantification.rows: array 4
 whole.quantification.rows[0].element = "Al"
 whole.quantification.rows[0].groupID = "Al_Ka"
-whole.quantification.rows[0].net = 407d360b4d1ba5d6 467.37775908279343
-whole.quantification.rows[0].sigma = 4037238842cf7c9d 23.138797927528334
+whole.quantification.rows[0].net = 407d361888d229a7 467.38098985762412
+whole.quantification.rows[0].sigma = 4037238d471544f6 23.138874476139755
 whole.quantification.rows[0].supported = true
 whole.quantification.rows[0].atBound = false
 whole.quantification.rows[0].isReference = true
 whole.quantification.rows[0].kFreeRatio = 3ff0000000000000 1
 whole.quantification.rows[0].kFreeSigma = nil
-whole.quantification.rows[0].atomicPercent = 40555512acc1e70b 85.329264821393892
-whole.quantification.rows[0].atomicSigma = 4003201ed5110571 2.3906838079280353
-whole.quantification.rows[0].weightPercent = 405524ab2edc6c17 84.572948184257584
-whole.quantification.rows[0].weightSigma = 4003f45853624d6d 2.4943090929388547
+whole.quantification.rows[0].atomicPercent = 40555518dce738f0 85.329642511180054
+whole.quantification.rows[0].atomicSigma = 4003201c137111d0 2.390678550613508
+whole.quantification.rows[0].weightPercent = 405524b5230984b5 84.573555716796207
+whole.quantification.rows[0].weightSigma = 4003f45862691e46 2.4943092048959299
 whole.quantification.rows[0].atomicTerms.relative: dict 4
 whole.quantification.rows[0].atomicTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[0].atomicTerms.relative.counting = 3f93b587e351a268 0.019247172593539835
-whole.quantification.rows[0].atomicTerms.relative.k = 3f94d91c5ed76146 0.020359462059645915
+whole.quantification.rows[0].atomicTerms.relative.counting = 3f93b58e53ee2844 0.019247268555354205
+whole.quantification.rows[0].atomicTerms.relative.k = 3f94d90523d58e64 0.020359115898271787
 whole.quantification.rows[0].atomicTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[0].weightTerms.relative: dict 4
 whole.quantification.rows[0].weightTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[0].weightTerms.relative.counting = 3f95a3c57f6c623e 0.021132551100068613
-whole.quantification.rows[0].weightTerms.relative.k = 3f95111c33cc11ef 0.020573082601019917
+whole.quantification.rows[0].weightTerms.relative.counting = 3f95a3cea88d52d0 0.021132687604523082
+whole.quantification.rows[0].weightTerms.relative.k = 3f9510fe898f2b9e 0.020572640558195958
 whole.quantification.rows[0].weightTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[0].absorptionSpreadAtomic = nil
 whole.quantification.rows[0].absorptionSpreadWeight = nil
@@ -420,26 +420,26 @@ whole.quantification.rows[0].failure = nil
 whole.quantification.rows[0].lineNote = nil
 whole.quantification.rows[1].element = "Mg"
 whole.quantification.rows[1].groupID = "Mg_Ka"
-whole.quantification.rows[1].net = 403b7e08ed0552ad 27.492323697852658
-whole.quantification.rows[1].sigma = 4016ad7c0dd58db4 5.6694185411064844
+whole.quantification.rows[1].net = 403b7e117b1a077f 27.492454236845784
+whole.quantification.rows[1].sigma = 4016ad7fb72b60d8 5.669432508490182
 whole.quantification.rows[1].supported = true
 whole.quantification.rows[1].atBound = false
 whole.quantification.rows[1].isReference = false
-whole.quantification.rows[1].kFreeRatio = 3fae1dfb402cafbc 0.058822490295227209
-whole.quantification.rows[1].kFreeSigma = 3f898c6c3f1b3a2e 0.012474866557934918
-whole.quantification.rows[1].atomicPercent = 4014a1e9b4b12117 5.1581180794821853
-whole.quantification.rows[1].atomicSigma = 3ff6d507298d3d6b 1.4270087836374283
-whole.quantification.rows[1].weightPercent = 40126bc7e770e009 4.6052547609942929
-whole.quantification.rows[1].weightSigma = 3ff483219439d25d 1.2820144453118225
+whole.quantification.rows[1].kFreeRatio = 3fae1df6fa928be1 0.058822362983185668
+whole.quantification.rows[1].kFreeSigma = 3f898c64ac83c885 0.012474810137494305
+whole.quantification.rows[1].atomicPercent = 4014a1ecc3aa242b 5.1581297466846463
+whole.quantification.rows[1].atomicSigma = 3ff6d5080bab4804 1.4270096259901957
+whole.quantification.rows[1].weightPercent = 40126bcdf6a24410 4.6052778755702235
+whole.quantification.rows[1].weightSigma = 3ff48325b15cc8c2 1.2820183685512778
 whole.quantification.rows[1].atomicTerms.relative: dict 4
 whole.quantification.rows[1].atomicTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[1].atomicTerms.relative.counting = 3fc9ad54dfee5fbf 0.20060215887201413
-whole.quantification.rows[1].atomicTerms.relative.k = 3fc862c4b730f8e2 0.19051417298209744
+whole.quantification.rows[1].atomicTerms.relative.counting = 3fc9ad500389ee46 0.20060157940666751
+whole.quantification.rows[1].atomicTerms.relative.k = 3fc862c433542686 0.19051411157879644
 whole.quantification.rows[1].atomicTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[1].weightTerms.relative: dict 4
 whole.quantification.rows[1].weightTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[1].weightTerms.relative.counting = 3fc9d6cebfdbcf7d 0.20186790817353631
-whole.quantification.rows[1].weightTerms.relative.k = 3fc8894fa431ff69 0.19169040219639591
+whole.quantification.rows[1].weightTerms.relative.counting = 3fc9d6c933ad4f9a 0.20186724684992613
+whole.quantification.rows[1].weightTerms.relative.k = 3fc8894ed7107eba 0.19169030667489101
 whole.quantification.rows[1].weightTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[1].absorptionSpreadAtomic = nil
 whole.quantification.rows[1].absorptionSpreadWeight = nil
@@ -449,26 +449,26 @@ whole.quantification.rows[1].failure = nil
 whole.quantification.rows[1].lineNote = nil
 whole.quantification.rows[2].element = "Si"
 whole.quantification.rows[2].groupID = "Si_Ka"
-whole.quantification.rows[2].net = 404839a28fd62278 48.45027349429887
-whole.quantification.rows[2].sigma = 401e363ae963f5e7 7.5529591052304346
+whole.quantification.rows[2].net = 40483983ddea3400 48.449336757046694
+whole.quantification.rows[2].sigma = 401e363c0b09721c 7.552963421298525
 whole.quantification.rows[2].supported = true
 whole.quantification.rows[2].atBound = false
 whole.quantification.rows[2].isReference = false
-whole.quantification.rows[2].kFreeRatio = 3fba89ba3be4197d 0.10366405450995404
-whole.quantification.rows[2].kFreeSigma = 3f915cbe45ae5fce 0.016955349925041045
-whole.quantification.rows[2].atomicPercent = 40217a5c7b3f4420 8.7389868273476736
-whole.quantification.rows[2].atomicSigma = 40007bbe22ea0e91 2.060421250121927
-whole.quantification.rows[2].weightPercent = 4022082687dd7725 9.0159189660876766
-whole.quantification.rows[2].weightSigma = 4000f4dacd19bc75 2.1195579551199963
+whole.quantification.rows[2].kFreeRatio = 3fba898c961f83e4 0.10366133370509051
+whole.quantification.rows[2].kFreeSigma = 3f915cbc44018189 0.016955320025205309
+whole.quantification.rows[2].atomicPercent = 40217a437cddaf89 8.7387961407291801
+whole.quantification.rows[2].atomicSigma = 40007bb315f0785f 2.0604001726160699
+whole.quantification.rows[2].weightPercent = 4022081000d7a029 9.0157470954146266
+whole.quantification.rows[2].weightSigma = 4000f4d1fd109533 2.1195411463437721
 whole.quantification.rows[2].atomicTerms.relative: dict 4
 whole.quantification.rows[2].atomicTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[2].atomicTerms.relative.counting = 3fc30c571a923bab 0.14881409451888081
-whole.quantification.rows[2].atomicTerms.relative.k = 3fc76877f006a9d6 0.18287562580128619
+whole.quantification.rows[2].atomicTerms.relative.counting = 3fc30c778b2c210c 0.14881796165014582
+whole.quantification.rows[2].atomicTerms.relative.k = 3fc7687b18530908 0.18287600219452593
 whole.quantification.rows[2].atomicTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[2].weightTerms.relative: dict 4
 whole.quantification.rows[2].weightTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[2].weightTerms.relative.counting = 3fc3003a2ac7ce7f 0.14844443406001415
-whole.quantification.rows[2].weightTerms.relative.k = 3fc7557a118d5c4c 0.18229604584732539
+whole.quantification.rows[2].weightTerms.relative.counting = 3fc30059961c2b5a 0.14844817952720285
+whole.quantification.rows[2].weightTerms.relative.k = 3fc7557ccc061e8f 0.18229637109856298
 whole.quantification.rows[2].weightTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[2].absorptionSpreadAtomic = nil
 whole.quantification.rows[2].absorptionSpreadWeight = nil
@@ -478,26 +478,26 @@ whole.quantification.rows[2].failure = nil
 whole.quantification.rows[2].lineNote = nil
 whole.quantification.rows[3].element = "Cu"
 whole.quantification.rows[3].groupID = "Cu_Ka"
-whole.quantification.rows[3].net = 4012d8cc316f74db 4.7117164348867062
-whole.quantification.rows[3].sigma = 4004b15b858302bc 2.586600344715718
+whole.quantification.rows[3].net = 4012d79212e5305e 4.7105181648622345
+whole.quantification.rows[3].sigma = 4004b13cf510b651 2.5865420480466033
 whole.quantification.rows[3].supported = true
 whole.quantification.rows[3].atBound = false
 whole.quantification.rows[3].isReference = false
-whole.quantification.rows[3].kFreeRatio = 3f84a5703f562475 0.010081173832775495
-whole.quantification.rows[3].kFreeSigma = 3f76c284933881f3 0.005556600448045834
-whole.quantification.rows[3].atomicPercent = 3fe8c194458f2fd9 0.77363027177625121
-whole.quantification.rows[3].atomicSigma = 3fdcce2cda6c09f6 0.450083936026345
-whole.quantification.rows[3].weightPercent = 3ffce4e06c35c10e 1.8058780886604526
-whole.quantification.rows[3].weightSigma = 3ff0a29e6fd4468c 1.0397018783882315
+whole.quantification.rows[3].kFreeRatio = 3f84a40ec98a253e 0.010078540349484851
+whole.quantification.rows[3].kFreeSigma = 3f76c25e340de62c 0.0055564575021605327
+whole.quantification.rows[3].atomicPercent = 3fe8bff3a1376e42 0.77343160140612377
+whole.quantification.rows[3].atomicSigma = 3fdccdd34bcf8fca 0.4500625839557385
+whole.quantification.rows[3].weightPercent = 3ffce2ff5c58c165 1.8054193122189528
+whole.quantification.rows[3].weightSigma = 3ff0a270a22a93f2 1.039658196890056
 whole.quantification.rows[3].atomicTerms.relative: dict 4
 whole.quantification.rows[3].atomicTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[3].atomicTerms.relative.counting = 3fe17d0469ac9a20 0.54651089324471869
-whole.quantification.rows[3].atomicTerms.relative.k = 3fc988d9919c6da0 0.19948882684626046
+whole.quantification.rows[3].atomicTerms.relative.counting = 3fe17e142078d41f 0.5466404566019526
+whole.quantification.rows[3].atomicTerms.relative.k = 3fc988dc9cb20d1f 0.19948918963573534
 whole.quantification.rows[3].atomicTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[3].weightTerms.relative: dict 4
 whole.quantification.rows[3].weightTerms.relative.absorption = 0000000000000000 0
-whole.quantification.rows[3].weightTerms.relative.counting = 3fe14e68c2df800b 0.54082143841878982
-whole.quantification.rows[3].weightTerms.relative.k = 3fc9457710b67c3f 0.19743240657860103
+whole.quantification.rows[3].weightTerms.relative.counting = 3fe14f78af4d5c8f 0.5409511016722649
+whole.quantification.rows[3].weightTerms.relative.k = 3fc9457e771e9ad5 0.19743328873047142
 whole.quantification.rows[3].weightTerms.relative.thickness = 0000000000000000 0
 whole.quantification.rows[3].absorptionSpreadAtomic = nil
 whole.quantification.rows[3].absorptionSpreadWeight = nil
@@ -515,16 +515,16 @@ whole.quantification.fit.groupIDs[4] = "Ga_La"
 whole.quantification.fit.groupIDs[5] = "Mg_Ka"
 whole.quantification.fit.groupIDs[6] = "O_Ka"
 whole.quantification.fit.groupIDs[7] = "Si_Ka"
-whole.quantification.fit.values: n 8 sum 408168d58fbe5bbc 557.10427807538463 fnv c0409bcca2004c9
-whole.quantification.fit.values[0] = 407d360b4d1ba5d6 467.37775908279343
-whole.quantification.fit.values[1] = 4012d8cc316f74db 4.7117164348867062
+whole.quantification.fit.values: n 8 sum 408168d814a0ac9e 557.10550809408937 fnv b9bf86634c735ba
+whole.quantification.fit.values[0] = 407d361888d229a7 467.38098985762412
+whole.quantification.fit.values[1] = 4012d79212e5305e 4.7105181648622345
 whole.quantification.fit.values[2] = 0000000000000000 0
 whole.quantification.fit.values[3] = 0000000000000000 0
-whole.quantification.fit.values[4] = 402224f81a074a95 9.0722053655529553
-whole.quantification.fit.values[5] = 403b7e08ed0552ad 27.492323697852658
+whole.quantification.fit.values[4] = 402224f896967b51 9.0722090777104842
+whole.quantification.fit.values[5] = 403b7e117b1a077f 27.492454236845784
 whole.quantification.fit.values[6] = 0000000000000000 0
-whole.quantification.fit.values[7] = 404839a28fd62278 48.45027349429887
-whole.quantification.fit.covariance: n 64 sum 4084c845a5b3ad3f 665.03400745747047 fnv a93c2e2a445ca43b
+whole.quantification.fit.values[7] = 40483983ddea3400 48.449336757046694
+whole.quantification.fit.covariance: n 64 sum 4084cb3a4f54b52f 665.4034716241639 fnv 7f6c1ff08732eda9
 whole.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 whole.quantification.fit.supported: n 8 sum-bits 8 fnv c8ca863b3f69fa5
 whole.quantification.fit.atBound: n 8 sum-bits 3 fnv c05687a1529311c4
@@ -532,7 +532,7 @@ whole.quantification.fit.escapeValues: array 8
 whole.quantification.fit.escapeValues[0] = nil
 whole.quantification.fit.escapeValues[1] = 0000000000000000 0
 whole.quantification.fit.escapeValues[2] = nil
-whole.quantification.fit.escapeValues[3] = 400aac866d132e1d 3.3342407723882972
+whole.quantification.fit.escapeValues[3] = 400aabf7225320cf 3.3339674646013928
 whole.quantification.fit.escapeValues[4] = nil
 whole.quantification.fit.escapeValues[5] = nil
 whole.quantification.fit.escapeValues[6] = nil
@@ -554,25 +554,25 @@ whole.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 whole.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 whole.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 whole.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-whole.quantification.fit.backgroundCoefficients: n 16 sum 40703f9961f8c659 259.97494694879202 fnv 7c812ca4228d303f
+whole.quantification.fit.backgroundCoefficients: n 16 sum 40704022e2a11ca9 260.00851691183431 fnv e99637d3ba95dce5
 whole.quantification.fit.channels = 34..<512
-whole.quantification.fit.model: n 478 sum 40864226cc480c98 712.26894432342942 fnv 7f99469955a9e4c9
-whole.quantification.fit.residual: n 478 sum c019136624064c3f -6.268944323429479 fnv 6bd7e68934d84e1e
-whole.quantification.fit.standardizedResidual: n 478 sum c00845ca316f80a0 -3.0340770589974255 fnv e2826325f1c19242
+whole.quantification.fit.model: n 478 sum 408642460c1ad601 712.28420277562702 fnv 63735467716dc517
+whole.quantification.fit.residual: n 478 sum c01923060d6b00b5 -6.2842027756270697 fnv 2727a45327eea217
+whole.quantification.fit.standardizedResidual: n 478 sum c0086dc813cc6db7 -3.0536042734872484 fnv bf189c09481952e5
 whole.quantification.fit.negativeModelChannels = 0
 whole.quantification.fit.degreesOfFreedom = 452
-whole.quantification.fit.reducedChiSquared = 3fe2b07b81b2b408 0.58404326755192049
-whole.quantification.fit.pearsonReducedChiSquared = 3fd88099ae816c7e 0.38284914056357155
-whole.quantification.fit.deviance = 40769f9f033e0e6a 361.9763214515757
-whole.quantification.fit.reducedDeviance = 3fe9a06b9ffdcc5d 0.80083256958313209
+whole.quantification.fit.reducedChiSquared = 3fe2afe304f4bc9c 0.58397055595368697
+whole.quantification.fit.pearsonReducedChiSquared = 3fd88041fb6a599f 0.38282823135650718
+whole.quantification.fit.deviance = 4076a02f712bda1c 362.01158253793415
+whole.quantification.fit.reducedDeviance = 3fe9a10f39f6c539 0.80091058083613753
 whole.quantification.fit.methodLabel = "least squares, unweighted"
 whole.quantification.fit.referenceShapesLabel = "reference shapes: none"
 whole.quantification.fit.escapeLabel = "escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 whole.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-whole.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+whole.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 whole.quantification.fit.exit = "converged"
 whole.quantification.fit.warnings: array 1
-whole.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+whole.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 whole.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 whole.quantification.fit.escapeRatios: array 8
 whole.quantification.fit.escapeRatios[0] = nil
@@ -590,23 +590,23 @@ whole.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cbf29ce
 whole.quantification.fileAxis.offset = bfdf4b0e19448200 -0.48895599811115176
 whole.quantification.fileAxis.scale = 3f94855da0000000 0.020039999857544899
 whole.quantification.fileAxis.size = 512
-whole.quantification.usedAxis.offset = bfdf7cb2115c707f -0.49198581405085656
-whole.quantification.usedAxis.scale = 3f94a3caa5191c66 0.020156065298831648
+whole.quantification.usedAxis.offset = bfdf7cbba62011f3 -0.49198809836550977
+whole.quantification.usedAxis.scale = 3f94a3cc1c57b1b6 0.020156087140934274
 whole.quantification.usedAxis.size = 512
 whole.quantification.axisLocked = false
 whole.quantification.refinement.fileOffset = bfdf4b0e19448200 -0.48895599811115176
 whole.quantification.refinement.fileScale = 3f94855da0000000 0.020039999857544899
 whole.quantification.refinement.fileResolutionMnKaEV = 4060400000000000 130
-whole.quantification.refinement.offset = bfdf7cb2115c707f -0.49198581405085656
-whole.quantification.refinement.scale = 3f94a3caa5191c66 0.020156065298831648
-whole.quantification.refinement.resolutionMnKaEV = 406053a1da455c83 130.61350740000861
-whole.quantification.refinement.rssFile = 40958f902b10dff7 1379.8907892834375
-whole.quantification.refinement.rssRefined = 40707fcd087fc2ef 263.98755693346806
-whole.quantification.refinement.iterations = 100
+whole.quantification.refinement.offset = bfdf7cbba62011f3 -0.49198809836550977
+whole.quantification.refinement.scale = 3f94a3cc1c57b1b6 0.020156087140934274
+whole.quantification.refinement.resolutionMnKaEV = 406053a685f5ed43 130.61407754929141
+whole.quantification.refinement.rssFile = 40954ed514f96f63 1363.708087823318
+whole.quantification.refinement.rssRefined = 40707f466a600e82 263.95469129106652
+whole.quantification.refinement.iterations = 104
 whole.quantification.refinement.converged = true
 whole.quantification.refinement.size = 512
-whole.quantification.plotModel: n 512 sum 40864226cc480c98 712.26894432342942 fnv fae34651fd9a3109
-whole.quantification.plotBackground: n 512 sum 4061987a931efe84 140.76496273091846 fnv 1ddcff3b229cb1b7
+whole.quantification.plotModel: n 512 sum 408642460c1ad601 712.28420277562702 fnv 724e54731dbd18d7
+whole.quantification.plotBackground: n 512 sum 406198f0ded13ffe 140.77940312260756 fnv dfb53193382aa4b
 whole.quantification.kSet.kind = .computed
 whole.quantification.kSet.elements: array 4
 whole.quantification.kSet.elements[0] = "Al"
@@ -629,14 +629,14 @@ whole.quantification.kSet.reference = "Al"
 whole.quantification.abundanceRefusal = nil
 whole.quantification.absorption.refused = "GMS files: the stage tilt and the four detector segments are not read yet (open item), so the absorption geometry is unknown"
 whole.quantification.warnings: array 1
-whole.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+whole.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 whole.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-whole.quantification.quality = 3fd88099ae816c7e 0.38284914056357155
+whole.quantification.quality = 3fd88041fb6a599f 0.38282823135650718
 whole.quantification.footerLines: array 9
-whole.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
+whole.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 whole.quantification.footerLines[1] = "energy axis: file -0.489 keV + 0.0200 keV/ch → refined -3.0 eV, gain +0.579 %, FWHM(Mn Kα) 131 eV"
 whole.quantification.footerLines[2] = "beam 200 kV · typed"
-whole.quantification.footerLines[3] = "fit range 0.2–9.80776 keV (default; the axis end) · 24 px pooled (Whole map)"
+whole.quantification.footerLines[3] = "fit range 0.2–9.80777 keV (default; the axis end) · 24 px pooled (Whole map)"
 whole.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
 whole.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 0.38 (Pearson)"
 whole.quantification.footerLines[6] = "k: computed: Bote-Salvat 2008 (NIST EPQ tables, PRA 77 042701), edges DHS xionUis.csv; not Velox's Brown-Powell default; omega: Krause 1979 (NIST EPQ Krause1979.csv); epsilon: EPQ getDefaultSDDProperties (Au 0.0 nm, Al 10.0 nm, Si dead layer 0.0 µm, Si 450.0 µm); generic SDD model, not a measured calibration of this detector; FFAST MACs; relative to Al; beam 200.0 keV; UNVALIDATED (EPQ 249dd3f8 + Krause 1979 + FFAST); σ_k 20 % flat, 0 on the reference (Al)"
@@ -649,28 +649,28 @@ whole.quantification.fitSettings.elements[2] = "Si"
 whole.quantification.fitSettings.elements[3] = "Cu"
 whole.quantification.fitSettings.elements[4] = "O"
 whole.quantification.fitSettings.elements[5] = "Ga"
-whole.quantification.fitSettings.resolutionMnKaEV = 406053a1da455c83 130.61350740000861
+whole.quantification.fitSettings.resolutionMnKaEV = 406053a685f5ed43 130.61407754929141
 whole.quantification.fitSettings.beamEnergy = 4069000000000000 200
 whole.quantification.fitSettings.fitFrom = 3fc999999999999a 0.20000000000000001
-whole.quantification.fitSettings.fitTo = 40239d932f3bac54 9.8077635536521157
+whole.quantification.fitSettings.fitTo = 40239d945918854d 9.8077724306519034
 whole.quantification.fitSettings.background.continuum.beamEnergy = 4069000000000000 200
 whole.quantification.fitSettings.background.continuum.edges: n 1 sum 3ff8f41f212d7732 1.5596000000000001 fnv 81bcb0c79f3d52e2
 whole.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f212d7732 1.5596000000000001
 whole.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 whole.quantification.fitSettings.background.continuum.nonNegative = true
 whole.quantification.fitSettings.background.continuum.efficiency = nil
-whole.quantification.fitSettings.background.continuum.edgeStep = .sharp
+whole.quantification.fitSettings.background.continuum.edgeStep = .broadened
 whole.quantification.fitSettings.escapePeaks = true
 whole.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 whole.quantification.fitSettings.method = .leastSquares
 whole.quantification.fitSettings.lineTail = nil
 whole.quantification.sumEscapeCounts = nil
 whole.quantification.fitRange.fromKeV = 3fc999999999999a 0.20000000000000001
-whole.quantification.fitRange.toKeV = 40239d932f3bac54 9.8077635536521157
+whole.quantification.fitRange.toKeV = 40239d945918854d 9.8077724306519034
 whole.quantification.fitRange.source = .defaultReach
 whole.quantification.fitRange.axisEndKeV = 402380c28065dbf0 9.7514839290942916
 whole.quantification.fitRange.beamEnergyKeV = 4069000000000000 200
-whole.quantification.fitRange.reachKeV = 40239d932f3bac54 9.8077635536521157
+whole.quantification.fitRange.reachKeV = 40239d945918854d 9.8077724306519034
 whole.quantification.fitRange.typedKeV = nil
 whole.quantification.rangeSensitivity = nil
 whole.quantification.unlistedCheck = nil
@@ -678,7 +678,7 @@ whole.quantification.unlistedCheckPending = false
 whole.quantification.abundanceCaveat = nil
 whole.quantification.appliedSumEscape = nil
 whole.quantification.continuumDeadLayerMicrons = nil
-whole.csv-fnv = 37c2c8963acfc357
+whole.csv-fnv = f7c620561e1f0e17
 whole.rangeSensitivity = nil
 whole.unlistedProposal.candidates: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 whole.unlistedProposal.sumPeaks: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
@@ -702,31 +702,31 @@ whole.unlistedProposal.currie.beta = 3fa999999999999a 0.050000000000000003
 whole.unlistedProposal.notes: array 7
 whole.unlistedProposal.notes[0] = "Lines below 0.45 keV are not tested (a measured limit of the continuum model, not a property of the method)."
 whole.unlistedProposal.notes[1] = "Identification (validation: none): the residual's peaks at or above 5 σ of its top-hat filter (1.5 × below 1 keV); a candidate joins when Σ(y − μ)²/(μ + (0.01 μ)²) falls by at least 100, 20 % of that at its own lines, with its area at or above Currie L_D (α = β = 0.05, σ₀ from the fit's own variance with it absent) and no line against it; the final fit drops what it does not need (100). Kβ weights from NIST EPQ in this fit."
-whole.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data; escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV); reference shapes: none; 0 residual peaks examined, 0 candidate fits, 2 fits in all."
+whole.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data; escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV); reference shapes: none; 0 residual peaks examined, 0 candidate fits, 2 fits in all."
 whole.unlistedProposal.notes[3] = "Confirmation lines (validation: none): an element nominated by an L or M line needs its K or L alpha line at 3 σ in the residual where the fitted range holds it and the beam is at least 2.0 times its energy; otherwise it is withheld."
-whole.unlistedProposal.notes[4] = "Background check: data over model 0.60 off the lines in 1.0 to 2.5 keV (0.80 to 1.25 is healthy); a find there is only possible."
+whole.unlistedProposal.notes[4] = "Background check: data over model 0.59 off the lines in 1.0 to 2.5 keV (0.80 to 1.25 is healthy); a find there is only possible."
 whole.unlistedProposal.notes[5] = "Look-elsewhere: 0 candidates were tested, so about 0.00 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
-whole.unlistedProposal.notes[6] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+whole.unlistedProposal.notes[6] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 whole.unlistedProposal.passes = 2
 whole.unlistedProposal.settled = true
-whole.unlistedProposal.reducedChiSquared = 3fd8871c479cc16c 0.38324648850814103
+whole.unlistedProposal.reducedChiSquared = 3fd88696d3af7cf8 0.38321467087185068
 whole.unlistedCheck.candidates: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 whole.unlistedCheck.moves: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 whole.unlistedCheck.largest = nil
 whole.unlistedCheck.failure = nil
 whole.withholding: array 2
-whole.withholding[0]: n 4 sum 4059000000000000 100 fnv ce53b5d31774b456
-whole.withholding[0][0] = 40555512acc1e70b 85.329264821393892
-whole.withholding[0][1] = 4014a1e9b4b12117 5.1581180794821853
-whole.withholding[0][2] = 40217a5c7b3f4420 8.7389868273476736
-whole.withholding[0][3] = 3fe8c194458f2fd9 0.77363027177625121
-whole.withholding[1]: n 4 sum 40812041af563e92 548.03207270983171 fnv 3a304d7f0b520325
-whole.withholding[1][0] = 407d360b4d1ba5d6 467.37775908279343
-whole.withholding[1][1] = 403b7e08ed0552ad 27.492323697852658
-whole.withholding[1][2] = 404839a28fd62278 48.45027349429887
-whole.withholding[1][3] = 4012d8cc316f74db 4.7117164348867062
+whole.withholding[0]: n 4 sum 4059000000000001 100.00000000000001 fnv 8839591c4accd255
+whole.withholding[0][0] = 40555518dce738f0 85.329642511180054
+whole.withholding[0][1] = 4014a1ecc3aa242b 5.1581297466846463
+whole.withholding[0][2] = 40217a437cddaf89 8.7387961407291801
+whole.withholding[0][3] = 3fe8bff3a1376e42 0.77343160140612377
+whole.withholding[1]: n 4 sum 40812044324652b1 548.03329901637892 fnv 3bf34c80816b9918
+whole.withholding[1][0] = 407d361888d229a7 467.38098985762412
+whole.withholding[1][1] = 403b7e117b1a077f 27.492454236845784
+whole.withholding[1][2] = 40483983ddea3400 48.449336757046694
+whole.withholding[1][3] = 4012d79212e5305e 4.7105181648622345
 whole.withholding.caveat = nil
-whole.csv-withholding-fnv = afc2bf28add0ad9a
+whole.csv-withholding-fnv = 36b8c585c8640dfa
 region-locked-axis.quantification.method.version = 1
 region-locked-axis.quantification.method.estimator = .leastSquares
 region-locked-axis.quantification.method.background = .empiricalWithAlEdge
@@ -755,8 +755,8 @@ region-locked-axis.quantification.method.fitToKeV = nil
 region-locked-axis.quantification.rows: array 2
 region-locked-axis.quantification.rows[0].element = "Al"
 region-locked-axis.quantification.rows[0].groupID = "Al_Ka"
-region-locked-axis.quantification.rows[0].net = 40570dc8d88d02ab 92.215383660989275
-region-locked-axis.quantification.rows[0].sigma = 402739aae9ee1fc0 11.612632093732714
+region-locked-axis.quantification.rows[0].net = 4056e9707670d5e6 91.64748917597862
+region-locked-axis.quantification.rows[0].sigma = 40270ede76228a92 11.529040996281115
 region-locked-axis.quantification.rows[0].supported = true
 region-locked-axis.quantification.rows[0].atBound = false
 region-locked-axis.quantification.rows[0].isReference = true
@@ -776,13 +776,13 @@ region-locked-axis.quantification.rows[0].failure = nil
 region-locked-axis.quantification.rows[0].lineNote = nil
 region-locked-axis.quantification.rows[1].element = "Si"
 region-locked-axis.quantification.rows[1].groupID = "Si_Ka"
-region-locked-axis.quantification.rows[1].net = 40442faf842b8444 40.372543832062121
-region-locked-axis.quantification.rows[1].sigma = 401d47d3db9d1137 7.3201441111198653
+region-locked-axis.quantification.rows[1].net = 40443ec982d856a8 40.490524631151231
+region-locked-axis.quantification.rows[1].sigma = 401d9051da1c0180 7.3909372405618114
 region-locked-axis.quantification.rows[1].supported = true
 region-locked-axis.quantification.rows[1].atBound = false
 region-locked-axis.quantification.rows[1].isReference = false
-region-locked-axis.quantification.rows[1].kFreeRatio = 3fdc0507cdd5d5e8 0.43780703641036078
-region-locked-axis.quantification.rows[1].kFreeSigma = 3fb899a7de80b3ee 0.096094600507697442
+region-locked-axis.quantification.rows[1].kFreeRatio = 3fdc4691e43fc7dd 0.44180724420504963
+region-locked-axis.quantification.rows[1].kFreeSigma = 3fb8a31261030f1d 0.096238278088148069
 region-locked-axis.quantification.rows[1].atomicPercent = nil
 region-locked-axis.quantification.rows[1].atomicSigma = nil
 region-locked-axis.quantification.rows[1].weightPercent = nil
@@ -801,12 +801,12 @@ region-locked-axis.quantification.fit.groupIDs[0] = "Al_Ka"
 region-locked-axis.quantification.fit.groupIDs[1] = "Cu_Ka"
 region-locked-axis.quantification.fit.groupIDs[2] = "Cu_La"
 region-locked-axis.quantification.fit.groupIDs[3] = "Si_Ka"
-region-locked-axis.quantification.fit.values: n 4 sum 406092d04d516266 132.58792749305138 fnv d15e6f1ea5b849c0
-region-locked-axis.quantification.fit.values[0] = 40570dc8d88d02ab 92.215383660989275
+region-locked-axis.quantification.fit.values: n 4 sum 4060846a9bee809d 132.13801380712985 fnv 3304d86e66343b4c
+region-locked-axis.quantification.fit.values[0] = 4056e9707670d5e6 91.64748917597862
 region-locked-axis.quantification.fit.values[1] = 0000000000000000 0
 region-locked-axis.quantification.fit.values[2] = 0000000000000000 0
-region-locked-axis.quantification.fit.values[3] = 40442faf842b8444 40.372543832062121
-region-locked-axis.quantification.fit.covariance: n 16 sum 4068b2ce333998be 197.58767091035219 fnv d1f2e9d2567e2582
+region-locked-axis.quantification.fit.values[3] = 40443ec982d856a8 40.490524631151231
+region-locked-axis.quantification.fit.covariance: n 16 sum 40690a0be1c0deee 200.31395042104799 fnv 9f3d8b9032910024
 region-locked-axis.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 region-locked-axis.quantification.fit.supported: n 4 sum-bits 4 fnv fdcdb80e5fd8d165
 region-locked-axis.quantification.fit.atBound: n 4 sum-bits 2 fnv 34d87d04a3362385
@@ -832,25 +832,25 @@ region-locked-axis.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 region-locked-axis.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 region-locked-axis.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 region-locked-axis.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-region-locked-axis.quantification.fit.backgroundCoefficients: n 16 sum 406bee3b156cfb03 223.44471236500985 fnv 704945ec66b7a812
+region-locked-axis.quantification.fit.backgroundCoefficients: n 16 sum 406c73c242b533e2 227.61746344939371 fnv 8c7cf2791ebbb537
 region-locked-axis.quantification.fit.channels = 34..<512
-region-locked-axis.quantification.fit.model: n 478 sum 406a4a85645ae634 210.32878320459133 fnv f09d879f2f42d599
-region-locked-axis.quantification.fit.residual: n 478 sum c01950ac8b5cc53b -6.3287832045910433 fnv 9000421ab6c0697e
-region-locked-axis.quantification.fit.standardizedResidual: n 478 sum c0166907646f65ad -5.6025672619811475 fnv 55f6899ff6bf69d
+region-locked-axis.quantification.fit.model: n 478 sum 406a43ff6653d1c4 210.12492672320343 fnv 8262fdbe59f47a1c
+region-locked-axis.quantification.fit.residual: n 478 sum c0187fecca7a3771 -6.1249267232031892 fnv df77d713a28385c4
+region-locked-axis.quantification.fit.standardizedResidual: n 478 sum c014a65c0d8483d6 -5.1624605285769203 fnv 7eae3685e155d40f
 region-locked-axis.quantification.fit.negativeModelChannels = 0
 region-locked-axis.quantification.fit.degreesOfFreedom = 457
-region-locked-axis.quantification.fit.reducedChiSquared = 3fe361ccc74d7f69 0.60568846632302809
-region-locked-axis.quantification.fit.pearsonReducedChiSquared = 3fd135c6af4322d9 0.26890723338560246
-region-locked-axis.quantification.fit.deviance = 4070af49a6f4e34c 266.95548148783996
-region-locked-axis.quantification.fit.reducedDeviance = 3fe2b1566ffc836a 0.58414766189899336
+region-locked-axis.quantification.fit.reducedChiSquared = 3fe356ea91bd7220 0.60435989823196579
+region-locked-axis.quantification.fit.pearsonReducedChiSquared = 3fd121e3f27ba544 0.26769350700358907
+region-locked-axis.quantification.fit.deviance = 4070b20ae606c9d7 267.12766077663167
+region-locked-axis.quantification.fit.reducedDeviance = 3fe2b46c8f6f3ce1 0.58452442183070386
 region-locked-axis.quantification.fit.methodLabel = "least squares, unweighted"
 region-locked-axis.quantification.fit.referenceShapesLabel = "reference shapes: none"
 region-locked-axis.quantification.fit.escapeLabel = "escape peaks: fitted for 1 line group above the Si K edge (1.839 keV)"
 region-locked-axis.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-region-locked-axis.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+region-locked-axis.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 region-locked-axis.quantification.fit.exit = "converged"
 region-locked-axis.quantification.fit.warnings: array 1
-region-locked-axis.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+region-locked-axis.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 region-locked-axis.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region-locked-axis.quantification.fit.escapeRatios: array 4
 region-locked-axis.quantification.fit.escapeRatios[0] = nil
@@ -869,17 +869,17 @@ region-locked-axis.quantification.usedAxis.scale = 3f94855da0000000 0.0200399998
 region-locked-axis.quantification.usedAxis.size = 512
 region-locked-axis.quantification.axisLocked = true
 region-locked-axis.quantification.refinement = nil
-region-locked-axis.quantification.plotModel: n 512 sum 406a4a85645ae634 210.32878320459133 fnv d355ee51c905d0d9
-region-locked-axis.quantification.plotBackground: n 512 sum 4052d9b4cab1a4c7 75.401659654121531 fnv 2032f8daf8755c17
+region-locked-axis.quantification.plotModel: n 512 sum 406a43ff6653d1c4 210.12492672320343 fnv 75ad8257fd926e5c
+region-locked-axis.quantification.plotBackground: n 512 sum 4052e9b94af9b83b 75.651934379450651 fnv 918f79970c64ae0c
 region-locked-axis.quantification.kSet = nil
 region-locked-axis.quantification.abundanceRefusal = "The computed-k data files are not available in this build."
 region-locked-axis.quantification.absorption.refused = "GMS files: the stage tilt and the four detector segments are not read yet (open item), so the absorption geometry is unknown"
 region-locked-axis.quantification.warnings: array 1
-region-locked-axis.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+region-locked-axis.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 region-locked-axis.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-region-locked-axis.quantification.quality = 3fd135c6af4322d9 0.26890723338560246
+region-locked-axis.quantification.quality = 3fd121e3f27ba544 0.26769350700358907
 region-locked-axis.quantification.footerLines: array 8
-region-locked-axis.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 1 line group above the Si K edge (1.839 keV)"
+region-locked-axis.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 1 line group above the Si K edge (1.839 keV)"
 region-locked-axis.quantification.footerLines[1] = "energy axis: the file's (locked)"
 region-locked-axis.quantification.footerLines[2] = "beam 200 kV · typed"
 region-locked-axis.quantification.footerLines[3] = "fit range 0.2–9.75148 keV (default; the axis end) · 24 px pooled (Whole map)"
@@ -901,7 +901,7 @@ region-locked-axis.quantification.fitSettings.background.continuum.edges[0] = 3f
 region-locked-axis.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 region-locked-axis.quantification.fitSettings.background.continuum.nonNegative = true
 region-locked-axis.quantification.fitSettings.background.continuum.efficiency = nil
-region-locked-axis.quantification.fitSettings.background.continuum.edgeStep = .sharp
+region-locked-axis.quantification.fitSettings.background.continuum.edgeStep = .broadened
 region-locked-axis.quantification.fitSettings.escapePeaks = true
 region-locked-axis.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region-locked-axis.quantification.fitSettings.method = .leastSquares
@@ -920,5 +920,5 @@ region-locked-axis.quantification.unlistedCheckPending = false
 region-locked-axis.quantification.abundanceCaveat = nil
 region-locked-axis.quantification.appliedSumEscape = nil
 region-locked-axis.quantification.continuumDeadLayerMicrons = nil
-region-locked-axis.csv-fnv = 90f4608d5329d926
+region-locked-axis.csv-fnv = de6c63e7fca3cf8f
 region-locked-axis.rangeSensitivity = nil
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.f64 b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.f64
index 6b9d667..071892a 100644
Binary files a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.f64 and b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.f64 differ
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.json b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.json
index 5bd68e3..3f5edef 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.json
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.arrays.json
@@ -1 +1 @@
-[{"count":2,"offset":0,"path":"region2(beta'' 300 counts\/px).proposal.candidates[0].conflicts[0].energiesKeV"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[10].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[11].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[12].conflicts"},{"count":2,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[13].conflicts[0].energiesKeV"},{"count":2,"offset":4,"path":"region2(beta'' 300 counts\/px).proposal.candidates[14].conflicts[0].energiesKeV"},{"count":2,"offset":6,"path":"region2(beta'' 300 counts\/px).proposal.candidates[1].conflicts[0].energiesKeV"},{"count":2,"offset":8,"path":"region2(beta'' 300 counts\/px).proposal.candidates[2].conflicts[0].energiesKeV"},{"count":0,"offset":10,"path":"region2(beta'' 300 counts\/px).proposal.candidates[3].conflicts"},{"count":2,"offset":10,"path":"region2(beta'' 300 counts\/px).proposal.candidates[4].conflicts[0].energiesKeV"},{"count":0,"offset":12,"path":"region2(beta'' 300 counts\/px).proposal.candidates[5].conflicts"},{"count":2,"offset":12,"path":"region2(beta'' 300 counts\/px).proposal.candidates[6].conflicts[0].energiesKeV"},{"count":0,"offset":14,"path":"region2(beta'' 300 counts\/px).proposal.candidates[7].conflicts"},{"count":0,"offset":14,"path":"region2(beta'' 300 counts\/px).proposal.candidates[8].conflicts"},{"count":0,"offset":14,"path":"region2(beta'' 300 counts\/px).proposal.candidates[9].conflicts"},{"count":16,"offset":14,"path":"region2.fit.backgroundCoefficients"},{"count":16,"offset":30,"path":"region2.fit.covariance"},{"count":0,"offset":46,"path":"region2.fit.devianceHistory"},{"count":0,"offset":46,"path":"region2.fit.droppedLines"},{"count":3960,"offset":46,"path":"region2.fit.model"},{"count":3960,"offset":4006,"path":"region2.fit.residual"},{"count":3960,"offset":7966,"path":"region2.fit.standardizedResidual"},{"count":4,"offset":11926,"path":"region2.fit.values"}]
\ No newline at end of file
+[{"count":2,"offset":0,"path":"region2(beta'' 300 counts\/px).proposal.candidates[0].conflicts[0].energiesKeV"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[10].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[11].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[12].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[13].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[14].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[15].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[16].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[17].conflicts"},{"count":0,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[18].conflicts"},{"count":2,"offset":2,"path":"region2(beta'' 300 counts\/px).proposal.candidates[19].conflicts[0].energiesKeV"},{"count":2,"offset":4,"path":"region2(beta'' 300 counts\/px).proposal.candidates[1].conflicts[0].energiesKeV"},{"count":2,"offset":6,"path":"region2(beta'' 300 counts\/px).proposal.candidates[20].conflicts[0].energiesKeV"},{"count":0,"offset":8,"path":"region2(beta'' 300 counts\/px).proposal.candidates[2].conflicts"},{"count":2,"offset":8,"path":"region2(beta'' 300 counts\/px).proposal.candidates[3].conflicts[0].energiesKeV"},{"count":0,"offset":10,"path":"region2(beta'' 300 counts\/px).proposal.candidates[4].conflicts"},{"count":2,"offset":10,"path":"region2(beta'' 300 counts\/px).proposal.candidates[5].conflicts[0].energiesKeV"},{"count":2,"offset":12,"path":"region2(beta'' 300 counts\/px).proposal.candidates[5].conflicts[1].energiesKeV"},{"count":0,"offset":14,"path":"region2(beta'' 300 counts\/px).proposal.candidates[6].conflicts"},{"count":2,"offset":14,"path":"region2(beta'' 300 counts\/px).proposal.candidates[7].conflicts[0].energiesKeV"},{"count":0,"offset":16,"path":"region2(beta'' 300 counts\/px).proposal.candidates[8].conflicts"},{"count":1,"offset":16,"path":"region2(beta'' 300 counts\/px).proposal.candidates[9].conflicts[0].energiesKeV"},{"count":0,"offset":17,"path":"region2(beta'' 300 counts\/px).proposal.candidates[9].conflicts[0].requires"},{"count":16,"offset":17,"path":"region2.fit.backgroundCoefficients"},{"count":16,"offset":33,"path":"region2.fit.covariance"},{"count":0,"offset":49,"path":"region2.fit.devianceHistory"},{"count":0,"offset":49,"path":"region2.fit.droppedLines"},{"count":3960,"offset":49,"path":"region2.fit.model"},{"count":3960,"offset":4009,"path":"region2.fit.residual"},{"count":3960,"offset":7969,"path":"region2.fit.standardizedResidual"},{"count":4,"offset":11929,"path":"region2.fit.values"}]
\ No newline at end of file
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.txt b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.txt
index 5f852d3..9ee24ca 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.txt
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-proposer-sim.txt
@@ -1,189 +1,201 @@
 # SpectroGolden eds-proposer-sim
-region2(beta'' 300 counts/px).proposal.candidates: array 15
-region2(beta'' 300 counts/px).proposal.candidates[0].element = "Ag"
-region2(beta'' 300 counts/px).proposal.candidates[0].group = "Ag_La"
-region2(beta'' 300 counts/px).proposal.candidates[0].energyKeV = 4007e00d1b71758e 2.9843999999999999
-region2(beta'' 300 counts/px).proposal.candidates[0].net = 40b95d0594b641c7 6493.0218004141416
-region2(beta'' 300 counts/px).proposal.candidates[0].sigma = 405fb788b806f28c 126.86771965673887
-region2(beta'' 300 counts/px).proposal.candidates[0].sigmaZero = 404bf361c553cb67 55.90142122832804
-region2(beta'' 300 counts/px).proposal.candidates[0].criticalLevel = 4056fcc727b0e323 91.949655459157427
-region2(beta'' 300 counts/px).proposal.candidates[0].detectionLimit = 4067535af78e8b08 186.60485437241027
+region2(beta'' 300 counts/px).proposal.candidates: array 21
+region2(beta'' 300 counts/px).proposal.candidates[0].element = "Rh"
+region2(beta'' 300 counts/px).proposal.candidates[0].group = "Rh_La"
+region2(beta'' 300 counts/px).proposal.candidates[0].energyKeV = 4005930be0ded289 2.6968000000000001
+region2(beta'' 300 counts/px).proposal.candidates[0].net = 409ab8f450e08b1e 1710.238589771739
+region2(beta'' 300 counts/px).proposal.candidates[0].sigma = 404678920d880bda 44.941957179478507
+region2(beta'' 300 counts/px).proposal.candidates[0].sigmaZero = 4036614112b28342 22.379899185735901
+region2(beta'' 300 counts/px).proposal.candidates[0].criticalLevel = 404267e46bb2cc68 36.811658346466004
+region2(beta'' 300 counts/px).proposal.candidates[0].detectionLimit = 4053150c0b6e1c32 76.328860147027427
 region2(beta'' 300 counts/px).proposal.candidates[0].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].id = "sum-Al+Al sum-Ag"
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].id = "sum-Al+Mg sum-Rh"
 region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].element = "Ag"
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].line = "Ag_La"
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV: n 2 sum 4017d460aa64c2f8 5.9573999999999998 fnv 3854f55e8c8b86cc
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV[0] = 4007c8b439581062 2.9729999999999999
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV[1] = 4007e00d1b71758e 2.9843999999999999
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].requires: array 1
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].element = "Rh"
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].line = "Rh_La"
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV: n 2 sum 4015bf62b6ae7d56 5.4368999999999996 fnv e9a9ba2b1991a100
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV[0] = 4005ebb98c7e2824 2.7401
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].energiesKeV[1] = 4005930be0ded289 2.6968000000000001
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].requires: array 2
 region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].requires[0] = "Al"
-region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].question = "Al+Al sum peak (2.973 keV) or Ag Lα (2.984 keV)? They are 11 eV apart, far inside the detector resolution."
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].requires[1] = "Mg"
+region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].question = "Al+Mg sum peak (2.740 keV) or Rh Lα (2.697 keV)?"
 region2(beta'' 300 counts/px).proposal.candidates[0].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 region2(beta'' 300 counts/px).proposal.candidates[0].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[0].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[0].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[0].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[0].possibleReason = "The peak at 3.227 keV went to Al+Si sum, which explains it better (gain there 203739 against 177970)."
+region2(beta'' 300 counts/px).proposal.candidates[0].possibleReason = "The peak at 2.737 keV went to Al+Mg sum, which explains it better (gain there 33387 against 29635)."
 region2(beta'' 300 counts/px).proposal.candidates[0].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[1].element = "Rh"
-region2(beta'' 300 counts/px).proposal.candidates[1].group = "Rh_La"
-region2(beta'' 300 counts/px).proposal.candidates[1].energyKeV = 4005930be0ded289 2.6968000000000001
-region2(beta'' 300 counts/px).proposal.candidates[1].net = 409a826592fa75e6 1696.5991934904537
-region2(beta'' 300 counts/px).proposal.candidates[1].sigma = 40465ae6e577a91a 44.710171397617344
-region2(beta'' 300 counts/px).proposal.candidates[1].sigmaZero = 403642a83a87d660 22.260379465259007
-region2(beta'' 300 counts/px).proposal.candidates[1].criticalLevel = 40424eba7abc4c1f 36.615065900747361
-region2(beta'' 300 counts/px).proposal.candidates[1].detectionLimit = 4052fbe21a779be9 75.935675255590141
+region2(beta'' 300 counts/px).proposal.candidates[1].element = "Ar"
+region2(beta'' 300 counts/px).proposal.candidates[1].group = "Ar_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[1].energyKeV = 4007a95e9e1b089a 2.9577
+region2(beta'' 300 counts/px).proposal.candidates[1].net = 40b6f2e3bd26736b 5874.8896049529822
+region2(beta'' 300 counts/px).proposal.candidates[1].sigma = 407005c75d6985a8 256.36117306918686
+region2(beta'' 300 counts/px).proposal.candidates[1].sigmaZero = 406305b0456ceb27 152.17776747964055
+region2(beta'' 300 counts/px).proposal.candidates[1].criticalLevel = 406f49ecc5860000 250.31015278026462
+region2(beta'' 300 counts/px).proposal.candidates[1].detectionLimit = 407f7536ad74d3f2 503.32584901462462
 region2(beta'' 300 counts/px).proposal.candidates[1].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].id = "sum-Al+Mg sum-Rh"
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].id = "sum-Al+Al sum-Ar"
 region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].element = "Rh"
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].line = "Rh_La"
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV: n 2 sum 4015bf62b6ae7d56 5.4368999999999996 fnv e9a9ba2b1991a100
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV[0] = 4005ebb98c7e2824 2.7401
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV[1] = 4005930be0ded289 2.6968000000000001
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].requires: array 2
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].element = "Ar"
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].line = "Ar_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV: n 2 sum 4017b9096bb98c7e 5.9306999999999999 fnv ccfdcc7427df7932
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV[0] = 4007c8b439581062 2.9729999999999999
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].energiesKeV[1] = 4007a95e9e1b089a 2.9577
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].requires: array 1
 region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].requires[0] = "Al"
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].requires[1] = "Mg"
-region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].question = "Al+Mg sum peak (2.740 keV) or Rh Lα (2.697 keV)?"
+region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].question = "Al+Al sum peak (2.973 keV) or Ar Kα (2.958 keV)? They are 15 eV apart, far inside the detector resolution."
 region2(beta'' 300 counts/px).proposal.candidates[1].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 region2(beta'' 300 counts/px).proposal.candidates[1].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[1].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[1].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[1].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[1].possibleReason = "The peak at 2.742 keV went to Al+Mg sum, which explains it better (gain there 31777 against 28049)."
+region2(beta'' 300 counts/px).proposal.candidates[1].possibleReason = "The peak at 3.227 keV went to Al+Si sum, which explains it better (gain there 212982 against 140417)."
 region2(beta'' 300 counts/px).proposal.candidates[1].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[2].element = "Ar"
-region2(beta'' 300 counts/px).proposal.candidates[2].group = "Ar_Ka"
-region2(beta'' 300 counts/px).proposal.candidates[2].energyKeV = 4007a95e9e1b089a 2.9577
-region2(beta'' 300 counts/px).proposal.candidates[2].net = 40b828f9a79b3446 6184.9752137186642
-region2(beta'' 300 counts/px).proposal.candidates[2].sigma = 406ffaa4205c8ce7 255.83253496242762
-region2(beta'' 300 counts/px).proposal.candidates[2].sigmaZero = 40621745937b9e11 144.72724317688019
-region2(beta'' 300 counts/px).proposal.candidates[2].criticalLevel = 406dc1c3a1ca1c28 238.05513085817915
-region2(beta'' 300 counts/px).proposal.candidates[2].detectionLimit = 407ded0d89b8f01a 478.8158051704537
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].id = "sum-Al+Al sum-Ar"
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].element = "Ar"
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].line = "Ar_Ka"
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].energiesKeV: n 2 sum 4017b9096bb98c7e 5.9306999999999999 fnv ccfdcc7427df7932
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].energiesKeV[0] = 4007c8b439581062 2.9729999999999999
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].energiesKeV[1] = 4007a95e9e1b089a 2.9577
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].requires: array 1
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].requires[0] = "Al"
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].question = "Al+Al sum peak (2.973 keV) or Ar Kα (2.958 keV)? They are 15 eV apart, far inside the detector resolution."
-region2(beta'' 300 counts/px).proposal.candidates[2].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[2].element = "In"
+region2(beta'' 300 counts/px).proposal.candidates[2].group = "In_La"
+region2(beta'' 300 counts/px).proposal.candidates[2].energyKeV = 400a4bc6a7ef9db2 3.2869999999999999
+region2(beta'' 300 counts/px).proposal.candidates[2].net = 4092e7384f3f6edc 1209.80498980631
+region2(beta'' 300 counts/px).proposal.candidates[2].sigma = 404b2287cf3b84dd 54.269769577085505
+region2(beta'' 300 counts/px).proposal.candidates[2].sigmaZero = 404502f2af005080 42.02303111567835
+region2(beta'' 300 counts/px).proposal.candidates[2].criticalLevel = 405147ca8235d679 69.121735146118127
+region2(beta'' 300 counts/px).proposal.candidates[2].detectionLimit = 40619e5e52137e5e 140.94901374633167
+region2(beta'' 300 counts/px).proposal.candidates[2].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[2].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[2].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[2].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[2].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[2].possibleReason = "The peak at 3.227 keV went to Al+Si sum, which explains it better (gain there 203739 against 136297)."
+region2(beta'' 300 counts/px).proposal.candidates[2].possibleReason = "The peak at 3.477 keV went to Si+Si sum, which explains it better (gain there 24509 against 18445)."
 region2(beta'' 300 counts/px).proposal.candidates[2].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[3].element = "In"
-region2(beta'' 300 counts/px).proposal.candidates[3].group = "In_La"
-region2(beta'' 300 counts/px).proposal.candidates[3].energyKeV = 400a4bc6a7ef9db2 3.2869999999999999
-region2(beta'' 300 counts/px).proposal.candidates[3].net = 40921868f64f413a 1158.1025020965158
-region2(beta'' 300 counts/px).proposal.candidates[3].sigma = 404adbb6121e69e8 53.716493859148443
-region2(beta'' 300 counts/px).proposal.candidates[3].sigmaZero = 4044ed97e8936500 41.856198379487978
-region2(beta'' 300 counts/px).proposal.candidates[3].criticalLevel = 4051363a7c78306a 68.847319714901147
-region2(beta'' 300 counts/px).proposal.candidates[3].detectionLimit = 40618cce4c55d84f 140.40018288389771
-region2(beta'' 300 counts/px).proposal.candidates[3].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[3].element = "Sn"
+region2(beta'' 300 counts/px).proposal.candidates[3].group = "Sn_La"
+region2(beta'' 300 counts/px).proposal.candidates[3].energyKeV = 400b8d4fdf3b645a 3.444
+region2(beta'' 300 counts/px).proposal.candidates[3].net = 407ee631323cc042 494.38701080065596
+region2(beta'' 300 counts/px).proposal.candidates[3].sigma = 403fa466ad749cca 31.642191735238875
+region2(beta'' 300 counts/px).proposal.candidates[3].sigmaZero = 4035fd3a84b71a46 21.989174170210639
+region2(beta'' 300 counts/px).proposal.candidates[3].criticalLevel = 404215a0e750f1cb 36.168972887538608
+region2(beta'' 300 counts/px).proposal.candidates[3].detectionLimit = 4052c2c8870c4195 75.043489229172636
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts: array 1
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].id = "sum-Si+Si sum-Sn"
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].element = "Sn"
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].line = "Sn_La"
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].energiesKeV: n 2 sum 401bb18fc504816f 6.9234 fnv 6b6c3c40b17fbb08
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].energiesKeV[0] = 400bd5cfaacd9e84 3.4794
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].energiesKeV[1] = 400b8d4fdf3b645a 3.444
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].requires: array 1
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].requires[0] = "Si"
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].question = "Si+Si sum peak (3.479 keV) or Sn Lα (3.444 keV)?"
+region2(beta'' 300 counts/px).proposal.candidates[3].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 region2(beta'' 300 counts/px).proposal.candidates[3].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[3].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[3].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[3].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[3].possibleReason = "The peak at 3.487 keV went to Si+Si sum, which explains it better (gain there 23464 against 17540)."
+region2(beta'' 300 counts/px).proposal.candidates[3].possibleReason = "The peak at 3.477 keV went to Si+Si sum, which explains it better (gain there 24509 against 16177)."
 region2(beta'' 300 counts/px).proposal.candidates[3].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[4].element = "Sn"
-region2(beta'' 300 counts/px).proposal.candidates[4].group = "Sn_La"
-region2(beta'' 300 counts/px).proposal.candidates[4].energyKeV = 400b8d4fdf3b645a 3.444
-region2(beta'' 300 counts/px).proposal.candidates[4].net = 407e9d2fa853f0d0 489.82413513936353
-region2(beta'' 300 counts/px).proposal.candidates[4].sigma = 403f2391bd6f8c4d 31.138942565663729
-region2(beta'' 300 counts/px).proposal.candidates[4].sigmaZero = 4035c095be1c105a 21.75228489098695
-region2(beta'' 300 counts/px).proposal.candidates[4].criticalLevel = 4041e3c0e9643208 35.7793246974216
-region2(beta'' 300 counts/px).proposal.candidates[4].detectionLimit = 405290e8891f81d2 74.26419284893862
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].id = "sum-Si+Si sum-Sn"
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].element = "Sn"
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].line = "Sn_La"
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].energiesKeV: n 2 sum 401bb18fc504816f 6.9234 fnv 6b6c3c40b17fbb08
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].energiesKeV[0] = 400bd5cfaacd9e84 3.4794
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].energiesKeV[1] = 400b8d4fdf3b645a 3.444
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].requires: array 1
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].requires[0] = "Si"
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].question = "Si+Si sum peak (3.479 keV) or Sn Lα (3.444 keV)?"
-region2(beta'' 300 counts/px).proposal.candidates[4].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[4].element = "Pd"
+region2(beta'' 300 counts/px).proposal.candidates[4].group = "Pd_La"
+region2(beta'' 300 counts/px).proposal.candidates[4].energyKeV = 4006b573eab367a1 2.8386
+region2(beta'' 300 counts/px).proposal.candidates[4].net = 407c8954736f225d 456.58311789905366
+region2(beta'' 300 counts/px).proposal.candidates[4].sigma = 4041aa9c00dfe57b 35.33288584644739
+region2(beta'' 300 counts/px).proposal.candidates[4].sigmaZero = 403892524dd282f6 24.571568359274316
+region2(beta'' 300 counts/px).proposal.candidates[4].criticalLevel = 404435543dbb7ec3 40.416633335638402
+region2(beta'' 300 counts/px).proposal.candidates[4].detectionLimit = 4054e27bdd76ce8d 83.538810125372223
+region2(beta'' 300 counts/px).proposal.candidates[4].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[4].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[4].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[4].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[4].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[4].possibleReason = "The peak at 3.487 keV went to Si+Si sum, which explains it better (gain there 23464 against 14997)."
+region2(beta'' 300 counts/px).proposal.candidates[4].possibleReason = "The peak at 2.737 keV went to Al+Mg sum, which explains it better (gain there 33387 against 5175)."
 region2(beta'' 300 counts/px).proposal.candidates[4].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[5].element = "Pd"
-region2(beta'' 300 counts/px).proposal.candidates[5].group = "Pd_La"
-region2(beta'' 300 counts/px).proposal.candidates[5].energyKeV = 4006b573eab367a1 2.8386
-region2(beta'' 300 counts/px).proposal.candidates[5].net = 407a4b33a583cf6f 420.70010901916879
-region2(beta'' 300 counts/px).proposal.candidates[5].sigma = 404150ab2315a23d 34.630222688258506
-region2(beta'' 300 counts/px).proposal.candidates[5].sigmaZero = 4038877d2766f815 24.529253447188314
-region2(beta'' 300 counts/px).proposal.candidates[5].criticalLevel = 40442c6b87357c4c 40.347031499019607
-region2(beta'' 300 counts/px).proposal.candidates[5].detectionLimit = 4054d99326f0cc16 83.399606452134634
-region2(beta'' 300 counts/px).proposal.candidates[5].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[5].element = "Ag"
+region2(beta'' 300 counts/px).proposal.candidates[5].group = "Ag_La"
+region2(beta'' 300 counts/px).proposal.candidates[5].energyKeV = 4007e00d1b71758e 2.9843999999999999
+region2(beta'' 300 counts/px).proposal.candidates[5].net = 40956f10285751cd 1371.7657788890531
+region2(beta'' 300 counts/px).proposal.candidates[5].sigma = 405eb647f08ce4b5 122.84814084776993
+region2(beta'' 300 counts/px).proposal.candidates[5].sigmaZero = 405a9c1f7599c77f 106.43942012803562
+region2(beta'' 300 counts/px).proposal.candidates[5].criticalLevel = 4065e278f71124d3 175.07726624821098
+region2(beta'' 300 counts/px).proposal.candidates[5].detectionLimit = 40760dc2defff8c5 352.86007595051734
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts: array 2
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].id = "sum-Al+Al sum-Ag"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].element = "Ag"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].line = "Ag_La"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].energiesKeV: n 2 sum 4017d460aa64c2f8 5.9573999999999998 fnv 3854f55e8c8b86cc
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].energiesKeV[0] = 4007c8b439581062 2.9729999999999999
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].energiesKeV[1] = 4007e00d1b71758e 2.9843999999999999
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].requires: array 1
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].requires[0] = "Al"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].question = "Al+Al sum peak (2.973 keV) or Ag Lα (2.984 keV)? They are 11 eV apart, far inside the detector resolution."
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].id = "sum-Mg+Si sum-Ag"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].element = "Ag"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].line = "Ag_La"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].energiesKeV: n 2 sum 4017e92a30553262 5.9777000000000005 fnv 9a1a81efa69d3d7b
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].energiesKeV[0] = 4007f2474538ef35 2.9933000000000001
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].energiesKeV[1] = 4007e00d1b71758e 2.9843999999999999
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].requires: array 2
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].requires[0] = "Mg"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].requires[1] = "Si"
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].question = "Mg+Si sum peak (2.993 keV) or Ag Lα (2.984 keV)? They are 9 eV apart, far inside the detector resolution."
+region2(beta'' 300 counts/px).proposal.candidates[5].conflicts[1].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 region2(beta'' 300 counts/px).proposal.candidates[5].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[5].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[5].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[5].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[5].possibleReason = "The peak at 2.742 keV went to Al+Mg sum, which explains it better (gain there 31777 against 4730)."
+region2(beta'' 300 counts/px).proposal.candidates[5].possibleReason = "The peak at 3.477 keV went to Si+Si sum, which explains it better (gain there 24509 against 4106)."
 region2(beta'' 300 counts/px).proposal.candidates[5].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[6].element = "Ru"
-region2(beta'' 300 counts/px).proposal.candidates[6].group = "Ru_La"
-region2(beta'' 300 counts/px).proposal.candidates[6].energyKeV = 400477ced916872b 2.5585
-region2(beta'' 300 counts/px).proposal.candidates[6].net = 406d27dce1c85d1e 233.24571313031714
-region2(beta'' 300 counts/px).proposal.candidates[6].sigma = 40388cb7fb052127 24.549682320358581
-region2(beta'' 300 counts/px).proposal.candidates[6].sigmaZero = 40327c16515f4258 18.484715543514852
-region2(beta'' 300 counts/px).proposal.candidates[6].criticalLevel = 403e67973c0665c5 30.404651404916667
-region2(beta'' 300 counts/px).proposal.candidates[6].detectionLimit = 404fc1e67b7d0558 63.514846263928746
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].id = "sum-Mg+Mg sum-Ru"
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].element = "Ru"
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].line = "Ru_La"
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].energiesKeV: n 2 sum 40144346dc5d6388 5.0656999999999996 fnv 303007786e8a1d73
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].energiesKeV[0] = 40040ebedfa43fe6 2.5072000000000001
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].energiesKeV[1] = 400477ced916872b 2.5585
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].requires: array 1
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].requires[0] = "Mg"
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].question = "Mg+Mg sum peak (2.507 keV) or Ru Lα (2.558 keV)?"
-region2(beta'' 300 counts/px).proposal.candidates[6].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[6].element = "Cd"
+region2(beta'' 300 counts/px).proposal.candidates[6].group = "Cd_La"
+region2(beta'' 300 counts/px).proposal.candidates[6].energyKeV = 40091205bc01a36e 3.1337999999999999
+region2(beta'' 300 counts/px).proposal.candidates[6].net = 4079683bfed244c6 406.51464731346312
+region2(beta'' 300 counts/px).proposal.candidates[6].sigma = 4044421765a13745 40.516339019507122
+region2(beta'' 300 counts/px).proposal.candidates[6].sigmaZero = 404130be7d516873 34.3808132789135
+region2(beta'' 300 counts/px).proposal.candidates[6].criticalLevel = 404c469473e97fbc 56.551405419362226
+region2(beta'' 300 counts/px).proposal.candidates[6].detectionLimit = 405cf3bc13a4cf86 115.80835429281987
+region2(beta'' 300 counts/px).proposal.candidates[6].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[6].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[6].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[6].misfit = 3ff0000000000000 1
-region2(beta'' 300 counts/px).proposal.candidates[6].familyNote = "Ru Kα (19.28 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.56 keV) needs: not Ru."
-region2(beta'' 300 counts/px).proposal.candidates[6].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[6].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[6].possibleReason = "The peak at 3.477 keV went to Si+Si sum, which explains it better (gain there 24509 against 4481)."
 region2(beta'' 300 counts/px).proposal.candidates[6].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[7].element = "Cd"
-region2(beta'' 300 counts/px).proposal.candidates[7].group = "Cd_La"
-region2(beta'' 300 counts/px).proposal.candidates[7].energyKeV = 40091205bc01a36e 3.1337999999999999
-region2(beta'' 300 counts/px).proposal.candidates[7].net = 407973766c20b3b2 407.21641171240037
-region2(beta'' 300 counts/px).proposal.candidates[7].sigma = 40442786372b1d10 40.308783432055975
-region2(beta'' 300 counts/px).proposal.candidates[7].sigmaZero = 40411836750caecc 34.189161902611517
-region2(beta'' 300 counts/px).proposal.candidates[7].criticalLevel = 404c1e3ab80860ac 56.236166957941663
-region2(beta'' 300 counts/px).proposal.candidates[7].detectionLimit = 405ccb6257c3b076 115.17787736997875
-region2(beta'' 300 counts/px).proposal.candidates[7].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[7].element = "Ru"
+region2(beta'' 300 counts/px).proposal.candidates[7].group = "Ru_La"
+region2(beta'' 300 counts/px).proposal.candidates[7].energyKeV = 400477ced916872b 2.5585
+region2(beta'' 300 counts/px).proposal.candidates[7].net = 406a844eaac760c8 212.13460291806246
+region2(beta'' 300 counts/px).proposal.candidates[7].sigma = 4038153b3338011e 24.082934571431103
+region2(beta'' 300 counts/px).proposal.candidates[7].sigmaZero = 40327479abb5e378 18.454981548220047
+region2(beta'' 300 counts/px).proposal.candidates[7].criticalLevel = 403e5b11fec537d4 30.355743334912248
+region2(beta'' 300 counts/px).proposal.candidates[7].detectionLimit = 404fb5613e3bd767 63.417030123919908
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts: array 1
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].id = "sum-Mg+Mg sum-Ru"
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].element = "Ru"
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].line = "Ru_La"
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].energiesKeV: n 2 sum 40144346dc5d6388 5.0656999999999996 fnv 303007786e8a1d73
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].energiesKeV[0] = 40040ebedfa43fe6 2.5072000000000001
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].energiesKeV[1] = 400477ced916872b 2.5585
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].requires: array 1
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].requires[0] = "Mg"
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].question = "Mg+Mg sum peak (2.507 keV) or Ru Lα (2.558 keV)?"
+region2(beta'' 300 counts/px).proposal.candidates[7].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 region2(beta'' 300 counts/px).proposal.candidates[7].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[7].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[7].misfit = 3ff0000000000000 1
-region2(beta'' 300 counts/px).proposal.candidates[7].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[7].possibleReason = "The peak at 3.487 keV went to Si+Si sum, which explains it better (gain there 23464 against 4284)."
+region2(beta'' 300 counts/px).proposal.candidates[7].familyNote = "Ru Kα (19.28 keV) has a residual peak of 1.7 σ, below the 3 σ its Lα (2.56 keV) needs: not Ru."
+region2(beta'' 300 counts/px).proposal.candidates[7].possibleReason = nil
 region2(beta'' 300 counts/px).proposal.candidates[7].unconfirmable = false
 region2(beta'' 300 counts/px).proposal.candidates[8].element = "Bi"
 region2(beta'' 300 counts/px).proposal.candidates[8].group = "Bi_Ma"
 region2(beta'' 300 counts/px).proposal.candidates[8].energyKeV = 400360aa64c2f838 2.4222000000000001
-region2(beta'' 300 counts/px).proposal.candidates[8].net = 4065a1b91bf032fa 173.05384632982151
-region2(beta'' 300 counts/px).proposal.candidates[8].sigma = 40339d9442b0f871 19.615543525891955
-region2(beta'' 300 counts/px).proposal.candidates[8].sigmaZero = 402f6fd9252c3d21 15.718453561449282
-region2(beta'' 300 counts/px).proposal.candidates[8].criticalLevel = 4039dac423b386d8 25.854555350618142
-region2(beta'' 300 counts/px).proposal.candidates[8].detectionLimit = 404b3513632a266b 54.414654155331696
+region2(beta'' 300 counts/px).proposal.candidates[8].net = 40652186ddcddc05 169.04771318633007
+region2(beta'' 300 counts/px).proposal.candidates[8].sigma = 403396f7ddf27cb3 19.589719649983362
+region2(beta'' 300 counts/px).proposal.candidates[8].sigmaZero = 402f895e42f6411d 15.768297283706994
+region2(beta'' 300 counts/px).proposal.candidates[8].criticalLevel = 4039efc12647adaf 25.936540977954504
+region2(beta'' 300 counts/px).proposal.candidates[8].detectionLimit = 404b4a1065be4d42 54.57862541000442
 region2(beta'' 300 counts/px).proposal.candidates[8].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[8].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[8].holeRegionNote = nil
@@ -191,161 +203,260 @@ region2(beta'' 300 counts/px).proposal.candidates[8].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[8].familyNote = "Bi Lα (10.84 keV) has a residual peak of 2.4 σ, below the 3 σ its Mβ (2.53 keV) needs: not Bi."
 region2(beta'' 300 counts/px).proposal.candidates[8].possibleReason = nil
 region2(beta'' 300 counts/px).proposal.candidates[8].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[9].element = "Cl"
-region2(beta'' 300 counts/px).proposal.candidates[9].group = "Cl_Ka"
-region2(beta'' 300 counts/px).proposal.candidates[9].energyKeV = 4004faacd9e83e42 2.6223999999999998
-region2(beta'' 300 counts/px).proposal.candidates[9].net = 4066e40692f32621 183.12580249300029
-region2(beta'' 300 counts/px).proposal.candidates[9].sigma = 403a3148327781b8 26.192507890869564
-region2(beta'' 300 counts/px).proposal.candidates[9].sigmaZero = 4034ee10bbc55ba1 20.929942832644546
-region2(beta'' 300 counts/px).proposal.candidates[9].criticalLevel = 4041369ddb1d1ff7 34.426692380162358
-region2(beta'' 300 counts/px).proposal.candidates[9].detectionLimit = 4051e3c57ad86fc1 71.558928214420135
-region2(beta'' 300 counts/px).proposal.candidates[9].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
-region2(beta'' 300 counts/px).proposal.candidates[9].suggestedRole = .fitOnly
-region2(beta'' 300 counts/px).proposal.candidates[9].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[9].element = "Cu"
+region2(beta'' 300 counts/px).proposal.candidates[9].group = "Cu_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[9].energyKeV = 402018793dd97f63 8.0478000000000005
+region2(beta'' 300 counts/px).proposal.candidates[9].net = 405e9083f03b98c1 122.25805288143148
+region2(beta'' 300 counts/px).proposal.candidates[9].sigma = 4031ebe12d0a6699 17.921404662169696
+region2(beta'' 300 counts/px).proposal.candidates[9].sigmaZero = 402aee7166df2481 13.465708937396132
+region2(beta'' 300 counts/px).proposal.candidates[9].criticalLevel = 4036262cbd8e6350 22.149120185148888
+region2(beta'' 300 counts/px).proposal.candidates[9].detectionLimit = 4047807bfd0502e3 47.003783824393189
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts: array 1
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].id = "cu-grid"
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].kind = .gridOrSample
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].element = "Cu"
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].line = "Cu_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].energiesKeV: n 1 sum 402018793dd97f63 8.0478000000000005 fnv 531237518ebd7b74
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].energiesKeV[0] = 402018793dd97f63 8.0478000000000005
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].requires: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].question = "Cu from the grid or from the Q phase?"
+region2(beta'' 300 counts/px).proposal.candidates[9].conflicts[0].remedy = "Measure Cu on a hole region (no sample): net Cu there is grid and holder signal."
+region2(beta'' 300 counts/px).proposal.candidates[9].suggestedRole = .quantify
+region2(beta'' 300 counts/px).proposal.candidates[9].holeRegionNote = "No hole region available: Cu grid and Q phase cannot be separated."
 region2(beta'' 300 counts/px).proposal.candidates[9].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[9].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[9].possibleReason = "The peak at 2.742 keV went to Al+Mg sum, which explains it better (gain there 31777 against 1174)."
+region2(beta'' 300 counts/px).proposal.candidates[9].possibleReason = nil
 region2(beta'' 300 counts/px).proposal.candidates[9].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[10].element = "K"
-region2(beta'' 300 counts/px).proposal.candidates[10].group = "K_Ka"
-region2(beta'' 300 counts/px).proposal.candidates[10].energyKeV = 400a82a9930be0df 3.3138000000000001
-region2(beta'' 300 counts/px).proposal.candidates[10].net = 40608ef18885ea66 132.46698404460329
-region2(beta'' 300 counts/px).proposal.candidates[10].sigma = 40432917e45a4db7 38.321041626065771
-region2(beta'' 300 counts/px).proposal.candidates[10].sigmaZero = 4041d231163d8b38 35.642123012591071
-region2(beta'' 300 counts/px).proposal.candidates[10].criticalLevel = 404d50233c599763 58.626075309510973
-region2(beta'' 300 counts/px).proposal.candidates[10].detectionLimit = 405dfd4adc14e72d 119.95769407311737
+region2(beta'' 300 counts/px).proposal.candidates[10].element = "Cl"
+region2(beta'' 300 counts/px).proposal.candidates[10].group = "Cl_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[10].energyKeV = 4004faacd9e83e42 2.6223999999999998
+region2(beta'' 300 counts/px).proposal.candidates[10].net = 4062738fe2333381 147.6113139152549
+region2(beta'' 300 counts/px).proposal.candidates[10].sigma = 403948a6d33df144 25.283795549986522
+region2(beta'' 300 counts/px).proposal.candidates[10].sigmaZero = 4034e8fecc602e52 20.910137914163279
+region2(beta'' 300 counts/px).proposal.candidates[10].criticalLevel = 404132726635802b 34.394116188166969
+region2(beta'' 300 counts/px).proposal.candidates[10].detectionLimit = 4051df9a05f0cff5 71.493775830429357
 region2(beta'' 300 counts/px).proposal.candidates[10].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[10].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[10].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[10].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[10].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[10].possibleReason = "The peak at 3.487 keV went to Si+Si sum, which explains it better (gain there 23464 against 208)."
+region2(beta'' 300 counts/px).proposal.candidates[10].possibleReason = "The peak at 2.737 keV went to Al+Mg sum, which explains it better (gain there 33387 against 1009)."
 region2(beta'' 300 counts/px).proposal.candidates[10].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[11].element = "Pb"
-region2(beta'' 300 counts/px).proposal.candidates[11].group = "Pb_Ma"
-region2(beta'' 300 counts/px).proposal.candidates[11].energyKeV = 4002c467381d7dbf 2.3458999999999999
-region2(beta'' 300 counts/px).proposal.candidates[11].net = 4046d78f6eb0cfb2 45.684064709027908
-region2(beta'' 300 counts/px).proposal.candidates[11].sigma = 4030c9e82714a25a 16.788698618447917
-region2(beta'' 300 counts/px).proposal.candidates[11].sigmaZero = 402f71468a1f761b 15.72124129900026
-region2(beta'' 300 counts/px).proposal.candidates[11].criticalLevel = 4039dbf0a6496adc 25.859140770839858
-region2(beta'' 300 counts/px).proposal.candidates[11].detectionLimit = 404b363fe5c00a6f 54.423824995775128
+region2(beta'' 300 counts/px).proposal.candidates[11].element = "K"
+region2(beta'' 300 counts/px).proposal.candidates[11].group = "K_Ka"
+region2(beta'' 300 counts/px).proposal.candidates[11].energyKeV = 400a82a9930be0df 3.3138000000000001
+region2(beta'' 300 counts/px).proposal.candidates[11].net = 4068a4cc51cd436e 197.14994134989269
+region2(beta'' 300 counts/px).proposal.candidates[11].sigma = 4043d6e73eac1c49 39.678932031668019
+region2(beta'' 300 counts/px).proposal.candidates[11].sigmaZero = 4041ec46a3cab8d6 35.845905755982741
+region2(beta'' 300 counts/px).proposal.candidates[11].criticalLevel = 404d7b0ad5396666 58.961268094088879
+region2(beta'' 300 counts/px).proposal.candidates[11].detectionLimit = 405e283274f4b630 120.62807964227318
 region2(beta'' 300 counts/px).proposal.candidates[11].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[11].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[11].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[11].misfit = 3ff0000000000000 1
-region2(beta'' 300 counts/px).proposal.candidates[11].familyNote = "Pb Lα (10.55 keV) has a residual peak of 2.4 σ, below the 3 σ its Mβ (2.44 keV) needs: not Pb."
-region2(beta'' 300 counts/px).proposal.candidates[11].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[11].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[11].possibleReason = "The peak at 3.477 keV went to Si+Si sum, which explains it better (gain there 24509 against 337)."
 region2(beta'' 300 counts/px).proposal.candidates[11].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[12].element = "Sb"
-region2(beta'' 300 counts/px).proposal.candidates[12].group = "Sb_La"
-region2(beta'' 300 counts/px).proposal.candidates[12].energyKeV = 400cd66cf41f212d 3.6046999999999998
-region2(beta'' 300 counts/px).proposal.candidates[12].net = 4011a4de7b62d4ed 4.4110049513885601
-region2(beta'' 300 counts/px).proposal.candidates[12].sigma = 40318bde17c15daf 17.546357617100224
-region2(beta'' 300 counts/px).proposal.candidates[12].sigmaZero = 403170c12433e364 17.440447104137448
-region2(beta'' 300 counts/px).proposal.candidates[12].criticalLevel = 403cafde18b99894 28.686982674895788
-region2(beta'' 300 counts/px).proposal.candidates[12].detectionLimit = 404e0a2d58303827 60.079508803886988
+region2(beta'' 300 counts/px).proposal.candidates[12].element = "Ta"
+region2(beta'' 300 counts/px).proposal.candidates[12].group = "Ta_La"
+region2(beta'' 300 counts/px).proposal.candidates[12].energyKeV = 40204ac083126e98 8.1460000000000008
+region2(beta'' 300 counts/px).proposal.candidates[12].net = 4037314023edcb1e 23.192384954028164
+region2(beta'' 300 counts/px).proposal.candidates[12].sigma = 4028ff5630f777a9 12.498704462250162
+region2(beta'' 300 counts/px).proposal.candidates[12].sigmaZero = 4027a0568a192f52 11.813160243582079
+region2(beta'' 300 counts/px).proposal.candidates[12].criticalLevel = 40336e50bd113b4f 19.430919472414924
+region2(beta'' 300 counts/px).proposal.candidates[12].detectionLimit = 4044c89ffc87dae2 41.567382398925261
 region2(beta'' 300 counts/px).proposal.candidates[12].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[12].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[12].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[12].misfit = 3ff0000000000000 1
 region2(beta'' 300 counts/px).proposal.candidates[12].familyNote = nil
-region2(beta'' 300 counts/px).proposal.candidates[12].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+region2(beta'' 300 counts/px).proposal.candidates[12].possibleReason = "Adding it improves the fit by 13, below the 100 a new line needs."
 region2(beta'' 300 counts/px).proposal.candidates[12].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[13].element = "Mo"
-region2(beta'' 300 counts/px).proposal.candidates[13].group = "Mo_La"
-region2(beta'' 300 counts/px).proposal.candidates[13].energyKeV = 400258793dd97f63 2.2932000000000001
-region2(beta'' 300 counts/px).proposal.candidates[13].net = 4012c67f61df27d7 4.6938452999547371
-region2(beta'' 300 counts/px).proposal.candidates[13].sigma = 4032d4b6190460bf 18.830903590744807
-region2(beta'' 300 counts/px).proposal.candidates[13].sigmaZero = 4032b4b3000f5828 18.705856326814825
-region2(beta'' 300 counts/px).proposal.candidates[13].criticalLevel = 403ec4b5935d29f8 30.768395624394515
-region2(beta'' 300 counts/px).proposal.candidates[13].detectionLimit = 40500f826969e4c6 64.242334702884449
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].id = "sum-O+Si sum-Mo"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].element = "Mo"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].line = "Mo_La"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].energiesKeV: n 2 sum 40123b2fec56d5d0 4.5578000000000003 fnv 83e16c96c1ecba8e
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].energiesKeV[0] = 40021de69ad42c3d 2.2646000000000002
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].energiesKeV[1] = 400258793dd97f63 2.2932000000000001
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].requires: array 2
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].requires[0] = "O"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].requires[1] = "Si"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].question = "O+Si sum peak (2.265 keV) or Mo Lα (2.293 keV)?"
-region2(beta'' 300 counts/px).proposal.candidates[13].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[13].element = "Tm"
+region2(beta'' 300 counts/px).proposal.candidates[13].group = "Tm_La"
+region2(beta'' 300 counts/px).proposal.candidates[13].energyKeV = 401cb8a0902de00d 7.1802999999999999
+region2(beta'' 300 counts/px).proposal.candidates[13].net = 40378df16c2fdc6e 23.554465066609218
+region2(beta'' 300 counts/px).proposal.candidates[13].sigma = 4029d870fa98b74a 12.922736960546576
+region2(beta'' 300 counts/px).proposal.candidates[13].sigmaZero = 40284787b56c153e 12.139707250064586
+region2(beta'' 300 counts/px).proposal.candidates[13].criticalLevel = 4033f7d191596121 19.96804150039782
+region2(beta'' 300 counts/px).proposal.candidates[13].detectionLimit = 40455220d0d000b4 42.641626454891053
+region2(beta'' 300 counts/px).proposal.candidates[13].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[13].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[13].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[13].misfit = 3ff0000000000000 1
-region2(beta'' 300 counts/px).proposal.candidates[13].familyNote = "Mo Kα (17.48 keV) has a residual peak of 1.4 σ, below the 3 σ its Lβ1 (2.39 keV) needs: not Mo."
-region2(beta'' 300 counts/px).proposal.candidates[13].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[13].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[13].possibleReason = "Adding it improves the fit by 13, below the 100 a new line needs."
 region2(beta'' 300 counts/px).proposal.candidates[13].unconfirmable = false
-region2(beta'' 300 counts/px).proposal.candidates[14].element = "Tl"
-region2(beta'' 300 counts/px).proposal.candidates[14].group = "Tl_Ma"
-region2(beta'' 300 counts/px).proposal.candidates[14].energyKeV = 40022a9930be0ded 2.2707999999999999
-region2(beta'' 300 counts/px).proposal.candidates[14].net = 0000000000000000 0
-region2(beta'' 300 counts/px).proposal.candidates[14].sigma = 402fe562ccb2c5d2 15.948019406149715
-region2(beta'' 300 counts/px).proposal.candidates[14].sigmaZero = 402fe562ccb2c5d2 15.948019406149715
-region2(beta'' 300 counts/px).proposal.candidates[14].criticalLevel = 403a3b6ead942a4d 26.232157562897829
-region2(beta'' 300 counts/px).proposal.candidates[14].detectionLimit = 404b95bded0ac9e0 55.16985857989107
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts: array 1
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].id = "sum-O+Si sum-Tl"
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].kind = .sumPeak
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].element = "Tl"
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].line = "Tl_Ma"
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].energiesKeV: n 2 sum 4012243fe5c91d15 4.5354000000000001 fnv 53069bf7b2532f4
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].energiesKeV[0] = 40021de69ad42c3d 2.2646000000000002
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].energiesKeV[1] = 40022a9930be0ded 2.2707999999999999
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].requires: array 2
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].requires[0] = "O"
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].requires[1] = "Si"
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].question = "O+Si sum peak (2.265 keV) or Tl Mα (2.271 keV)? They are 6 eV apart, far inside the detector resolution."
-region2(beta'' 300 counts/px).proposal.candidates[14].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[14].element = "Hf"
+region2(beta'' 300 counts/px).proposal.candidates[14].group = "Hf_La"
+region2(beta'' 300 counts/px).proposal.candidates[14].energyKeV = 401f989374bc6a7f 7.899
+region2(beta'' 300 counts/px).proposal.candidates[14].net = 402a22cafec91c2c 13.06795498089749
+region2(beta'' 300 counts/px).proposal.candidates[14].sigma = 4028a9645694622a 12.330843644726958
+region2(beta'' 300 counts/px).proposal.candidates[14].sigmaZero = 4027d0b98f517f1c 11.907665709207826
+region2(beta'' 300 counts/px).proposal.candidates[14].criticalLevel = 4033961c28002847 19.586367130316173
+region2(beta'' 300 counts/px).proposal.candidates[14].detectionLimit = 4044f06b6776c7da 41.878277714727759
+region2(beta'' 300 counts/px).proposal.candidates[14].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2(beta'' 300 counts/px).proposal.candidates[14].suggestedRole = .fitOnly
 region2(beta'' 300 counts/px).proposal.candidates[14].holeRegionNote = nil
 region2(beta'' 300 counts/px).proposal.candidates[14].misfit = 3ff0000000000000 1
-region2(beta'' 300 counts/px).proposal.candidates[14].familyNote = "Tl Lα (10.27 keV) has a residual peak of 0.0 σ, below the 3 σ its Mγ (2.57 keV) needs: not Tl."
-region2(beta'' 300 counts/px).proposal.candidates[14].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[14].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[14].possibleReason = "Adding it improves the fit by 4, below the 100 a new line needs."
 region2(beta'' 300 counts/px).proposal.candidates[14].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[15].element = "Pb"
+region2(beta'' 300 counts/px).proposal.candidates[15].group = "Pb_Ma"
+region2(beta'' 300 counts/px).proposal.candidates[15].energyKeV = 4002c467381d7dbf 2.3458999999999999
+region2(beta'' 300 counts/px).proposal.candidates[15].net = 4028d98cd2f80e44 12.424902527599563
+region2(beta'' 300 counts/px).proposal.candidates[15].sigma = 40303bb2cd56734b 16.233197053533598
+region2(beta'' 300 counts/px).proposal.candidates[15].sigmaZero = 402fd9cd95470765 15.925396599693793
+region2(beta'' 300 counts/px).proposal.candidates[15].criticalLevel = 403a31e801269170 26.194946357646984
+region2(beta'' 300 counts/px).proposal.candidates[15].detectionLimit = 404b8c37409d3103 55.09543616938938
+region2(beta'' 300 counts/px).proposal.candidates[15].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[15].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[15].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[15].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[15].familyNote = "Pb Lα (10.55 keV) has a residual peak of 2.2 σ, below the 3 σ its Mβ (2.44 keV) needs: not Pb."
+region2(beta'' 300 counts/px).proposal.candidates[15].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[15].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[16].element = "Sb"
+region2(beta'' 300 counts/px).proposal.candidates[16].group = "Sb_La"
+region2(beta'' 300 counts/px).proposal.candidates[16].energyKeV = 400cd66cf41f212d 3.6046999999999998
+region2(beta'' 300 counts/px).proposal.candidates[16].net = 40298c28b8997e9c 12.773748177277689
+region2(beta'' 300 counts/px).proposal.candidates[16].sigma = 4031999bd39ba913 17.600033975127257
+region2(beta'' 300 counts/px).proposal.candidates[16].sigmaZero = 40314aee6cbdd014 17.292700573292748
+region2(beta'' 300 counts/px).proposal.candidates[16].criticalLevel = 403c71a771eacc33 28.443961257766386
+region2(beta'' 300 counts/px).proposal.candidates[16].detectionLimit = 404dcbf6b1616bc6 59.593465969628184
+region2(beta'' 300 counts/px).proposal.candidates[16].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[16].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[16].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[16].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[16].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[16].possibleReason = "Adding it improves the fit by 7, below the 100 a new line needs."
+region2(beta'' 300 counts/px).proposal.candidates[16].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[17].element = "Er"
+region2(beta'' 300 counts/px).proposal.candidates[17].group = "Er_La"
+region2(beta'' 300 counts/px).proposal.candidates[17].energyKeV = 401bcb5dcc63f141 6.9485999999999999
+region2(beta'' 300 counts/px).proposal.candidates[17].net = 0000000000000000 0
+region2(beta'' 300 counts/px).proposal.candidates[17].sigma = 4028564cb4c82351 12.168553971701529
+region2(beta'' 300 counts/px).proposal.candidates[17].sigmaZero = 4028540a709f2967 12.164142150334284
+region2(beta'' 300 counts/px).proposal.candidates[17].criticalLevel = 4034021b946f67b4 20.008233334730633
+region2(beta'' 300 counts/px).proposal.candidates[17].detectionLimit = 40455c6ad3e60747 42.722010123556679
+region2(beta'' 300 counts/px).proposal.candidates[17].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[17].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[17].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[17].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[17].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[17].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
+region2(beta'' 300 counts/px).proposal.candidates[17].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[18].element = "Ho"
+region2(beta'' 300 counts/px).proposal.candidates[18].group = "Ho_La"
+region2(beta'' 300 counts/px).proposal.candidates[18].energyKeV = 401ae0f9096bb98c 6.7196999999999996
+region2(beta'' 300 counts/px).proposal.candidates[18].net = 0000000000000000 0
+region2(beta'' 300 counts/px).proposal.candidates[18].sigma = 4028af4c95012c81 12.342381149667064
+region2(beta'' 300 counts/px).proposal.candidates[18].sigmaZero = 4028af4c95012c81 12.342381149667064
+region2(beta'' 300 counts/px).proposal.candidates[18].criticalLevel = 40344d293b5f7113 20.301410399247356
+region2(beta'' 300 counts/px).proposal.candidates[18].detectionLimit = 4045a7787ad610a6 43.308364252590124
+region2(beta'' 300 counts/px).proposal.candidates[18].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+region2(beta'' 300 counts/px).proposal.candidates[18].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[18].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[18].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[18].familyNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[18].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
+region2(beta'' 300 counts/px).proposal.candidates[18].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[19].element = "Mo"
+region2(beta'' 300 counts/px).proposal.candidates[19].group = "Mo_La"
+region2(beta'' 300 counts/px).proposal.candidates[19].energyKeV = 400258793dd97f63 2.2932000000000001
+region2(beta'' 300 counts/px).proposal.candidates[19].net = 0000000000000000 0
+region2(beta'' 300 counts/px).proposal.candidates[19].sigma = 4032addd998e5f4b 18.679162595042083
+region2(beta'' 300 counts/px).proposal.candidates[19].sigmaZero = 4032addd998e5f4b 18.679162595042083
+region2(beta'' 300 counts/px).proposal.candidates[19].criticalLevel = 403eb978116af71b 30.724488342871251
+region2(beta'' 300 counts/px).proposal.candidates[19].detectionLimit = 405009e3a870cb57 64.154520139837913
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts: array 1
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].id = "sum-O+Si sum-Mo"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].element = "Mo"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].line = "Mo_La"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].energiesKeV: n 2 sum 40123b2fec56d5d0 4.5578000000000003 fnv 83e16c96c1ecba8e
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].energiesKeV[0] = 40021de69ad42c3d 2.2646000000000002
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].energiesKeV[1] = 400258793dd97f63 2.2932000000000001
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].requires: array 2
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].requires[0] = "O"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].requires[1] = "Si"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].question = "O+Si sum peak (2.265 keV) or Mo Lα (2.293 keV)?"
+region2(beta'' 300 counts/px).proposal.candidates[19].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[19].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[19].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[19].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[19].familyNote = "Mo Kα (17.48 keV) has a residual peak of 1.4 σ, below the 3 σ its Lβ1 (2.39 keV) needs: not Mo."
+region2(beta'' 300 counts/px).proposal.candidates[19].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[19].unconfirmable = false
+region2(beta'' 300 counts/px).proposal.candidates[20].element = "Tl"
+region2(beta'' 300 counts/px).proposal.candidates[20].group = "Tl_Ma"
+region2(beta'' 300 counts/px).proposal.candidates[20].energyKeV = 40022a9930be0ded 2.2707999999999999
+region2(beta'' 300 counts/px).proposal.candidates[20].net = 0000000000000000 0
+region2(beta'' 300 counts/px).proposal.candidates[20].sigma = 402fd0882bc6e36a 15.907288902309762
+region2(beta'' 300 counts/px).proposal.candidates[20].sigmaZero = 402fd0882bc6e36a 15.907288902309762
+region2(beta'' 300 counts/px).proposal.candidates[20].criticalLevel = 403a2a480bf6d005 26.165161845929124
+region2(beta'' 300 counts/px).proposal.candidates[20].detectionLimit = 404b84974b6d6f98 55.035867145953659
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts: array 1
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].id = "sum-O+Si sum-Tl"
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].kind = .sumPeak
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].element = "Tl"
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].line = "Tl_Ma"
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].energiesKeV: n 2 sum 4012243fe5c91d15 4.5354000000000001 fnv 53069bf7b2532f4
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].energiesKeV[0] = 40021de69ad42c3d 2.2646000000000002
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].energiesKeV[1] = 40022a9930be0ded 2.2707999999999999
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].requires: array 2
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].requires[0] = "O"
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].requires[1] = "Si"
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].question = "O+Si sum peak (2.265 keV) or Tl Mα (2.271 keV)? They are 6 eV apart, far inside the detector resolution."
+region2(beta'' 300 counts/px).proposal.candidates[20].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+region2(beta'' 300 counts/px).proposal.candidates[20].suggestedRole = .fitOnly
+region2(beta'' 300 counts/px).proposal.candidates[20].holeRegionNote = nil
+region2(beta'' 300 counts/px).proposal.candidates[20].misfit = 3ff0000000000000 1
+region2(beta'' 300 counts/px).proposal.candidates[20].familyNote = "Tl Lα (10.27 keV) has a residual peak of 1.7 σ, below the 3 σ its Mγ (2.57 keV) needs: not Tl."
+region2(beta'' 300 counts/px).proposal.candidates[20].possibleReason = nil
+region2(beta'' 300 counts/px).proposal.candidates[20].unconfirmable = false
 region2(beta'' 300 counts/px).proposal.sumPeaks: array 5
 region2(beta'' 300 counts/px).proposal.sumPeaks[0].label = "Al+Al sum"
 region2(beta'' 300 counts/px).proposal.sumPeaks[0].elements: array 2
 region2(beta'' 300 counts/px).proposal.sumPeaks[0].elements[0] = "Al"
 region2(beta'' 300 counts/px).proposal.sumPeaks[0].elements[1] = "Al"
 region2(beta'' 300 counts/px).proposal.sumPeaks[0].energyKeV = 4007c8b439581062 2.9729999999999999
-region2(beta'' 300 counts/px).proposal.sumPeaks[0].net = 40c15041fa199e86 8864.5154449485817
-region2(beta'' 300 counts/px).proposal.sumPeaks[0].sigmaZero = 40329968c06177bd 18.599254630847771
-region2(beta'' 300 counts/px).proposal.sumPeaks[0].detectionLimit = 404ff221778a4c1a 63.891646330383267
+region2(beta'' 300 counts/px).proposal.sumPeaks[0].net = 40c18b2263045631 8982.2686467572075
+region2(beta'' 300 counts/px).proposal.sumPeaks[0].sigmaZero = 4032a81ad7b505ba 18.656659585661806
+region2(beta'' 300 counts/px).proposal.sumPeaks[0].detectionLimit = 40500526c730c245 64.080491826644973
 region2(beta'' 300 counts/px).proposal.sumPeaks[1].label = "Al+Si sum"
 region2(beta'' 300 counts/px).proposal.sumPeaks[1].elements: array 2
 region2(beta'' 300 counts/px).proposal.sumPeaks[1].elements[0] = "Al"
 region2(beta'' 300 counts/px).proposal.sumPeaks[1].elements[1] = "Si"
 region2(beta'' 300 counts/px).proposal.sumPeaks[1].energyKeV = 4009cf41f212d773 3.2262
-region2(beta'' 300 counts/px).proposal.sumPeaks[1].net = 40c08b779e47cd25 8470.9345178367312
-region2(beta'' 300 counts/px).proposal.sumPeaks[1].sigmaZero = 40324a41325a065d 18.290057322481847
-region2(beta'' 300 counts/px).proposal.sumPeaks[1].detectionLimit = 404f6feee2a5f06c 62.874477702164626
+region2(beta'' 300 counts/px).proposal.sumPeaks[1].net = 40c0d1429330e313 8610.5201169117699
+region2(beta'' 300 counts/px).proposal.sumPeaks[1].sigmaZero = 403266e2ff1c7491 18.401901192137817
+region2(beta'' 300 counts/px).proposal.sumPeaks[1].detectionLimit = 404f9f07554c8946 63.242411291476444
 region2(beta'' 300 counts/px).proposal.sumPeaks[2].label = "Al+Mg sum"
 region2(beta'' 300 counts/px).proposal.sumPeaks[2].elements: array 2
 region2(beta'' 300 counts/px).proposal.sumPeaks[2].elements[0] = "Al"
 region2(beta'' 300 counts/px).proposal.sumPeaks[2].elements[1] = "Mg"
 region2(beta'' 300 counts/px).proposal.sumPeaks[2].energyKeV = 4005ebb98c7e2824 2.7401
-region2(beta'' 300 counts/px).proposal.sumPeaks[2].net = 40aac31b2e22ff52 3425.5530863701506
-region2(beta'' 300 counts/px).proposal.sumPeaks[2].sigmaZero = 40333581dee24bdc 19.209012918708922
-region2(beta'' 300 counts/px).proposal.sumPeaks[2].detectionLimit = 40507971d4514634 65.897572593087546
+region2(beta'' 300 counts/px).proposal.sumPeaks[2].net = 40ab3a47653eef09 3485.139444319419
+region2(beta'' 300 counts/px).proposal.sumPeaks[2].sigmaZero = 403336dc8b69f8ec 19.214302743312984
+region2(beta'' 300 counts/px).proposal.sumPeaks[2].detectionLimit = 40507a8ef17cfa3b 65.914974567459396
 region2(beta'' 300 counts/px).proposal.sumPeaks[3].label = "Si+Si sum"
 region2(beta'' 300 counts/px).proposal.sumPeaks[3].elements: array 2
 region2(beta'' 300 counts/px).proposal.sumPeaks[3].elements[0] = "Si"
 region2(beta'' 300 counts/px).proposal.sumPeaks[3].elements[1] = "Si"
 region2(beta'' 300 counts/px).proposal.sumPeaks[3].energyKeV = 400bd5cfaacd9e84 3.4794
-region2(beta'' 300 counts/px).proposal.sumPeaks[3].net = 40a4b0dfa8b2a159 2648.436833936878
-region2(beta'' 300 counts/px).proposal.sumPeaks[3].sigmaZero = 40322508b589d14a 18.14466414084135
-region2(beta'' 300 counts/px).proposal.sumPeaks[3].detectionLimit = 404f32b5eb045c1b 62.396176697853853
+region2(beta'' 300 counts/px).proposal.sumPeaks[3].net = 40a4fd5632f2796a 2686.668357446023
+region2(beta'' 300 counts/px).proposal.sumPeaks[3].sigmaZero = 40324d114491a1fb 18.301044736437671
+region2(beta'' 300 counts/px).proposal.sumPeaks[3].detectionLimit = 404f748f4c088b66 62.910623077556735
 region2(beta'' 300 counts/px).proposal.sumPeaks[4].label = "Mg+Mg sum"
 region2(beta'' 300 counts/px).proposal.sumPeaks[4].elements: array 2
 region2(beta'' 300 counts/px).proposal.sumPeaks[4].elements[0] = "Mg"
 region2(beta'' 300 counts/px).proposal.sumPeaks[4].elements[1] = "Mg"
 region2(beta'' 300 counts/px).proposal.sumPeaks[4].energyKeV = 40040ebedfa43fe6 2.5072000000000001
-region2(beta'' 300 counts/px).proposal.sumPeaks[4].net = 4079c7c61dafb6a4 412.48586815488875
-region2(beta'' 300 counts/px).proposal.sumPeaks[4].sigmaZero = 4033d9812e1e256a 19.849627382621669
-region2(beta'' 300 counts/px).proposal.sumPeaks[4].detectionLimit = 405100520760e34f 68.005006641976465
+region2(beta'' 300 counts/px).proposal.sumPeaks[4].net = 407a63d720e01368 422.24002158670055
+region2(beta'' 300 counts/px).proposal.sumPeaks[4].sigmaZero = 4033d19fb382822c 19.818843097078727
+region2(beta'' 300 counts/px).proposal.sumPeaks[4].detectionLimit = 4050f9d6cccff9a6 67.903735354519625
 region2(beta'' 300 counts/px).proposal.refused: array 7
 region2(beta'' 300 counts/px).proposal.refused[0].element = "H"
 region2(beta'' 300 counts/px).proposal.refused[0].reason = "H has no characteristic X-ray line: it cannot be detected by EDX."
@@ -363,32 +474,33 @@ region2(beta'' 300 counts/px).proposal.refused[6].element = "N"
 region2(beta'' 300 counts/px).proposal.refused[6].reason = "Its line at 0.39 keV lies below the proposer's lowest tested line (0.45 keV): under the detector window the continuum is too model-dependent for a net area to be trusted. List it by hand if you know it is there."
 region2(beta'' 300 counts/px).proposal.currie.alpha = 3fa999999999999a 0.050000000000000003
 region2(beta'' 300 counts/px).proposal.currie.beta = 3fa999999999999a 0.050000000000000003
-region2(beta'' 300 counts/px).proposal.notes: array 11
+region2(beta'' 300 counts/px).proposal.notes: array 12
 region2(beta'' 300 counts/px).proposal.notes[0] = "Lines below 0.45 keV are not tested (a measured limit of the continuum model, not a property of the method)."
 region2(beta'' 300 counts/px).proposal.notes[1] = "Identification (validation: none): the residual's peaks at or above 5 σ of its top-hat filter (1.5 × below 1 keV); a candidate joins when Σ(y − μ)²/(μ + (0.01 μ)²) falls by at least 100, 20 % of that at its own lines, with its area at or above Currie L_D (α = β = 0.05, σ₀ from the fit's own variance with it absent) and no line against it; the final fit drops what it does not need (100). Kβ weights from NIST EPQ in this fit."
-region2(beta'' 300 counts/px).proposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data; escape peaks: none (no line above the Si K edge, 1.839 keV); reference shapes: none; 5 residual peaks examined, 31 candidate fits, 33 fits in all."
+region2(beta'' 300 counts/px).proposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data; escape peaks: fitted for 1 line group above the Si K edge (1.839 keV); reference shapes: none; 6 residual peaks examined, 38 candidate fits, 41 fits in all."
 region2(beta'' 300 counts/px).proposal.notes[3] = "Confirmation lines (validation: none): an element nominated by an L or M line needs its K or L alpha line at 3 σ in the residual where the fitted range holds it and the beam is at least 2.0 times its energy; otherwise it is withheld."
-region2(beta'' 300 counts/px).proposal.notes[4] = "Confirmation withheld Ru: Ru Kα (19.28 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.56 keV) needs: not Ru."
+region2(beta'' 300 counts/px).proposal.notes[4] = "Confirmation withheld Ru: Ru Kα (19.28 keV) has a residual peak of 1.7 σ, below the 3 σ its Lα (2.56 keV) needs: not Ru."
 region2(beta'' 300 counts/px).proposal.notes[5] = "Confirmation withheld Bi: Bi Lα (10.84 keV) has a residual peak of 2.4 σ, below the 3 σ its Mβ (2.53 keV) needs: not Bi."
-region2(beta'' 300 counts/px).proposal.notes[6] = "Confirmation withheld Pb: Pb Lα (10.55 keV) has a residual peak of 2.4 σ, below the 3 σ its Mβ (2.44 keV) needs: not Pb."
+region2(beta'' 300 counts/px).proposal.notes[6] = "Confirmation withheld Pb: Pb Lα (10.55 keV) has a residual peak of 2.2 σ, below the 3 σ its Mβ (2.44 keV) needs: not Pb."
 region2(beta'' 300 counts/px).proposal.notes[7] = "Confirmation withheld Mo: Mo Kα (17.48 keV) has a residual peak of 1.4 σ, below the 3 σ its Lβ1 (2.39 keV) needs: not Mo."
-region2(beta'' 300 counts/px).proposal.notes[8] = "Confirmation withheld Tl: Tl Lα (10.27 keV) has a residual peak of 0.0 σ, below the 3 σ its Mγ (2.57 keV) needs: not Tl."
-region2(beta'' 300 counts/px).proposal.notes[9] = "Look-elsewhere: 31 candidates were tested, so about 0.02 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
-region2(beta'' 300 counts/px).proposal.notes[10] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
-region2(beta'' 300 counts/px).proposal.passes = 33
+region2(beta'' 300 counts/px).proposal.notes[8] = "Confirmation withheld Tl: Tl Lα (10.27 keV) has a residual peak of 1.7 σ, below the 3 σ its Mγ (2.57 keV) needs: not Tl."
+region2(beta'' 300 counts/px).proposal.notes[9] = "Look-elsewhere: 38 candidates were tested, so about 0.02 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
+region2(beta'' 300 counts/px).proposal.notes[10] = "Cu_Ka: Si-escape/parent ratio 22.5 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+region2(beta'' 300 counts/px).proposal.notes[11] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
+region2(beta'' 300 counts/px).proposal.passes = 41
 region2(beta'' 300 counts/px).proposal.settled = true
-region2(beta'' 300 counts/px).proposal.reducedChiSquared = 3ff0dc3303be3c81 1.0537595888343108
+region2(beta'' 300 counts/px).proposal.reducedChiSquared = 3ff099f33b7c33b4 1.0375854800833908
 region2.fit.groupIDs: array 4
 region2.fit.groupIDs[0] = "Al_Ka"
 region2.fit.groupIDs[1] = "Mg_Ka"
 region2.fit.groupIDs[2] = "O_Ka"
 region2.fit.groupIDs[3] = "Si_Ka"
-region2.fit.values: n 4 sum 40dc47c154356f4f 28959.020764692974 fnv 1d3e09995c112218
-region2.fit.values[0] = 40ce04c3e9c9a4c9 15369.530572133504
-region2.fit.values[1] = 40b0364f1c0d6689 4150.3090217948275
-region2.fit.values[2] = 4068969b3f41db92 196.70645106184799
-region2.fit.values[3] = 40c20d3cc39d7f22 9242.4747197027937
-region2.fit.covariance: n 16 sum 40eb9c8cc9edca52 56548.39964952007 fnv 3841fe76ba7a0bfc
+region2.fit.values: n 4 sum 40dcf247931991e2 29641.118353264297 fnv 2072c6682f09b939
+region2.fit.values[0] = 40cf028ded228e66 15877.108799285441
+region2.fit.values[1] = 40b038cb31c9f062 4152.7937284671661
+region2.fit.values[2] = 4070d3a1574a4e00 269.22688988709706
+region2.fit.values[3] = 40c23efe95714abd 9341.9889356245931
+region2.fit.covariance: n 16 sum 40edd0884af9da8e 61060.259152342667 fnv 3486991234ff3148
 region2.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 region2.fit.supported: n 4 sum-bits 4 fnv fdcdb80e5fd8d165
 region2.fit.atBound: n 4 sum-bits 0 fnv c8210784d8af5a5
@@ -414,32 +526,32 @@ region2.fit.backgroundNames[12] = "continuum s1 t^2"
 region2.fit.backgroundNames[13] = "continuum s1 t^3"
 region2.fit.backgroundNames[14] = "continuum s1 t^4"
 region2.fit.backgroundNames[15] = "continuum s1 t^5"
-region2.fit.backgroundCoefficients: n 16 sum 40eeb260109795fb 62867.002025406771 fnv d8711c27ad9547dd
+region2.fit.backgroundCoefficients: n 16 sum 40ed5541e31298ed 60074.058968828853 fnv 94d66bd241fa1908
 region2.fit.channels = 136..<4096
-region2.fit.model: n 3960 sum 40f426df30a4969d 82541.949375713666 fnv e959d12bb6094660
-region2.fit.residual: n 3960 sum c0b910f30a4969da -6416.9493757136752 fnv 94e4e90f1a399644
-region2.fit.standardizedResidual: n 3960 sum c09a3867f7f8c2c5 -1678.1015318745497 fnv f84c950f63bf735d
+region2.fit.model: n 3960 sum 40f4494925d2d007 83092.571734249694 fnv d65a7db3294fc6b6
+region2.fit.residual: n 3960 sum c0b8fe925d2cff90 -6398.57173424949 fnv 2fbd976660c36124
+region2.fit.standardizedResidual: n 3960 sum c09a2c087d5c07a6 -1675.0082907085102 fnv 64b0d11fe884543b
 region2.fit.negativeModelChannels = 0
 region2.fit.degreesOfFreedom = 3940
-region2.fit.reducedChiSquared = 40938ebc9ee4b678 1251.6841998802538
-region2.fit.pearsonReducedChiSquared = 403f340687b3faa5 31.203224641266065
-region2.fit.deviance = 40f19180bb9f77e5 71960.045806377733
-region2.fit.reducedDeviance = 403243939ac47349 18.26397101684714
+region2.fit.reducedChiSquared = 40941de97bf6025c 1287.4780119360867
+region2.fit.pearsonReducedChiSquared = 403fa806247a00c1 31.656343726907611
+region2.fit.deviance = 40f1d01fd85414e3 72961.990314561452
+region2.fit.reducedDeviance = 403284ad7379fa2a 18.518271653441992
 region2.fit.methodLabel = "least squares, unweighted"
 region2.fit.referenceShapesLabel = "reference shapes: none"
 region2.fit.escapeLabel = "escape peaks: none (no line above the Si K edge, 1.839 keV)"
 region2.fit.lineShapeLabel = "line shape: Gaussian"
-region2.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+region2.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 region2.fit.exit = "converged"
 region2.fit.warnings: array 1
-region2.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+region2.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 region2.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 region2.fit.escapeRatios: array 4
 region2.fit.escapeRatios[0] = nil
 region2.fit.escapeRatios[1] = nil
 region2.fit.escapeRatios[2] = nil
 region2.fit.escapeRatios[3] = nil
-region2.fit.iterations = 16
+region2.fit.iterations = 18
 region2.fit.converged = true
 region2.fit.irls = nil
 region2.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.f64 b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.f64
index 241a270..4d128c7 100644
Binary files a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.f64 and b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.f64 differ
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.json b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.json
index 14303db..461ac79 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.json
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.arrays.json
@@ -1 +1 @@
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\ No newline at end of file
+[{"count":16,"offset":0,"path":"seed0.four.quantification.fit.backgroundCoefficients"},{"count":36,"offset":16,"path":"seed0.four.quantification.fit.covariance"},{"count":0,"offset":52,"path":"seed0.four.quantification.fit.devianceHistory"},{"count":0,"offset":52,"path":"seed0.four.quantification.fit.droppedLines"},{"count":991,"offset":52,"path":"seed0.four.quantification.fit.model"},{"count":991,"offset":1043,"path":"seed0.four.quantification.fit.residual"},{"count":991,"offset":2034,"path":"seed0.four.quantification.fit.standardizedResidual"},{"count":6,"offset":3025,"path":"seed0.four.quantification.fit.values"},{"count":1,"offset":3031,"path":"seed0.four.quantification.fitSettings.background.continuum.edges"},{"count":0,"offset":3032,"path":"seed0.four.quantification.fitSettings.referenceShapes.shapes"},{"count":4,"offset":3032,"path":"seed0.four.quantification.kSet.relativeSigma"},{"count":4,"offset":3036,"path":"seed0.four.quantification.kSet.values"},{"count":0,"offset":3040,"path":"seed0.four.quantification.method.typedK"},{"count":4096,"offset":3040,"path":"seed0.four.quantification.plotBackground"},{"count":4096,"offset":7136,"path":"seed0.four.quantification.plotModel"},{"count":0,"offset":11232,"path":"seed0.four.quantification.warnings"},{"count":0,"offset":11232,"path":"seed0.four.unlistedProposal.candidates[0].conflicts"},{"count":2,"offset":11232,"path":"seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV"},{"count":2,"offset":11234,"path":"seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV"},{"count":2,"offset":11236,"path":"seed0.four.unlistedProposal.candidates[12].conflicts[0].energiesKeV"},{"count":0,"offset":11238,"path":"seed0.four.unlistedProposal.candidates[13].conflicts"},{"count":0,"offset":11238,"path":"seed0.four.unlistedProposal.candidates[14].conflicts"},{"count":0,"offset":11238,"path":"seed0.four.unlistedProposal.candidates[15].conflicts"},{"count":0,"offset":11238,"path":"seed0.four.unlistedProposal.candidates[16].conflicts"},{"count":2,"offset":11238,"path":"seed0.four.unlistedProposal.candidates[17].conflicts[0].energiesKeV"},{"count":2,"offset":11240,"path":"seed0.four.unlistedProposal.candidates[18].conflicts[0].energiesKeV"},{"count":0,"offset":11242,"path":"seed0.four.unlistedProposal.candidates[19].conflicts"},{"count":2,"offset":11242,"path":"seed0.four.unlistedProposal.candidates[1].conflicts[0].energiesKeV"},{"count":0,"offset":11244,"path":"seed0.four.unlistedProposal.candidates[1].conflicts[0].requires"},{"count":0,"offset":11244,"path":"seed0.four.unlistedProposal.candidates[20].conflicts"},{"count":2,"offset":11244,"path":"seed0.four.unlistedProposal.candidates[21].conflicts[0].energiesKeV"},{"count":2,"offset":11246,"path":"seed0.four.unlistedProposal.candidates[21].conflicts[1].energiesKeV"},{"count":2,"offset":11248,"path":"seed0.four.unlistedProposal.candidates[22].conflicts[0].energiesKeV"},{"count":2,"offset":11250,"path":"seed0.four.unlistedProposal.candidates[22].conflicts[1].energiesKeV"},{"count":0,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[23].conflicts"},{"count":0,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[24].conflicts"},{"count":0,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[25].conflicts"},{"count":0,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[26].conflicts"},{"count":0,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[27].conflicts"},{"count":2,"offset":11252,"path":"seed0.four.unlistedProposal.candidates[28].conflicts[0].energiesKeV"},{"count":0,"offset":11254,"path":"seed0.four.unlistedProposal.candidates[29].conflicts"},{"count":2,"offset":11254,"path":"seed0.four.unlistedProposal.candidates[2].conflicts[0].energiesKeV"},{"count":1,"offset":11256,"path":"seed0.four.unlistedProposal.candidates[2].conflicts[1].energiesKeV"},{"count":0,"offset":11257,"path":"seed0.four.unlistedProposal.candidates[2].conflicts[1].requires"},{"count":0,"offset":11257,"path":"seed0.four.unlistedProposal.candidates[30].conflicts"},{"count":2,"offset":11257,"path":"seed0.four.unlistedProposal.candidates[31].conflicts[0].energiesKeV"},{"count":2,"offset":11259,"path":"seed0.four.unlistedProposal.candidates[32].conflicts[0].energiesKeV"},{"count":0,"offset":11261,"path":"seed0.four.unlistedProposal.candidates[33].conflicts"},{"count":0,"offset":11261,"path":"seed0.four.unlistedProposal.candidates[34].conflicts"},{"count":0,"offset":11261,"path":"seed0.four.unlistedProposal.candidates[3].conflicts"},{"count":0,"offset":11261,"path":"seed0.four.unlistedProposal.candidates[4].conflicts"},{"count":2,"offset":11261,"path":"seed0.four.unlistedProposal.candidates[5].conflicts[0].energiesKeV"},{"count":2,"offset":11263,"path":"seed0.four.unlistedProposal.candidates[6].conflicts[0].energiesKeV"},{"count":0,"offset":11265,"path":"seed0.four.unlistedProposal.candidates[7].conflicts"},{"count":0,"offset":11265,"path":"seed0.four.unlistedProposal.candidates[8].conflicts"},{"count":2,"offset":11265,"path":"seed0.four.unlistedProposal.candidates[9].conflicts[0].energiesKeV"},{"count":0,"offset":11267,"path":"seed0.four.unlistedProposal.sumPeaks"},{"count":4,"offset":11267,"path":"seed0.four.withholding[0]"},{"count":4,"offset":11271,"path":"seed0.four.withholding[1]"},{"count":16,"offset":11275,"path":"seed0.seven-60keV.quantification.fit.backgroundCoefficients"},{"count":144,"offset":11291,"path":"seed0.seven-60keV.quantification.fit.covariance"},{"count":0,"offset":11435,"path":"seed0.seven-60keV.quantification.fit.devianceHistory"},{"count":0,"offset":11435,"path":"seed0.seven-60keV.quantification.fit.droppedLines"},{"count":2991,"offset":11435,"path":"seed0.seven-60keV.quantification.fit.model"},{"count":2991,"offset":14426,"path":"seed0.seven-60keV.quantification.fit.residual"},{"count":2991,"offset":17417,"path":"seed0.seven-60keV.quantification.fit.standardizedResidual"},{"count":12,"offset":20408,"path":"seed0.seven-60keV.quantification.fit.values"},{"count":1,"offset":20420,"path":"seed0.seven-60keV.quantification.fitSettings.background.continuum.edges"},{"count":0,"offset":20421,"path":"seed0.seven-60keV.quantification.fitSettings.referenceShapes.shapes"},{"count":0,"offset":20421,"path":"seed0.seven-60keV.quantification.method.typedK"},{"count":4096,"offset":20421,"path":"seed0.seven-60keV.quantification.plotBackground"},{"count":4096,"offset":24517,"path":"seed0.seven-60keV.quantification.plotModel"},{"count":0,"offset":28613,"path":"seed0.seven-60keV.quantification.warnings"},{"count":16,"offset":28613,"path":"seed0.seven.quantification.fit.backgroundCoefficients"},{"count":144,"offset":28629,"path":"seed0.seven.quantification.fit.covariance"},{"count":0,"offset":28773,"path":"seed0.seven.quantification.fit.devianceHistory"},{"count":0,"offset":28773,"path":"seed0.seven.quantification.fit.droppedLines"},{"count":991,"offset":28773,"path":"seed0.seven.quantification.fit.model"},{"count":991,"offset":29764,"path":"seed0.seven.quantification.fit.residual"},{"count":991,"offset":30755,"path":"seed0.seven.quantification.fit.standardizedResidual"},{"count":12,"offset":31746,"path":"seed0.seven.quantification.fit.values"},{"count":1,"offset":31758,"path":"seed0.seven.quantification.fitSettings.background.continuum.edges"},{"count":0,"offset":31759,"path":"seed0.seven.quantification.fitSettings.referenceShapes.shapes"},{"count":0,"offset":31759,"path":"seed0.seven.quantification.method.typedK"},{"count":4096,"offset":31759,"path":"seed0.seven.quantification.plotBackground"},{"count":4096,"offset":35855,"path":"seed0.seven.quantification.plotModel"},{"count":0,"offset":39951,"path":"seed0.seven.quantification.warnings"}]
\ No newline at end of file
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.txt b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.txt
index 1750ab8..55d1077 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.txt
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-realistic-l-sim.txt
@@ -1,5 +1,5 @@
 # SpectroGolden eds-realistic-l-sim
-seed 0: counts fnv c03d80e40cfcee0f
+seed 0: counts fnv 3214af1880ccc54f
 seed0.seven.quantification.method.version = 1
 seed0.seven.quantification.method.estimator = .leastSquares
 seed0.seven.quantification.method.background = .empiricalWithAlEdge
@@ -40,13 +40,13 @@ seed0.seven.quantification.method.fitToKeV = nil
 seed0.seven.quantification.rows: array 7
 seed0.seven.quantification.rows[0].element = "O"
 seed0.seven.quantification.rows[0].groupID = "O_Ka"
-seed0.seven.quantification.rows[0].net = 40fd60dde3ff77b3 120333.86816355474
-seed0.seven.quantification.rows[0].sigma = 4081a32560997cf5 564.39325065529431
+seed0.seven.quantification.rows[0].net = 40fd60be4025ab2e 120331.89066092364
+seed0.seven.quantification.rows[0].sigma = 4080c0db7bfdd333 536.10717008877543
 seed0.seven.quantification.rows[0].supported = true
 seed0.seven.quantification.rows[0].atBound = false
 seed0.seven.quantification.rows[0].isReference = false
-seed0.seven.quantification.rows[0].kFreeRatio = 3fc00a357a27b3a5 0.12531155075649028
-seed0.seven.quantification.rows[0].kFreeSigma = 3f43d6dff1010d5d 0.0006054490531898594
+seed0.seven.quantification.rows[0].kFreeRatio = 3fc00a63bbd71c1e 0.12531706497085876
+seed0.seven.quantification.rows[0].kFreeSigma = 3f42e3c6d9c87b7f 0.00057646951205812802
 seed0.seven.quantification.rows[0].atomicPercent = nil
 seed0.seven.quantification.rows[0].atomicSigma = nil
 seed0.seven.quantification.rows[0].weightPercent = nil
@@ -61,8 +61,8 @@ seed0.seven.quantification.rows[0].failure = nil
 seed0.seven.quantification.rows[0].lineNote = nil
 seed0.seven.quantification.rows[1].element = "Si"
 seed0.seven.quantification.rows[1].groupID = "Si_Ka"
-seed0.seven.quantification.rows[1].net = 412d4e2b1665fda7 960277.54374687828
-seed0.seven.quantification.rows[1].sigma = 409167c19a34be63 1113.9390648118213
+seed0.seven.quantification.rows[1].net = 412d4db704dfee3d 960219.50952095503
+seed0.seven.quantification.rows[1].sigma = 40919d94b315f135 1127.395214407775
 seed0.seven.quantification.rows[1].supported = true
 seed0.seven.quantification.rows[1].atBound = false
 seed0.seven.quantification.rows[1].isReference = true
@@ -82,13 +82,13 @@ seed0.seven.quantification.rows[1].failure = nil
 seed0.seven.quantification.rows[1].lineNote = nil
 seed0.seven.quantification.rows[2].element = "Ti"
 seed0.seven.quantification.rows[2].groupID = "Ti_Ka"
-seed0.seven.quantification.rows[2].net = 40a738b7760b8089 2972.3583224863437
-seed0.seven.quantification.rows[2].sigma = 405abefe98537015 106.98428924701905
+seed0.seven.quantification.rows[2].net = 40a746189564817c 2979.0480147750914
+seed0.seven.quantification.rows[2].sigma = 405aee6a6cb764e7 107.72524564656815
 seed0.seven.quantification.rows[2].supported = true
 seed0.seven.quantification.rows[2].atBound = false
 seed0.seven.quantification.rows[2].isReference = false
-seed0.seven.quantification.rows[2].kFreeRatio = 3f695b56d1967644 0.0030953117063308461
-seed0.seven.quantification.rows[2].kFreeSigma = 3f1d4a36ea5e5c08 0.00011173210313440718
+seed0.seven.quantification.rows[2].kFreeRatio = 3f696a578bd4214b 0.0031024656187847214
+seed0.seven.quantification.rows[2].kFreeSigma = 3f1d83f3be04fa86 0.00011259246048654124
 seed0.seven.quantification.rows[2].atomicPercent = nil
 seed0.seven.quantification.rows[2].atomicSigma = nil
 seed0.seven.quantification.rows[2].weightPercent = nil
@@ -103,13 +103,13 @@ seed0.seven.quantification.rows[2].failure = nil
 seed0.seven.quantification.rows[2].lineNote = nil
 seed0.seven.quantification.rows[3].element = "Ni"
 seed0.seven.quantification.rows[3].groupID = "Ni_Ka"
-seed0.seven.quantification.rows[3].net = 4118264f4239c1e0 395667.81467345171
-seed0.seven.quantification.rows[3].sigma = 408545587130045a 680.66818463815002
+seed0.seven.quantification.rows[3].net = 411826333f46869c 395660.81179247214
+seed0.seven.quantification.rows[3].sigma = 4085471a2d1af02d 680.88778134389361
 seed0.seven.quantification.rows[3].supported = true
 seed0.seven.quantification.rows[3].atBound = false
 seed0.seven.quantification.rows[3].isReference = false
-seed0.seven.quantification.rows[3].kFreeRatio = 3fda5ec76c7bbf1b 0.41203485101776643
-seed0.seven.quantification.rows[3].kFreeSigma = 3f4bdbefc7d5b7c1 0.00085019310033173517
+seed0.seven.quantification.rows[3].kFreeRatio = 3fda5f1148d3e056 0.41205246078562163
+seed0.seven.quantification.rows[3].kFreeSigma = 3f4bead5a5b6f26c 0.00085196907041724728
 seed0.seven.quantification.rows[3].atomicPercent = nil
 seed0.seven.quantification.rows[3].atomicSigma = nil
 seed0.seven.quantification.rows[3].weightPercent = nil
@@ -124,13 +124,13 @@ seed0.seven.quantification.rows[3].failure = nil
 seed0.seven.quantification.rows[3].lineNote = nil
 seed0.seven.quantification.rows[4].element = "Ge"
 seed0.seven.quantification.rows[4].groupID = "Ge_Ka"
-seed0.seven.quantification.rows[4].net = 41104d1e99f5d5a2 267079.65035184671
-seed0.seven.quantification.rows[4].sigma = 40816fafc17bb98f 557.96081825885801
+seed0.seven.quantification.rows[4].net = 41104d16180419e4 267077.52345314459
+seed0.seven.quantification.rows[4].sigma = 40816fd947e3b379 557.98109414950807
 seed0.seven.quantification.rows[4].supported = true
 seed0.seven.quantification.rows[4].atBound = false
 seed0.seven.quantification.rows[4].isReference = false
-seed0.seven.quantification.rows[4].kFreeRatio = 3fd1ccd789c9b1b3 0.27812756019445856
-seed0.seven.quantification.rows[4].kFreeSigma = 3f45ba2665e8c739 0.00066305994898228145
+seed0.seven.quantification.rows[4].kFreeRatio = 3fd1cd14c09e98c4 0.27814215479373794
+seed0.seven.quantification.rows[4].kFreeSigma = 3f45c71ecb1b0aeb 0.00066460612853122319
 seed0.seven.quantification.rows[4].atomicPercent = nil
 seed0.seven.quantification.rows[4].atomicSigma = nil
 seed0.seven.quantification.rows[4].weightPercent = nil
@@ -145,13 +145,13 @@ seed0.seven.quantification.rows[4].failure = nil
 seed0.seven.quantification.rows[4].lineNote = nil
 seed0.seven.quantification.rows[5].element = "Cu"
 seed0.seven.quantification.rows[5].groupID = "Cu_Ka"
-seed0.seven.quantification.rows[5].net = 40ed1e4ee3ed19cb 59634.465323019387
-seed0.seven.quantification.rows[5].sigma = 4073e04ddc5061ca 318.01900893592085
+seed0.seven.quantification.rows[5].net = 40ed1da3ba43dd39 59629.116487438274
+seed0.seven.quantification.rows[5].sigma = 4073e322799b3418 318.19591675402035
 seed0.seven.quantification.rows[5].supported = true
 seed0.seven.quantification.rows[5].atBound = false
 seed0.seven.quantification.rows[5].isReference = false
-seed0.seven.quantification.rows[5].kFreeRatio = 3fafcbbd338d0403 0.06210128073008294
-seed0.seven.quantification.rows[5].kFreeSigma = 3f36210e6710c059 0.00033766366601906611
+seed0.seven.quantification.rows[5].kFreeRatio = 3fafcb803a97deb2 0.062099463608260477
+seed0.seven.quantification.rows[5].kFreeSigma = 3f361ffb92746881 0.00033759967705438576
 seed0.seven.quantification.rows[5].atomicPercent = nil
 seed0.seven.quantification.rows[5].atomicSigma = nil
 seed0.seven.quantification.rows[5].weightPercent = nil
@@ -166,13 +166,13 @@ seed0.seven.quantification.rows[5].failure = nil
 seed0.seven.quantification.rows[5].lineNote = nil
 seed0.seven.quantification.rows[6].element = "Ga"
 seed0.seven.quantification.rows[6].groupID = "Ga_Ka"
-seed0.seven.quantification.rows[6].net = 40dd6f5976ed9da1 30141.397883800444
-seed0.seven.quantification.rows[6].sigma = 40690ec7cdd7d05b 200.46189014578962
+seed0.seven.quantification.rows[6].net = 40dd6e5cc083dded 30137.449250189518
+seed0.seven.quantification.rows[6].sigma = 406913b25ed92523 200.61552374278207
 seed0.seven.quantification.rows[6].supported = true
 seed0.seven.quantification.rows[6].atBound = false
 seed0.seven.quantification.rows[6].isReference = false
-seed0.seven.quantification.rows[6].kFreeRatio = 3fa0121db8bec2da 0.031388214876079082
-seed0.seven.quantification.rows[6].kFreeSigma = 3f2baa830fb559ac 0.00021107530470017061
+seed0.seven.quantification.rows[6].kFreeRatio = 3fa011d364a38412 0.031385999712945659
+seed0.seven.quantification.rows[6].kFreeSigma = 3f2ba9cd5588790b 0.00021105414886419429
 seed0.seven.quantification.rows[6].atomicPercent = nil
 seed0.seven.quantification.rows[6].atomicSigma = nil
 seed0.seven.quantification.rows[6].weightPercent = nil
@@ -199,8 +199,8 @@ seed0.seven.quantification.fit.groupIDs[8] = "O_Ka"
 seed0.seven.quantification.fit.groupIDs[9] = "Si_Ka"
 seed0.seven.quantification.fit.groupIDs[10] = "Ti_Ka"
 seed0.seven.quantification.fit.groupIDs[11] = "Ti_La"
-seed0.seven.quantification.fit.values: n 12 sum 4145521ae45164d6 2794549.7837339444 fnv a71011a24adeba4a
-seed0.seven.quantification.fit.covariance: n 144 sum 4153c5815f6b2e24 5182981.4909167625 fnv 7e638a0558f997b8
+seed0.seven.quantification.fit.values: n 12 sum 414551fcf4ac7237 2794489.9115126389 fnv bceecad80e068e42
+seed0.seven.quantification.fit.covariance: n 144 sum 4154203022d1027e 5275840.5440069418 fnv ddeaa28e15872051
 seed0.seven.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 seed0.seven.quantification.fit.supported: n 12 sum-bits c fnv 9a4297133c0b8de5
 seed0.seven.quantification.fit.atBound: n 12 sum-bits 0 fnv 243cfa845185aa5
@@ -209,7 +209,7 @@ seed0.seven.quantification.fit.escapeValues[0] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeValues[1] = nil
 seed0.seven.quantification.fit.escapeValues[2] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeValues[3] = nil
-seed0.seven.quantification.fit.escapeValues[4] = 4052c84d18589876 75.129705511588185
+seed0.seven.quantification.fit.escapeValues[4] = 4051fd84e71e46a8 71.961236743513496
 seed0.seven.quantification.fit.escapeValues[5] = nil
 seed0.seven.quantification.fit.escapeValues[6] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeValues[7] = nil
@@ -234,32 +234,32 @@ seed0.seven.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 seed0.seven.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 seed0.seven.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 seed0.seven.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-seed0.seven.quantification.fit.backgroundCoefficients: n 16 sum 41368dd83f5af999 1478104.2474819182 fnv 8b47c31ef508023f
+seed0.seven.quantification.fit.backgroundCoefficients: n 16 sum 41368c2a32886208 1477674.1973935384 fnv b2b9cc29c8778ce1
 seed0.seven.quantification.fit.channels = 107..<1098
-seed0.seven.quantification.fit.model: n 991 sum 414e49a47fff536e 3969864.999979428 fnv 6136dc40c4418f4
-seed0.seven.quantification.fit.residual: n 991 sum 3ef5912139200000 2.0567811198191066e-05 fnv bc63530837b0e13e
-seed0.seven.quantification.fit.standardizedResidual: n 991 sum c02944d659b1120e -12.634447863450102 fnv 597a3d78c89d6c32
+seed0.seven.quantification.fit.model: n 991 sum 414e49a5bff43005 3969867.4996395134 fnv 8c669ecc6decb3a5
+seed0.seven.quantification.fit.residual: n 991 sum bfdffa1804484380 -0.49963951509658244 fnv 93e0e96511f0f30d
+seed0.seven.quantification.fit.standardizedResidual: n 991 sum c0262700d39fbb48 -11.076178181885226 fnv fca933fd7c1c9b1b
 seed0.seven.quantification.fit.negativeModelChannels = 0
 seed0.seven.quantification.fit.degreesOfFreedom = 958
-seed0.seven.quantification.fit.reducedChiSquared = 40a75376eabe6648 2985.7322597026687
-seed0.seven.quantification.fit.pearsonReducedChiSquared = 3ff0614647eadfd8 1.0237486657406318
-seed0.seven.quantification.fit.deviance = 408ebf67f13bb87f 983.92575308472431
-seed0.seven.quantification.fit.reducedDeviance = 3ff06ed8f45de9d2 1.0270623727397958
+seed0.seven.quantification.fit.reducedChiSquared = 40a72f567f8845c8 2967.6689417443449
+seed0.seven.quantification.fit.pearsonReducedChiSquared = 3ff08ec7a5a7d6d0 1.0348583670542446
+seed0.seven.quantification.fit.deviance = 408f1404de896811 994.50237758015476
+seed0.seven.quantification.fit.reducedDeviance = 3ff09c11911f3715 1.0381026905847126
 seed0.seven.quantification.fit.methodLabel = "least squares, unweighted"
 seed0.seven.quantification.fit.referenceShapesLabel = "reference shapes: none"
 seed0.seven.quantification.fit.escapeLabel = "escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-seed0.seven.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+seed0.seven.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 seed0.seven.quantification.fit.exit = "converged"
 seed0.seven.quantification.fit.warnings: array 1
-seed0.seven.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.seven.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.seven.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.fit.escapeRatios: array 12
 seed0.seven.quantification.fit.escapeRatios[0] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[1] = nil
 seed0.seven.quantification.fit.escapeRatios[2] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[3] = nil
-seed0.seven.quantification.fit.escapeRatios[4] = 3f326f7183b4fc68 0.00028130074834459848
+seed0.seven.quantification.fit.escapeRatios[4] = 3f31a871e0f5e08d 0.00026943950884784283
 seed0.seven.quantification.fit.escapeRatios[5] = nil
 seed0.seven.quantification.fit.escapeRatios[6] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[7] = nil
@@ -267,7 +267,7 @@ seed0.seven.quantification.fit.escapeRatios[8] = nil
 seed0.seven.quantification.fit.escapeRatios[9] = nil
 seed0.seven.quantification.fit.escapeRatios[10] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[11] = nil
-seed0.seven.quantification.fit.iterations = 31
+seed0.seven.quantification.fit.iterations = 30
 seed0.seven.quantification.fit.converged = true
 seed0.seven.quantification.fit.irls = nil
 seed0.seven.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
@@ -279,21 +279,21 @@ seed0.seven.quantification.usedAxis.scale = 3f947ae147ae147b 0.02
 seed0.seven.quantification.usedAxis.size = 4096
 seed0.seven.quantification.axisLocked = true
 seed0.seven.quantification.refinement = nil
-seed0.seven.quantification.plotModel: n 4096 sum 414e49a47fff536e 3969864.999979428 fnv 74c77408a97e9f54
-seed0.seven.quantification.plotBackground: n 4096 sum 4127eb33ac207221 783769.83618504193 fnv f5ecef6eb21802bb
+seed0.seven.quantification.plotModel: n 4096 sum 414e49a5bff43005 3969867.4996395134 fnv ffb3329bca558205
+seed0.seven.quantification.plotBackground: n 4096 sum 4127eba9693f2323 783828.70555982401 fnv 33d0419c8b442d2d
 seed0.seven.quantification.kSet = nil
 seed0.seven.quantification.abundanceRefusal = "The computed-k data files are not available in this build."
 seed0.seven.quantification.absorption = .off
 seed0.seven.quantification.warnings: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-seed0.seven.quantification.quality = 3ff0614647eadfd8 1.0237486657406318
+seed0.seven.quantification.quality = 3ff08ec7a5a7d6d0 1.0348583670542446
 seed0.seven.quantification.footerLines: array 8
-seed0.seven.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
+seed0.seven.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven.quantification.footerLines[1] = "energy axis: the file's (locked)"
 seed0.seven.quantification.footerLines[2] = "beam 200 kV · typed"
 seed0.seven.quantification.footerLines[3] = "fit range 0.2–20 keV (default; axis to 79.97 keV) · 1 px pooled (synthetic)"
 seed0.seven.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-seed0.seven.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 1.02 (Pearson)"
+seed0.seven.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 1.03 (Pearson)"
 seed0.seven.quantification.footerLines[6] = "at%: not computed — The computed-k data files are not available in this build."
 seed0.seven.quantification.footerLines[7] = "absorption correction: off"
 seed0.seven.quantification.fitSettings.elements: array 7
@@ -314,7 +314,7 @@ seed0.seven.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f2
 seed0.seven.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 seed0.seven.quantification.fitSettings.background.continuum.nonNegative = true
 seed0.seven.quantification.fitSettings.background.continuum.efficiency = nil
-seed0.seven.quantification.fitSettings.background.continuum.edgeStep = .sharp
+seed0.seven.quantification.fitSettings.background.continuum.edgeStep = .broadened
 seed0.seven.quantification.fitSettings.escapePeaks = true
 seed0.seven.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.fitSettings.method = .leastSquares
@@ -333,44 +333,44 @@ seed0.seven.quantification.unlistedCheckPending = false
 seed0.seven.quantification.abundanceCaveat = nil
 seed0.seven.quantification.appliedSumEscape = nil
 seed0.seven.quantification.continuumDeadLayerMicrons = nil
-seed0.seven.csv-fnv = 176c2eb938b3c80a
+seed0.seven.csv-fnv = fa34fdbd5753ab9e
 seed0.seven.rangeSensitivity.alternativeToKeV = 4053fdf036df3a38 79.967786520000004
 seed0.seven.rangeSensitivity.moves: array 7
 seed0.seven.rangeSensitivity.moves[0].element = "O"
 seed0.seven.rangeSensitivity.moves[0].group = "O_Ka"
-seed0.seven.rangeSensitivity.moves[0].before = 40fd60dde3ff77b3 120333.86816355474
-seed0.seven.rangeSensitivity.moves[0].sigma = 4081a32560997cf5 564.39325065529431
-seed0.seven.rangeSensitivity.moves[0].after = 40fd60dde4065bea 120333.86817012695
+seed0.seven.rangeSensitivity.moves[0].before = 40fd60be4025ab2e 120331.89066092364
+seed0.seven.rangeSensitivity.moves[0].sigma = 4080c0db7bfdd333 536.10717008877543
+seed0.seven.rangeSensitivity.moves[0].after = 40fd5efd281e2ca7 120303.82229440157
 seed0.seven.rangeSensitivity.moves[1].element = "Si"
 seed0.seven.rangeSensitivity.moves[1].group = "Si_Ka"
-seed0.seven.rangeSensitivity.moves[1].before = 412d4e2b1665fda7 960277.54374687828
-seed0.seven.rangeSensitivity.moves[1].sigma = 409167c19a34be63 1113.9390648118213
-seed0.seven.rangeSensitivity.moves[1].after = 412d5435799cfe7c 961050.73752589477
+seed0.seven.rangeSensitivity.moves[1].before = 412d4db704dfee3d 960219.50952095503
+seed0.seven.rangeSensitivity.moves[1].sigma = 40919d94b315f135 1127.395214407775
+seed0.seven.rangeSensitivity.moves[1].after = 412d545710a6a1e2 961067.53252130398
 seed0.seven.rangeSensitivity.moves[2].element = "Ti"
 seed0.seven.rangeSensitivity.moves[2].group = "Ti_Ka"
-seed0.seven.rangeSensitivity.moves[2].before = 40a738b7760b8089 2972.3583224863437
-seed0.seven.rangeSensitivity.moves[2].sigma = 405abefe98537015 106.98428924701905
-seed0.seven.rangeSensitivity.moves[2].after = 40a4700bcc0763e5 2616.0230409917299
+seed0.seven.rangeSensitivity.moves[2].before = 40a746189564817c 2979.0480147750914
+seed0.seven.rangeSensitivity.moves[2].sigma = 405aee6a6cb764e7 107.72524564656815
+seed0.seven.rangeSensitivity.moves[2].after = 40a48afbc18e54ec 2629.4917110899605
 seed0.seven.rangeSensitivity.moves[3].element = "Ni"
 seed0.seven.rangeSensitivity.moves[3].group = "Ni_Ka"
-seed0.seven.rangeSensitivity.moves[3].before = 4118264f4239c1e0 395667.81467345171
-seed0.seven.rangeSensitivity.moves[3].sigma = 408545587130045a 680.66818463815002
-seed0.seven.rangeSensitivity.moves[3].after = 411820e574d2b243 395321.36408499273
+seed0.seven.rangeSensitivity.moves[3].before = 411826333f46869c 395660.81179247214
+seed0.seven.rangeSensitivity.moves[3].sigma = 4085471a2d1af02d 680.88778134389361
+seed0.seven.rangeSensitivity.moves[3].after = 41182105f61d3a89 395329.49034587346
 seed0.seven.rangeSensitivity.moves[4].element = "Ge"
 seed0.seven.rangeSensitivity.moves[4].group = "Ge_Ka"
-seed0.seven.rangeSensitivity.moves[4].before = 41104d1e99f5d5a2 267079.65035184671
-seed0.seven.rangeSensitivity.moves[4].sigma = 40816fafc17bb98f 557.96081825885801
-seed0.seven.rangeSensitivity.moves[4].after = 411047890733f8bb 266722.25703419343
+seed0.seven.rangeSensitivity.moves[4].before = 41104d16180419e4 267077.52345314459
+seed0.seven.rangeSensitivity.moves[4].sigma = 40816fd947e3b379 557.98109414950807
+seed0.seven.rangeSensitivity.moves[4].after = 411047a06e7f8780 266728.10790836066
 seed0.seven.rangeSensitivity.moves[5].element = "Cu"
 seed0.seven.rangeSensitivity.moves[5].group = "Cu_Ka"
-seed0.seven.rangeSensitivity.moves[5].before = 40ed1e4ee3ed19cb 59634.465323019387
-seed0.seven.rangeSensitivity.moves[5].sigma = 4073e04ddc5061ca 318.01900893592085
-seed0.seven.rangeSensitivity.moves[5].after = 40ecf7d8e27b0ff5 59326.777646571318
+seed0.seven.rangeSensitivity.moves[5].before = 40ed1da3ba43dd39 59629.116487438274
+seed0.seven.rangeSensitivity.moves[5].sigma = 4073e322799b3418 318.19591675402035
+seed0.seven.rangeSensitivity.moves[5].after = 40ecf8c83acb0e23 59334.2571769024
 seed0.seven.rangeSensitivity.moves[6].element = "Ga"
 seed0.seven.rangeSensitivity.moves[6].group = "Ga_Ka"
-seed0.seven.rangeSensitivity.moves[6].before = 40dd6f5976ed9da1 30141.397883800444
-seed0.seven.rangeSensitivity.moves[6].sigma = 40690ec7cdd7d05b 200.46189014578962
-seed0.seven.rangeSensitivity.moves[6].after = 40dd19aec493c438 29798.730748120899
+seed0.seven.rangeSensitivity.moves[6].before = 40dd6e5cc083dded 30137.449250189518
+seed0.seven.rangeSensitivity.moves[6].sigma = 406913b25ed92523 200.61552374278207
+seed0.seven.rangeSensitivity.moves[6].after = 40dd1b45b67db1d7 29805.089263366386
 seed0.seven.rangeSensitivity.failure = nil
 seed0.seven-60keV.quantification.method.version = 1
 seed0.seven-60keV.quantification.method.estimator = .leastSquares
@@ -412,13 +412,13 @@ seed0.seven-60keV.quantification.method.fitToKeV = 404e000000000000 60
 seed0.seven-60keV.quantification.rows: array 7
 seed0.seven-60keV.quantification.rows[0].element = "O"
 seed0.seven-60keV.quantification.rows[0].groupID = "O_Ka"
-seed0.seven-60keV.quantification.rows[0].net = 40fd60dde401ddd4 120333.86816584255
-seed0.seven-60keV.quantification.rows[0].sigma = 4081a325609992aa 564.39325065592607
+seed0.seven-60keV.quantification.rows[0].net = 40fd60c9d078be71 120332.61339640037
+seed0.seven-60keV.quantification.rows[0].sigma = 40819ca5d42b8eee 563.58097108869492
 seed0.seven-60keV.quantification.rows[0].supported = true
 seed0.seven-60keV.quantification.rows[0].atBound = false
 seed0.seven-60keV.quantification.rows[0].isReference = false
-seed0.seven-60keV.quantification.rows[0].kFreeRatio = 3fc0090eede9a203 0.1252764379198795
-seed0.seven-60keV.quantification.rows[0].kFreeSigma = 3f43cb78cb3c0a24 0.00060408971918974154
+seed0.seven-60keV.quantification.rows[0].kFreeRatio = 3fc0090b34dae3d8 0.12527599411785562
+seed0.seven-60keV.quantification.rows[0].kFreeSigma = 3f43c7c29ad545c0 0.00060364725292510329
 seed0.seven-60keV.quantification.rows[0].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[0].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[0].weightPercent = nil
@@ -433,8 +433,8 @@ seed0.seven-60keV.quantification.rows[0].failure = nil
 seed0.seven-60keV.quantification.rows[0].lineNote = nil
 seed0.seven-60keV.quantification.rows[1].element = "Si"
 seed0.seven-60keV.quantification.rows[1].groupID = "Si_Ka"
-seed0.seven-60keV.quantification.rows[1].net = 412d504562dc7dbf 960546.69308846432
-seed0.seven-60keV.quantification.rows[1].sigma = 4090ce8141c53537 1075.6262274564485
+seed0.seven-60keV.quantification.rows[1].net = 412d503828e5645a 960540.07987512206
+seed0.seven-60keV.quantification.rows[1].sigma = 4090d237b6adb7ef 1076.5544078010096
 seed0.seven-60keV.quantification.rows[1].supported = true
 seed0.seven-60keV.quantification.rows[1].atBound = false
 seed0.seven-60keV.quantification.rows[1].isReference = true
@@ -454,13 +454,13 @@ seed0.seven-60keV.quantification.rows[1].failure = nil
 seed0.seven-60keV.quantification.rows[1].lineNote = nil
 seed0.seven-60keV.quantification.rows[2].element = "Ti"
 seed0.seven-60keV.quantification.rows[2].groupID = "Ti_Ka"
-seed0.seven-60keV.quantification.rows[2].net = 40a64f0f40508a3a 2855.5297875565275
-seed0.seven-60keV.quantification.rows[2].sigma = 405a7f21bdd34973 105.98643441804397
+seed0.seven-60keV.quantification.rows[2].net = 40a6529958cd9e0d 2857.2995056395944
+seed0.seven-60keV.quantification.rows[2].sigma = 405a8dc9ff718c57 106.21545396889393
 seed0.seven-60keV.quantification.rows[2].supported = true
 seed0.seven-60keV.quantification.rows[2].atBound = false
 seed0.seven-60keV.quantification.rows[2].isReference = false
-seed0.seven-60keV.quantification.rows[2].kFreeRatio = 3f685a731cfa90d5 0.002972817259278763
-seed0.seven-60keV.quantification.rows[2].kFreeSigma = 3f1cdcc287d45f54 0.00011010110207043444
+seed0.seven-60keV.quantification.rows[2].kFreeRatio = 3f685e5b3e4405de 0.0029746801466223735
+seed0.seven-60keV.quantification.rows[2].kFreeSigma = 3f1cebe066ee6f1c 0.00011032635823798566
 seed0.seven-60keV.quantification.rows[2].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[2].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[2].weightPercent = nil
@@ -475,13 +475,13 @@ seed0.seven-60keV.quantification.rows[2].failure = nil
 seed0.seven-60keV.quantification.rows[2].lineNote = nil
 seed0.seven-60keV.quantification.rows[3].element = "Ni"
 seed0.seven-60keV.quantification.rows[3].groupID = "Ni_Ka"
-seed0.seven-60keV.quantification.rows[3].net = 41182729c2039c41 395722.43946689746
-seed0.seven-60keV.quantification.rows[3].sigma = 4085057c33e39745 672.68564584546459
+seed0.seven-60keV.quantification.rows[3].net = 4118272ce8af2888 395723.22723067598
+seed0.seven-60keV.quantification.rows[3].sigma = 408505a72aed5ee8 672.70662484594232
 seed0.seven-60keV.quantification.rows[3].supported = true
 seed0.seven-60keV.quantification.rows[3].atBound = false
 seed0.seven-60keV.quantification.rows[3].isReference = false
-seed0.seven-60keV.quantification.rows[3].kFreeRatio = 3fda5dd1b2c616e1 0.41197626551034544
-seed0.seven-60keV.quantification.rows[3].kFreeSigma = 3f4b628fbc7f9054 0.00083572405219146462
+seed0.seven-60keV.quantification.rows[3].kFreeRatio = 3fda5de108f36ee1 0.41197992204773298
+seed0.seven-60keV.quantification.rows[3].kFreeSigma = 3f4b636d6dea1e67 0.00083582728605420271
 seed0.seven-60keV.quantification.rows[3].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[3].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[3].weightPercent = nil
@@ -496,13 +496,13 @@ seed0.seven-60keV.quantification.rows[3].failure = nil
 seed0.seven-60keV.quantification.rows[3].lineNote = nil
 seed0.seven-60keV.quantification.rows[4].element = "Ge"
 seed0.seven-60keV.quantification.rows[4].groupID = "Ge_Ka"
-seed0.seven-60keV.quantification.rows[4].net = 41104e0110df4f25 267136.26647685684
-seed0.seven-60keV.quantification.rows[4].sigma = 40813751a10a51d2 550.91485794126697
+seed0.seven-60keV.quantification.rows[4].net = 41104e02731d1481 267136.61241561925
+seed0.seven-60keV.quantification.rows[4].sigma = 4081375994a45d87 550.91874054346488
 seed0.seven-60keV.quantification.rows[4].supported = true
 seed0.seven-60keV.quantification.rows[4].atBound = false
 seed0.seven-60keV.quantification.rows[4].isReference = false
-seed0.seven-60keV.quantification.rows[4].kFreeRatio = 3fd1cc87e260631b 0.27810856921273491
-seed0.seven-60keV.quantification.rows[4].kFreeSigma = 3f455a0bcdee6028 0.00065160347354531901
+seed0.seven-60keV.quantification.rows[4].kFreeRatio = 3fd1cc916d076758 0.27811084411006481
+seed0.seven-60keV.quantification.rows[4].kFreeSigma = 3f455ac5a7cfd16e 0.00065169001720603663
 seed0.seven-60keV.quantification.rows[4].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[4].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[4].weightPercent = nil
@@ -517,13 +517,13 @@ seed0.seven-60keV.quantification.rows[4].failure = nil
 seed0.seven-60keV.quantification.rows[4].lineNote = nil
 seed0.seven-60keV.quantification.rows[5].element = "Cu"
 seed0.seven-60keV.quantification.rows[5].groupID = "Cu_Ka"
-seed0.seven-60keV.quantification.rows[5].net = 40ed24a0fb6ab49e 59685.030690529602
-seed0.seven-60keV.quantification.rows[5].sigma = 4073a97c0ea81927 314.59278741515521
+seed0.seven-60keV.quantification.rows[5].net = 40ed24b1c9710c5f 59685.555840038454
+seed0.seven-60keV.quantification.rows[5].sigma = 4073a9a6baf0e075 314.6032056245088
 seed0.seven-60keV.quantification.rows[5].supported = true
 seed0.seven-60keV.quantification.rows[5].atBound = false
 seed0.seven-60keV.quantification.rows[5].isReference = false
-seed0.seven-60keV.quantification.rows[5].kFreeRatio = 3fafd05bb36d5a85 0.062136521961908144
-seed0.seven-60keV.quantification.rows[5].kFreeSigma = 3f35e6dbdc06a798 0.00033419482863427654
+seed0.seven-60keV.quantification.rows[5].kFreeRatio = 3fafd07c668b6270 0.062137496488223642
+seed0.seven-60keV.quantification.rows[5].kFreeSigma = 3f35e6c3a33c8d2e 0.00033418918904911082
 seed0.seven-60keV.quantification.rows[5].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[5].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[5].weightPercent = nil
@@ -538,13 +538,13 @@ seed0.seven-60keV.quantification.rows[5].failure = nil
 seed0.seven-60keV.quantification.rows[5].lineNote = nil
 seed0.seven-60keV.quantification.rows[6].element = "Ga"
 seed0.seven-60keV.quantification.rows[6].groupID = "Ga_Ka"
-seed0.seven-60keV.quantification.rows[6].net = 40dd7ed6e2cf3540 30203.357593347551
-seed0.seven-60keV.quantification.rows[6].sigma = 406887fc379a036e 196.24953823166601
+seed0.seven-60keV.quantification.rows[6].net = 40dd7ef157c0d912 30203.770981037123
+seed0.seven-60keV.quantification.rows[6].sigma = 406888464d9cdeb5 196.25858193052923
 seed0.seven-60keV.quantification.rows[6].supported = true
 seed0.seven-60keV.quantification.rows[6].atBound = false
 seed0.seven-60keV.quantification.rows[6].isReference = false
-seed0.seven-60keV.quantification.rows[6].kFreeRatio = 3fa0196b05d9dc3c 0.031443924392924733
-seed0.seven-60keV.quantification.rows[6].kFreeSigma = 3f2b1f46e0fff36d 0.00020692577572836314
+seed0.seven-60keV.quantification.rows[6].kFreeRatio = 3fa01980ba51b9ab 0.031444571250961083
+seed0.seven-60keV.quantification.rows[6].kFreeSigma = 3f2b1f27178abc80 0.0002069220752409541
 seed0.seven-60keV.quantification.rows[6].atomicPercent = nil
 seed0.seven-60keV.quantification.rows[6].atomicSigma = nil
 seed0.seven-60keV.quantification.rows[6].weightPercent = nil
@@ -571,8 +571,8 @@ seed0.seven-60keV.quantification.fit.groupIDs[8] = "O_Ka"
 seed0.seven-60keV.quantification.fit.groupIDs[9] = "Si_Ka"
 seed0.seven-60keV.quantification.fit.groupIDs[10] = "Ti_Ka"
 seed0.seven-60keV.quantification.fit.groupIDs[11] = "Ti_La"
-seed0.seven-60keV.quantification.fit.values: n 12 sum 414552d6ef6dd3f0 2794925.8705391809 fnv e1c955133e544082
-seed0.seven-60keV.quantification.fit.covariance: n 144 sum 41533d6867474dbf 5043617.6137270322 fnv b0e9ff9e385e5f97
+seed0.seven-60keV.quantification.fit.values: n 12 sum 414552d2d7609aa6 2794917.682635623 fnv 704bad5039dc5f82
+seed0.seven-60keV.quantification.fit.covariance: n 144 sum 41534659bd9d0af8 5052774.9627101347 fnv 3010ade67df4c519
 seed0.seven-60keV.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 seed0.seven-60keV.quantification.fit.supported: n 12 sum-bits c fnv 9a4297133c0b8de5
 seed0.seven-60keV.quantification.fit.atBound: n 12 sum-bits 0 fnv 243cfa845185aa5
@@ -581,7 +581,7 @@ seed0.seven-60keV.quantification.fit.escapeValues[0] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeValues[1] = nil
 seed0.seven-60keV.quantification.fit.escapeValues[2] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeValues[3] = nil
-seed0.seven-60keV.quantification.fit.escapeValues[4] = 405a4f97a3dbd927 105.24363037557178
+seed0.seven-60keV.quantification.fit.escapeValues[4] = 405a61784334dd7a 105.5229652420293
 seed0.seven-60keV.quantification.fit.escapeValues[5] = nil
 seed0.seven-60keV.quantification.fit.escapeValues[6] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeValues[7] = nil
@@ -606,32 +606,32 @@ seed0.seven-60keV.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 seed0.seven-60keV.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 seed0.seven-60keV.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 seed0.seven-60keV.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-seed0.seven-60keV.quantification.fit.backgroundCoefficients: n 16 sum 4133150a30e3665b 1250570.190969846 fnv 64df94e485bb4026
+seed0.seven-60keV.quantification.fit.backgroundCoefficients: n 16 sum 41331600b0c43407 1250816.6904938237 fnv 44424241fea367b6
 seed0.seven-60keV.quantification.fit.channels = 107..<3098
-seed0.seven-60keV.quantification.fit.model: n 2991 sum 414e6fff73af55be 3989502.9037882974 fnv 2e4d9a04160955dc
-seed0.seven-60keV.quantification.fit.residual: n 2991 sum c087ef3af55d6bd1 -765.9037883089569 fnv d866c8b94fd75edb
-seed0.seven-60keV.quantification.fit.standardizedResidual: n 2991 sum c051564b48f463dd -69.348345030462454 fnv d620e6bf55896c62
+seed0.seven-60keV.quantification.fit.model: n 2991 sum 414e6ff60b784216 3989484.0896074874 fnv 81a8656245a3f940
+seed0.seven-60keV.quantification.fit.residual: n 2991 sum c08748b78423e76b -745.089607506275 fnv 50b6a2695aa982af
+seed0.seven-60keV.quantification.fit.standardizedResidual: n 2991 sum c051cac842d65277 -71.168472966479257 fnv deca4deb49e42576
 seed0.seven-60keV.quantification.fit.negativeModelChannels = 0
 seed0.seven-60keV.quantification.fit.degreesOfFreedom = 2958
-seed0.seven-60keV.quantification.fit.reducedChiSquared = 408f1a5d75fec21d 995.29563521413695
-seed0.seven-60keV.quantification.fit.pearsonReducedChiSquared = 3ff007f3259c7cd5 1.0019408673468224
-seed0.seven-60keV.quantification.fit.deviance = 40a917fcdd3a7365 3211.9938753381598
-seed0.seven-60keV.quantification.fit.reducedDeviance = 3ff15fb5d2cefb41 1.0858667597492089
+seed0.seven-60keV.quantification.fit.reducedChiSquared = 408ef825734c228e 991.01828631859257
+seed0.seven-60keV.quantification.fit.pearsonReducedChiSquared = 3ff0069acb7e1b3e 1.001612467663747
+seed0.seven-60keV.quantification.fit.deviance = 40a919156e262b69 3212.5418559959403
+seed0.seven-60keV.quantification.fit.reducedDeviance = 3ff16078137d42ec 1.0860520135212779
 seed0.seven-60keV.quantification.fit.methodLabel = "least squares, unweighted"
 seed0.seven-60keV.quantification.fit.referenceShapesLabel = "reference shapes: none"
 seed0.seven-60keV.quantification.fit.escapeLabel = "escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven-60keV.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-seed0.seven-60keV.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+seed0.seven-60keV.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 seed0.seven-60keV.quantification.fit.exit = "converged"
 seed0.seven-60keV.quantification.fit.warnings: array 1
-seed0.seven-60keV.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.seven-60keV.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.seven-60keV.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven-60keV.quantification.fit.escapeRatios: array 12
 seed0.seven-60keV.quantification.fit.escapeRatios[0] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeRatios[1] = nil
 seed0.seven-60keV.quantification.fit.escapeRatios[2] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeRatios[3] = nil
-seed0.seven-60keV.quantification.fit.escapeRatios[4] = 3f39d1b78cb84bb8 0.00039396983331235367
+seed0.seven-60keV.quantification.fit.escapeRatios[4] = 3f39e340725ed49a 0.00039501498610700905
 seed0.seven-60keV.quantification.fit.escapeRatios[5] = nil
 seed0.seven-60keV.quantification.fit.escapeRatios[6] = 0000000000000000 0
 seed0.seven-60keV.quantification.fit.escapeRatios[7] = nil
@@ -651,16 +651,16 @@ seed0.seven-60keV.quantification.usedAxis.scale = 3f947ae147ae147b 0.02
 seed0.seven-60keV.quantification.usedAxis.size = 4096
 seed0.seven-60keV.quantification.axisLocked = true
 seed0.seven-60keV.quantification.refinement = nil
-seed0.seven-60keV.quantification.plotModel: n 4096 sum 414e6fff73af55be 3989502.9037882974 fnv 331b42eb7124f2bc
-seed0.seven-60keV.quantification.plotBackground: n 4096 sum 4128813d41d7531f 802974.62859592203 fnv fb780a7ab4b1118a
+seed0.seven-60keV.quantification.plotModel: n 4096 sum 414e6ff60b784216 3989484.0896074874 fnv 2612e19225169da0
+seed0.seven-60keV.quantification.plotBackground: n 4096 sum 4128812e00d20edf 802967.00160261604 fnv 6b378f8d7994ae8c
 seed0.seven-60keV.quantification.kSet = nil
 seed0.seven-60keV.quantification.abundanceRefusal = "The computed-k data files are not available in this build."
 seed0.seven-60keV.quantification.absorption = .off
 seed0.seven-60keV.quantification.warnings: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven-60keV.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-seed0.seven-60keV.quantification.quality = 3ff007f3259c7cd5 1.0019408673468224
+seed0.seven-60keV.quantification.quality = 3ff0069acb7e1b3e 1.001612467663747
 seed0.seven-60keV.quantification.footerLines: array 8
-seed0.seven-60keV.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
+seed0.seven-60keV.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven-60keV.quantification.footerLines[1] = "energy axis: the file's (locked)"
 seed0.seven-60keV.quantification.footerLines[2] = "beam 200 kV · typed"
 seed0.seven-60keV.quantification.footerLines[3] = "fit range 0.2–60 keV (typed; axis to 79.97 keV) · 1 px pooled (synthetic)"
@@ -686,7 +686,7 @@ seed0.seven-60keV.quantification.fitSettings.background.continuum.edges[0] = 3ff
 seed0.seven-60keV.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 seed0.seven-60keV.quantification.fitSettings.background.continuum.nonNegative = true
 seed0.seven-60keV.quantification.fitSettings.background.continuum.efficiency = nil
-seed0.seven-60keV.quantification.fitSettings.background.continuum.edgeStep = .sharp
+seed0.seven-60keV.quantification.fitSettings.background.continuum.edgeStep = .broadened
 seed0.seven-60keV.quantification.fitSettings.escapePeaks = true
 seed0.seven-60keV.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven-60keV.quantification.fitSettings.method = .leastSquares
@@ -705,7 +705,7 @@ seed0.seven-60keV.quantification.unlistedCheckPending = false
 seed0.seven-60keV.quantification.abundanceCaveat = nil
 seed0.seven-60keV.quantification.appliedSumEscape = nil
 seed0.seven-60keV.quantification.continuumDeadLayerMicrons = nil
-seed0.seven-60keV.csv-fnv = b4f647ee0ab928a3
+seed0.seven-60keV.csv-fnv = 3f1de22086af1796
 seed0.seven-60keV.rangeSensitivity = nil
 seed0.four.quantification.method.version = 1
 seed0.four.quantification.method.estimator = .leastSquares
@@ -738,26 +738,26 @@ seed0.four.quantification.method.fitToKeV = nil
 seed0.four.quantification.rows: array 4
 seed0.four.quantification.rows[0].element = "O"
 seed0.four.quantification.rows[0].groupID = "O_Ka"
-seed0.four.quantification.rows[0].net = 410072e0ffd7bda3 134748.12492321161
-seed0.four.quantification.rows[0].sigma = 407a79a834ecfd2b 423.60356609891704
+seed0.four.quantification.rows[0].net = 410072e05827d1ff 134748.04304470119
+seed0.four.quantification.rows[0].sigma = 407a79a87f152bb6 423.60363682050536
 seed0.four.quantification.rows[0].supported = true
 seed0.four.quantification.rows[0].atBound = false
 seed0.four.quantification.rows[0].isReference = false
-seed0.four.quantification.rows[0].kFreeRatio = 3fc1ef7868aea8ca 0.14012055503309845
-seed0.four.quantification.rows[0].kFreeSigma = 3f3eaf92a568134d 0.00046822862842104269
-seed0.four.quantification.rows[0].atomicPercent = 402827591f12439f 12.076851817111502
-seed0.four.quantification.rows[0].atomicSigma = 4001944ac5bbb27c 2.1974082420259133
-seed0.four.quantification.rows[0].weightPercent = 4016f0d3216581f4 5.7351803987698879
-seed0.four.quantification.rows[0].weightSigma = 3ff2d4da7ec15c88 1.1769661857013336
+seed0.four.quantification.rows[0].kFreeRatio = 3fc1f2095856a945 0.14019886792568506
+seed0.four.quantification.rows[0].kFreeSigma = 3f3eb5a2e079c7c2 0.00046859003530308138
+seed0.four.quantification.rows[0].atomicPercent = 40282949696714e0 12.080638212044903
+seed0.four.quantification.rows[0].atomicSigma = 400195ad42b6cebe 2.198084374622197
+seed0.four.quantification.rows[0].weightPercent = 4016f21969ad05be 5.7364250671247969
+seed0.four.quantification.rows[0].weightSigma = 3ff2d62bff7c6f55 1.1772880535053976
 seed0.four.quantification.rows[0].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[0].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[0].atomicTerms.relative.counting = 3f67a900470b5c7e 0.0028882031841522262
-seed0.four.quantification.rows[0].atomicTerms.relative.k = 3fc749745342d89b 0.18192915025219211
+seed0.four.quantification.rows[0].atomicTerms.relative.counting = 3f67a95ae78d023d 0.0028883719900536773
+seed0.four.quantification.rows[0].atomicTerms.relative.k = 3fc7496b681d6326 0.181928087079336
 seed0.four.quantification.rows[0].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[0].weightTerms.relative: dict 4
 seed0.four.quantification.rows[0].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[0].weightTerms.relative.counting = 3f69743102f6c094 0.003107162214028911
-seed0.four.quantification.rows[0].weightTerms.relative.k = 3fca43d5c7c5c8c4 0.20519516233941293
+seed0.four.quantification.rows[0].weightTerms.relative.counting = 3f69747e494ac00b 0.003107306149409799
+seed0.four.quantification.rows[0].weightTerms.relative.k = 3fca4436edd89dd7 0.20520674336988406
 seed0.four.quantification.rows[0].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[0].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[0].absorptionSpreadWeight = nil
@@ -767,26 +767,26 @@ seed0.four.quantification.rows[0].failure = nil
 seed0.four.quantification.rows[0].lineNote = nil
 seed0.four.quantification.rows[1].element = "Si"
 seed0.four.quantification.rows[1].groupID = "Si_Ka"
-seed0.four.quantification.rows[1].net = 412d58f507dc03e7 961658.5153504581
-seed0.four.quantification.rows[1].sigma = 409106490a893abc 1089.5713292543505
+seed0.four.quantification.rows[1].net = 412d54c187238ef3 961120.76394316403
+seed0.four.quantification.rows[1].sigma = 40910c0806bbf4c8 1091.0078381889489
 seed0.four.quantification.rows[1].supported = true
 seed0.four.quantification.rows[1].atBound = false
 seed0.four.quantification.rows[1].isReference = true
 seed0.four.quantification.rows[1].kFreeRatio = 3ff0000000000000 1
 seed0.four.quantification.rows[1].kFreeSigma = nil
-seed0.four.quantification.rows[1].atomicPercent = 405035d9260f67db 64.841378703159918
-seed0.four.quantification.rows[1].atomicSigma = 400b13c7f37cb6fd 3.3846587202486931
-seed0.four.quantification.rows[1].weightPercent = 404b06da064ee81f 54.053528584030794
-seed0.four.quantification.rows[1].weightSigma = 4011ad7b6a240a95 4.4194161018846403
+seed0.four.quantification.rows[1].atomicPercent = 405034d49effee11 64.825477361613835
+seed0.four.quantification.rows[1].atomicSigma = 400b156b1100a3ac 3.3854581192321884
+seed0.four.quantification.rows[1].weightPercent = 404b047cd40afdff 54.035059457175514
+seed0.four.quantification.rows[1].weightSigma = 4011ade1489ab69e 4.4198047012738737
 seed0.four.quantification.rows[1].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[1].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[1].atomicTerms.relative.counting = 3f469122c787e23b 0.0006886882611630349
-seed0.four.quantification.rows[1].atomicTerms.relative.k = 3faab93d3520fb97 0.052194512114957785
+seed0.four.quantification.rows[1].atomicTerms.relative.counting = 3f46984f4caf4205 0.00068954345749189293
+seed0.four.quantification.rows[1].atomicTerms.relative.k = 3faabc885105c456 0.052219638719983294
 seed0.four.quantification.rows[1].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[1].weightTerms.relative: dict 4
 seed0.four.quantification.rows[1].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[1].weightTerms.relative.counting = 3f4da0985dc3705d 0.00090415420302348735
-seed0.four.quantification.rows[1].weightTerms.relative.k = 3fb4ede52dfdc1f6 0.081754993179636276
+seed0.four.quantification.rows[1].weightTerms.relative.counting = 3f4da9fb69f723c4 0.0009052732092921169
+seed0.four.quantification.rows[1].weightTerms.relative.k = 3fb4f03282bb4541 0.081790120045543993
 seed0.four.quantification.rows[1].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[1].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[1].absorptionSpreadWeight = nil
@@ -797,12 +797,12 @@ seed0.four.quantification.rows[1].lineNote = nil
 seed0.four.quantification.rows[2].element = "Ti"
 seed0.four.quantification.rows[2].groupID = "Ti_Ka"
 seed0.four.quantification.rows[2].net = 0000000000000000 0
-seed0.four.quantification.rows[2].sigma = 405acf5ea0066303 107.24015045760829
+seed0.four.quantification.rows[2].sigma = 405b0b9abb14c5e6 108.18131901768319
 seed0.four.quantification.rows[2].supported = true
 seed0.four.quantification.rows[2].atBound = true
 seed0.four.quantification.rows[2].isReference = false
 seed0.four.quantification.rows[2].kFreeRatio = 0000000000000000 0
-seed0.four.quantification.rows[2].kFreeSigma = 3f1d3bb36c84a14d 0.00011151583305902165
+seed0.four.quantification.rows[2].kFreeSigma = 3f1d819a90a0645e 0.00011255746736117805
 seed0.four.quantification.rows[2].atomicPercent = 0000000000000000 0
 seed0.four.quantification.rows[2].atomicSigma = 0000000000000000 0
 seed0.four.quantification.rows[2].weightPercent = 0000000000000000 0
@@ -825,26 +825,26 @@ seed0.four.quantification.rows[2].failure = nil
 seed0.four.quantification.rows[2].lineNote = nil
 seed0.four.quantification.rows[3].element = "Ni"
 seed0.four.quantification.rows[3].groupID = "Ni_Ka"
-seed0.four.quantification.rows[3].net = 411770298624487b 384010.38099778414
-seed0.four.quantification.rows[3].sigma = 4085133b2bf1e553 674.40389241200535
+seed0.four.quantification.rows[3].net = 4117716d1fe5a512 384091.28114946291
+seed0.four.quantification.rows[3].sigma = 408513881c1ae9d4 674.44145985628211
 seed0.four.quantification.rows[3].supported = true
 seed0.four.quantification.rows[3].atBound = false
 seed0.four.quantification.rows[3].isReference = false
-seed0.four.quantification.rows[3].kFreeRatio = 3fd98e7969036347 0.39932093863676638
-seed0.four.quantification.rows[3].kFreeSigma = 3f4b791b3cd4ba47 0.00083841161691628689
-seed0.four.quantification.rows[3].atomicPercent = 403714eed8393ec7 23.081769479728589
-seed0.four.quantification.rows[3].atomicSigma = 400cd0fe5aa01b84 3.6020476417647291
-seed0.four.quantification.rows[3].weightPercent = 40441b0b958467a3 40.211291017199322
-seed0.four.quantification.rows[3].weightSigma = 40137289ce62158f 4.8618538138738492
+seed0.four.quantification.rows[3].kFreeRatio = 3fd993838e30c78d 0.39962853322787667
+seed0.four.quantification.rows[3].kFreeSigma = 3f4b832655a2e916 0.00083960887720671801
+seed0.four.quantification.rows[3].atomicPercent = 40371808cf4cbd4e 23.093884426341269
+seed0.four.quantification.rows[3].atomicSigma = 400cd3cd92d8781a 3.6034194443045751
+seed0.four.quantification.rows[3].weightPercent = 40441d3ffebf6148 40.22851547569968
+seed0.four.quantification.rows[3].weightSigma = 401373495633eba8 4.862584444922426
 seed0.four.quantification.rows[3].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[3].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[3].atomicTerms.relative.counting = 3f5a12fb0c0705ee 0.0015914394026456074
-seed0.four.quantification.rows[3].atomicTerms.relative.k = 3fc3f9602ed156ca 0.15604784284612655
+seed0.four.quantification.rows[3].atomicTerms.relative.counting = 3f5a154800bd0227 0.0015919879105724761
+seed0.four.quantification.rows[3].atomicTerms.relative.k = 3fc3f8a3accc54f8 0.15602537095461577
 seed0.four.quantification.rows[3].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[3].weightTerms.relative: dict 4
 seed0.four.quantification.rows[3].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[3].weightTerms.relative.counting = 3f5445c0119c86fa 0.0012373328849623597
-seed0.four.quantification.rows[3].weightTerms.relative.k = 3fbef364004fc520 0.12090134627921545
+seed0.four.quantification.rows[3].weightTerms.relative.counting = 3f54475bb2fca5a1 0.0012377162456210582
+seed0.four.quantification.rows[3].weightTerms.relative.k = 3fbef13015389b6a 0.12086773412793908
 seed0.four.quantification.rows[3].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[3].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[3].absorptionSpreadWeight = nil
@@ -860,14 +860,14 @@ seed0.four.quantification.fit.groupIDs[2] = "O_Ka"
 seed0.four.quantification.fit.groupIDs[3] = "Si_Ka"
 seed0.four.quantification.fit.groupIDs[4] = "Ti_Ka"
 seed0.four.quantification.fit.groupIDs[5] = "Ti_La"
-seed0.four.quantification.fit.values: n 6 sum 4136bcb5debf0ebc 1490101.8701028069 fnv e9504855c542ff07
-seed0.four.quantification.fit.values[0] = 411770298624487b 384010.38099778414
+seed0.four.quantification.fit.values: n 6 sum 4136baed151f3ea5 1489645.0825080064 fnv 74e65ec394615117
+seed0.four.quantification.fit.values[0] = 4117716d1fe5a512 384091.28114946291
 seed0.four.quantification.fit.values[1] = 0000000000000000 0
-seed0.four.quantification.fit.values[2] = 410072e0ffd7bda3 134748.12492321161
-seed0.four.quantification.fit.values[3] = 412d58f507dc03e7 961658.5153504581
+seed0.four.quantification.fit.values[2] = 410072e05827d1ff 134748.04304470119
+seed0.four.quantification.fit.values[3] = 412d54c187238ef3 961120.76394316403
 seed0.four.quantification.fit.values[4] = 0000000000000000 0
-seed0.four.quantification.fit.values[5] = 40c2ea6ca6817af0 9684.8488313532143
-seed0.four.quantification.fit.covariance: n 36 sum 413fc89953fc1d2b 2082969.3280657034 fnv 97bbc2166e93c8af
+seed0.four.quantification.fit.values[5] = 40c2ea7f4789d34d 9684.9943706781141
+seed0.four.quantification.fit.covariance: n 36 sum 413fd1aa2231356a 2085290.1335633644 fnv ec3d10f6bcac348c
 seed0.four.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 seed0.four.quantification.fit.supported: n 6 sum-bits 6 fnv e78b9a1f4dd1d485
 seed0.four.quantification.fit.atBound: n 6 sum-bits 2 fnv 50ffa157bd1b5485
@@ -876,7 +876,7 @@ seed0.four.quantification.fit.escapeValues[0] = 0000000000000000 0
 seed0.four.quantification.fit.escapeValues[1] = nil
 seed0.four.quantification.fit.escapeValues[2] = nil
 seed0.four.quantification.fit.escapeValues[3] = nil
-seed0.four.quantification.fit.escapeValues[4] = 40896ec8258bbca1 813.84772786301994
+seed0.four.quantification.fit.escapeValues[4] = 40810d5f65230899 545.67157962198246
 seed0.four.quantification.fit.escapeValues[5] = nil
 seed0.four.quantification.fit.backgroundNames: array 16
 seed0.four.quantification.fit.backgroundNames[0] = "continuum s0 t^0"
@@ -895,25 +895,25 @@ seed0.four.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 seed0.four.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 seed0.four.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 seed0.four.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-seed0.four.quantification.fit.backgroundCoefficients: n 16 sum 415e936db1302a36 8015286.7685647514 fnv 69dff6bc0e2ecbb9
+seed0.four.quantification.fit.backgroundCoefficients: n 16 sum 415e96a57b4d3a71 8018581.9265886405 fnv d0f505fab5f79974
 seed0.four.quantification.fit.channels = 107..<1098
-seed0.four.quantification.fit.model: n 991 sum 41501dbc7e83e8a4 4224753.9768010713 fnv 357dca7656b10069
-seed0.four.quantification.fit.residual: n 991 sum c10f1d47d07d155a -254888.97680107766 fnv bafbc846f5c1a72
-seed0.four.quantification.fit.standardizedResidual: n 991 sum c0af9f682fa837a3 -4047.7034885948101 fnv e5e528b3d4a6ca6f
+seed0.four.quantification.fit.model: n 991 sum 415020fcfd219da8 4228083.9551767483 fnv c8e121e4bdde427e
+seed0.four.quantification.fit.residual: n 991 sum c10f8547a433b5c2 -258216.95517675398 fnv 8b33b56bc3183b0f
+seed0.four.quantification.fit.standardizedResidual: n 991 sum c0b0ab26797803c5 -4267.1502909669116 fnv 315cd585b8d143d5
 seed0.four.quantification.fit.negativeModelChannels = 0
 seed0.four.quantification.fit.degreesOfFreedom = 967
-seed0.four.quantification.fit.reducedChiSquared = 41858934a7469b14 45164180.909475476
-seed0.four.quantification.fit.pearsonReducedChiSquared = 40b4fd23611b3aab 5373.1382004755242
-seed0.four.quantification.fit.deviance = 4141a8e7b4c89529 2314703.4123712969
-seed0.four.quantification.fit.reducedDeviance = 40a2b364061fdb1b 2393.6953592257464
+seed0.four.quantification.fit.reducedChiSquared = 4185889d299bd826 45159333.201095864
+seed0.four.quantification.fit.pearsonReducedChiSquared = 40b4dc743a7b2e32 5340.4540173518926
+seed0.four.quantification.fit.deviance = 4141999325f0507b 2306854.2963963128
+seed0.four.quantification.fit.reducedDeviance = 40a2a32821d244d0 2385.5783830365181
 seed0.four.quantification.fit.methodLabel = "least squares, unweighted"
 seed0.four.quantification.fit.referenceShapesLabel = "reference shapes: none"
 seed0.four.quantification.fit.escapeLabel = "escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 seed0.four.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-seed0.four.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+seed0.four.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 seed0.four.quantification.fit.exit = "converged"
 seed0.four.quantification.fit.warnings: array 1
-seed0.four.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.four.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.four.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.fit.escapeRatios: array 6
 seed0.four.quantification.fit.escapeRatios[0] = 0000000000000000 0
@@ -934,8 +934,8 @@ seed0.four.quantification.usedAxis.scale = 3f947ae147ae147b 0.02
 seed0.four.quantification.usedAxis.size = 4096
 seed0.four.quantification.axisLocked = true
 seed0.four.quantification.refinement = nil
-seed0.four.quantification.plotModel: n 4096 sum 41501dbc7e83e8a4 4224753.9768010713 fnv 11532a28fd96b589
-seed0.four.quantification.plotBackground: n 4096 sum 414428066c925c61 2641932.8482165788 fnv 5bebb16bc511c4c9
+seed0.four.quantification.plotModel: n 4096 sum 415020fcfd219da8 4228083.9551767483 fnv 9a1d413114ee80de
+seed0.four.quantification.plotBackground: n 4096 sum 41443003bbb79abd 2646023.466540663 fnv b151048f7ab1e745
 seed0.four.quantification.kSet.kind = .computed
 seed0.four.quantification.kSet.elements: array 4
 seed0.four.quantification.kSet.elements[0] = "O"
@@ -959,14 +959,14 @@ seed0.four.quantification.abundanceRefusal = nil
 seed0.four.quantification.absorption = .off
 seed0.four.quantification.warnings: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-seed0.four.quantification.quality = 40b4fd23611b3aab 5373.1382004755242
+seed0.four.quantification.quality = 40b4dc743a7b2e32 5340.4540173518926
 seed0.four.quantification.footerLines: array 9
-seed0.four.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
+seed0.four.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 seed0.four.quantification.footerLines[1] = "energy axis: the file's (locked)"
 seed0.four.quantification.footerLines[2] = "beam 200 kV · typed"
 seed0.four.quantification.footerLines[3] = "fit range 0.2–20 keV (default; axis to 79.97 keV) · 1 px pooled (synthetic)"
 seed0.four.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-seed0.four.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 5373 (Pearson)"
+seed0.four.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 5340 (Pearson)"
 seed0.four.quantification.footerLines[6] = "k: computed: Bote-Salvat 2008 (NIST EPQ tables, PRA 77 042701), edges DHS xionUis.csv; not Velox's Brown-Powell default; omega: Krause 1979 (NIST EPQ Krause1979.csv); epsilon: EPQ getDefaultSDDProperties (Au 0.0 nm, Al 10.0 nm, Si dead layer 0.0 µm, Si 450.0 µm); generic SDD model, not a measured calibration of this detector; FFAST MACs; relative to Si; beam 200.0 keV; UNVALIDATED (EPQ 249dd3f8 + Krause 1979 + FFAST); σ_k 20 % flat, 0 on the reference (Si)"
 seed0.four.quantification.footerLines[7] = "k-free ratio: net / net(Si)"
 seed0.four.quantification.footerLines[8] = "absorption correction: off"
@@ -985,7 +985,7 @@ seed0.four.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f21
 seed0.four.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 seed0.four.quantification.fitSettings.background.continuum.nonNegative = true
 seed0.four.quantification.fitSettings.background.continuum.efficiency = nil
-seed0.four.quantification.fitSettings.background.continuum.edgeStep = .sharp
+seed0.four.quantification.fitSettings.background.continuum.edgeStep = .broadened
 seed0.four.quantification.fitSettings.escapePeaks = true
 seed0.four.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.fitSettings.method = .leastSquares
@@ -1004,39 +1004,39 @@ seed0.four.quantification.unlistedCheckPending = false
 seed0.four.quantification.abundanceCaveat = nil
 seed0.four.quantification.appliedSumEscape = nil
 seed0.four.quantification.continuumDeadLayerMicrons = nil
-seed0.four.csv-fnv = 527d12db2afd525d
+seed0.four.csv-fnv = b6f7747c67428fa7
 seed0.four.rangeSensitivity.alternativeToKeV = 4053fdf036df3a38 79.967786520000004
 seed0.four.rangeSensitivity.moves: array 4
 seed0.four.rangeSensitivity.moves[0].element = "O"
 seed0.four.rangeSensitivity.moves[0].group = "O_Ka"
-seed0.four.rangeSensitivity.moves[0].before = 410072e0ffd7bda3 134748.12492321161
-seed0.four.rangeSensitivity.moves[0].sigma = 407a79a834ecfd2b 423.60356609891704
-seed0.four.rangeSensitivity.moves[0].after = 410072e0ffd7bc8b 134748.12492320346
+seed0.four.rangeSensitivity.moves[0].before = 410072e05827d1ff 134748.04304470119
+seed0.four.rangeSensitivity.moves[0].sigma = 407a79a87f152bb6 423.60363682050536
+seed0.four.rangeSensitivity.moves[0].after = 410072e1ab1b8010 134748.2085485463
 seed0.four.rangeSensitivity.moves[1].element = "Si"
 seed0.four.rangeSensitivity.moves[1].group = "Si_Ka"
-seed0.four.rangeSensitivity.moves[1].before = 412d58f507dc03e7 961658.5153504581
-seed0.four.rangeSensitivity.moves[1].sigma = 409106490a893abc 1089.5713292543505
-seed0.four.rangeSensitivity.moves[1].after = 412d667f2d6828d1 963391.58868529845
+seed0.four.rangeSensitivity.moves[1].before = 412d54c187238ef3 961120.76394316403
+seed0.four.rangeSensitivity.moves[1].sigma = 40910c0806bbf4c8 1091.0078381889489
+seed0.four.rangeSensitivity.moves[1].after = 412d641486917a16 963082.26282865065
 seed0.four.rangeSensitivity.moves[2].element = "Ti"
 seed0.four.rangeSensitivity.moves[2].group = "Ti_Ka"
 seed0.four.rangeSensitivity.moves[2].before = 0000000000000000 0
-seed0.four.rangeSensitivity.moves[2].sigma = 405acf5ea0066303 107.24015045760829
+seed0.four.rangeSensitivity.moves[2].sigma = 405b0b9abb14c5e6 108.18131901768319
 seed0.four.rangeSensitivity.moves[2].after = 0000000000000000 0
 seed0.four.rangeSensitivity.moves[3].element = "Ni"
 seed0.four.rangeSensitivity.moves[3].group = "Ni_Ka"
-seed0.four.rangeSensitivity.moves[3].before = 411770298624487b 384010.38099778414
-seed0.four.rangeSensitivity.moves[3].sigma = 4085133b2bf1e553 674.40389241200535
-seed0.four.rangeSensitivity.moves[3].after = 4117c12b7d9b3fe8 389194.87266254285
+seed0.four.rangeSensitivity.moves[3].before = 4117716d1fe5a512 384091.28114946291
+seed0.four.rangeSensitivity.moves[3].sigma = 408513881c1ae9d4 674.44145985628211
+seed0.four.rangeSensitivity.moves[3].after = 4117c15d66dead6c 389207.35045882198
 seed0.four.rangeSensitivity.failure = nil
 seed0.four.unlistedProposal.candidates: array 35
 seed0.four.unlistedProposal.candidates[0].element = "Ge"
 seed0.four.unlistedProposal.candidates[0].group = "Ge_Ka"
 seed0.four.unlistedProposal.candidates[0].energyKeV = 4023c5d63886594b 9.8864000000000001
-seed0.four.unlistedProposal.candidates[0].net = 41104af3e5234541 266940.97376735887
-seed0.four.unlistedProposal.candidates[0].sigma = 4081584a08b9bf7d 555.03614945521952
-seed0.four.unlistedProposal.candidates[0].sigmaZero = 404b17f887e351df 54.187272058483124
-seed0.four.unlistedProposal.candidates[0].criticalLevel = 4056485410e3d391 89.130130980002164
-seed0.four.unlistedProposal.candidates[0].detectionLimit = 40669ee7e0c17b76 180.96580541409975
+seed0.four.unlistedProposal.candidates[0].net = 411049cdc388fb6a 266867.44095223269
+seed0.four.unlistedProposal.candidates[0].sigma = 4081588dd361b77a 555.06925083485771
+seed0.four.unlistedProposal.candidates[0].sigmaZero = 404b9f72d1dd515f 55.245691521706924
+seed0.four.unlistedProposal.candidates[0].criticalLevel = 4056b7bfb5db61c2 90.871076072921852
+seed0.four.unlistedProposal.candidates[0].detectionLimit = 40670e5385b909a7 184.44769559993912
 seed0.four.unlistedProposal.candidates[0].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[0].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[0].holeRegionNote = nil
@@ -1047,11 +1047,11 @@ seed0.four.unlistedProposal.candidates[0].unconfirmable = false
 seed0.four.unlistedProposal.candidates[1].element = "Ga"
 seed0.four.unlistedProposal.candidates[1].group = "Ga_La"
 seed0.four.unlistedProposal.candidates[1].energyKeV = 3ff1916872b020c5 1.0980000000000001
-seed0.four.unlistedProposal.candidates[1].net = 41124e507cb5ebc7 299924.12178772356
-seed0.four.unlistedProposal.candidates[1].sigma = 408a91d9dcabf1f2 850.23137792904004
-seed0.four.unlistedProposal.candidates[1].sigmaZero = 407d940ee1e131de 473.25363338438717
-seed0.four.unlistedProposal.candidates[1].criticalLevel = 40885376b14a18c4 778.43295534027175
-seed0.four.unlistedProposal.candidates[1].detectionLimit = 40985e492b45cdc1 1559.571454134639
+seed0.four.unlistedProposal.candidates[1].net = 41124dfaa286d6ca 299902.65871749504
+seed0.four.unlistedProposal.candidates[1].sigma = 408a79ef44862f65 847.24182991821419
+seed0.four.unlistedProposal.candidates[1].sigmaZero = 407d6469ecd1c8cf 470.27586061427149
+seed0.four.unlistedProposal.candidates[1].criticalLevel = 40882c47967c9010 773.53495499910969
+seed0.four.unlistedProposal.candidates[1].detectionLimit = 4098371a1078450d 1549.7754534523149
 seed0.four.unlistedProposal.candidates[1].conflicts: array 1
 seed0.four.unlistedProposal.candidates[1].conflicts[0].id = "ga-fib"
 seed0.four.unlistedProposal.candidates[1].conflicts[0].kind = .fibContamination
@@ -1072,11 +1072,11 @@ seed0.four.unlistedProposal.candidates[1].unconfirmable = false
 seed0.four.unlistedProposal.candidates[2].element = "Cu"
 seed0.four.unlistedProposal.candidates[2].group = "Cu_Ka"
 seed0.four.unlistedProposal.candidates[2].energyKeV = 402018793dd97f63 8.0478000000000005
-seed0.four.unlistedProposal.candidates[2].net = 40ed124e96f699c3 59538.455928135219
-seed0.four.unlistedProposal.candidates[2].sigma = 4073f78015ce7148 319.46877079621891
-seed0.four.unlistedProposal.candidates[2].sigmaZero = 405ec48c382054b8 123.07105830342596
-seed0.four.unlistedProposal.candidates[2].criticalLevel = 40694de2513a5d33 202.43387662314635
-seed0.four.unlistedProposal.candidates[2].detectionLimit = 4079792c39293125 407.57329670038808
+seed0.four.unlistedProposal.candidates[2].net = 40ecff852541abdb 59388.160797916084
+seed0.four.unlistedProposal.candidates[2].sigma = 4073fae52e270665 319.68095221752293
+seed0.four.unlistedProposal.candidates[2].sigmaZero = 405f1afeb5348922 124.42179613237798
+seed0.four.unlistedProposal.candidates[2].criticalLevel = 406994fb06462b05 204.65564264015862
+seed0.four.unlistedProposal.candidates[2].detectionLimit = 4079c044ee34fef7 412.01682873441263
 seed0.four.unlistedProposal.candidates[2].conflicts: array 2
 seed0.four.unlistedProposal.candidates[2].conflicts[0].id = "sum-Ni+O sum-Cu"
 seed0.four.unlistedProposal.candidates[2].conflicts[0].kind = .sumPeak
@@ -1108,11 +1108,11 @@ seed0.four.unlistedProposal.candidates[2].unconfirmable = false
 seed0.four.unlistedProposal.candidates[3].element = "Pr"
 seed0.four.unlistedProposal.candidates[3].group = "Pr_Ma"
 seed0.four.unlistedProposal.candidates[3].energyKeV = 3fec985f06f69446 0.89359999999999995
-seed0.four.unlistedProposal.candidates[3].net = 40ed220dd3b7e979 59664.432094532014
-seed0.four.unlistedProposal.candidates[3].sigma = 40772db285c1fab2 370.85608459256321
-seed0.four.unlistedProposal.candidates[3].sigmaZero = 4073016430f6c141 304.08696075810082
-seed0.four.unlistedProposal.candidates[3].criticalLevel = 407f42db4d15f647 500.17854031161227
-seed0.four.unlistedProposal.candidates[3].detectionLimit = 408f5880410d6040 1003.0626240773199
+seed0.four.unlistedProposal.candidates[3].net = 40ed15382bb8840b 59561.755337007424
+seed0.four.unlistedProposal.candidates[3].sigma = 407728fc60975f5a 370.56161555414076
+seed0.four.unlistedProposal.candidates[3].sigmaZero = 4072fcfb67b29844 303.81137819064702
+seed0.four.unlistedProposal.candidates[3].criticalLevel = 407f3b9a9cf0abae 499.7252473260113
+seed0.four.unlistedProposal.candidates[3].detectionLimit = 408f513f90e815a7 1002.156038106118
 seed0.four.unlistedProposal.candidates[3].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[3].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[3].holeRegionNote = nil
@@ -1123,11 +1123,11 @@ seed0.four.unlistedProposal.candidates[3].unconfirmable = false
 seed0.four.unlistedProposal.candidates[4].element = "Eu"
 seed0.four.unlistedProposal.candidates[4].group = "Eu_Ma"
 seed0.four.unlistedProposal.candidates[4].energyKeV = 3ff195e9e1b089a0 1.0991
-seed0.four.unlistedProposal.candidates[4].net = 40f252b6c2632c7a 75051.422457860695
-seed0.four.unlistedProposal.candidates[4].sigma = 4086bec9f430a987 727.84861028687817
-seed0.four.unlistedProposal.candidates[4].sigmaZero = 408209b6e8f77b7d 577.2143115362702
-seed0.four.unlistedProposal.candidates[4].criticalLevel = 408dab76e4f10543 949.43305385873134
-seed0.four.unlistedProposal.candidates[4].detectionLimit = 409db6495eecba40 1901.5716511715582
+seed0.four.unlistedProposal.candidates[4].net = 40f2507137ad8a20 75015.076093234587
+seed0.four.unlistedProposal.candidates[4].sigma = 4086be0cfb6af5f9 727.75633891642713
+seed0.four.unlistedProposal.candidates[4].sigmaZero = 408209678d2648b6 577.17556219014546
+seed0.four.unlistedProposal.candidates[4].criticalLevel = 408daaf45c655a79 949.36931685621596
+seed0.four.unlistedProposal.candidates[4].detectionLimit = 409db5c6d6610f76 1901.4441771665274
 seed0.four.unlistedProposal.candidates[4].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[4].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[4].holeRegionNote = nil
@@ -1138,11 +1138,11 @@ seed0.four.unlistedProposal.candidates[4].unconfirmable = false
 seed0.four.unlistedProposal.candidates[5].element = "Sm"
 seed0.four.unlistedProposal.candidates[5].group = "Sm_Ma"
 seed0.four.unlistedProposal.candidates[5].energyKeV = 3ff0af4f0d844d01 1.0427999999999999
-seed0.four.unlistedProposal.candidates[5].net = 40d678fe0ccda928 23011.969531455223
-seed0.four.unlistedProposal.candidates[5].sigma = 4081e744731f2984 572.90842270226904
-seed0.four.unlistedProposal.candidates[5].sigmaZero = 4080de8f8ed84c6c 539.82009667380544
-seed0.four.unlistedProposal.candidates[5].criticalLevel = 408bbf667d6c994d 887.92504391520345
-seed0.four.unlistedProposal.candidates[5].detectionLimit = 409bca38f7684e4a 1778.5556312845024
+seed0.four.unlistedProposal.candidates[5].net = 40d6c91ede1800e8 23332.482305527577
+seed0.four.unlistedProposal.candidates[5].sigma = 4081ca88bad78f19 569.31676262288522
+seed0.four.unlistedProposal.candidates[5].sigmaZero = 4080bf733acd1cce 535.93126449817805
+seed0.four.unlistedProposal.candidates[5].criticalLevel = 408b8c3a55ed7b8d 881.52848420651719
+seed0.four.unlistedProposal.candidates[5].detectionLimit = 409b970ccfe9308a 1765.7625118671299
 seed0.four.unlistedProposal.candidates[5].conflicts: array 1
 seed0.four.unlistedProposal.candidates[5].conflicts[0].id = "sum-O+O sum-Sm"
 seed0.four.unlistedProposal.candidates[5].conflicts[0].kind = .sumPeak
@@ -1164,11 +1164,11 @@ seed0.four.unlistedProposal.candidates[5].unconfirmable = false
 seed0.four.unlistedProposal.candidates[6].element = "Rb"
 seed0.four.unlistedProposal.candidates[6].group = "Rb_La"
 seed0.four.unlistedProposal.candidates[6].energyKeV = 3ffb1b089a027525 1.6940999999999999
-seed0.four.unlistedProposal.candidates[6].net = 40d7cfab1c9229a7 24382.673618832279
-seed0.four.unlistedProposal.candidates[6].sigma = 4089effa748353d0 829.99729254340673
-seed0.four.unlistedProposal.candidates[6].sigmaZero = 40884614911c597b 776.76004240177224
-seed0.four.unlistedProposal.candidates[6].criticalLevel = 4093f6a054ad34a2 1277.6565730155348
-seed0.four.unlistedProposal.candidates[6].detectionLimit = 40a3fc0991ab0f20 2558.0186894851649
+seed0.four.unlistedProposal.candidates[6].net = 40d7192ed8e64e76 23652.731988503096
+seed0.four.unlistedProposal.candidates[6].sigma = 408987c614d0d7f1 816.97171939047814
+seed0.four.unlistedProposal.candidates[6].sigmaZero = 4087dbcfa732f193 763.47639312553144
+seed0.four.unlistedProposal.candidates[6].criticalLevel = 40939f3a47bfa72e 1255.8069143243588
+seed0.four.unlistedProposal.candidates[6].detectionLimit = 40a3a4a384bd81ac 2514.3193721028128
 seed0.four.unlistedProposal.candidates[6].conflicts: array 1
 seed0.four.unlistedProposal.candidates[6].conflicts[0].id = "sum-Ge+O sum-Rb"
 seed0.four.unlistedProposal.candidates[6].conflicts[0].kind = .sumPeak
@@ -1186,16 +1186,16 @@ seed0.four.unlistedProposal.candidates[6].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[6].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[6].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[6].familyNote = nil
-seed0.four.unlistedProposal.candidates[6].possibleReason = "The peak at 1.748 keV went to Ta, which explains it better (gain there 111 against 77)."
+seed0.four.unlistedProposal.candidates[6].possibleReason = "The peak at 1.748 keV went to Ta, which explains it better (gain there 117 against 79)."
 seed0.four.unlistedProposal.candidates[6].unconfirmable = false
 seed0.four.unlistedProposal.candidates[7].element = "Nd"
 seed0.four.unlistedProposal.candidates[7].group = "Nd_Ma"
 seed0.four.unlistedProposal.candidates[7].energyKeV = 3fee161e4f765fd9 0.94020000000000004
-seed0.four.unlistedProposal.candidates[7].net = 40c98ebdbf9eccb4 13085.482410287812
-seed0.four.unlistedProposal.candidates[7].sigma = 407ef6a2e098be17 495.41476497330717
-seed0.four.unlistedProposal.candidates[7].sigmaZero = 407da67f250b73b4 474.4060411879866
-seed0.four.unlistedProposal.candidates[7].criticalLevel = 408862a0c34b887f 780.3284974957495
-seed0.four.unlistedProposal.candidates[7].detectionLimit = 40986d733d473d7c 1563.3625384455945
+seed0.four.unlistedProposal.candidates[7].net = 40c9ddf2d7160b43 13243.897188907145
+seed0.four.unlistedProposal.candidates[7].sigma = 407eeddafd712498 494.86596435734236
+seed0.four.unlistedProposal.candidates[7].sigmaZero = 407d99282477306d 473.57230040128962
+seed0.four.unlistedProposal.candidates[7].criticalLevel = 408857a82c66bd7a 778.95711593881356
+seed0.four.unlistedProposal.candidates[7].detectionLimit = 4098627aa6627277 1560.6197753317226
 seed0.four.unlistedProposal.candidates[7].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[7].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[7].holeRegionNote = nil
@@ -1206,11 +1206,11 @@ seed0.four.unlistedProposal.candidates[7].unconfirmable = false
 seed0.four.unlistedProposal.candidates[8].element = "Ce"
 seed0.four.unlistedProposal.candidates[8].group = "Ce_Ma"
 seed0.four.unlistedProposal.candidates[8].energyKeV = 3feb0e5604189375 0.84550000000000003
-seed0.four.unlistedProposal.candidates[8].net = 40b46b31883981b5 5227.193484872977
-seed0.four.unlistedProposal.candidates[8].sigma = 40766ecbe996281f 358.92478331236811
-seed0.four.unlistedProposal.candidates[8].sigmaZero = 4075b095ec3293ef 347.0366022086809
-seed0.four.unlistedProposal.candidates[8].criticalLevel = 4081d6986646e860 570.82441382786419
-seed0.four.unlistedProposal.candidates[8].detectionLimit = 4091e16ae0429d5d 1144.3543711098239
+seed0.four.unlistedProposal.candidates[8].net = 40b46f1b1a1ac4b1 5231.1058670740322
+seed0.four.unlistedProposal.candidates[8].sigma = 40766fba94ec9d85 358.98305218150955
+seed0.four.unlistedProposal.candidates[8].sigmaZero = 4075b14bb15052dc 347.08097964645799
+seed0.four.unlistedProposal.candidates[8].criticalLevel = 4081d72de45c0553 570.89740821734665
+seed0.four.unlistedProposal.candidates[8].detectionLimit = 4091e2005e57ba50 1144.5003598887888
 seed0.four.unlistedProposal.candidates[8].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[8].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[8].holeRegionNote = nil
@@ -1221,11 +1221,11 @@ seed0.four.unlistedProposal.candidates[8].unconfirmable = false
 seed0.four.unlistedProposal.candidates[9].element = "Hf"
 seed0.four.unlistedProposal.candidates[9].group = "Hf_Ma"
 seed0.four.unlistedProposal.candidates[9].energyKeV = 3ffa504816f0068e 1.6446000000000001
-seed0.four.unlistedProposal.candidates[9].net = 40a0cded4ddb7fa6 2150.9634846299477
-seed0.four.unlistedProposal.candidates[9].sigma = 406ea355cef1f1e2 245.1042246556745
-seed0.four.unlistedProposal.candidates[9].sigmaZero = 406d9c6a85b980e1 236.88800321799411
-seed0.four.unlistedProposal.candidates[9].criticalLevel = 40785a5663cddd22 389.64609127440974
-seed0.four.unlistedProposal.candidates[9].detectionLimit = 40886ffb57c5471b 781.99772600291487
+seed0.four.unlistedProposal.candidates[9].net = 409e6f64d5717871 1947.8484704713594
+seed0.four.unlistedProposal.candidates[9].sigma = 406e3785931c5b86 241.73505549944474
+seed0.four.unlistedProposal.candidates[9].sigmaZero = 406d44b175e1a2ae 234.14666265553882
+seed0.four.unlistedProposal.candidates[9].criticalLevel = 40781231199a5e08 385.13698730754595
+seed0.four.unlistedProposal.candidates[9].detectionLimit = 408827d60d91c801 772.97951806918729
 seed0.four.unlistedProposal.candidates[9].conflicts: array 1
 seed0.four.unlistedProposal.candidates[9].conflicts[0].id = "sum-Ga+O sum-Hf"
 seed0.four.unlistedProposal.candidates[9].conflicts[0].kind = .sumPeak
@@ -1245,68 +1245,68 @@ seed0.four.unlistedProposal.candidates[9].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[9].familyNote = "Hf Lα (7.90 keV) has a residual peak of 0.0 σ, below the 3 σ its Mβ (1.70 keV) needs: not Hf."
 seed0.four.unlistedProposal.candidates[9].possibleReason = nil
 seed0.four.unlistedProposal.candidates[9].unconfirmable = false
-seed0.four.unlistedProposal.candidates[10].element = "Ta"
-seed0.four.unlistedProposal.candidates[10].group = "Ta_Ma"
-seed0.four.unlistedProposal.candidates[10].energyKeV = 3ffb5c91d14e3bcd 1.7101
-seed0.four.unlistedProposal.candidates[10].net = 40cacfa148661eb4 13727.26002193927
-seed0.four.unlistedProposal.candidates[10].sigma = 409e58fddbdc747b 1942.2479090162367
-seed0.four.unlistedProposal.candidates[10].sigmaZero = 409df1893afb7ad9 1916.3840140622835
-seed0.four.unlistedProposal.candidates[10].criticalLevel = 40a8a057a705fb6f 3152.1711961621691
-seed0.four.unlistedProposal.candidates[10].detectionLimit = 40b8a30c4584e8ae 6307.0479357784334
+seed0.four.unlistedProposal.candidates[10].element = "Zr"
+seed0.four.unlistedProposal.candidates[10].group = "Zr_La"
+seed0.four.unlistedProposal.candidates[10].energyKeV = 400056a161e4f766 2.0423
+seed0.four.unlistedProposal.candidates[10].net = 408d784575c98a9b 943.03391606764069
+seed0.four.unlistedProposal.candidates[10].sigma = 405f2da50242943f 124.71319633962501
+seed0.four.unlistedProposal.candidates[10].sigmaZero = 405e415cde27c448 121.02129320033521
+seed0.four.unlistedProposal.candidates[10].criticalLevel = 4068e1fe77f4c6d6 199.06231305892896
+seed0.four.unlistedProposal.candidates[10].detectionLimit = 40790d485fe39ac8 400.83016957195332
 seed0.four.unlistedProposal.candidates[10].conflicts: array 1
-seed0.four.unlistedProposal.candidates[10].conflicts[0].id = "sum-Ge+O sum-Ta"
+seed0.four.unlistedProposal.candidates[10].conflicts[0].id = "sum-Cu+Ga sum-Zr"
 seed0.four.unlistedProposal.candidates[10].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[10].conflicts[0].element = "Ta"
-seed0.four.unlistedProposal.candidates[10].conflicts[0].line = "Ta_Ma"
-seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV: n 2 sum 400b624dd2f1a9fc 3.423 fnv 68783dd05bbdee5f
-seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV[0] = 3ffb6809d495182a 1.7128999999999999
-seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV[1] = 3ffb5c91d14e3bcd 1.7101
+seed0.four.unlistedProposal.candidates[10].conflicts[0].element = "Zr"
+seed0.four.unlistedProposal.candidates[10].conflicts[0].line = "Zr_La"
+seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV: n 2 sum 40104779a6b50b0f 4.0697999999999999 fnv ba214a29fa5c4a55
+seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV[0] = 40003851eb851eb8 2.0274999999999999
+seed0.four.unlistedProposal.candidates[10].conflicts[0].energiesKeV[1] = 400056a161e4f766 2.0423
 seed0.four.unlistedProposal.candidates[10].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[10].conflicts[0].requires[0] = "Ge"
-seed0.four.unlistedProposal.candidates[10].conflicts[0].requires[1] = "O"
-seed0.four.unlistedProposal.candidates[10].conflicts[0].question = "Ge+O sum peak (1.713 keV) or Ta Mα (1.710 keV)? They are 3 eV apart, far inside the detector resolution."
+seed0.four.unlistedProposal.candidates[10].conflicts[0].requires[0] = "Cu"
+seed0.four.unlistedProposal.candidates[10].conflicts[0].requires[1] = "Ga"
+seed0.four.unlistedProposal.candidates[10].conflicts[0].question = "Cu+Ga sum peak (2.027 keV) or Zr Lα (2.042 keV)? They are 15 eV apart, far inside the detector resolution."
 seed0.four.unlistedProposal.candidates[10].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[10].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[10].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[10].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[10].familyNote = nil
+seed0.four.unlistedProposal.candidates[10].familyNote = "Zr Kα (15.78 keV) has a residual peak of 1.3 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
 seed0.four.unlistedProposal.candidates[10].possibleReason = nil
 seed0.four.unlistedProposal.candidates[10].unconfirmable = false
-seed0.four.unlistedProposal.candidates[11].element = "Zr"
-seed0.four.unlistedProposal.candidates[11].group = "Zr_La"
-seed0.four.unlistedProposal.candidates[11].energyKeV = 400056a161e4f766 2.0423
-seed0.four.unlistedProposal.candidates[11].net = 4086fbd3a895e060 735.47834889498699
-seed0.four.unlistedProposal.candidates[11].sigma = 405e21f18d67e978 120.53036818645148
-seed0.four.unlistedProposal.candidates[11].sigmaZero = 405d69db6d16bc32 117.65401770801762
-seed0.four.unlistedProposal.candidates[11].criticalLevel = 406830c1a3f5b68d 193.52363775244558
-seed0.four.unlistedProposal.candidates[11].detectionLimit = 40785c0b8be48a7f 389.75281895898655
+seed0.four.unlistedProposal.candidates[11].element = "Ta"
+seed0.four.unlistedProposal.candidates[11].group = "Ta_Ma"
+seed0.four.unlistedProposal.candidates[11].energyKeV = 3ffb5c91d14e3bcd 1.7101
+seed0.four.unlistedProposal.candidates[11].net = 40cd8add1d9315e1 15125.727465043719
+seed0.four.unlistedProposal.candidates[11].sigma = 409efebe495e9187 1983.6858267570803
+seed0.four.unlistedProposal.candidates[11].sigmaZero = 409e8aec51fb101e 1954.7307814816081
+seed0.four.unlistedProposal.candidates[11].criticalLevel = 40a91e7df5c2da2d 3215.2460156337097
+seed0.four.unlistedProposal.candidates[11].detectionLimit = 40b921329441c76c 6433.1975747215147
 seed0.four.unlistedProposal.candidates[11].conflicts: array 1
-seed0.four.unlistedProposal.candidates[11].conflicts[0].id = "sum-Cu+Ga sum-Zr"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].id = "sum-Ge+O sum-Ta"
 seed0.four.unlistedProposal.candidates[11].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[11].conflicts[0].element = "Zr"
-seed0.four.unlistedProposal.candidates[11].conflicts[0].line = "Zr_La"
-seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV: n 2 sum 40104779a6b50b0f 4.0697999999999999 fnv ba214a29fa5c4a55
-seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[0] = 40003851eb851eb8 2.0274999999999999
-seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[1] = 400056a161e4f766 2.0423
+seed0.four.unlistedProposal.candidates[11].conflicts[0].element = "Ta"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].line = "Ta_Ma"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV: n 2 sum 400b624dd2f1a9fc 3.423 fnv 68783dd05bbdee5f
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[0] = 3ffb6809d495182a 1.7128999999999999
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[1] = 3ffb5c91d14e3bcd 1.7101
 seed0.four.unlistedProposal.candidates[11].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[0] = "Cu"
-seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[1] = "Ga"
-seed0.four.unlistedProposal.candidates[11].conflicts[0].question = "Cu+Ga sum peak (2.027 keV) or Zr Lα (2.042 keV)? They are 15 eV apart, far inside the detector resolution."
+seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[0] = "Ge"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[1] = "O"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].question = "Ge+O sum peak (1.713 keV) or Ta Mα (1.710 keV)? They are 3 eV apart, far inside the detector resolution."
 seed0.four.unlistedProposal.candidates[11].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[11].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[11].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[11].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[11].familyNote = "Zr Kα (15.78 keV) has a residual peak of 1.3 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
+seed0.four.unlistedProposal.candidates[11].familyNote = nil
 seed0.four.unlistedProposal.candidates[11].possibleReason = nil
 seed0.four.unlistedProposal.candidates[11].unconfirmable = false
 seed0.four.unlistedProposal.candidates[12].element = "P"
 seed0.four.unlistedProposal.candidates[12].group = "P_Ka"
 seed0.four.unlistedProposal.candidates[12].energyKeV = 40001b3d07c84b5e 2.0133000000000001
-seed0.four.unlistedProposal.candidates[12].net = 4089d96dfce1262d 827.17870498559716
-seed0.four.unlistedProposal.candidates[12].sigma = 40613ccca52c867e 137.89998110481605
-seed0.four.unlistedProposal.candidates[12].sigmaZero = 4060c30463bde2b8 134.09428584181819
-seed0.four.unlistedProposal.candidates[12].criticalLevel = 406b9218599e0a9a 220.56547242038215
-seed0.four.unlistedProposal.candidates[12].detectionLimit = 407bbd62418cde8c 443.83648829485969
+seed0.four.unlistedProposal.candidates[12].net = 4090036210af153c 1024.8457667690955
+seed0.four.unlistedProposal.candidates[12].sigma = 4061b343fde07517 141.60204976882298
+seed0.four.unlistedProposal.candidates[12].sigmaZero = 40611c82fbea2f78 136.89098926295605
+seed0.four.unlistedProposal.candidates[12].criticalLevel = 406c254ceca5cd23 225.16564018614835
+seed0.four.unlistedProposal.candidates[12].detectionLimit = 407c5096d494a115 453.03682382639209
 seed0.four.unlistedProposal.candidates[12].conflicts: array 1
 seed0.four.unlistedProposal.candidates[12].conflicts[0].id = "sum-Cu+Ga sum-P"
 seed0.four.unlistedProposal.candidates[12].conflicts[0].kind = .sumPeak
@@ -1324,31 +1324,31 @@ seed0.four.unlistedProposal.candidates[12].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[12].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[12].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[12].familyNote = nil
-seed0.four.unlistedProposal.candidates[12].possibleReason = "Adding it improves the fit by 4, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[12].possibleReason = "Adding it improves the fit by 8, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[12].unconfirmable = false
 seed0.four.unlistedProposal.candidates[13].element = "Hg"
 seed0.four.unlistedProposal.candidates[13].group = "Hg_La"
 seed0.four.unlistedProposal.candidates[13].energyKeV = 4023fa5e353f7cee 9.9890000000000008
-seed0.four.unlistedProposal.candidates[13].net = 407d8cb14cf5afd0 472.79328628512758
-seed0.four.unlistedProposal.candidates[13].sigma = 40577ed88c0fe84d 93.981966987166018
-seed0.four.unlistedProposal.candidates[13].sigmaZero = 405657be523ed0ad 89.370991288512144
-seed0.four.unlistedProposal.candidates[13].criticalLevel = 4062601203fbcdc8 147.00219916515766
-seed0.four.unlistedProposal.candidates[13].detectionLimit = 40728b5bebeaa1ba 296.70994178441072
+seed0.four.unlistedProposal.candidates[13].net = 407c86667ab180fa 456.40001935326984
+seed0.four.unlistedProposal.candidates[13].sigma = 40577dcafe34bd22 93.965514708998427
+seed0.four.unlistedProposal.candidates[13].sigmaZero = 4056600ca18cf5df 89.50077093854587
+seed0.four.unlistedProposal.candidates[13].criticalLevel = 406266e6bfef25e5 147.21566769322013
+seed0.four.unlistedProposal.candidates[13].detectionLimit = 40729230a7ddf9d7 297.13687884053564
 seed0.four.unlistedProposal.candidates[13].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[13].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[13].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[13].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[13].familyNote = nil
-seed0.four.unlistedProposal.candidates[13].possibleReason = "The peak at 9.888 keV went to Ge, which explains it better (gain there 16932230 against 1791941)."
+seed0.four.unlistedProposal.candidates[13].possibleReason = "The peak at 9.888 keV went to Ge, which explains it better (gain there 16900529 against 1753845)."
 seed0.four.unlistedProposal.candidates[13].unconfirmable = false
 seed0.four.unlistedProposal.candidates[14].element = "Gd"
 seed0.four.unlistedProposal.candidates[14].group = "Gd_Ma"
 seed0.four.unlistedProposal.candidates[14].energyKeV = 3ff2d3ae685db76b 1.1766799999999999
-seed0.four.unlistedProposal.candidates[14].net = 40b8be795c4fd020 6334.4740648158186
-seed0.four.unlistedProposal.candidates[14].sigma = 4093e41396491302 1273.019127980981
-seed0.four.unlistedProposal.candidates[14].sigmaZero = 40936fd28655b663 1243.9555905716486
-seed0.four.unlistedProposal.candidates[14].criticalLevel = 409ff87fdc96d2b5 2046.1248649183374
-seed0.four.unlistedProposal.candidates[14].detectionLimit = 40affde91994ad33 4094.95527329077
+seed0.four.unlistedProposal.candidates[14].net = 40b7dcf526663b90 6108.9576171775261
+seed0.four.unlistedProposal.candidates[14].sigma = 4093eae78813afde 1274.726105029687
+seed0.four.unlistedProposal.candidates[14].sigmaZero = 40937a18162ebc69 1246.5235221197602
+seed0.four.unlistedProposal.candidates[14].criticalLevel = 40a004b28d9520f5 2050.3487364390116
+seed0.four.unlistedProposal.candidates[14].detectionLimit = 40b007672c140e34 4103.4030163321186
 seed0.four.unlistedProposal.candidates[14].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[14].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[14].holeRegionNote = nil
@@ -1359,41 +1359,41 @@ seed0.four.unlistedProposal.candidates[14].unconfirmable = false
 seed0.four.unlistedProposal.candidates[15].element = "Lu"
 seed0.four.unlistedProposal.candidates[15].group = "Lu_La"
 seed0.four.unlistedProposal.candidates[15].energyKeV = 401e9f559b3d07c8 7.6555999999999997
-seed0.four.unlistedProposal.candidates[15].net = 407156fe1a8372c1 277.43703700396514
-seed0.four.unlistedProposal.candidates[15].sigma = 4055d896014aac3a 87.384155581400506
-seed0.four.unlistedProposal.candidates[15].sigmaZero = 405570b3b8ec4566 85.760969382031902
-seed0.four.unlistedProposal.candidates[15].criticalLevel = 4061a20e44459522 141.06424153890936
-seed0.four.unlistedProposal.candidates[15].detectionLimit = 4071cd582c346914 284.83402653191411
+seed0.four.unlistedProposal.candidates[15].net = 40714aeafc1e40ce 276.68236934487948
+seed0.four.unlistedProposal.candidates[15].sigma = 4055d92f6c58b07d 87.39351948414874
+seed0.four.unlistedProposal.candidates[15].sigmaZero = 4055719724a50c91 85.774850045376539
+seed0.four.unlistedProposal.candidates[15].criticalLevel = 4061a2c94dbb698c 141.08707319835628
+seed0.four.unlistedProposal.candidates[15].detectionLimit = 4071ce1335aa3d7e 284.87968985080795
 seed0.four.unlistedProposal.candidates[15].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[15].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[15].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[15].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[15].familyNote = nil
-seed0.four.unlistedProposal.candidates[15].possibleReason = "Its area 277 is below its detection limit 285."
+seed0.four.unlistedProposal.candidates[15].possibleReason = "Adding it improves the fit by 73, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[15].unconfirmable = false
 seed0.four.unlistedProposal.candidates[16].element = "Ho"
 seed0.four.unlistedProposal.candidates[16].group = "Ho_La"
 seed0.four.unlistedProposal.candidates[16].energyKeV = 401ae0f9096bb98c 6.7196999999999996
-seed0.four.unlistedProposal.candidates[16].net = 40674502d76d47d2 186.1565968641649
-seed0.four.unlistedProposal.candidates[16].sigma = 40525b253db7fd47 73.424148015668024
-seed0.four.unlistedProposal.candidates[16].sigmaZero = 4051fbc6c73609cf 71.934007456561844
-seed0.four.unlistedProposal.candidates[16].criticalLevel = 405d9489d6f4eb0f 118.32091306608002
-seed0.four.unlistedProposal.candidates[16].detectionLimit = 406deb1da6d292f4 239.34736958625547
+seed0.four.unlistedProposal.candidates[16].net = 4065209380f66478 169.01800583003546
+seed0.four.unlistedProposal.candidates[16].sigma = 40525a53296d6622 73.411325795016211
+seed0.four.unlistedProposal.candidates[16].sigmaZero = 405203c8fe1f79b1 72.059142618882802
+seed0.four.unlistedProposal.candidates[16].criticalLevel = 405da1b624764d14 118.52674209168282
+seed0.four.unlistedProposal.candidates[16].detectionLimit = 406df849f453f4f9 239.75902763746106
 seed0.four.unlistedProposal.candidates[16].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[16].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[16].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[16].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[16].familyNote = nil
-seed0.four.unlistedProposal.candidates[16].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[16].possibleReason = "Adding it improves the fit by 7, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[16].unconfirmable = false
 seed0.four.unlistedProposal.candidates[17].element = "Zn"
 seed0.four.unlistedProposal.candidates[17].group = "Zn_Ka"
 seed0.four.unlistedProposal.candidates[17].energyKeV = 4021471de69ad42c 8.6388999999999996
-seed0.four.unlistedProposal.candidates[17].net = 405d77ccaf4b80f8 117.87186796544472
-seed0.four.unlistedProposal.candidates[17].sigma = 405152b05e3deadd 69.29201465651154
-seed0.four.unlistedProposal.candidates[17].sigmaZero = 405104ac31ac7062 68.073009889981705
-seed0.four.unlistedProposal.candidates[17].criticalLevel = 405bfe16ba66cea4 111.97013721503987
-seed0.four.unlistedProposal.candidates[17].detectionLimit = 406c54aa8a447689 226.64581788417516
+seed0.four.unlistedProposal.candidates[17].net = 405bb1957f4385fa 110.77474958032681
+seed0.four.unlistedProposal.candidates[17].sigma = 4051574d0fc62d0d 69.3640784678757
+seed0.four.unlistedProposal.candidates[17].sigmaZero = 40510e113df2b573 68.219802367229747
+seed0.four.unlistedProposal.candidates[17].criticalLevel = 405c0d8aae128716 112.21158935365051
+seed0.four.unlistedProposal.candidates[17].detectionLimit = 406c641e7df02efb 227.12872216139644
 seed0.four.unlistedProposal.candidates[17].conflicts: array 1
 seed0.four.unlistedProposal.candidates[17].conflicts[0].id = "sum-Ge+Ni sum-Zn"
 seed0.four.unlistedProposal.candidates[17].conflicts[0].kind = .sumPeak
@@ -1411,73 +1411,73 @@ seed0.four.unlistedProposal.candidates[17].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[17].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[17].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[17].familyNote = nil
-seed0.four.unlistedProposal.candidates[17].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[17].possibleReason = "Adding it improves the fit by 12, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[17].unconfirmable = false
-seed0.four.unlistedProposal.candidates[18].element = "Tm"
-seed0.four.unlistedProposal.candidates[18].group = "Tm_La"
-seed0.four.unlistedProposal.candidates[18].energyKeV = 401cb8a0902de00d 7.1802999999999999
-seed0.four.unlistedProposal.candidates[18].net = 40594915317f5cc2 101.14191853940704
-seed0.four.unlistedProposal.candidates[18].sigma = 405209ce1ac4d26d 72.153204624375306
-seed0.four.unlistedProposal.candidates[18].sigmaZero = 4051d123988c02ad 71.267797600487668
-seed0.four.unlistedProposal.candidates[18].criticalLevel = 405d4e67f667042b 117.2250953680056
-seed0.four.unlistedProposal.candidates[18].detectionLimit = 406da4fbc644ac10 237.15573419010661
-seed0.four.unlistedProposal.candidates[18].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+seed0.four.unlistedProposal.candidates[18].element = "Re"
+seed0.four.unlistedProposal.candidates[18].group = "Re_La"
+seed0.four.unlistedProposal.candidates[18].energyKeV = 40214e075f6fd220 8.6524000000000001
+seed0.four.unlistedProposal.candidates[18].net = 405529e5e2ea3b44 84.654656151525217
+seed0.four.unlistedProposal.candidates[18].sigma = 4050897fc234fff2 66.148422767407993
+seed0.four.unlistedProposal.candidates[18].sigmaZero = 405056617438e136 65.349698119684803
+seed0.four.unlistedProposal.candidates[18].criticalLevel = 405adf676e867171 107.49068797234737
+seed0.four.unlistedProposal.candidates[18].detectionLimit = 406b35fb3e641956 217.68691939879017
+seed0.four.unlistedProposal.candidates[18].conflicts: array 1
+seed0.four.unlistedProposal.candidates[18].conflicts[0].id = "sum-Ge+Ni sum-Re"
+seed0.four.unlistedProposal.candidates[18].conflicts[0].kind = .sumPeak
+seed0.four.unlistedProposal.candidates[18].conflicts[0].element = "Re"
+seed0.four.unlistedProposal.candidates[18].conflicts[0].line = "Re_La"
+seed0.four.unlistedProposal.candidates[18].conflicts[0].energiesKeV: n 2 sum 40315189374bc6a8 17.3185 fnv d815a3b163ca0d63
+seed0.four.unlistedProposal.candidates[18].conflicts[0].energiesKeV[0] = 4021550b0f27bb30 8.6661000000000001
+seed0.four.unlistedProposal.candidates[18].conflicts[0].energiesKeV[1] = 40214e075f6fd220 8.6524000000000001
+seed0.four.unlistedProposal.candidates[18].conflicts[0].requires: array 2
+seed0.four.unlistedProposal.candidates[18].conflicts[0].requires[0] = "Ge"
+seed0.four.unlistedProposal.candidates[18].conflicts[0].requires[1] = "Ni"
+seed0.four.unlistedProposal.candidates[18].conflicts[0].question = "Ge+Ni sum peak (8.666 keV) or Re Lα (8.652 keV)? They are 14 eV apart, far inside the detector resolution."
+seed0.four.unlistedProposal.candidates[18].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[18].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[18].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[18].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[18].familyNote = nil
-seed0.four.unlistedProposal.candidates[18].possibleReason = "Adding it improves the fit by 11, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[18].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[18].unconfirmable = false
-seed0.four.unlistedProposal.candidates[19].element = "Re"
-seed0.four.unlistedProposal.candidates[19].group = "Re_La"
-seed0.four.unlistedProposal.candidates[19].energyKeV = 40214e075f6fd220 8.6524000000000001
-seed0.four.unlistedProposal.candidates[19].net = 40542d99f08c9c7f 80.712520730319724
-seed0.four.unlistedProposal.candidates[19].sigma = 40507f47a69d934e 65.988748220331416
-seed0.four.unlistedProposal.candidates[19].sigmaZero = 40504e88fe9c9d7d 65.227111485428352
-seed0.four.unlistedProposal.candidates[19].criticalLevel = 405ad27fcf5b2515 107.28905090237488
-seed0.four.unlistedProposal.candidates[19].detectionLimit = 406b29139f38ccfa 217.28364525884518
-seed0.four.unlistedProposal.candidates[19].conflicts: array 1
-seed0.four.unlistedProposal.candidates[19].conflicts[0].id = "sum-Ge+Ni sum-Re"
-seed0.four.unlistedProposal.candidates[19].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[19].conflicts[0].element = "Re"
-seed0.four.unlistedProposal.candidates[19].conflicts[0].line = "Re_La"
-seed0.four.unlistedProposal.candidates[19].conflicts[0].energiesKeV: n 2 sum 40315189374bc6a8 17.3185 fnv d815a3b163ca0d63
-seed0.four.unlistedProposal.candidates[19].conflicts[0].energiesKeV[0] = 4021550b0f27bb30 8.6661000000000001
-seed0.four.unlistedProposal.candidates[19].conflicts[0].energiesKeV[1] = 40214e075f6fd220 8.6524000000000001
-seed0.four.unlistedProposal.candidates[19].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[19].conflicts[0].requires[0] = "Ge"
-seed0.four.unlistedProposal.candidates[19].conflicts[0].requires[1] = "Ni"
-seed0.four.unlistedProposal.candidates[19].conflicts[0].question = "Ge+Ni sum peak (8.666 keV) or Re Lα (8.652 keV)? They are 14 eV apart, far inside the detector resolution."
-seed0.four.unlistedProposal.candidates[19].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.four.unlistedProposal.candidates[19].element = "Tm"
+seed0.four.unlistedProposal.candidates[19].group = "Tm_La"
+seed0.four.unlistedProposal.candidates[19].energyKeV = 401cb8a0902de00d 7.1802999999999999
+seed0.four.unlistedProposal.candidates[19].net = 40569d4cb0d099bc 90.4578058278193
+seed0.four.unlistedProposal.candidates[19].sigma = 40520a17facc1379 72.157713603299172
+seed0.four.unlistedProposal.candidates[19].sigmaZero = 4051d79aa54d4af5 71.368813825112582
+seed0.four.unlistedProposal.candidates[19].criticalLevel = 405d590a46f79a3d 117.39125227146083
+seed0.four.unlistedProposal.candidates[19].detectionLimit = 406daf9e16d54222 237.48804799701708
+seed0.four.unlistedProposal.candidates[19].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[19].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[19].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[19].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[19].familyNote = nil
-seed0.four.unlistedProposal.candidates[19].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[19].possibleReason = "Adding it improves the fit by 7, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[19].unconfirmable = false
 seed0.four.unlistedProposal.candidates[20].element = "Se"
 seed0.four.unlistedProposal.candidates[20].group = "Se_Ka"
 seed0.four.unlistedProposal.candidates[20].energyKeV = 402671a9fbe76c8b 11.222
-seed0.four.unlistedProposal.candidates[20].net = 404a313087442d94 52.384293468751963
-seed0.four.unlistedProposal.candidates[20].sigma = 404c97760a3d0e06 57.183289794742493
-seed0.four.unlistedProposal.candidates[20].sigmaZero = 404c4b469b01fc22 56.588092208832919
-seed0.four.unlistedProposal.candidates[20].criticalLevel = 4057451071df839e 93.079128711963193
-seed0.four.unlistedProposal.candidates[20].detectionLimit = 40679ba441bd2b83 188.86380087802181
+seed0.four.unlistedProposal.candidates[20].net = 404d8833dfdce455 59.064083083016762
+seed0.four.unlistedProposal.candidates[20].sigma = 404c9b0e1101ebad 57.211366773546025
+seed0.four.unlistedProposal.candidates[20].sigmaZero = 404c4526f06082e2 56.5402508231398
+seed0.four.unlistedProposal.candidates[20].criticalLevel = 405740072761766f 93.000436635187484
+seed0.four.unlistedProposal.candidates[20].detectionLimit = 4067969af73f1e54 188.70641672447039
 seed0.four.unlistedProposal.candidates[20].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[20].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[20].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[20].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[20].familyNote = nil
-seed0.four.unlistedProposal.candidates[20].possibleReason = "Adding it improves the fit by -1, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[20].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[20].unconfirmable = false
 seed0.four.unlistedProposal.candidates[21].element = "Tb"
 seed0.four.unlistedProposal.candidates[21].group = "Tb_La"
 seed0.four.unlistedProposal.candidates[21].energyKeV = 40191758e219652c 6.2728000000000002
-seed0.four.unlistedProposal.candidates[21].net = 4053cf9764d07c33 79.24361534461859
-seed0.four.unlistedProposal.candidates[21].sigma = 405b8a1992e55959 110.15781090161671
-seed0.four.unlistedProposal.candidates[21].sigmaZero = 405b664c42ed2783 109.59840462836841
-seed0.four.unlistedProposal.candidates[21].criticalLevel = 406688bf259ad603 180.27333336106685
-seed0.four.unlistedProposal.candidates[21].detectionLimit = 4076b4090d89a9f5 363.25221017622908
+seed0.four.unlistedProposal.candidates[21].net = 404f8f8344226ce7 63.12119342499664
+seed0.four.unlistedProposal.candidates[21].sigma = 405b8b7b92fa4ba7 110.17941736643716
+seed0.four.unlistedProposal.candidates[21].sigmaZero = 405b6efbe600c5ba 109.73412466121127
+seed0.four.unlistedProposal.candidates[21].criticalLevel = 40668fe3ecf42f93 180.4965729493384
+seed0.four.unlistedProposal.candidates[21].detectionLimit = 4076bb2dd4e30385 363.69868935277219
 seed0.four.unlistedProposal.candidates[21].conflicts: array 2
 seed0.four.unlistedProposal.candidates[21].conflicts[0].id = "sum-Si+Ti sum-Tb"
 seed0.four.unlistedProposal.candidates[21].conflicts[0].kind = .sumPeak
@@ -1507,56 +1507,56 @@ seed0.four.unlistedProposal.candidates[21].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[21].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[21].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[21].familyNote = nil
-seed0.four.unlistedProposal.candidates[21].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[21].possibleReason = "Adding it improves the fit by 4, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[21].unconfirmable = false
-seed0.four.unlistedProposal.candidates[22].element = "Dy"
-seed0.four.unlistedProposal.candidates[22].group = "Dy_La"
-seed0.four.unlistedProposal.candidates[22].energyKeV = 4019fb15b573eab3 6.4951999999999996
-seed0.four.unlistedProposal.candidates[22].net = 403defaab6d56b3b 29.936198641876427
-seed0.four.unlistedProposal.candidates[22].sigma = 4052d2f54b6b642e 75.29622159469065
-seed0.four.unlistedProposal.candidates[22].sigmaZero = 4052c54a1040d9f2 75.082645476657291
-seed0.four.unlistedProposal.candidates[22].criticalLevel = 405edfff5f7f8ab4 123.49996173339133
-seed0.four.unlistedProposal.candidates[22].detectionLimit = 406f36932f5d3299 249.70546692087808
-seed0.four.unlistedProposal.candidates[22].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+seed0.four.unlistedProposal.candidates[22].element = "Ir"
+seed0.four.unlistedProposal.candidates[22].group = "Ir_La"
+seed0.four.unlistedProposal.candidates[22].energyKeV = 4022597f62b6ae7d 9.1747999999999994
+seed0.four.unlistedProposal.candidates[22].net = 4048c9eed4e106f6 49.577601060749586
+seed0.four.unlistedProposal.candidates[22].sigma = 405b080a6e848d04 108.12563670105379
+seed0.four.unlistedProposal.candidates[22].sigmaZero = 405ae97d9bef2da4 107.64829157216315
+seed0.four.unlistedProposal.candidates[22].criticalLevel = 4066221a12df8eba 177.06568282760219
+seed0.four.unlistedProposal.candidates[22].detectionLimit = 40764d63face62ac 356.83690910929977
+seed0.four.unlistedProposal.candidates[22].conflicts: array 2
+seed0.four.unlistedProposal.candidates[22].conflicts[0].id = "sum-Ni+Si sum-Ir"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].kind = .sumPeak
+seed0.four.unlistedProposal.candidates[22].conflicts[0].element = "Ir"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].line = "Ir_La"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].energiesKeV: n 2 sum 403264816f0068dc 18.392600000000002 fnv b5bb6bf6fd95334c
+seed0.four.unlistedProposal.candidates[22].conflicts[0].energiesKeV[0] = 40226f837b4a233a 9.2178000000000004
+seed0.four.unlistedProposal.candidates[22].conflicts[0].energiesKeV[1] = 4022597f62b6ae7d 9.1747999999999994
+seed0.four.unlistedProposal.candidates[22].conflicts[0].requires: array 2
+seed0.four.unlistedProposal.candidates[22].conflicts[0].requires[0] = "Ni"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].requires[1] = "Si"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].question = "Ni+Si sum peak (9.218 keV) or Ir Lα (9.175 keV)?"
+seed0.four.unlistedProposal.candidates[22].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.four.unlistedProposal.candidates[22].conflicts[1].id = "sum-Ni+Ta sum-Ir"
+seed0.four.unlistedProposal.candidates[22].conflicts[1].kind = .sumPeak
+seed0.four.unlistedProposal.candidates[22].conflicts[1].element = "Ir"
+seed0.four.unlistedProposal.candidates[22].conflicts[1].line = "Ir_La"
+seed0.four.unlistedProposal.candidates[22].conflicts[1].energiesKeV: n 2 sum 40325ced916872b0 18.363 fnv b242d4055ccdc366
+seed0.four.unlistedProposal.candidates[22].conflicts[1].energiesKeV[0] = 4022605bc01a36e3 9.1882000000000001
+seed0.four.unlistedProposal.candidates[22].conflicts[1].energiesKeV[1] = 4022597f62b6ae7d 9.1747999999999994
+seed0.four.unlistedProposal.candidates[22].conflicts[1].requires: array 2
+seed0.four.unlistedProposal.candidates[22].conflicts[1].requires[0] = "Ni"
+seed0.four.unlistedProposal.candidates[22].conflicts[1].requires[1] = "Ta"
+seed0.four.unlistedProposal.candidates[22].conflicts[1].question = "Ni+Ta sum peak (9.188 keV) or Ir Lα (9.175 keV)? They are 13 eV apart, far inside the detector resolution."
+seed0.four.unlistedProposal.candidates[22].conflicts[1].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[22].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[22].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[22].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[22].familyNote = nil
 seed0.four.unlistedProposal.candidates[22].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[22].unconfirmable = false
-seed0.four.unlistedProposal.candidates[23].element = "Ir"
-seed0.four.unlistedProposal.candidates[23].group = "Ir_La"
-seed0.four.unlistedProposal.candidates[23].energyKeV = 4022597f62b6ae7d 9.1747999999999994
-seed0.four.unlistedProposal.candidates[23].net = 4041c13f9b1a8fbe 35.509753597230414
-seed0.four.unlistedProposal.candidates[23].sigma = 405b04a096a575c4 108.07230154188352
-seed0.four.unlistedProposal.candidates[23].sigmaZero = 405aec5020b240e5 107.69239060790603
-seed0.four.unlistedProposal.candidates[23].criticalLevel = 4066246c4ada64b0 177.13821928648895
-seed0.four.unlistedProposal.candidates[23].detectionLimit = 40764fb632c938a2 356.98198202707329
-seed0.four.unlistedProposal.candidates[23].conflicts: array 2
-seed0.four.unlistedProposal.candidates[23].conflicts[0].id = "sum-Ni+Si sum-Ir"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[23].conflicts[0].element = "Ir"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].line = "Ir_La"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].energiesKeV: n 2 sum 403264816f0068dc 18.392600000000002 fnv b5bb6bf6fd95334c
-seed0.four.unlistedProposal.candidates[23].conflicts[0].energiesKeV[0] = 40226f837b4a233a 9.2178000000000004
-seed0.four.unlistedProposal.candidates[23].conflicts[0].energiesKeV[1] = 4022597f62b6ae7d 9.1747999999999994
-seed0.four.unlistedProposal.candidates[23].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[23].conflicts[0].requires[0] = "Ni"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].requires[1] = "Si"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].question = "Ni+Si sum peak (9.218 keV) or Ir Lα (9.175 keV)?"
-seed0.four.unlistedProposal.candidates[23].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
-seed0.four.unlistedProposal.candidates[23].conflicts[1].id = "sum-Ni+Ta sum-Ir"
-seed0.four.unlistedProposal.candidates[23].conflicts[1].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[23].conflicts[1].element = "Ir"
-seed0.four.unlistedProposal.candidates[23].conflicts[1].line = "Ir_La"
-seed0.four.unlistedProposal.candidates[23].conflicts[1].energiesKeV: n 2 sum 40325ced916872b0 18.363 fnv b242d4055ccdc366
-seed0.four.unlistedProposal.candidates[23].conflicts[1].energiesKeV[0] = 4022605bc01a36e3 9.1882000000000001
-seed0.four.unlistedProposal.candidates[23].conflicts[1].energiesKeV[1] = 4022597f62b6ae7d 9.1747999999999994
-seed0.four.unlistedProposal.candidates[23].conflicts[1].requires: array 2
-seed0.four.unlistedProposal.candidates[23].conflicts[1].requires[0] = "Ni"
-seed0.four.unlistedProposal.candidates[23].conflicts[1].requires[1] = "Ta"
-seed0.four.unlistedProposal.candidates[23].conflicts[1].question = "Ni+Ta sum peak (9.188 keV) or Ir Lα (9.175 keV)? They are 13 eV apart, far inside the detector resolution."
-seed0.four.unlistedProposal.candidates[23].conflicts[1].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.four.unlistedProposal.candidates[23].element = "Dy"
+seed0.four.unlistedProposal.candidates[23].group = "Dy_La"
+seed0.four.unlistedProposal.candidates[23].energyKeV = 4019fb15b573eab3 6.4951999999999996
+seed0.four.unlistedProposal.candidates[23].net = 40357fd2bd289bfc 21.49930937043608
+seed0.four.unlistedProposal.candidates[23].sigma = 4052d32739aaefef 75.29926912015047
+seed0.four.unlistedProposal.candidates[23].sigmaZero = 4052c9572bf137e6 75.145945535244749
+seed0.four.unlistedProposal.candidates[23].criticalLevel = 405ee6a9439fdfb3 123.60408106434515
+seed0.four.unlistedProposal.candidates[23].detectionLimit = 406f3d3d137d8798 249.91370558278572
+seed0.four.unlistedProposal.candidates[23].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[23].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[23].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[23].misfit = 3ff0000000000000 1
@@ -1567,70 +1567,70 @@ seed0.four.unlistedProposal.candidates[24].element = "Au"
 seed0.four.unlistedProposal.candidates[24].group = "Au_La"
 seed0.four.unlistedProposal.candidates[24].energyKeV = 40236d0e56041893 9.7129999999999992
 seed0.four.unlistedProposal.candidates[24].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[24].sigma = 4057a72868e92d55 94.611841418945303
-seed0.four.unlistedProposal.candidates[24].sigmaZero = 4054dfc00faed233 83.496097489093515
-seed0.four.unlistedProposal.candidates[24].criticalLevel = 40612ad7ee644955 137.33885879122923
-seed0.four.unlistedProposal.candidates[24].detectionLimit = 40715621d6531d47 277.38326103655385
+seed0.four.unlistedProposal.candidates[24].sigma = 4057ac5c3b210cb6 94.693129331851054
+seed0.four.unlistedProposal.candidates[24].sigmaZero = 4054e632c905bc5a 83.596849685288731
+seed0.four.unlistedProposal.candidates[24].criticalLevel = 4061302587e7eb9f 137.50458140656426
+seed0.four.unlistedProposal.candidates[24].detectionLimit = 40715b6f6fd6bf91 277.7147062672239
 seed0.four.unlistedProposal.candidates[24].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[24].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[24].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[24].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[24].familyNote = nil
-seed0.four.unlistedProposal.candidates[24].possibleReason = "Its area 0 is below its detection limit 277."
+seed0.four.unlistedProposal.candidates[24].possibleReason = "Its area 0 is below its detection limit 278."
 seed0.four.unlistedProposal.candidates[24].unconfirmable = false
 seed0.four.unlistedProposal.candidates[25].element = "Bi"
 seed0.four.unlistedProposal.candidates[25].group = "Bi_La"
 seed0.four.unlistedProposal.candidates[25].energyKeV = 4025ad916872b021 10.839
 seed0.four.unlistedProposal.candidates[25].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[25].sigma = 404d6dac3f2482db 58.856819050624573
-seed0.four.unlistedProposal.candidates[25].sigmaZero = 404d6cfe52d1d4a1 58.851511337715472
-seed0.four.unlistedProposal.candidates[25].criticalLevel = 40583355f6fd949f 96.802121875417001
-seed0.four.unlistedProposal.candidates[25].detectionLimit = 406889e9c6db3c84 196.30978720492942
+seed0.four.unlistedProposal.candidates[25].sigma = 404d68277ba37408 58.813704924403339
+seed0.four.unlistedProposal.candidates[25].sigmaZero = 404d6770dc2df217 58.808131716188818
+seed0.four.unlistedProposal.candidates[25].criticalLevel = 40582ec4ea47fbfb 96.730768747613112
+seed0.four.unlistedProposal.candidates[25].detectionLimit = 40688558ba25a3e0 196.16708094932164
 seed0.four.unlistedProposal.candidates[25].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[25].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[25].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[25].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[25].familyNote = nil
-seed0.four.unlistedProposal.candidates[25].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[25].possibleReason = "Adding it improves the fit by 16, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[25].unconfirmable = false
 seed0.four.unlistedProposal.candidates[26].element = "Er"
 seed0.four.unlistedProposal.candidates[26].group = "Er_La"
 seed0.four.unlistedProposal.candidates[26].energyKeV = 401bcb5dcc63f141 6.9485999999999999
 seed0.four.unlistedProposal.candidates[26].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[26].sigma = 4050b0ae55119b02 66.760640399163123
-seed0.four.unlistedProposal.candidates[26].sigmaZero = 4050b0ae55119b02 66.760640399163123
-seed0.four.unlistedProposal.candidates[26].criticalLevel = 405b73ef5017fbc8 109.81148149816647
-seed0.four.unlistedProposal.candidates[26].detectionLimit = 406bca831ff5a3ad 222.32850645042836
+seed0.four.unlistedProposal.candidates[26].sigma = 4050af2937e18078 66.736890764443046
+seed0.four.unlistedProposal.candidates[26].sigmaZero = 4050af2937e18078 66.736890764443046
+seed0.four.unlistedProposal.candidates[26].criticalLevel = 405b716f46faf2d7 109.77241682535838
+seed0.four.unlistedProposal.candidates[26].detectionLimit = 406bc80316d89abc 222.25037710481217
 seed0.four.unlistedProposal.candidates[26].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[26].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[26].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[26].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[26].familyNote = nil
-seed0.four.unlistedProposal.candidates[26].possibleReason = "Only -16 % of its gain 704 is at its own lines (20 % needed): it mostly reshapes the background."
+seed0.four.unlistedProposal.candidates[26].possibleReason = "Only -45 % of its gain 589 is at its own lines (20 % needed): it mostly reshapes the background."
 seed0.four.unlistedProposal.candidates[26].unconfirmable = false
 seed0.four.unlistedProposal.candidates[27].element = "La"
 seed0.four.unlistedProposal.candidates[27].group = "La_Ma"
 seed0.four.unlistedProposal.candidates[27].energyKeV = 3fea27525460aa65 0.81730000000000003
 seed0.four.unlistedProposal.candidates[27].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[27].sigma = 406c47c43799297d 226.24270229258028
-seed0.four.unlistedProposal.candidates[27].sigmaZero = 406c47c43799297d 226.24270229258028
-seed0.four.unlistedProposal.candidates[27].criticalLevel = 4077422d960f9063 372.13612943725292
-seed0.four.unlistedProposal.candidates[27].detectionLimit = 408757d28a06fa5c 746.97780232860123
+seed0.four.unlistedProposal.candidates[27].sigma = 406c47306ff6b68f 226.22466276346356
+seed0.four.unlistedProposal.candidates[27].sigmaZero = 406c47306ff6b68f 226.22466276346356
+seed0.four.unlistedProposal.candidates[27].criticalLevel = 407741b40c4f64d1 372.1064570523568
+seed0.four.unlistedProposal.candidates[27].detectionLimit = 408757590046ceca 746.918457558809
 seed0.four.unlistedProposal.candidates[27].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[27].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[27].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[27].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[27].familyNote = "La Lα (4.65 keV) has a residual peak of 1.3 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
+seed0.four.unlistedProposal.candidates[27].familyNote = "La Lα (4.65 keV) has a residual peak of 1.2 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
 seed0.four.unlistedProposal.candidates[27].possibleReason = nil
 seed0.four.unlistedProposal.candidates[27].unconfirmable = false
 seed0.four.unlistedProposal.candidates[28].element = "Na"
 seed0.four.unlistedProposal.candidates[28].group = "Na_Ka"
 seed0.four.unlistedProposal.candidates[28].energyKeV = 3ff0a7ef9db22d0e 1.0409999999999999
 seed0.four.unlistedProposal.candidates[28].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[28].sigma = 40825862f5ad97f3 587.04832015628779
-seed0.four.unlistedProposal.candidates[28].sigmaZero = 40825862f5ad97f3 587.04832015628779
-seed0.four.unlistedProposal.candidates[28].criticalLevel = 408e2cde53f94bdf 965.60855860483923
-seed0.four.unlistedProposal.candidates[28].detectionLimit = 409e37b0cdf500dc 1933.922660663774
+seed0.four.unlistedProposal.candidates[28].sigma = 40824a20d0f8c3d5 585.26602358195908
+seed0.four.unlistedProposal.candidates[28].sigmaZero = 40824a20d0f8c3d5 585.26602358195908
+seed0.four.unlistedProposal.candidates[28].criticalLevel = 408e156a605e4240 962.67694162025145
+seed0.four.unlistedProposal.candidates[28].detectionLimit = 409e203cda59f73d 1928.0594266945984
 seed0.four.unlistedProposal.candidates[28].conflicts: array 1
 seed0.four.unlistedProposal.candidates[28].conflicts[0].id = "sum-O+O sum-Na"
 seed0.four.unlistedProposal.candidates[28].conflicts[0].kind = .sumPeak
@@ -1653,40 +1653,40 @@ seed0.four.unlistedProposal.candidates[29].element = "Os"
 seed0.four.unlistedProposal.candidates[29].group = "Os_La"
 seed0.four.unlistedProposal.candidates[29].energyKeV = 4021d25460aa64c3 8.9108000000000001
 seed0.four.unlistedProposal.candidates[29].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[29].sigma = 40566022fe6ed1fc 89.502135856840994
-seed0.four.unlistedProposal.candidates[29].sigmaZero = 40565d98a157c2af 89.462440810874554
-seed0.four.unlistedProposal.candidates[29].criticalLevel = 406264e243d96c8f 147.15262024369846
-seed0.four.unlistedProposal.candidates[29].detectionLimit = 4072902c2bc84081 297.01078394149232
+seed0.four.unlistedProposal.candidates[29].sigma = 405671683116b2cc 89.771984359899932
+seed0.four.unlistedProposal.candidates[29].sigmaZero = 40566f2242e1bdf5 89.73646614117736
+seed0.four.unlistedProposal.candidates[29].criticalLevel = 4062734ea8704350 147.6033518021236
+seed0.four.unlistedProposal.candidates[29].detectionLimit = 40729e98905f1742 297.91224705834259
 seed0.four.unlistedProposal.candidates[29].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[29].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[29].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[29].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[29].familyNote = nil
-seed0.four.unlistedProposal.candidates[29].possibleReason = "Adding it improves the fit by 0, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[29].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[29].unconfirmable = false
 seed0.four.unlistedProposal.candidates[30].element = "Pt"
 seed0.four.unlistedProposal.candidates[30].group = "Pt_La"
 seed0.four.unlistedProposal.candidates[30].energyKeV = 4022e25aee631f8a 9.4420999999999999
 seed0.four.unlistedProposal.candidates[30].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[30].sigma = 4057693668d22ed3 93.643945889717813
-seed0.four.unlistedProposal.candidates[30].sigmaZero = 405733483f418378 92.801284612634731
-seed0.four.unlistedProposal.candidates[30].criticalLevel = 4063149ffc7fe183 152.64452958084811
-seed0.four.unlistedProposal.candidates[30].detectionLimit = 40733fe9e46eb575 307.99460261579162
+seed0.four.unlistedProposal.candidates[30].sigma = 405768241592642c 93.62720240875268
+seed0.four.unlistedProposal.candidates[30].sigmaZero = 4057367b45b0f015 92.851273939886894
+seed0.four.unlistedProposal.candidates[30].criticalLevel = 40631741931664fc 152.72675470708771
+seed0.four.unlistedProposal.candidates[30].detectionLimit = 4073428b7b0538ee 308.15905286827081
 seed0.four.unlistedProposal.candidates[30].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[30].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[30].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[30].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[30].familyNote = nil
-seed0.four.unlistedProposal.candidates[30].possibleReason = "Adding it improves the fit by 29, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[30].possibleReason = "Adding it improves the fit by 61, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[30].unconfirmable = false
 seed0.four.unlistedProposal.candidates[31].element = "Sr"
 seed0.four.unlistedProposal.candidates[31].group = "Sr_La"
 seed0.four.unlistedProposal.candidates[31].energyKeV = 3ffce76c8b439581 1.8065
 seed0.four.unlistedProposal.candidates[31].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[31].sigma = 40794244ef0d35ea 404.14182953987495
-seed0.four.unlistedProposal.candidates[31].sigmaZero = 40794244ef0d35ea 404.14182953987495
-seed0.four.unlistedProposal.candidates[31].criticalLevel = 4084c60881f4bec2 664.75415412146708
-seed0.four.unlistedProposal.candidates[31].detectionLimit = 4094d0dafbf073bf 1332.2138516970297
+seed0.four.unlistedProposal.candidates[31].sigma = 40794359782a2843 404.20934311359105
+seed0.four.unlistedProposal.candidates[31].sigmaZero = 40794359782a2843 404.20934311359105
+seed0.four.unlistedProposal.candidates[31].criticalLevel = 4084c6ebf01c458e 664.86520406806244
+seed0.four.unlistedProposal.candidates[31].detectionLimit = 4094d1be6a17fa8b 1332.4359515902204
 seed0.four.unlistedProposal.candidates[31].conflicts: array 1
 seed0.four.unlistedProposal.candidates[31].conflicts[0].id = "sum-Cu+Cu sum-Sr"
 seed0.four.unlistedProposal.candidates[31].conflicts[0].kind = .sumPeak
@@ -1709,10 +1709,10 @@ seed0.four.unlistedProposal.candidates[32].element = "W"
 seed0.four.unlistedProposal.candidates[32].group = "W_La"
 seed0.four.unlistedProposal.candidates[32].energyKeV = 4020cb923a29c77a 8.3976000000000006
 seed0.four.unlistedProposal.candidates[32].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[32].sigma = 4059f00c4245cacd 103.75074822250026
-seed0.four.unlistedProposal.candidates[32].sigmaZero = 4059ef75f3cf10f1 103.74157424184138
-seed0.four.unlistedProposal.candidates[32].criticalLevel = 4065547875e6cd1c 170.63970465734826
-seed0.four.unlistedProposal.candidates[32].detectionLimit = 40757fc25dd5a10e 343.98495276879191
+seed0.four.unlistedProposal.candidates[32].sigma = 4059f2528f294648 103.78628901510922
+seed0.four.unlistedProposal.candidates[32].sigmaZero = 4059f1cf9ea3dddb 103.77829710009193
+seed0.four.unlistedProposal.candidates[32].criticalLevel = 4065566749b294d3 170.70010838393372
+seed0.four.unlistedProposal.candidates[32].detectionLimit = 407581b131a168c5 344.10576022196284
 seed0.four.unlistedProposal.candidates[32].conflicts: array 1
 seed0.four.unlistedProposal.candidates[32].conflicts[0].id = "sum-Cu+Ni sum-W"
 seed0.four.unlistedProposal.candidates[32].conflicts[0].kind = .sumPeak
@@ -1730,16 +1730,16 @@ seed0.four.unlistedProposal.candidates[32].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[32].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[32].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[32].familyNote = nil
-seed0.four.unlistedProposal.candidates[32].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[32].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[32].unconfirmable = false
 seed0.four.unlistedProposal.candidates[33].element = "Y"
 seed0.four.unlistedProposal.candidates[33].group = "Y_La"
 seed0.four.unlistedProposal.candidates[33].energyKeV = 3ffec2f837b4a234 1.9226000000000001
 seed0.four.unlistedProposal.candidates[33].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[33].sigma = 40604ae825f322a0 130.34083840834955
-seed0.four.unlistedProposal.candidates[33].sigmaZero = 40604ae825f32298 130.34083840834933
-seed0.four.unlistedProposal.candidates[33].criticalLevel = 406acc87fe646b11 214.39160079586921
-seed0.four.unlistedProposal.candidates[33].detectionLimit = 407af7d1e6533f03 431.48874504583381
+seed0.four.unlistedProposal.candidates[33].sigma = 4060c84b4b931343 134.25919131017335
+seed0.four.unlistedProposal.candidates[33].sigmaZero = 4060c848b00dd590 134.2588730116081
+seed0.four.unlistedProposal.candidates[33].criticalLevel = 406b9ac21a636986 220.83619422356077
+seed0.four.unlistedProposal.candidates[33].detectionLimit = 407bc60c02523d78 444.37793190121693
 seed0.four.unlistedProposal.candidates[33].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[33].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[33].holeRegionNote = nil
@@ -1751,16 +1751,16 @@ seed0.four.unlistedProposal.candidates[34].element = "Yb"
 seed0.four.unlistedProposal.candidates[34].group = "Yb_La"
 seed0.four.unlistedProposal.candidates[34].energyKeV = 401da9c779a6b50b 7.4157999999999999
 seed0.four.unlistedProposal.candidates[34].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[34].sigma = 4066bbef690a1c2c 181.87297489142054
-seed0.four.unlistedProposal.candidates[34].sigmaZero = 4066bbd49e2da1cb 181.86970433151723
-seed0.four.unlistedProposal.candidates[34].criticalLevel = 4072b2627ab49881 299.14904280228808
-seed0.four.unlistedProposal.candidates[34].detectionLimit = 4082c8076eac027a 601.00362905867155
+seed0.four.unlistedProposal.candidates[34].sigma = 4066bb2d30d032e3 181.84926644004653
+seed0.four.unlistedProposal.candidates[34].sigmaZero = 4066bb051ad77710 181.84437315066361
+seed0.four.unlistedProposal.candidates[34].criticalLevel = 4072b1b7d0a62624 299.10737671758602
+seed0.four.unlistedProposal.candidates[34].detectionLimit = 4082c75cc49d901d 600.92029688926743
 seed0.four.unlistedProposal.candidates[34].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[34].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[34].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[34].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[34].familyNote = nil
-seed0.four.unlistedProposal.candidates[34].possibleReason = "Adding it improves the fit by 74, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[34].possibleReason = "Adding it improves the fit by 18, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[34].unconfirmable = false
 seed0.four.unlistedProposal.sumPeaks: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.refused: array 7
@@ -1783,7 +1783,7 @@ seed0.four.unlistedProposal.currie.beta = 3fa999999999999a 0.050000000000000003
 seed0.four.unlistedProposal.notes: array 19
 seed0.four.unlistedProposal.notes[0] = "Lines below 0.45 keV are not tested (a measured limit of the continuum model, not a property of the method)."
 seed0.four.unlistedProposal.notes[1] = "Identification (validation: none): the residual's peaks at or above 5 σ of its top-hat filter (1.5 × below 1 keV); a candidate joins when Σ(y − μ)²/(μ + (0.01 μ)²) falls by at least 100, 20 % of that at its own lines, with its area at or above Currie L_D (α = β = 0.05, σ₀ from the fit's own variance with it absent) and no line against it; the final fit drops what it does not need (100). Kβ weights from NIST EPQ in this fit."
-seed0.four.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data; escape peaks: fitted for 7 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 62 candidate fits, 68 fits in all."
+seed0.four.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data; escape peaks: fitted for 7 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 62 candidate fits, 68 fits in all."
 seed0.four.unlistedProposal.notes[3] = "Confirmation lines (validation: none): an element nominated by an L or M line needs its K or L alpha line at 3 σ in the residual where the fitted range holds it and the beam is at least 2.0 times its energy; otherwise it is withheld."
 seed0.four.unlistedProposal.notes[4] = "Confirmation withheld Pr: Pr Lα (5.03 keV) has a residual peak of 1.7 σ, below the 3 σ its Mγ (1.13 keV) needs: not Pr."
 seed0.four.unlistedProposal.notes[5] = "Confirmation withheld Eu: Eu Lα (5.85 keV) has a residual peak of 0.5 σ, below the 3 σ its Mα (1.10 keV) needs: not Eu."
@@ -1793,154 +1793,150 @@ seed0.four.unlistedProposal.notes[8] = "Confirmation withheld Ce: Ce Lα (4.84 k
 seed0.four.unlistedProposal.notes[9] = "Confirmation withheld Hf: Hf Lα (7.90 keV) has a residual peak of 0.0 σ, below the 3 σ its Mβ (1.70 keV) needs: not Hf."
 seed0.four.unlistedProposal.notes[10] = "Confirmation withheld Zr: Zr Kα (15.78 keV) has a residual peak of 1.3 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
 seed0.four.unlistedProposal.notes[11] = "Confirmation withheld Gd: Gd Lα (6.06 keV) has a residual peak of 0.0 σ, below the 3 σ its Mα (1.18 keV) needs: not Gd."
-seed0.four.unlistedProposal.notes[12] = "Confirmation withheld La: La Lα (4.65 keV) has a residual peak of 1.3 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
+seed0.four.unlistedProposal.notes[12] = "Confirmation withheld La: La Lα (4.65 keV) has a residual peak of 1.2 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
 seed0.four.unlistedProposal.notes[13] = "Confirmation withheld Sr: Sr Kα (14.16 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (1.81 keV) needs: not Sr."
 seed0.four.unlistedProposal.notes[14] = "Confirmation withheld Y: Y Kα (14.96 keV) has a residual peak of 0.9 σ, below the 3 σ its Lα (1.92 keV) needs: not Y."
 seed0.four.unlistedProposal.notes[15] = "Look-elsewhere: 62 candidates were tested, so about 0.03 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
-seed0.four.unlistedProposal.notes[16] = "Ti_Ka: Si-escape/parent ratio 59.1 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.four.unlistedProposal.notes[17] = "Ga_Ka: Si-escape/parent ratio 11.5 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.four.unlistedProposal.notes[18] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.four.unlistedProposal.notes[16] = "Ti_Ka: Si-escape/parent ratio 72.7 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.four.unlistedProposal.notes[17] = "Ga_Ka: Si-escape/parent ratio 11.3 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.four.unlistedProposal.notes[18] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.four.unlistedProposal.passes = 68
 seed0.four.unlistedProposal.settled = true
-seed0.four.unlistedProposal.reducedChiSquared = 4031950157190f8d 17.582051700228067
+seed0.four.unlistedProposal.reducedChiSquared = 403210e2abf619c6 18.065958736022161
 seed0.four.unlistedCheck.candidates: array 15
 seed0.four.unlistedCheck.candidates[0].element = "Ge"
 seed0.four.unlistedCheck.candidates[0].group = "Ge_Ka"
-seed0.four.unlistedCheck.candidates[0].net = 41104af3e5234541 266940.97376735887
-seed0.four.unlistedCheck.candidates[0].detectionLimit = 40669ee7e0c17b76 180.96580541409975
+seed0.four.unlistedCheck.candidates[0].net = 411049cdc388fb6a 266867.44095223269
+seed0.four.unlistedCheck.candidates[0].detectionLimit = 40670e5385b909a7 184.44769559993912
 seed0.four.unlistedCheck.candidates[0].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[0].besideLine = nil
 seed0.four.unlistedCheck.candidates[0].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[1].element = "Ga"
 seed0.four.unlistedCheck.candidates[1].group = "Ga_La"
-seed0.four.unlistedCheck.candidates[1].net = 41124e507cb5ebc7 299924.12178772356
-seed0.four.unlistedCheck.candidates[1].detectionLimit = 40985e492b45cdc1 1559.571454134639
+seed0.four.unlistedCheck.candidates[1].net = 41124dfaa286d6ca 299902.65871749504
+seed0.four.unlistedCheck.candidates[1].detectionLimit = 4098371a1078450d 1549.7754534523149
 seed0.four.unlistedCheck.candidates[1].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[1].besideLine = nil
 seed0.four.unlistedCheck.candidates[1].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[2].element = "Cu"
 seed0.four.unlistedCheck.candidates[2].group = "Cu_Ka"
-seed0.four.unlistedCheck.candidates[2].net = 40ed124e96f699c3 59538.455928135219
-seed0.four.unlistedCheck.candidates[2].detectionLimit = 4079792c39293125 407.57329670038808
+seed0.four.unlistedCheck.candidates[2].net = 40ecff852541abdb 59388.160797916084
+seed0.four.unlistedCheck.candidates[2].detectionLimit = 4079c044ee34fef7 412.01682873441263
 seed0.four.unlistedCheck.candidates[2].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[2].besideLine = nil
 seed0.four.unlistedCheck.candidates[2].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[3].element = "Pr"
 seed0.four.unlistedCheck.candidates[3].group = "Pr_Ma"
-seed0.four.unlistedCheck.candidates[3].net = 40ed220dd3b7e979 59664.432094532014
-seed0.four.unlistedCheck.candidates[3].detectionLimit = 408f5880410d6040 1003.0626240773199
+seed0.four.unlistedCheck.candidates[3].net = 40ed15382bb8840b 59561.755337007424
+seed0.four.unlistedCheck.candidates[3].detectionLimit = 408f513f90e815a7 1002.156038106118
 seed0.four.unlistedCheck.candidates[3].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[3].besideLine = "Ni Lα"
 seed0.four.unlistedCheck.candidates[3].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[4].element = "Eu"
 seed0.four.unlistedCheck.candidates[4].group = "Eu_Ma"
-seed0.four.unlistedCheck.candidates[4].net = 40f252b6c2632c7a 75051.422457860695
-seed0.four.unlistedCheck.candidates[4].detectionLimit = 409db6495eecba40 1901.5716511715582
+seed0.four.unlistedCheck.candidates[4].net = 40f2507137ad8a20 75015.076093234587
+seed0.four.unlistedCheck.candidates[4].detectionLimit = 409db5c6d6610f76 1901.4441771665274
 seed0.four.unlistedCheck.candidates[4].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[4].besideLine = nil
 seed0.four.unlistedCheck.candidates[4].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[5].element = "Sm"
 seed0.four.unlistedCheck.candidates[5].group = "Sm_Ma"
-seed0.four.unlistedCheck.candidates[5].net = 40d678fe0ccda928 23011.969531455223
-seed0.four.unlistedCheck.candidates[5].detectionLimit = 409bca38f7684e4a 1778.5556312845024
+seed0.four.unlistedCheck.candidates[5].net = 40d6c91ede1800e8 23332.482305527577
+seed0.four.unlistedCheck.candidates[5].detectionLimit = 409b970ccfe9308a 1765.7625118671299
 seed0.four.unlistedCheck.candidates[5].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[5].besideLine = nil
 seed0.four.unlistedCheck.candidates[5].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[6].element = "Rb"
 seed0.four.unlistedCheck.candidates[6].group = "Rb_La"
-seed0.four.unlistedCheck.candidates[6].net = 40d7cfab1c9229a7 24382.673618832279
-seed0.four.unlistedCheck.candidates[6].detectionLimit = 40a3fc0991ab0f20 2558.0186894851649
+seed0.four.unlistedCheck.candidates[6].net = 40d7192ed8e64e76 23652.731988503096
+seed0.four.unlistedCheck.candidates[6].detectionLimit = 40a3a4a384bd81ac 2514.3193721028128
 seed0.four.unlistedCheck.candidates[6].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[6].besideLine = "Si Kα"
-seed0.four.unlistedCheck.candidates[6].fractionOfNeighbour = 3f99f69cd28b142c 0.025354814863721639
+seed0.four.unlistedCheck.candidates[6].fractionOfNeighbour = 3f99333db8ba7074 0.02460953178398069
 seed0.four.unlistedCheck.candidates[7].element = "Nd"
 seed0.four.unlistedCheck.candidates[7].group = "Nd_Ma"
-seed0.four.unlistedCheck.candidates[7].net = 40c98ebdbf9eccb4 13085.482410287812
-seed0.four.unlistedCheck.candidates[7].detectionLimit = 40986d733d473d7c 1563.3625384455945
+seed0.four.unlistedCheck.candidates[7].net = 40c9ddf2d7160b43 13243.897188907145
+seed0.four.unlistedCheck.candidates[7].detectionLimit = 4098627aa6627277 1560.6197753317226
 seed0.four.unlistedCheck.candidates[7].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[7].besideLine = "Ni Lα"
 seed0.four.unlistedCheck.candidates[7].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[8].element = "Ce"
 seed0.four.unlistedCheck.candidates[8].group = "Ce_Ma"
-seed0.four.unlistedCheck.candidates[8].net = 40b46b31883981b5 5227.193484872977
-seed0.four.unlistedCheck.candidates[8].detectionLimit = 4091e16ae0429d5d 1144.3543711098239
+seed0.four.unlistedCheck.candidates[8].net = 40b46f1b1a1ac4b1 5231.1058670740322
+seed0.four.unlistedCheck.candidates[8].detectionLimit = 4091e2005e57ba50 1144.5003598887888
 seed0.four.unlistedCheck.candidates[8].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[8].besideLine = "Ni Lα"
 seed0.four.unlistedCheck.candidates[8].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[9].element = "Hf"
 seed0.four.unlistedCheck.candidates[9].group = "Hf_Ma"
-seed0.four.unlistedCheck.candidates[9].net = 40a0cded4ddb7fa6 2150.9634846299477
-seed0.four.unlistedCheck.candidates[9].detectionLimit = 40886ffb57c5471b 781.99772600291487
+seed0.four.unlistedCheck.candidates[9].net = 409e6f64d5717871 1947.8484704713594
+seed0.four.unlistedCheck.candidates[9].detectionLimit = 408827d60d91c801 772.97951806918729
 seed0.four.unlistedCheck.candidates[9].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[9].besideLine = "Si Kα"
-seed0.four.unlistedCheck.candidates[9].fractionOfNeighbour = 3f6252bf62c4f80b 0.0022367227558381989
-seed0.four.unlistedCheck.candidates[10].element = "Ta"
-seed0.four.unlistedCheck.candidates[10].group = "Ta_Ma"
-seed0.four.unlistedCheck.candidates[10].net = 40cacfa148661eb4 13727.26002193927
-seed0.four.unlistedCheck.candidates[10].detectionLimit = 40b8a30c4584e8ae 6307.0479357784334
+seed0.four.unlistedCheck.candidates[9].fractionOfNeighbour = 3f609a2d90ad85a4 0.0020266427940646859
+seed0.four.unlistedCheck.candidates[10].element = "Zr"
+seed0.four.unlistedCheck.candidates[10].group = "Zr_La"
+seed0.four.unlistedCheck.candidates[10].net = 408d784575c98a9b 943.03391606764069
+seed0.four.unlistedCheck.candidates[10].detectionLimit = 40790d485fe39ac8 400.83016957195332
 seed0.four.unlistedCheck.candidates[10].sumPeakQuestion = true
-seed0.four.unlistedCheck.candidates[10].besideLine = "Si Kα"
-seed0.four.unlistedCheck.candidates[10].fractionOfNeighbour = 3f8d3bfc1b383a02 0.014274568157842008
-seed0.four.unlistedCheck.candidates[11].element = "Zr"
-seed0.four.unlistedCheck.candidates[11].group = "Zr_La"
-seed0.four.unlistedCheck.candidates[11].net = 4086fbd3a895e060 735.47834889498699
-seed0.four.unlistedCheck.candidates[11].detectionLimit = 40785c0b8be48a7f 389.75281895898655
+seed0.four.unlistedCheck.candidates[10].besideLine = nil
+seed0.four.unlistedCheck.candidates[10].fractionOfNeighbour = nil
+seed0.four.unlistedCheck.candidates[11].element = "Ta"
+seed0.four.unlistedCheck.candidates[11].group = "Ta_Ma"
+seed0.four.unlistedCheck.candidates[11].net = 40cd8add1d9315e1 15125.727465043719
+seed0.four.unlistedCheck.candidates[11].detectionLimit = 40b921329441c76c 6433.1975747215147
 seed0.four.unlistedCheck.candidates[11].sumPeakQuestion = true
-seed0.four.unlistedCheck.candidates[11].besideLine = nil
-seed0.four.unlistedCheck.candidates[11].fractionOfNeighbour = nil
+seed0.four.unlistedCheck.candidates[11].besideLine = "Si Kα"
+seed0.four.unlistedCheck.candidates[11].fractionOfNeighbour = 3f901d83fe0d6824 0.015737593060613744
 seed0.four.unlistedCheck.candidates[12].element = "P"
 seed0.four.unlistedCheck.candidates[12].group = "P_Ka"
-seed0.four.unlistedCheck.candidates[12].net = 4089d96dfce1262d 827.17870498559716
-seed0.four.unlistedCheck.candidates[12].detectionLimit = 407bbd62418cde8c 443.83648829485969
+seed0.four.unlistedCheck.candidates[12].net = 4090036210af153c 1024.8457667690955
+seed0.four.unlistedCheck.candidates[12].detectionLimit = 407c5096d494a115 453.03682382639209
 seed0.four.unlistedCheck.candidates[12].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[12].besideLine = nil
 seed0.four.unlistedCheck.candidates[12].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[13].element = "Hg"
 seed0.four.unlistedCheck.candidates[13].group = "Hg_La"
-seed0.four.unlistedCheck.candidates[13].net = 407d8cb14cf5afd0 472.79328628512758
-seed0.four.unlistedCheck.candidates[13].detectionLimit = 40728b5bebeaa1ba 296.70994178441072
+seed0.four.unlistedCheck.candidates[13].net = 407c86667ab180fa 456.40001935326984
+seed0.four.unlistedCheck.candidates[13].detectionLimit = 40729230a7ddf9d7 297.13687884053564
 seed0.four.unlistedCheck.candidates[13].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[13].besideLine = nil
 seed0.four.unlistedCheck.candidates[13].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[14].element = "Gd"
 seed0.four.unlistedCheck.candidates[14].group = "Gd_Ma"
-seed0.four.unlistedCheck.candidates[14].net = 40b8be795c4fd020 6334.4740648158186
-seed0.four.unlistedCheck.candidates[14].detectionLimit = 40affde91994ad33 4094.95527329077
+seed0.four.unlistedCheck.candidates[14].net = 40b7dcf526663b90 6108.9576171775261
+seed0.four.unlistedCheck.candidates[14].detectionLimit = 40b007672c140e34 4103.4030163321186
 seed0.four.unlistedCheck.candidates[14].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[14].besideLine = nil
 seed0.four.unlistedCheck.candidates[14].fractionOfNeighbour = nil
-seed0.four.unlistedCheck.moves: array 4
+seed0.four.unlistedCheck.moves: array 3
 seed0.four.unlistedCheck.moves[0].element = "O"
-seed0.four.unlistedCheck.moves[0].before = 410072e0ffd7bda3 134748.12492321161
-seed0.four.unlistedCheck.moves[0].after = 40fd5aa8dd62be56 120234.55404924726
-seed0.four.unlistedCheck.moves[0].sigma = 407a79a834ecfd2b 423.60356609891704
-seed0.four.unlistedCheck.moves[1].element = "Si"
-seed0.four.unlistedCheck.moves[1].before = 412d58f507dc03e7 961658.5153504581
-seed0.four.unlistedCheck.moves[1].after = 412d4e13fd3de09d 960265.99461271206
-seed0.four.unlistedCheck.moves[1].sigma = 409106490a893abc 1089.5713292543505
-seed0.four.unlistedCheck.moves[2].element = "Ti"
-seed0.four.unlistedCheck.moves[2].before = 0000000000000000 0
-seed0.four.unlistedCheck.moves[2].after = 40a7016d52892399 2944.7135203224138
-seed0.four.unlistedCheck.moves[2].sigma = 405acf5ea0066303 107.24015045760829
-seed0.four.unlistedCheck.moves[3].element = "Ni"
-seed0.four.unlistedCheck.moves[3].before = 411770298624487b 384010.38099778414
-seed0.four.unlistedCheck.moves[3].after = 4118269d10d86cb6 395687.26645059453
-seed0.four.unlistedCheck.moves[3].sigma = 4085133b2bf1e553 674.40389241200535
+seed0.four.unlistedCheck.moves[0].before = 410072e05827d1ff 134748.04304470119
+seed0.four.unlistedCheck.moves[0].after = 40fd5a1fc204f243 120225.98486799844
+seed0.four.unlistedCheck.moves[0].sigma = 407a79a87f152bb6 423.60363682050536
+seed0.four.unlistedCheck.moves[1].element = "Ti"
+seed0.four.unlistedCheck.moves[1].before = 0000000000000000 0
+seed0.four.unlistedCheck.moves[1].after = 40a7071feb7b700f 2947.5623434614458
+seed0.four.unlistedCheck.moves[1].sigma = 405b0b9abb14c5e6 108.18131901768319
+seed0.four.unlistedCheck.moves[2].element = "Ni"
+seed0.four.unlistedCheck.moves[2].before = 4117716d1fe5a512 384091.28114946291
+seed0.four.unlistedCheck.moves[2].after = 411826863f342d46 395681.56172247638
+seed0.four.unlistedCheck.moves[2].sigma = 408513881c1ae9d4 674.44145985628211
 seed0.four.unlistedCheck.largest.element = "O"
-seed0.four.unlistedCheck.largest.before = 410072e0ffd7bda3 134748.12492321161
-seed0.four.unlistedCheck.largest.after = 40fd5aa8dd62be56 120234.55404924726
-seed0.four.unlistedCheck.largest.sigma = 407a79a834ecfd2b 423.60356609891704
+seed0.four.unlistedCheck.largest.before = 410072e05827d1ff 134748.04304470119
+seed0.four.unlistedCheck.largest.after = 40fd5a1fc204f243 120225.98486799844
+seed0.four.unlistedCheck.largest.sigma = 407a79a87f152bb6 423.60363682050536
 seed0.four.unlistedCheck.failure = nil
 seed0.four.withholding: array 2
-seed0.four.withholding[0]: n 4 sum 4059000000000001 100.00000000000001 fnv 88988f9b68172c5c
-seed0.four.withholding[0][0] = 402827591f12439f 12.076851817111502
-seed0.four.withholding[0][1] = 405035d9260f67db 64.841378703159918
+seed0.four.withholding[0]: n 4 sum 4059000000000000 100 fnv 5b71a223b53c43f6
+seed0.four.withholding[0][0] = 40282949696714e0 12.080638212044903
+seed0.four.withholding[0][1] = 405034d49effee11 64.825477361613835
 seed0.four.withholding[0][2] = 0000000000000000 0
-seed0.four.withholding[0][3] = 403714eed8393ec7 23.081769479728589
-seed0.four.withholding[1]: n 4 sum 413696e105720bc7 1480417.0212714539 fnv 1d3bca855b2aca36
-seed0.four.withholding[1][0] = 410072e0ffd7bda3 134748.12492321161
-seed0.four.withholding[1][1] = 412d58f507dc03e7 961658.5153504581
+seed0.four.withholding[0][3] = 40371808cf4cbd4e 23.093884426341269
+seed0.four.withholding[1]: n 4 sum 4136951816902afe 1479960.0881373282 fnv 79057b7c1460521c
+seed0.four.withholding[1][0] = 410072e05827d1ff 134748.04304470119
+seed0.four.withholding[1][1] = 412d54c187238ef3 961120.76394316403
 seed0.four.withholding[1][2] = 0000000000000000 0
-seed0.four.withholding[1][3] = 411770298624487b 384010.38099778414
-seed0.four.withholding.caveat = "assumes the listed elements only; unlisted: Ge (net 266 941), Ga (net 299 924), Cu (net 59 538), excess beside Ni Lα (net 59 664), Eu (net 75 051), Sm (net 23 012), excess beside Si Kα (net 24 383), excess beside Ni Lα (net 13 085), excess beside Ni Lα (net 5 227), excess beside Si Kα (net 2 151), excess beside Si Kα (net 13 727), Zr (net 735), P (net 827), Hg (net 473), Gd (net 6 334); largest move 34.3 σ (O)"
-seed0.four.csv-withholding-fnv = cecfa8405bceef7c
+seed0.four.withholding[1][3] = 4117716d1fe5a512 384091.28114946291
+seed0.four.withholding.caveat = "assumes the listed elements only; unlisted: Ge (net 266 867), Ga (net 299 903), Cu (net 59 388), excess beside Ni Lα (net 59 562), Eu (net 75 015), Sm (net 23 332), excess beside Si Kα (net 23 653), excess beside Ni Lα (net 13 244), excess beside Ni Lα (net 5 231), excess beside Si Kα (net 1 948), Zr (net 943), excess beside Si Kα (net 15 126), P (net 1 025), Hg (net 456), Gd (net 6 109); largest move 34.3 σ (O)"
+seed0.four.csv-withholding-fnv = 5d17985677fac897
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.f64 b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.f64
index 66cc9bb..0c5420e 100644
Binary files a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.f64 and b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.f64 differ
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.json b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.json
index 1242107..cca96eb 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.json
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.arrays.json
@@ -1 +1 @@
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\ No newline at end of file
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\ No newline at end of file
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.txt b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.txt
index 694f645..bbbb8b8 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.txt
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-unlisted-sim.txt
@@ -31,26 +31,26 @@ seed0.four.quantification.method.fitToKeV = nil
 seed0.four.quantification.rows: array 4
 seed0.four.quantification.rows[0].element = "O"
 seed0.four.quantification.rows[0].groupID = "O_Ka"
-seed0.four.quantification.rows[0].net = 41007c278ba3815b 135044.94318295535
-seed0.four.quantification.rows[0].sigma = 407a8f6b1d851b72 424.96365119929317
+seed0.four.quantification.rows[0].net = 41007a2dbb41443f 134981.71643307988
+seed0.four.quantification.rows[0].sigma = 407a8daff277c697 424.85545584475898
 seed0.four.quantification.rows[0].supported = true
 seed0.four.quantification.rows[0].atBound = false
 seed0.four.quantification.rows[0].isReference = false
-seed0.four.quantification.rows[0].kFreeRatio = 3fc1f4128e701b23 0.14026100115753434
-seed0.four.quantification.rows[0].kFreeSigma = 3f3ebe4ff1cf3d2a 0.00046910716792765656
-seed0.four.quantification.rows[0].atomicPercent = 402830a26b31d83e 12.094989156565244
-seed0.four.quantification.rows[0].atomicSigma = 4001998ccde6cb82 2.1999755941446333
-seed0.four.quantification.rows[0].weightPercent = 4016fcba228c8e91 5.7468037985123752
-seed0.four.quantification.rows[0].weightSigma = 3ff2dcdb8708fd90 1.1789202952203119
+seed0.four.quantification.rows[0].kFreeRatio = 3fc1f59ed2c031bf 0.14030823984684379
+seed0.four.quantification.rows[0].kFreeSigma = 3f3ec441fc6996ca 0.00046946154581060647
+seed0.four.quantification.rows[0].atomicPercent = 4028311a1c0a17c4 12.0959023248978
+seed0.four.quantification.rows[0].atomicSigma = 40019a0cd0045b55 2.2002197505311565
+seed0.four.quantification.rows[0].weightPercent = 4016fc554a3624e6 5.7464191051051099
+seed0.four.quantification.rows[0].weightSigma = 3ff2dcf8adabbaea 1.1789480957046927
 seed0.four.quantification.rows[0].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[0].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[0].atomicTerms.relative.counting = 3f67ad75c94b3630 0.0028903294099567253
-seed0.four.quantification.rows[0].atomicTerms.relative.k = 3fc74777c11d409d 0.18186852387816979
+seed0.four.quantification.rows[0].atomicTerms.relative.counting = 3f67af411e1a20c0 0.0028911849811415757
+seed0.four.quantification.rows[0].atomicTerms.relative.k = 3fc747adc8147f48 0.18187496442350892
 seed0.four.quantification.rows[0].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[0].weightTerms.relative: dict 4
 seed0.four.quantification.rows[0].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[0].weightTerms.relative.counting = 3f6979821bcc2036 0.0031096974547644386
-seed0.four.quantification.rows[0].weightTerms.relative.k = 3fca415febab755a 0.20512007720291586
+seed0.four.quantification.rows[0].weightTerms.relative.counting = 3f697b3ffd09eec1 0.0031105279707029647
+seed0.four.quantification.rows[0].weightTerms.relative.k = 3fca41fb9e8eff08 0.20513863794439424
 seed0.four.quantification.rows[0].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[0].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[0].absorptionSpreadWeight = nil
@@ -60,26 +60,26 @@ seed0.four.quantification.rows[0].failure = nil
 seed0.four.quantification.rows[0].lineNote = nil
 seed0.four.quantification.rows[1].element = "Si"
 seed0.four.quantification.rows[1].groupID = "Si_Ka"
-seed0.four.quantification.rows[1].net = 412d61f78baff631 962811.77282685612
-seed0.four.quantification.rows[1].sigma = 40910adcd689dddf 1090.7156621495885
+seed0.four.quantification.rows[1].net = 412d5be9f9c7be46 962036.9878520451
+seed0.four.quantification.rows[1].sigma = 40911039ab9dd587 1092.0563187276437
 seed0.four.quantification.rows[1].supported = true
 seed0.four.quantification.rows[1].atBound = false
 seed0.four.quantification.rows[1].isReference = true
 seed0.four.quantification.rows[1].kFreeRatio = 3ff0000000000000 1
 seed0.four.quantification.rows[1].kFreeSigma = nil
-seed0.four.quantification.rows[1].atomicPercent = 405037eb452be34c 64.87373475347448
-seed0.four.quantification.rows[1].atomicSigma = 400b0d8428f100b6 3.3815997313068591
-seed0.four.quantification.rows[1].weightPercent = 404b0dee9510c631 54.108843453588982
-seed0.four.quantification.rows[1].weightSigma = 4011aace7d70faba 4.4168033218581346
+seed0.four.quantification.rows[1].atomicPercent = 405036d5a39e5ff6 64.856789498007714
+seed0.four.quantification.rows[1].atomicSigma = 400b0f9e20a7f7d0 3.3826258231410762
+seed0.four.quantification.rows[1].weightPercent = 404b0b22fdc837be 54.087005350840158
+seed0.four.quantification.rows[1].weightSigma = 4011ab75eaf45eee 4.4174420081760513
 seed0.four.quantification.rows[1].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[1].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[1].atomicTerms.relative.counting = 3f46923faafccc3a 0.00068882092270994917
-seed0.four.quantification.rows[1].atomicTerms.relative.k = 3faaafa52bbb1aa9 0.052121316517106671
+seed0.four.quantification.rows[1].atomicTerms.relative.counting = 3f469a285fe3e899 0.00068976375021569385
+seed0.four.quantification.rows[1].atomicTerms.relative.k = 3faab380ada65a93 0.052150746533859003
 seed0.four.quantification.rows[1].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[1].weightTerms.relative: dict 4
 seed0.four.quantification.rows[1].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[1].weightTerms.relative.counting = 3f4d9d2a8bbb2b6a 0.00090374543602798657
-seed0.four.quantification.rows[1].weightTerms.relative.k = 3fb4e540b62fa110 0.08162311981107373
+seed0.four.quantification.rows[1].weightTerms.relative.counting = 3f4da7d94945a008 0.00090501889876026895
+seed0.four.quantification.rows[1].weightTerms.relative.k = 3fb4e82f9458809c 0.08166787502023215
 seed0.four.quantification.rows[1].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[1].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[1].absorptionSpreadWeight = nil
@@ -90,12 +90,12 @@ seed0.four.quantification.rows[1].lineNote = nil
 seed0.four.quantification.rows[2].element = "Ti"
 seed0.four.quantification.rows[2].groupID = "Ti_Ka"
 seed0.four.quantification.rows[2].net = 0000000000000000 0
-seed0.four.quantification.rows[2].sigma = 405b2734a225834e 108.61258748687143
+seed0.four.quantification.rows[2].sigma = 405b656b296d9c10 109.58466563896241
 seed0.four.quantification.rows[2].supported = true
 seed0.four.quantification.rows[2].atBound = true
 seed0.four.quantification.rows[2].isReference = false
 seed0.four.quantification.rows[2].kFreeRatio = 0000000000000000 0
-seed0.four.quantification.rows[2].kFreeSigma = 3f1d9265a22f521b 0.00011280770608774369
+seed0.four.quantification.rows[2].kFreeSigma = 3f1ddc4d9e62aab5 0.00011390899416833629
 seed0.four.quantification.rows[2].atomicPercent = 0000000000000000 0
 seed0.four.quantification.rows[2].atomicSigma = 0000000000000000 0
 seed0.four.quantification.rows[2].weightPercent = 0000000000000000 0
@@ -118,26 +118,26 @@ seed0.four.quantification.rows[2].failure = nil
 seed0.four.quantification.rows[2].lineNote = nil
 seed0.four.quantification.rows[3].element = "Ni"
 seed0.four.quantification.rows[3].groupID = "Ni_Ka"
-seed0.four.quantification.rows[3].net = 4117673a001fc5cb 383438.50012120296
-seed0.four.quantification.rows[3].sigma = 40851191b7105393 674.19614994769142
+seed0.four.quantification.rows[3].net = 411768233e47be00 383496.81082054973
+seed0.four.quantification.rows[3].sigma = 408511ad670abf11 674.20966919322575
 seed0.four.quantification.rows[3].supported = true
 seed0.four.quantification.rows[3].atBound = false
 seed0.four.quantification.rows[3].isReference = false
-seed0.four.quantification.rows[3].kFreeRatio = 3fd97ce7f48eb806 0.39824866182868879
-seed0.four.quantification.rows[3].kFreeSigma = 3f4b6c298bb943bc 0.00083686855891517515
-seed0.four.quantification.rows[3].atomicPercent = 40370801b5b786b3 23.031276089960283
-seed0.four.quantification.rows[3].atomicSigma = 400cc5c56600ee57 3.5965679139169811
-seed0.four.quantification.rows[3].weightPercent = 4044127a269da7fc 40.144352747898637
-seed0.four.quantification.rows[3].weightSigma = 40136fbfea114fbf 4.8591305325571161
+seed0.four.quantification.rows[3].kFreeRatio = 3fd983276e645285 0.39863000660378872
+seed0.four.quantification.rows[3].kFreeSigma = 3f4b77f1979f10ce 0.00083827301499941344
+seed0.four.quantification.rows[3].atomicPercent = 40370c1c6381744a 23.0473081770945
+seed0.four.quantification.rows[3].atomicSigma = 400cc96f62ae84ba 3.5983569821842964
+seed0.four.quantification.rows[3].weightPercent = 4044155258f103a6 40.166575544054737
+seed0.four.quantification.rows[3].weightSigma = 401370b4857a7672 4.8600636344905173
 seed0.four.quantification.rows[3].atomicTerms.relative: dict 4
 seed0.four.quantification.rows[3].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[3].atomicTerms.relative.counting = 3f5a1dccdf7f25ca 0.0015940190041753171
-seed0.four.quantification.rows[3].atomicTerms.relative.k = 3fc3fcca2d15fe56 0.15615203095875313
+seed0.four.quantification.rows[3].atomicTerms.relative.counting = 3f5a202c455ef08b 0.0015945846875942439
+seed0.four.quantification.rows[3].atomicTerms.relative.k = 3fc3fbc60d9f9224 0.1561210218925605
 seed0.four.quantification.rows[3].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[3].weightTerms.relative: dict 4
 seed0.four.quantification.rows[3].weightTerms.relative.absorption = 0000000000000000 0
-seed0.four.quantification.rows[3].weightTerms.relative.counting = 3f54507e22694603 0.0012398940831598322
-seed0.four.quantification.rows[3].weightTerms.relative.k = 3fbefc27f33746a6 0.12103509605301585
+seed0.four.quantification.rows[3].weightTerms.relative.counting = 3f5452021a51cd38 0.0012402554068813975
+seed0.four.quantification.rows[3].weightTerms.relative.k = 3fbef94a0f302cf7 0.12099135275655103
 seed0.four.quantification.rows[3].weightTerms.relative.thickness = 0000000000000000 0
 seed0.four.quantification.rows[3].absorptionSpreadAtomic = nil
 seed0.four.quantification.rows[3].absorptionSpreadWeight = nil
@@ -153,14 +153,14 @@ seed0.four.quantification.fit.groupIDs[2] = "O_Ka"
 seed0.four.quantification.fit.groupIDs[3] = "Si_Ka"
 seed0.four.quantification.fit.groupIDs[4] = "Ti_Ka"
 seed0.four.quantification.fit.groupIDs[5] = "Ti_La"
-seed0.four.quantification.fit.values: n 6 sum 4136bfc969e4511f 1490889.4136400891 fnv c721ee7d2e9b8879
-seed0.four.quantification.fit.values[0] = 4117673a001fc5cb 383438.50012120296
+seed0.four.quantification.fit.values: n 6 sum 4136bcbb250ddf88 1490107.1447429378 fnv d6c5112e95c5b6d2
+seed0.four.quantification.fit.values[0] = 411768233e47be00 383496.81082054973
 seed0.four.quantification.fit.values[1] = 0000000000000000 0
-seed0.four.quantification.fit.values[2] = 41007c278ba3815b 135044.94318295535
-seed0.four.quantification.fit.values[3] = 412d61f78baff631 962811.77282685612
+seed0.four.quantification.fit.values[2] = 41007a2dbb41443f 134981.71643307988
+seed0.four.quantification.fit.values[3] = 412d5be9f9c7be46 962036.9878520451
 seed0.four.quantification.fit.values[4] = 0000000000000000 0
-seed0.four.quantification.fit.values[5] = 40c2bd1947fa34be 9594.1975090749293
-seed0.four.quantification.fit.covariance: n 36 sum 414001ec79b03a1d 2098136.9506905214 fnv ab6a8a1572e39ab6
+seed0.four.quantification.fit.values[5] = 40c2bbd097f42e46 9591.6296372629113
+seed0.four.quantification.fit.covariance: n 36 sum 4140055803608fc0 2099888.0263843238 fnv bfe9a1f1fe11d950
 seed0.four.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 seed0.four.quantification.fit.supported: n 6 sum-bits 6 fnv e78b9a1f4dd1d485
 seed0.four.quantification.fit.atBound: n 6 sum-bits 2 fnv 50ffa157bd1b5485
@@ -169,7 +169,7 @@ seed0.four.quantification.fit.escapeValues[0] = 0000000000000000 0
 seed0.four.quantification.fit.escapeValues[1] = nil
 seed0.four.quantification.fit.escapeValues[2] = nil
 seed0.four.quantification.fit.escapeValues[3] = nil
-seed0.four.quantification.fit.escapeValues[4] = 40906644dc6b0168 1049.5672470779045
+seed0.four.quantification.fit.escapeValues[4] = 4087cb40d9e3534a 761.40666558835915
 seed0.four.quantification.fit.escapeValues[5] = nil
 seed0.four.quantification.fit.backgroundNames: array 16
 seed0.four.quantification.fit.backgroundNames[0] = "continuum s0 t^0"
@@ -188,25 +188,25 @@ seed0.four.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 seed0.four.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 seed0.four.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 seed0.four.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-seed0.four.quantification.fit.backgroundCoefficients: n 16 sum 415ea0a1b3e4f8f6 8028806.8108503725 fnv 65671811d5a71829
+seed0.four.quantification.fit.backgroundCoefficients: n 16 sum 415ea43940ad5982 8032485.0105804224 fnv a3bacd317a0c4cc4
 seed0.four.quantification.fit.channels = 107..<1098
-seed0.four.quantification.fit.model: n 991 sum 415024326ad77e81 4231369.6694027195 fnv b9f4ad211b8da137
-seed0.four.quantification.fit.residual: n 991 sum c10ebb155aefd028 -251746.66940271971 fnv 505be1b95364ea7e
-seed0.four.quantification.fit.standardizedResidual: n 991 sum c0add36c7f90da56 -3817.7119107500575 fnv 3f07dc1432b1b34
+seed0.four.quantification.fit.model: n 991 sum 4150277a001e5418 4234728.0018511042 fnv 9fe87df9395adcd9
+seed0.four.quantification.fit.residual: n 991 sum c10f240803ca834c -255105.00185110641 fnv 49c111ea19797dba
+seed0.four.quantification.fit.standardizedResidual: n 991 sum c0afa71159f64a0c -4051.5338894811048 fnv a94bdad9b954af62
 seed0.four.quantification.fit.negativeModelChannels = 0
 seed0.four.quantification.fit.degreesOfFreedom = 967
-seed0.four.quantification.fit.reducedChiSquared = 418532e5d71edbfb 44457146.890068017
-seed0.four.quantification.fit.pearsonReducedChiSquared = 40b49ee7b74bd89a 5278.9051406291783
-seed0.four.quantification.fit.deviance = 4141711ada832629 2286133.7071273518
-seed0.four.quantification.fit.reducedDeviance = 40a2784d25decd13 2364.150679552587
+seed0.four.quantification.fit.reducedChiSquared = 4185325126c38f94 44452388.845488697
+seed0.four.quantification.fit.pearsonReducedChiSquared = 40b47ac6a66aa568 5242.7759768155884
+seed0.four.quantification.fit.deviance = 414160cc4f1a20ff 2277784.6179848905
+seed0.four.quantification.fit.reducedDeviance = 40a2670888b6466a 2355.5166680298762
 seed0.four.quantification.fit.methodLabel = "least squares, unweighted"
 seed0.four.quantification.fit.referenceShapesLabel = "reference shapes: none"
 seed0.four.quantification.fit.escapeLabel = "escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 seed0.four.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-seed0.four.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+seed0.four.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 seed0.four.quantification.fit.exit = "converged"
 seed0.four.quantification.fit.warnings: array 1
-seed0.four.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.four.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.four.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.fit.escapeRatios: array 6
 seed0.four.quantification.fit.escapeRatios[0] = 0000000000000000 0
@@ -222,23 +222,23 @@ seed0.four.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cb
 seed0.four.quantification.fileAxis.offset = bffeea58ae97d879 -1.9322134799999999
 seed0.four.quantification.fileAxis.scale = 3f947ae147ae147b 0.02
 seed0.four.quantification.fileAxis.size = 4096
-seed0.four.quantification.usedAxis.offset = bffee87dfd474f34 -1.9317607778256844
-seed0.four.quantification.usedAxis.scale = 3f947aacb0a20425 0.019999216347518129
+seed0.four.quantification.usedAxis.offset = bffee87642041f40 -1.9317534044984797
+seed0.four.quantification.usedAxis.scale = 3f947aab48a835af 0.019999195394168442
 seed0.four.quantification.usedAxis.size = 4096
 seed0.four.quantification.axisLocked = false
 seed0.four.quantification.refinement.fileOffset = bffeea58ae97d879 -1.9322134799999999
 seed0.four.quantification.refinement.fileScale = 3f947ae147ae147b 0.02
 seed0.four.quantification.refinement.fileResolutionMnKaEV = 4060400000000000 130
-seed0.four.quantification.refinement.offset = bffee87dfd474f34 -1.9317607778256844
-seed0.four.quantification.refinement.scale = 3f947aacb0a20425 0.019999216347518129
-seed0.four.quantification.refinement.resolutionMnKaEV = 40605ba00155e3f9 130.86328188682072
-seed0.four.quantification.refinement.rssFile = 4224082477bb76f7 43017976797.732353
-seed0.four.quantification.refinement.rssRefined = 422404d08be5643c 42990061042.69577
-seed0.four.quantification.refinement.iterations = 80
+seed0.four.quantification.refinement.offset = bffee87642041f40 -1.9317534044984797
+seed0.four.quantification.refinement.scale = 3f947aab48a835af 0.019999195394168442
+seed0.four.quantification.refinement.resolutionMnKaEV = 40605ae438898284 130.84035899026287
+seed0.four.quantification.refinement.rssFile = 4224077700731f16 43012292665.560715
+seed0.four.quantification.refinement.rssRefined = 42240444225b2cd6 42985460013.58757
+seed0.four.quantification.refinement.iterations = 71
 seed0.four.quantification.refinement.converged = true
 seed0.four.quantification.refinement.size = 4096
-seed0.four.quantification.plotModel: n 4096 sum 415024326ad77e81 4231369.6694027195 fnv 6e1ebe47387e8b17
-seed0.four.quantification.plotBackground: n 4096 sum 4144334479cee0d9 2647688.951625925 fnv ed1bcee77677a0fe
+seed0.four.quantification.plotModel: n 4096 sum 4150277a001e5418 4234728.0018511042 fnv 35bd38a650d42ab9
+seed0.four.quantification.plotBackground: n 4096 sum 41443c04d862488b 2652169.6904993705 fnv 733b41c1d521b3d4
 seed0.four.quantification.kSet.kind = .computed
 seed0.four.quantification.kSet.elements: array 4
 seed0.four.quantification.kSet.elements[0] = "O"
@@ -262,14 +262,14 @@ seed0.four.quantification.abundanceRefusal = nil
 seed0.four.quantification.absorption = .off
 seed0.four.quantification.warnings: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-seed0.four.quantification.quality = 40b49ee7b74bd89a 5278.9051406291783
+seed0.four.quantification.quality = 40b47ac6a66aa568 5242.7759768155884
 seed0.four.quantification.footerLines: array 9
-seed0.four.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
+seed0.four.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 2 line groups above the Si K edge (1.839 keV)"
 seed0.four.quantification.footerLines[1] = "energy axis: file -1.932 keV + 0.0200 keV/ch → refined +0.5 eV, gain -0.004 %, FWHM(Mn Kα) 131 eV"
 seed0.four.quantification.footerLines[2] = "beam 200 kV · typed"
 seed0.four.quantification.footerLines[3] = "fit range 0.2–20 keV (default; axis to 79.97 keV) · 1 px pooled (synthetic)"
 seed0.four.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-seed0.four.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 5279 (Pearson)"
+seed0.four.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 5243 (Pearson)"
 seed0.four.quantification.footerLines[6] = "k: computed: Bote-Salvat 2008 (NIST EPQ tables, PRA 77 042701), edges DHS xionUis.csv; not Velox's Brown-Powell default; omega: Krause 1979 (NIST EPQ Krause1979.csv); epsilon: EPQ getDefaultSDDProperties (Au 0.0 nm, Al 10.0 nm, Si dead layer 0.0 µm, Si 450.0 µm); generic SDD model, not a measured calibration of this detector; FFAST MACs; relative to Si; beam 200.0 keV; UNVALIDATED (EPQ 249dd3f8 + Krause 1979 + FFAST); σ_k 20 % flat, 0 on the reference (Si)"
 seed0.four.quantification.footerLines[7] = "k-free ratio: net / net(Si)"
 seed0.four.quantification.footerLines[8] = "absorption correction: off"
@@ -278,7 +278,7 @@ seed0.four.quantification.fitSettings.elements[0] = "O"
 seed0.four.quantification.fitSettings.elements[1] = "Si"
 seed0.four.quantification.fitSettings.elements[2] = "Ti"
 seed0.four.quantification.fitSettings.elements[3] = "Ni"
-seed0.four.quantification.fitSettings.resolutionMnKaEV = 40605ba00155e3f9 130.86328188682072
+seed0.four.quantification.fitSettings.resolutionMnKaEV = 40605ae438898284 130.84035899026287
 seed0.four.quantification.fitSettings.beamEnergy = 4069000000000000 200
 seed0.four.quantification.fitSettings.fitFrom = 3fc999999999999a 0.20000000000000001
 seed0.four.quantification.fitSettings.fitTo = 4034000000000000 20
@@ -288,7 +288,7 @@ seed0.four.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f21
 seed0.four.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 seed0.four.quantification.fitSettings.background.continuum.nonNegative = true
 seed0.four.quantification.fitSettings.background.continuum.efficiency = nil
-seed0.four.quantification.fitSettings.background.continuum.edgeStep = .sharp
+seed0.four.quantification.fitSettings.background.continuum.edgeStep = .broadened
 seed0.four.quantification.fitSettings.escapePeaks = true
 seed0.four.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.quantification.fitSettings.method = .leastSquares
@@ -299,7 +299,7 @@ seed0.four.quantification.fitRange.toKeV = 4034000000000000 20
 seed0.four.quantification.fitRange.source = .defaultLimit
 seed0.four.quantification.fitRange.axisEndKeV = 4053fdf036df3a38 79.967786520000004
 seed0.four.quantification.fitRange.beamEnergyKeV = 4069000000000000 200
-seed0.four.quantification.fitRange.reachKeV = 4053fdc30de1dcc8 79.965030165261055
+seed0.four.quantification.fitRange.reachKeV = 4053fdc1c4eb9aaf 79.964951734621295
 seed0.four.quantification.fitRange.typedKeV = nil
 seed0.four.quantification.rangeSensitivity = nil
 seed0.four.quantification.unlistedCheck = nil
@@ -307,39 +307,39 @@ seed0.four.quantification.unlistedCheckPending = false
 seed0.four.quantification.abundanceCaveat = nil
 seed0.four.quantification.appliedSumEscape = nil
 seed0.four.quantification.continuumDeadLayerMicrons = nil
-seed0.four.csv-fnv = 39e1a8432149c423
-seed0.four.rangeSensitivity.alternativeToKeV = 4053fdc30de1dcc8 79.965030165261055
+seed0.four.csv-fnv = 25a1e05b321a14fb
+seed0.four.rangeSensitivity.alternativeToKeV = 4053fdc1c4eb9aaf 79.964951734621295
 seed0.four.rangeSensitivity.moves: array 4
 seed0.four.rangeSensitivity.moves[0].element = "O"
 seed0.four.rangeSensitivity.moves[0].group = "O_Ka"
-seed0.four.rangeSensitivity.moves[0].before = 41007c278ba3815b 135044.94318295535
-seed0.four.rangeSensitivity.moves[0].sigma = 407a8f6b1d851b72 424.96365119929317
-seed0.four.rangeSensitivity.moves[0].after = 41007c278ba37f7e 135044.94318294147
+seed0.four.rangeSensitivity.moves[0].before = 41007a2dbb41443f 134981.71643307988
+seed0.four.rangeSensitivity.moves[0].sigma = 407a8daff277c697 424.85545584475898
+seed0.four.rangeSensitivity.moves[0].after = 41007a2f1cb63c32 134981.88901946094
 seed0.four.rangeSensitivity.moves[1].element = "Si"
 seed0.four.rangeSensitivity.moves[1].group = "Si_Ka"
-seed0.four.rangeSensitivity.moves[1].before = 412d61f78baff631 962811.77282685612
-seed0.four.rangeSensitivity.moves[1].sigma = 40910adcd689dddf 1090.7156621495885
-seed0.four.rangeSensitivity.moves[1].after = 412d6ea605e79e17 964435.01153272658
+seed0.four.rangeSensitivity.moves[1].before = 412d5be9f9c7be46 962036.9878520451
+seed0.four.rangeSensitivity.moves[1].sigma = 40911039ab9dd587 1092.0563187276437
+seed0.four.rangeSensitivity.moves[1].after = 412d6a702e74e2d3 963896.09073551965
 seed0.four.rangeSensitivity.moves[2].element = "Ti"
 seed0.four.rangeSensitivity.moves[2].group = "Ti_Ka"
 seed0.four.rangeSensitivity.moves[2].before = 0000000000000000 0
-seed0.four.rangeSensitivity.moves[2].sigma = 405b2734a225834e 108.61258748687143
+seed0.four.rangeSensitivity.moves[2].sigma = 405b656b296d9c10 109.58466563896241
 seed0.four.rangeSensitivity.moves[2].after = 0000000000000000 0
 seed0.four.rangeSensitivity.moves[3].element = "Ni"
 seed0.four.rangeSensitivity.moves[3].group = "Ni_Ka"
-seed0.four.rangeSensitivity.moves[3].before = 4117673a001fc5cb 383438.50012120296
-seed0.four.rangeSensitivity.moves[3].sigma = 40851191b7105393 674.19614994769142
-seed0.four.rangeSensitivity.moves[3].after = 4117ba51a4ea48b1 388756.41104997235
+seed0.four.rangeSensitivity.moves[3].before = 411768233e47be00 383496.81082054973
+seed0.four.rangeSensitivity.moves[3].sigma = 408511ad670abf11 674.20966919322575
+seed0.four.rangeSensitivity.moves[3].after = 4117ba16d9df2e23 388741.71276542748
 seed0.four.rangeSensitivity.failure = nil
 seed0.four.unlistedProposal.candidates: array 35
 seed0.four.unlistedProposal.candidates[0].element = "Ge"
 seed0.four.unlistedProposal.candidates[0].group = "Ge_Ka"
 seed0.four.unlistedProposal.candidates[0].energyKeV = 4023c5d63886594b 9.8864000000000001
-seed0.four.unlistedProposal.candidates[0].net = 411038038f36946d 265728.88985664287
-seed0.four.unlistedProposal.candidates[0].sigma = 4081510676b4e7c4 554.12815610248845
-seed0.four.unlistedProposal.candidates[0].sigmaZero = 404b8f43a6eb7fd7 55.119252076139382
-seed0.four.unlistedProposal.candidates[0].criticalLevel = 4056aa70421493cc 90.663101692290354
-seed0.four.unlistedProposal.candidates[0].detectionLimit = 4067010411f23bb1 184.03174683867613
+seed0.four.unlistedProposal.candidates[0].net = 411036da4b67f29f 265654.57363871665
+seed0.four.unlistedProposal.candidates[0].sigma = 408151122d52e3f2 554.13387551077017
+seed0.four.unlistedProposal.candidates[0].sigmaZero = 404bf5b85dfcd859 55.919688938579107
+seed0.four.unlistedProposal.candidates[0].criticalLevel = 4056feb374eb40ab 91.979703168619992
+seed0.four.unlistedProposal.candidates[0].detectionLimit = 4067554744c8e890 186.6649497913354
 seed0.four.unlistedProposal.candidates[0].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[0].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[0].holeRegionNote = nil
@@ -350,11 +350,11 @@ seed0.four.unlistedProposal.candidates[0].unconfirmable = false
 seed0.four.unlistedProposal.candidates[1].element = "Ga"
 seed0.four.unlistedProposal.candidates[1].group = "Ga_La"
 seed0.four.unlistedProposal.candidates[1].energyKeV = 3ff1916872b020c5 1.0980000000000001
-seed0.four.unlistedProposal.candidates[1].net = 4112560a6bedc119 300418.60539914813
-seed0.four.unlistedProposal.candidates[1].sigma = 408ab9bbdb1d1033 855.21672651963888
-seed0.four.unlistedProposal.candidates[1].sigmaZero = 407df1a251f5bbfb 479.10212894430123
-seed0.four.unlistedProposal.candidates[1].criticalLevel = 4088a06c4973cc10 788.05287447420596
-seed0.four.unlistedProposal.candidates[1].detectionLimit = 4098ab3ec36f810d 1578.8112924025074
+seed0.four.unlistedProposal.candidates[1].net = 4112510f8469e70f 300099.87931023625
+seed0.four.unlistedProposal.candidates[1].sigma = 408aa4158886e66a 852.51051431074779
+seed0.four.unlistedProposal.candidates[1].sigmaZero = 407dcd4cdbdd8b05 476.83126436748745
+seed0.four.unlistedProposal.candidates[1].criticalLevel = 4088828a84078af9 784.31763463871823
+seed0.four.unlistedProposal.candidates[1].detectionLimit = 40988d5cfe033ff6 1571.340812731532
 seed0.four.unlistedProposal.candidates[1].conflicts: array 1
 seed0.four.unlistedProposal.candidates[1].conflicts[0].id = "ga-fib"
 seed0.four.unlistedProposal.candidates[1].conflicts[0].kind = .fibContamination
@@ -375,11 +375,11 @@ seed0.four.unlistedProposal.candidates[1].unconfirmable = false
 seed0.four.unlistedProposal.candidates[2].element = "Cu"
 seed0.four.unlistedProposal.candidates[2].group = "Cu_Ka"
 seed0.four.unlistedProposal.candidates[2].energyKeV = 402018793dd97f63 8.0478000000000005
-seed0.four.unlistedProposal.candidates[2].net = 40ed6230e7539c2d 60177.528238110572
-seed0.four.unlistedProposal.candidates[2].sigma = 40741ebc217e5677 321.92093037939725
-seed0.four.unlistedProposal.candidates[2].sigmaZero = 405f2b302b979d2d 124.67481508070041
-seed0.four.unlistedProposal.candidates[2].criticalLevel = 4069a24c5d2dd7b5 205.07182177499422
-seed0.four.unlistedProposal.candidates[2].detectionLimit = 4079cd96451caba7 412.84918700408383
+seed0.four.unlistedProposal.candidates[2].net = 40ed52a7f9867c9d 60053.249209636102
+seed0.four.unlistedProposal.candidates[2].sigma = 40742193acd6c487 322.09855350392939
+seed0.four.unlistedProposal.candidates[2].sigmaZero = 405f74f81720e34f 125.82764223300659
+seed0.four.unlistedProposal.candidates[2].criticalLevel = 4069defa4bbf8e66 206.96805369771317
+seed0.four.unlistedProposal.candidates[2].detectionLimit = 407a0a4433ae6258 416.64165084952174
 seed0.four.unlistedProposal.candidates[2].conflicts: array 2
 seed0.four.unlistedProposal.candidates[2].conflicts[0].id = "sum-Ni+O sum-Cu"
 seed0.four.unlistedProposal.candidates[2].conflicts[0].kind = .sumPeak
@@ -411,11 +411,11 @@ seed0.four.unlistedProposal.candidates[2].unconfirmable = false
 seed0.four.unlistedProposal.candidates[3].element = "Eu"
 seed0.four.unlistedProposal.candidates[3].group = "Eu_Ma"
 seed0.four.unlistedProposal.candidates[3].energyKeV = 3ff195e9e1b089a0 1.0991
-seed0.four.unlistedProposal.candidates[3].net = 40f77c908fa9d086 96201.035074057145
-seed0.four.unlistedProposal.candidates[3].sigma = 40863f81c43fbec1 711.93836259652028
-seed0.four.unlistedProposal.candidates[3].sigmaZero = 40803665f41706be 518.79978197087598
-seed0.four.unlistedProposal.candidates[3].criticalLevel = 408aaacc311b062e 853.34970303642854
-seed0.four.unlistedProposal.candidates[3].detectionLimit = 409ab59eab16bb2b 1709.4049495269526
+seed0.four.unlistedProposal.candidates[3].net = 40f760d02b76a87d 95757.010611208112
+seed0.four.unlistedProposal.candidates[3].sigma = 40863e2f01b7df81 711.7729524960597
+seed0.four.unlistedProposal.candidates[3].sigmaZero = 40803dc85714ae69 519.72282234341867
+seed0.four.unlistedProposal.candidates[3].criticalLevel = 408ab6f199e8ed2b 854.86796934102802
+seed0.four.unlistedProposal.candidates[3].detectionLimit = 409ac1c413e4a228 1712.4414821361515
 seed0.four.unlistedProposal.candidates[3].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[3].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[3].holeRegionNote = nil
@@ -426,11 +426,11 @@ seed0.four.unlistedProposal.candidates[3].unconfirmable = false
 seed0.four.unlistedProposal.candidates[4].element = "Sm"
 seed0.four.unlistedProposal.candidates[4].group = "Sm_Ma"
 seed0.four.unlistedProposal.candidates[4].energyKeV = 3ff0af4f0d844d01 1.0427999999999999
-seed0.four.unlistedProposal.candidates[4].net = 40f5be087598035c 89056.528709424136
-seed0.four.unlistedProposal.candidates[4].sigma = 4086fa55c8f9c7ab 735.29188723698223
-seed0.four.unlistedProposal.candidates[4].sigmaZero = 4082a790a711dd5f 596.9456311603243
-seed0.four.unlistedProposal.candidates[4].criticalLevel = 408eaf1b0186feea 981.88818650689541
-seed0.four.unlistedProposal.candidates[4].detectionLimit = 409eb9ed7b82b3e7 1966.4819164678863
+seed0.four.unlistedProposal.candidates[4].net = 40f5c32272361a34 89138.152883627277
+seed0.four.unlistedProposal.candidates[4].sigma = 4086e2e243f43ff2 732.36048117466112
+seed0.four.unlistedProposal.candidates[4].sigmaZero = 40829734939f96f2 594.90067219428443
+seed0.four.unlistedProposal.candidates[4].criticalLevel = 408e94323be958c2 978.52452833463781
+seed0.four.unlistedProposal.candidates[4].detectionLimit = 409e9f04b5e50dbf 1959.7546001233711
 seed0.four.unlistedProposal.candidates[4].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[4].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[4].holeRegionNote = nil
@@ -441,11 +441,11 @@ seed0.four.unlistedProposal.candidates[4].unconfirmable = false
 seed0.four.unlistedProposal.candidates[5].element = "Pr"
 seed0.four.unlistedProposal.candidates[5].group = "Pr_Ma"
 seed0.four.unlistedProposal.candidates[5].energyKeV = 3fec985f06f69446 0.89359999999999995
-seed0.four.unlistedProposal.candidates[5].net = 40e832ee1ccf2caa 49559.441016757235
-seed0.four.unlistedProposal.candidates[5].sigma = 4088140776f14a77 770.50364483364581
-seed0.four.unlistedProposal.candidates[5].sigmaZero = 40854e7016b641c6 681.80473081958985
-seed0.four.unlistedProposal.candidates[5].criticalLevel = 409185e03d6fb80b 1121.4689843612748
-seed0.four.unlistedProposal.candidates[5].detectionLimit = 40a18b497a6d9289 2245.6435121766449
+seed0.four.unlistedProposal.candidates[5].net = 40e80e6ad62f9963 49267.338645743926
+seed0.four.unlistedProposal.candidates[5].sigma = 408807f378f9fc71 768.99388308812752
+seed0.four.unlistedProposal.candidates[5].sigmaZero = 4085478f7debd769 680.9450643944848
+seed0.four.unlistedProposal.candidates[5].criticalLevel = 409180384726f457 1120.0549589239724
+seed0.four.unlistedProposal.candidates[5].detectionLimit = 40a185a18424ced5 2242.8154613020401
 seed0.four.unlistedProposal.candidates[5].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[5].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[5].holeRegionNote = nil
@@ -456,11 +456,11 @@ seed0.four.unlistedProposal.candidates[5].unconfirmable = false
 seed0.four.unlistedProposal.candidates[6].element = "Na"
 seed0.four.unlistedProposal.candidates[6].group = "Na_Ka"
 seed0.four.unlistedProposal.candidates[6].energyKeV = 3ff0a7ef9db22d0e 1.0409999999999999
-seed0.four.unlistedProposal.candidates[6].net = 40d98ff787f65961 26175.867673480305
-seed0.four.unlistedProposal.candidates[6].sigma = 4089ba6ac82f348f 823.30213963393351
-seed0.four.unlistedProposal.candidates[6].sigmaZero = 408851430dea5c6a 778.15774138540769
-seed0.four.unlistedProposal.candidates[6].criticalLevel = 4093ffd2846ae981 1279.9555832581539
-seed0.four.unlistedProposal.candidates[6].detectionLimit = 40a4053bc168c3ff 2562.616709970403
+seed0.four.unlistedProposal.candidates[6].net = 40d900aa2a2ee658 25602.658824658341
+seed0.four.unlistedProposal.candidates[6].sigma = 4089b0b14e361400 822.08657495735679
+seed0.four.unlistedProposal.candidates[6].sigmaZero = 40884fbae738660e 777.96626133023688
+seed0.four.unlistedProposal.candidates[6].criticalLevel = 4093fe90006b0879 1279.6406265949174
+seed0.four.unlistedProposal.candidates[6].detectionLimit = 40a403f93d68e2f7 2561.9867966439301
 seed0.four.unlistedProposal.candidates[6].conflicts: array 1
 seed0.four.unlistedProposal.candidates[6].conflicts[0].id = "sum-O+O sum-Na"
 seed0.four.unlistedProposal.candidates[6].conflicts[0].kind = .sumPeak
@@ -477,16 +477,16 @@ seed0.four.unlistedProposal.candidates[6].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[6].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[6].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[6].familyNote = nil
-seed0.four.unlistedProposal.candidates[6].possibleReason = "Adding it improves the fit by -18127, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[6].possibleReason = "Adding it improves the fit by -13411, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[6].unconfirmable = false
 seed0.four.unlistedProposal.candidates[7].element = "Ce"
 seed0.four.unlistedProposal.candidates[7].group = "Ce_Ma"
 seed0.four.unlistedProposal.candidates[7].energyKeV = 3feb0e5604189375 0.84550000000000003
-seed0.four.unlistedProposal.candidates[7].net = 40c3b6e460a5630e 10093.784199403159
-seed0.four.unlistedProposal.candidates[7].sigma = 407786645ada5740 376.39950070657142
-seed0.four.unlistedProposal.candidates[7].sigmaZero = 4076087fad13be59 352.53117091858218
-seed0.four.unlistedProposal.candidates[7].criticalLevel = 40821ee5bc0ee8e7 579.86217509887945
-seed0.four.unlistedProposal.candidates[7].detectionLimit = 409229b8360a9de4 1162.4298936518544
+seed0.four.unlistedProposal.candidates[7].net = 40c3b7b0e4081487 10095.381958971046
+seed0.four.unlistedProposal.candidates[7].sigma = 407780e046998c12 376.05475482920986
+seed0.four.unlistedProposal.candidates[7].sigmaZero = 407602e6a910b46c 352.1813135769396
+seed0.four.unlistedProposal.candidates[7].criticalLevel = 40821a4b2f2089bd 579.28671098156303
+seed0.four.unlistedProposal.candidates[7].detectionLimit = 4092251da91c3eba 1161.2789654172216
 seed0.four.unlistedProposal.candidates[7].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[7].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[7].holeRegionNote = nil
@@ -497,11 +497,11 @@ seed0.four.unlistedProposal.candidates[7].unconfirmable = false
 seed0.four.unlistedProposal.candidates[8].element = "Rb"
 seed0.four.unlistedProposal.candidates[8].group = "Rb_La"
 seed0.four.unlistedProposal.candidates[8].energyKeV = 3ffb1b089a027525 1.6940999999999999
-seed0.four.unlistedProposal.candidates[8].net = 40d043acfc52dba5 16654.702900614258
-seed0.four.unlistedProposal.candidates[8].sigma = 408a1f8e728a7d3e 835.94455440706929
-seed0.four.unlistedProposal.candidates[8].sigmaZero = 4088fa0ae7f160af 799.25532520843797
-seed0.four.unlistedProposal.candidates[8].criticalLevel = 40948aa1d022371a 1314.6580205293781
-seed0.four.unlistedProposal.candidates[8].detectionLimit = 40a4900b0d201198 2632.0215845128514
+seed0.four.unlistedProposal.candidates[8].net = 40cf7af751330e5d 16117.93216551019
+seed0.four.unlistedProposal.candidates[8].sigma = 4089b23455d72f00 822.2755543528765
+seed0.four.unlistedProposal.candidates[8].sigmaZero = 40888bdc2d0577a1 785.48250774642304
+seed0.four.unlistedProposal.candidates[8].criticalLevel = 40943003d7814461 1292.0037517736421
+seed0.four.unlistedProposal.candidates[8].detectionLimit = 40a4356d147f1edf 2586.7130470013794
 seed0.four.unlistedProposal.candidates[8].conflicts: array 1
 seed0.four.unlistedProposal.candidates[8].conflicts[0].id = "sum-Ge+O sum-Rb"
 seed0.four.unlistedProposal.candidates[8].conflicts[0].kind = .sumPeak
@@ -524,11 +524,11 @@ seed0.four.unlistedProposal.candidates[8].unconfirmable = false
 seed0.four.unlistedProposal.candidates[9].element = "Ta"
 seed0.four.unlistedProposal.candidates[9].group = "Ta_Ma"
 seed0.four.unlistedProposal.candidates[9].energyKeV = 3ffb5c91d14e3bcd 1.7101
-seed0.four.unlistedProposal.candidates[9].net = 40d582600824b73f 22025.50049703498
-seed0.four.unlistedProposal.candidates[9].sigma = 40977cdff086ad26 1503.2186909716779
-seed0.four.unlistedProposal.candidates[9].sigmaZero = 40964ca80678b24c 1427.1640871867012
-seed0.four.unlistedProposal.candidates[9].criticalLevel = 40a256f3b98ea357 2347.4760250639333
-seed0.four.unlistedProposal.candidates[9].detectionLimit = 40b259a8580d9096 4697.6575935819619
+seed0.four.unlistedProposal.candidates[9].net = 40d7bb94c7d1728f 24302.324695932268
+seed0.four.unlistedProposal.candidates[9].sigma = 4098107325b65018 1540.1124485479722
+seed0.four.unlistedProposal.candidates[9].sigmaZero = 4096c477b79152b7 1457.1169111925826
+seed0.four.unlistedProposal.candidates[9].criticalLevel = 40a2b97cf2525771 2396.7440362674465
+seed0.four.unlistedProposal.candidates[9].detectionLimit = 40b2bc3190d144b0 4796.1936159889883
 seed0.four.unlistedProposal.candidates[9].conflicts: array 1
 seed0.four.unlistedProposal.candidates[9].conflicts[0].id = "sum-Ge+O sum-Ta"
 seed0.four.unlistedProposal.candidates[9].conflicts[0].kind = .sumPeak
@@ -551,11 +551,11 @@ seed0.four.unlistedProposal.candidates[9].unconfirmable = false
 seed0.four.unlistedProposal.candidates[10].element = "Zr"
 seed0.four.unlistedProposal.candidates[10].group = "Zr_La"
 seed0.four.unlistedProposal.candidates[10].energyKeV = 400056a161e4f766 2.0423
-seed0.four.unlistedProposal.candidates[10].net = 40886d9c1e4b3510 781.70122965579685
-seed0.four.unlistedProposal.candidates[10].sigma = 405ed70b2c0b1c97 123.36005688748479
-seed0.four.unlistedProposal.candidates[10].sigmaZero = 405e184b42c540e1 120.37959355605155
-seed0.four.unlistedProposal.candidates[10].criticalLevel = 4068c037cbda3adc 198.00681107161552
-seed0.four.unlistedProposal.candidates[10].detectionLimit = 4078eb81b3c90ece 398.71916559732642
+seed0.four.unlistedProposal.candidates[10].net = 408ec4789331b685 984.55887450063949
+seed0.four.unlistedProposal.candidates[10].sigma = 405fed88944c5986 127.71146113830591
+seed0.four.unlistedProposal.candidates[10].sigmaZero = 405efcfacb309a70 123.95280723329938
+seed0.four.unlistedProposal.candidates[10].criticalLevel = 40697c4b9147c55c 203.88422454850922
+seed0.four.unlistedProposal.candidates[10].detectionLimit = 4079a7957936994e 410.47399255111384
 seed0.four.unlistedProposal.candidates[10].conflicts: array 1
 seed0.four.unlistedProposal.candidates[10].conflicts[0].id = "sum-Cu+Ga sum-Zr"
 seed0.four.unlistedProposal.candidates[10].conflicts[0].kind = .sumPeak
@@ -575,101 +575,101 @@ seed0.four.unlistedProposal.candidates[10].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[10].familyNote = "Zr Kα (15.78 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
 seed0.four.unlistedProposal.candidates[10].possibleReason = nil
 seed0.four.unlistedProposal.candidates[10].unconfirmable = false
-seed0.four.unlistedProposal.candidates[11].element = "Gd"
-seed0.four.unlistedProposal.candidates[11].group = "Gd_Ma"
-seed0.four.unlistedProposal.candidates[11].energyKeV = 3ff2d3ae685db76b 1.1766799999999999
-seed0.four.unlistedProposal.candidates[11].net = 40bbcf09c4f36c51 7119.0381614818043
-seed0.four.unlistedProposal.candidates[11].sigma = 4094513eee0f04c2 1300.3114549967436
-seed0.four.unlistedProposal.candidates[11].sigmaZero = 4093cc70a6969730 1267.1100104837205
-seed0.four.unlistedProposal.candidates[11].criticalLevel = 40a0486bc6322eab 2084.2104964906662
-seed0.four.unlistedProposal.candidates[11].detectionLimit = 40b04b2064b11bea 4171.1265364354276
-seed0.four.unlistedProposal.candidates[11].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+seed0.four.unlistedProposal.candidates[11].element = "P"
+seed0.four.unlistedProposal.candidates[11].group = "P_Ka"
+seed0.four.unlistedProposal.candidates[11].energyKeV = 40001b3d07c84b5e 2.0133000000000001
+seed0.four.unlistedProposal.candidates[11].net = 408d744bd96157f5 942.53703571366952
+seed0.four.unlistedProposal.candidates[11].sigma = 406220b14ebe1e91 145.02164399273582
+seed0.four.unlistedProposal.candidates[11].sigmaZero = 40619938eac9cd82 140.78819789328196
+seed0.four.unlistedProposal.candidates[11].criticalLevel = 406cf26e69482ea7 231.5759779367265
+seed0.four.unlistedProposal.candidates[11].detectionLimit = 407d1db851370299 465.8574993275484
+seed0.four.unlistedProposal.candidates[11].conflicts: array 1
+seed0.four.unlistedProposal.candidates[11].conflicts[0].id = "sum-Cu+Ga sum-P"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].kind = .sumPeak
+seed0.four.unlistedProposal.candidates[11].conflicts[0].element = "P"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].line = "P_Ka"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV: n 2 sum 401029c779a6b50b 4.0407999999999999 fnv 2659d95522afa904
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[0] = 40003851eb851eb8 2.0274999999999999
+seed0.four.unlistedProposal.candidates[11].conflicts[0].energiesKeV[1] = 40001b3d07c84b5e 2.0133000000000001
+seed0.four.unlistedProposal.candidates[11].conflicts[0].requires: array 2
+seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[0] = "Cu"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].requires[1] = "Ga"
+seed0.four.unlistedProposal.candidates[11].conflicts[0].question = "Cu+Ga sum peak (2.027 keV) or P Kα (2.013 keV)? They are 14 eV apart, far inside the detector resolution."
+seed0.four.unlistedProposal.candidates[11].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[11].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[11].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[11].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[11].familyNote = "Gd Lα (6.06 keV) has a residual peak of 0.5 σ, below the 3 σ its Mα (1.18 keV) needs: not Gd."
-seed0.four.unlistedProposal.candidates[11].possibleReason = nil
+seed0.four.unlistedProposal.candidates[11].familyNote = nil
+seed0.four.unlistedProposal.candidates[11].possibleReason = "Adding it improves the fit by 11, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[11].unconfirmable = false
-seed0.four.unlistedProposal.candidates[12].element = "P"
-seed0.four.unlistedProposal.candidates[12].group = "P_Ka"
-seed0.four.unlistedProposal.candidates[12].energyKeV = 40001b3d07c84b5e 2.0133000000000001
-seed0.four.unlistedProposal.candidates[12].net = 40879122f0ad5b55 754.14206061778043
-seed0.four.unlistedProposal.candidates[12].sigma = 4061a5435fcd66a1 141.16447439305651
-seed0.four.unlistedProposal.candidates[12].sigmaZero = 406138cc99ce56fa 137.77497568417294
-seed0.four.unlistedProposal.candidates[12].criticalLevel = 406c53d452f1c9cf 226.6196684572628
-seed0.four.unlistedProposal.candidates[12].detectionLimit = 407c7f1e3ae09dc1 455.944880368621
-seed0.four.unlistedProposal.candidates[12].conflicts: array 1
-seed0.four.unlistedProposal.candidates[12].conflicts[0].id = "sum-Cu+Ga sum-P"
-seed0.four.unlistedProposal.candidates[12].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[12].conflicts[0].element = "P"
-seed0.four.unlistedProposal.candidates[12].conflicts[0].line = "P_Ka"
-seed0.four.unlistedProposal.candidates[12].conflicts[0].energiesKeV: n 2 sum 401029c779a6b50b 4.0407999999999999 fnv 2659d95522afa904
-seed0.four.unlistedProposal.candidates[12].conflicts[0].energiesKeV[0] = 40003851eb851eb8 2.0274999999999999
-seed0.four.unlistedProposal.candidates[12].conflicts[0].energiesKeV[1] = 40001b3d07c84b5e 2.0133000000000001
-seed0.four.unlistedProposal.candidates[12].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[12].conflicts[0].requires[0] = "Cu"
-seed0.four.unlistedProposal.candidates[12].conflicts[0].requires[1] = "Ga"
-seed0.four.unlistedProposal.candidates[12].conflicts[0].question = "Cu+Ga sum peak (2.027 keV) or P Kα (2.013 keV)? They are 14 eV apart, far inside the detector resolution."
-seed0.four.unlistedProposal.candidates[12].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.four.unlistedProposal.candidates[12].element = "Gd"
+seed0.four.unlistedProposal.candidates[12].group = "Gd_Ma"
+seed0.four.unlistedProposal.candidates[12].energyKeV = 3ff2d3ae685db76b 1.1766799999999999
+seed0.four.unlistedProposal.candidates[12].net = 40b8f8224c0aedc3 6392.1339728193734
+seed0.four.unlistedProposal.candidates[12].sigma = 409459bb0651b194 1302.4326412930141
+seed0.four.unlistedProposal.candidates[12].sigmaZero = 4093e1ca1a13b635 1272.4473651008568
+seed0.four.unlistedProposal.candidates[12].criticalLevel = 40a059fab52faaae 2092.989663590989
+seed0.four.unlistedProposal.candidates[12].detectionLimit = 40b05caf53ae97ed 4188.6848706360734
+seed0.four.unlistedProposal.candidates[12].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[12].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[12].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[12].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[12].familyNote = nil
-seed0.four.unlistedProposal.candidates[12].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[12].familyNote = "Gd Lα (6.06 keV) has a residual peak of 0.5 σ, below the 3 σ its Mα (1.18 keV) needs: not Gd."
+seed0.four.unlistedProposal.candidates[12].possibleReason = nil
 seed0.four.unlistedProposal.candidates[12].unconfirmable = false
 seed0.four.unlistedProposal.candidates[13].element = "Hg"
 seed0.four.unlistedProposal.candidates[13].group = "Hg_La"
 seed0.four.unlistedProposal.candidates[13].energyKeV = 4023fa5e353f7cee 9.9890000000000008
-seed0.four.unlistedProposal.candidates[13].net = 4076353055b0c028 355.32430047076423
-seed0.four.unlistedProposal.candidates[13].sigma = 4057a733c4022ab2 94.612534525028224
-seed0.four.unlistedProposal.candidates[13].sigmaZero = 4056c3b061779d88 91.057640425502655
-seed0.four.unlistedProposal.candidates[13].criticalLevel = 4062b8d901cc7bf2 149.77649011553109
-seed0.four.unlistedProposal.candidates[13].detectionLimit = 4072e422e9bb4fe4 302.25852368515757
+seed0.four.unlistedProposal.candidates[13].net = 4074e31a16cb3ffd 334.19386939425004
+seed0.four.unlistedProposal.candidates[13].sigma = 4057a59cfded4e81 94.587707025284558
+seed0.four.unlistedProposal.candidates[13].sigmaZero = 4056ce04fea83a79 91.219054855619007
+seed0.four.unlistedProposal.candidates[13].criticalLevel = 4062c158022dba7e 150.04199322635026
+seed0.four.unlistedProposal.candidates[13].detectionLimit = 4072eca1ea1c8e70 302.78952990679591
 seed0.four.unlistedProposal.candidates[13].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[13].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[13].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[13].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[13].familyNote = nil
-seed0.four.unlistedProposal.candidates[13].possibleReason = "The peak at 9.888 keV went to Ge, which explains it better (gain there 16151153 against 1464357)."
+seed0.four.unlistedProposal.candidates[13].possibleReason = "The peak at 9.888 keV went to Ge, which explains it better (gain there 16113088 against 1417710)."
 seed0.four.unlistedProposal.candidates[13].unconfirmable = false
 seed0.four.unlistedProposal.candidates[14].element = "Lu"
 seed0.four.unlistedProposal.candidates[14].group = "Lu_La"
 seed0.four.unlistedProposal.candidates[14].energyKeV = 401e9f559b3d07c8 7.6555999999999997
-seed0.four.unlistedProposal.candidates[14].net = 406c74d3eb108bde 227.65086892348967
-seed0.four.unlistedProposal.candidates[14].sigma = 4055b315d38e6110 86.798207177202357
-seed0.four.unlistedProposal.candidates[14].sigmaZero = 40555cd02b5806b2 85.450205646479645
-seed0.four.unlistedProposal.candidates[14].criticalLevel = 406191b2d641cfdf 140.55308068136125
-seed0.four.unlistedProposal.candidates[14].detectionLimit = 4071bcfcbe30a3d1 283.81170481681789
+seed0.four.unlistedProposal.candidates[14].net = 406cd3d5522bbef3 230.61979015869255
+seed0.four.unlistedProposal.candidates[14].sigma = 4055b305afa5ad0d 86.797222053330373
+seed0.four.unlistedProposal.candidates[14].sigmaZero = 40555ba4795e552b 85.431913702127233
+seed0.four.unlistedProposal.candidates[14].criticalLevel = 406190bc5c0c1f75 140.52299311034918
+seed0.four.unlistedProposal.candidates[14].detectionLimit = 4071bc0643faf367 283.75152967479374
 seed0.four.unlistedProposal.candidates[14].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[14].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[14].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[14].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[14].familyNote = nil
-seed0.four.unlistedProposal.candidates[14].possibleReason = "Adding it improves the fit by 32, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[14].possibleReason = "Adding it improves the fit by 22, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[14].unconfirmable = false
 seed0.four.unlistedProposal.candidates[15].element = "Hf"
 seed0.four.unlistedProposal.candidates[15].group = "Hf_La"
 seed0.four.unlistedProposal.candidates[15].energyKeV = 401f989374bc6a7f 7.899
-seed0.four.unlistedProposal.candidates[15].net = 40682c7012a84496 193.38868077149226
-seed0.four.unlistedProposal.candidates[15].sigma = 4056412564e4dd5e 89.017907355786036
-seed0.four.unlistedProposal.candidates[15].sigmaZero = 4055f971a0849118 87.897560243091334
-seed0.four.unlistedProposal.candidates[15].criticalLevel = 406212840fb25ced 144.57862076603433
-seed0.four.unlistedProposal.candidates[15].detectionLimit = 40723dcdf7a130df 291.86278498616406
+seed0.four.unlistedProposal.candidates[15].net = 406a7dca124e1f90 211.93091693170982
+seed0.four.unlistedProposal.candidates[15].sigma = 4056470b111fbc24 89.110050469390046
+seed0.four.unlistedProposal.candidates[15].sigmaZero = 4055f87477ed98de 87.882108671215491
+seed0.four.unlistedProposal.candidates[15].criticalLevel = 406211b3db5ff2b2 144.55320519199228
+seed0.four.unlistedProposal.candidates[15].detectionLimit = 40723cfdc34ec6a4 291.81195383807994
 seed0.four.unlistedProposal.candidates[15].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[15].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[15].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[15].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[15].familyNote = nil
-seed0.four.unlistedProposal.candidates[15].possibleReason = "Adding it improves the fit by 25, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[15].possibleReason = "Adding it improves the fit by 23, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[15].unconfirmable = false
 seed0.four.unlistedProposal.candidates[16].element = "Dy"
 seed0.four.unlistedProposal.candidates[16].group = "Dy_La"
 seed0.four.unlistedProposal.candidates[16].energyKeV = 4019fb15b573eab3 6.4951999999999996
-seed0.four.unlistedProposal.candidates[16].net = 405f291e103f3f33 124.64245992828801
-seed0.four.unlistedProposal.candidates[16].sigma = 40514c75a1225c3e 69.194679530673028
-seed0.four.unlistedProposal.candidates[16].sigmaZero = 4051177400f8955f 68.366455309636407
-seed0.four.unlistedProposal.candidates[16].criticalLevel = 405c1cfadf170c69 112.45281197787121
-seed0.four.unlistedProposal.candidates[16].detectionLimit = 406c738eaef4b44e 227.61116740983783
+seed0.four.unlistedProposal.candidates[16].net = 40602dab72779dfb 129.42717860567777
+seed0.four.unlistedProposal.candidates[16].sigma = 40514d36fc43ecdb 69.206481043179721
+seed0.four.unlistedProposal.candidates[16].sigmaZero = 4051162a8fb405f6 68.346347738079061
+seed0.four.unlistedProposal.candidates[16].criticalLevel = 405c1adcfca11228 112.41973796586592
+seed0.four.unlistedProposal.candidates[16].detectionLimit = 406c7170cc7eba0d 227.54501938582726
 seed0.four.unlistedProposal.candidates[16].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[16].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[16].holeRegionNote = nil
@@ -680,11 +680,11 @@ seed0.four.unlistedProposal.candidates[16].unconfirmable = false
 seed0.four.unlistedProposal.candidates[17].element = "Tm"
 seed0.four.unlistedProposal.candidates[17].group = "Tm_La"
 seed0.four.unlistedProposal.candidates[17].energyKeV = 401cb8a0902de00d 7.1802999999999999
-seed0.four.unlistedProposal.candidates[17].net = 4058af9a9757729d 98.743810496709969
-seed0.four.unlistedProposal.candidates[17].sigma = 40522f15aff12fdb 72.73569868615543
-seed0.four.unlistedProposal.candidates[17].sigmaZero = 4051f9355e7f3afa 71.893882393120208
-seed0.four.unlistedProposal.candidates[17].criticalLevel = 405d90507f7f0271 118.25491320994639
-seed0.four.unlistedProposal.candidates[17].detectionLimit = 406de6e44f5caa56 239.21536987398821
+seed0.four.unlistedProposal.candidates[17].net = 405a5d17c85bb353 105.4545765777123
+seed0.four.unlistedProposal.candidates[17].sigma = 40523061178e031c 72.755926026042687
+seed0.four.unlistedProposal.candidates[17].sigmaZero = 4051f6edf3fd515c 71.858273503666567
+seed0.four.unlistedProposal.candidates[17].criticalLevel = 405d8c90dd315c61 118.19634179897686
+seed0.four.unlistedProposal.candidates[17].detectionLimit = 406de324ad0f0446 239.09822705204914
 seed0.four.unlistedProposal.candidates[17].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[17].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[17].holeRegionNote = nil
@@ -695,11 +695,11 @@ seed0.four.unlistedProposal.candidates[17].unconfirmable = false
 seed0.four.unlistedProposal.candidates[18].element = "Zn"
 seed0.four.unlistedProposal.candidates[18].group = "Zn_Ka"
 seed0.four.unlistedProposal.candidates[18].energyKeV = 4021471de69ad42c 8.6388999999999996
-seed0.four.unlistedProposal.candidates[18].net = 40522f90005b5aa0 72.743164147580046
-seed0.four.unlistedProposal.candidates[18].sigma = 40519a7209fcd8ae 70.413210389061277
-seed0.four.unlistedProposal.candidates[18].sigmaZero = 40516b5038d9463d 69.676771366292954
-seed0.four.unlistedProposal.candidates[18].criticalLevel = 405ca6eaf2b8f599 114.60809009611548
-seed0.four.unlistedProposal.candidates[18].detectionLimit = 406cfd7ec2969d7e 231.92172364632637
+seed0.four.unlistedProposal.candidates[18].net = 40557b889c177106 85.930212996379936
+seed0.four.unlistedProposal.candidates[18].sigma = 40519ebc2238b1c2 70.480232768407433
+seed0.four.unlistedProposal.candidates[18].sigmaZero = 405167093347db05 69.609936542674475
+seed0.four.unlistedProposal.candidates[18].criticalLevel = 405c9fe1cc31f70d 114.49815659407996
+seed0.four.unlistedProposal.candidates[18].detectionLimit = 406cf6759c0f9ef2 231.70185664225534
 seed0.four.unlistedProposal.candidates[18].conflicts: array 1
 seed0.four.unlistedProposal.candidates[18].conflicts[0].id = "sum-Ge+Ni sum-Zn"
 seed0.four.unlistedProposal.candidates[18].conflicts[0].kind = .sumPeak
@@ -717,73 +717,73 @@ seed0.four.unlistedProposal.candidates[18].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[18].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[18].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[18].familyNote = nil
-seed0.four.unlistedProposal.candidates[18].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[18].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[18].unconfirmable = false
 seed0.four.unlistedProposal.candidates[19].element = "Se"
 seed0.four.unlistedProposal.candidates[19].group = "Se_Ka"
 seed0.four.unlistedProposal.candidates[19].energyKeV = 402671a9fbe76c8b 11.222
-seed0.four.unlistedProposal.candidates[19].net = 40499ea9d4666264 51.239557790748933
-seed0.four.unlistedProposal.candidates[19].sigma = 404ce830f67598b3 57.813994223995358
-seed0.four.unlistedProposal.candidates[19].sigmaZero = 404c9ebf83d38858 57.240219572341346
-seed0.four.unlistedProposal.candidates[19].criticalLevel = 405789b6cf157453 94.151782771064333
-seed0.four.unlistedProposal.candidates[19].detectionLimit = 4067e04a9ef31c38 191.00910899622409
+seed0.four.unlistedProposal.candidates[19].net = 404cfd0dcee75cd7 57.976983893365905
+seed0.four.unlistedProposal.candidates[19].sigma = 404cea2478414eee 57.829237968338802
+seed0.four.unlistedProposal.candidates[19].sigmaZero = 404c97026d3c834e 57.17976155714733
+seed0.four.unlistedProposal.candidates[19].criticalLevel = 405783598242c1e2 94.052338185494165
+seed0.four.unlistedProposal.candidates[19].detectionLimit = 4067d9ed522069c7 190.81021982508375
 seed0.four.unlistedProposal.candidates[19].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[19].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[19].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[19].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[19].familyNote = nil
-seed0.four.unlistedProposal.candidates[19].possibleReason = "Adding it improves the fit by 5, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[19].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[19].unconfirmable = false
-seed0.four.unlistedProposal.candidates[20].element = "Tb"
-seed0.four.unlistedProposal.candidates[20].group = "Tb_La"
-seed0.four.unlistedProposal.candidates[20].energyKeV = 40191758e219652c 6.2728000000000002
-seed0.four.unlistedProposal.candidates[20].net = 4052025bb29f0ae8 72.036846785845796
-seed0.four.unlistedProposal.candidates[20].sigma = 405a2198cd1201f8 104.52495123632968
-seed0.four.unlistedProposal.candidates[20].sigmaZero = 405a016e76aadd04 104.02236715970872
-seed0.four.unlistedProposal.candidates[20].criticalLevel = 406563400b56b694 171.10156790672465
-seed0.four.unlistedProposal.candidates[20].detectionLimit = 40758e89f3458a86 344.9086792675447
-seed0.four.unlistedProposal.candidates[20].conflicts: array 1
-seed0.four.unlistedProposal.candidates[20].conflicts[0].id = "sum-Si+Ti sum-Tb"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].kind = .sumPeak
-seed0.four.unlistedProposal.candidates[20].conflicts[0].element = "Tb"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].line = "Tb_La"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].energiesKeV: n 2 sum 40290bfb15b573eb 12.523400000000001 fnv 54d432d4f3bf186b
-seed0.four.unlistedProposal.candidates[20].conflicts[0].energiesKeV[0] = 4019009d495182aa 6.2506000000000004
-seed0.four.unlistedProposal.candidates[20].conflicts[0].energiesKeV[1] = 40191758e219652c 6.2728000000000002
-seed0.four.unlistedProposal.candidates[20].conflicts[0].requires: array 2
-seed0.four.unlistedProposal.candidates[20].conflicts[0].requires[0] = "Si"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].requires[1] = "Ti"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].question = "Si+Ti sum peak (6.251 keV) or Tb Lα (6.273 keV)?"
-seed0.four.unlistedProposal.candidates[20].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.four.unlistedProposal.candidates[20].element = "Ho"
+seed0.four.unlistedProposal.candidates[20].group = "Ho_La"
+seed0.four.unlistedProposal.candidates[20].energyKeV = 401ae0f9096bb98c 6.7196999999999996
+seed0.four.unlistedProposal.candidates[20].net = 404a1fe333f3f8d2 52.249121183516436
+seed0.four.unlistedProposal.candidates[20].sigma = 40524f1fc660de65 73.236314386938446
+seed0.four.unlistedProposal.candidates[20].sigmaZero = 4052348e533eab77 72.821186839295351
+seed0.four.unlistedProposal.candidates[20].criticalLevel = 405df1eeafd7ea5d 119.7801932915258
+seed0.four.unlistedProposal.candidates[20].detectionLimit = 406e48827fb59242 242.26593003714703
+seed0.four.unlistedProposal.candidates[20].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[20].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[20].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[20].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[20].familyNote = nil
 seed0.four.unlistedProposal.candidates[20].possibleReason = "Adding it improves the fit by 0, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[20].unconfirmable = false
-seed0.four.unlistedProposal.candidates[21].element = "Ho"
-seed0.four.unlistedProposal.candidates[21].group = "Ho_La"
-seed0.four.unlistedProposal.candidates[21].energyKeV = 401ae0f9096bb98c 6.7196999999999996
-seed0.four.unlistedProposal.candidates[21].net = 4048188ea3937a8d 48.191852995883075
-seed0.four.unlistedProposal.candidates[21].sigma = 40524e4f02d62894 73.223572453631562
-seed0.four.unlistedProposal.candidates[21].sigmaZero = 405235ce92cb4fab 72.840733240648362
-seed0.four.unlistedProposal.candidates[21].criticalLevel = 405df3fd72c82f1b 119.81234426068515
-seed0.four.unlistedProposal.candidates[21].detectionLimit = 406e4a9142a5d700 242.33023197546572
-seed0.four.unlistedProposal.candidates[21].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+seed0.four.unlistedProposal.candidates[21].element = "Tb"
+seed0.four.unlistedProposal.candidates[21].group = "Tb_La"
+seed0.four.unlistedProposal.candidates[21].energyKeV = 40191758e219652c 6.2728000000000002
+seed0.four.unlistedProposal.candidates[21].net = 4052182f7ecdb3cf 72.377898884659984
+seed0.four.unlistedProposal.candidates[21].sigma = 405a1fb91d543cef 104.49567349649782
+seed0.four.unlistedProposal.candidates[21].sigmaZero = 4059ffaf217f1ac2 103.99506413853217
+seed0.four.unlistedProposal.candidates[21].criticalLevel = 406561d02558c445 171.05665843331568
+seed0.four.unlistedProposal.candidates[21].detectionLimit = 40758d1a0d479837 344.81886032072674
+seed0.four.unlistedProposal.candidates[21].conflicts: array 1
+seed0.four.unlistedProposal.candidates[21].conflicts[0].id = "sum-Si+Ti sum-Tb"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].kind = .sumPeak
+seed0.four.unlistedProposal.candidates[21].conflicts[0].element = "Tb"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].line = "Tb_La"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].energiesKeV: n 2 sum 40290bfb15b573eb 12.523400000000001 fnv 54d432d4f3bf186b
+seed0.four.unlistedProposal.candidates[21].conflicts[0].energiesKeV[0] = 4019009d495182aa 6.2506000000000004
+seed0.four.unlistedProposal.candidates[21].conflicts[0].energiesKeV[1] = 40191758e219652c 6.2728000000000002
+seed0.four.unlistedProposal.candidates[21].conflicts[0].requires: array 2
+seed0.four.unlistedProposal.candidates[21].conflicts[0].requires[0] = "Si"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].requires[1] = "Ti"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].question = "Si+Ti sum peak (6.251 keV) or Tb Lα (6.273 keV)?"
+seed0.four.unlistedProposal.candidates[21].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.four.unlistedProposal.candidates[21].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[21].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[21].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[21].familyNote = nil
-seed0.four.unlistedProposal.candidates[21].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[21].possibleReason = "Adding it improves the fit by 0, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[21].unconfirmable = false
 seed0.four.unlistedProposal.candidates[22].element = "Re"
 seed0.four.unlistedProposal.candidates[22].group = "Re_La"
 seed0.four.unlistedProposal.candidates[22].energyKeV = 40214e075f6fd220 8.6524000000000001
-seed0.four.unlistedProposal.candidates[22].net = 402c9f9e571d7d56 14.311754915571026
-seed0.four.unlistedProposal.candidates[22].sigma = 40508085154fbb2c 66.008122756826822
-seed0.four.unlistedProposal.candidates[22].sigmaZero = 4050780d3fadcfb5 65.875808639276173
-seed0.four.unlistedProposal.candidates[22].criticalLevel = 405b16c9bb7eb1f3 108.35606276867456
-seed0.four.unlistedProposal.candidates[22].detectionLimit = 406b6d5d8b5c59d8 219.41766899144454
+seed0.four.unlistedProposal.candidates[22].net = 403b1b2d0ddcae4d 27.106156221749462
+seed0.four.unlistedProposal.candidates[22].sigma = 405085e8c92c2c6e 66.092333119524227
+seed0.four.unlistedProposal.candidates[22].sigmaZero = 405075dccb9f64ba 65.841601281793288
+seed0.four.unlistedProposal.candidates[22].criticalLevel = 405b132fde621eec 108.29979667265042
+seed0.four.unlistedProposal.candidates[22].detectionLimit = 406b69c3ae3fc6d1 219.30513679939625
 seed0.four.unlistedProposal.candidates[22].conflicts: array 1
 seed0.four.unlistedProposal.candidates[22].conflicts[0].id = "sum-Ge+Ni sum-Re"
 seed0.four.unlistedProposal.candidates[22].conflicts[0].kind = .sumPeak
@@ -807,10 +807,10 @@ seed0.four.unlistedProposal.candidates[23].element = "Au"
 seed0.four.unlistedProposal.candidates[23].group = "Au_La"
 seed0.four.unlistedProposal.candidates[23].energyKeV = 40236d0e56041893 9.7129999999999992
 seed0.four.unlistedProposal.candidates[23].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[23].sigma = 4058025178a0b74f 96.036222607564227
-seed0.four.unlistedProposal.candidates[23].sigmaZero = 40551ffafba6cc8e 84.499693787469567
-seed0.four.unlistedProposal.candidates[23].criticalLevel = 40615fab07eced42 138.98962780260814
-seed0.four.unlistedProposal.candidates[23].detectionLimit = 40718af4efdbc134 280.68479905931167
+seed0.four.unlistedProposal.candidates[23].sigma = 40580938e593fcd4 96.144097704428816
+seed0.four.unlistedProposal.candidates[23].sigmaZero = 4055288b945e8af3 84.633519260718273
+seed0.four.unlistedProposal.candidates[23].criticalLevel = 406166b647f9d4be 139.20975111765978
+seed0.four.unlistedProposal.candidates[23].detectionLimit = 407192002fe8a8b0 281.12504568941495
 seed0.four.unlistedProposal.candidates[23].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[23].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[23].holeRegionNote = nil
@@ -822,10 +822,10 @@ seed0.four.unlistedProposal.candidates[24].element = "Bi"
 seed0.four.unlistedProposal.candidates[24].group = "Bi_La"
 seed0.four.unlistedProposal.candidates[24].energyKeV = 4025ad916872b021 10.839
 seed0.four.unlistedProposal.candidates[24].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[24].sigma = 404df1bc7c57799c 59.888564627373142
-seed0.four.unlistedProposal.candidates[24].sigmaZero = 404df15a9c63f9ca 59.885577725235251
-seed0.four.unlistedProposal.candidates[24].criticalLevel = 4058a0314fb1eefd 98.503009723437529
-seed0.four.unlistedProposal.candidates[24].detectionLimit = 4068f6c51f8f96e2 199.71156290097048
+seed0.four.unlistedProposal.candidates[24].sigma = 404df299288c8066 59.895299023250843
+seed0.four.unlistedProposal.candidates[24].sigmaZero = 404df22a991fa8af 59.891924992044885
+seed0.four.unlistedProposal.candidates[24].criticalLevel = 4058a0dc5d975cea 98.513450048270585
+seed0.four.unlistedProposal.candidates[24].detectionLimit = 4068f7702d7504cf 199.73244355063659
 seed0.four.unlistedProposal.candidates[24].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[24].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[24].holeRegionNote = nil
@@ -837,25 +837,25 @@ seed0.four.unlistedProposal.candidates[25].element = "Er"
 seed0.four.unlistedProposal.candidates[25].group = "Er_La"
 seed0.four.unlistedProposal.candidates[25].energyKeV = 401bcb5dcc63f141 6.9485999999999999
 seed0.four.unlistedProposal.candidates[25].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[25].sigma = 40514d332f37f931 69.206249050771262
-seed0.four.unlistedProposal.candidates[25].sigmaZero = 40514d332f37f931 69.206249050771262
-seed0.four.unlistedProposal.candidates[25].criticalLevel = 405c7562b5ab937c 113.83414975886802
-seed0.four.unlistedProposal.candidates[25].detectionLimit = 406ccbf685893b61 230.37384297183146
+seed0.four.unlistedProposal.candidates[25].sigma = 40514f1aaef8aeb4 69.236003630498828
+seed0.four.unlistedProposal.candidates[25].sigmaZero = 40514f1aaef8aeb4 69.236003630498828
+seed0.four.unlistedProposal.candidates[25].criticalLevel = 405c788492ff074a 113.88309168725132
+seed0.four.unlistedProposal.candidates[25].detectionLimit = 406ccf1862dcaf2f 230.47172682859807
 seed0.four.unlistedProposal.candidates[25].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[25].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[25].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[25].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[25].familyNote = nil
-seed0.four.unlistedProposal.candidates[25].possibleReason = "Adding it improves the fit by -3024, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[25].possibleReason = "Adding it improves the fit by -2724, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[25].unconfirmable = false
 seed0.four.unlistedProposal.candidates[26].element = "Ir"
 seed0.four.unlistedProposal.candidates[26].group = "Ir_La"
 seed0.four.unlistedProposal.candidates[26].energyKeV = 4022597f62b6ae7d 9.1747999999999994
 seed0.four.unlistedProposal.candidates[26].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[26].sigma = 405b3ecc5d7aa612 108.98122345902837
-seed0.four.unlistedProposal.candidates[26].sigmaZero = 405b3ecc5d7aa612 108.98122345902837
-seed0.four.unlistedProposal.candidates[26].criticalLevel = 40666842da2dab6a 179.25816067619172
-seed0.four.unlistedProposal.candidates[26].detectionLimit = 4076938cc21c7f5c 361.22186480647883
+seed0.four.unlistedProposal.candidates[26].sigma = 405b33fec9d55c51 108.81242605052945
+seed0.four.unlistedProposal.candidates[26].sigmaZero = 405b33fec9d55c51 108.81242605052945
+seed0.four.unlistedProposal.candidates[26].criticalLevel = 40665f605e27ae08 178.98051364660228
+seed0.four.unlistedProposal.candidates[26].detectionLimit = 40768aaa461681fa 360.66657074729994
 seed0.four.unlistedProposal.candidates[26].conflicts: array 1
 seed0.four.unlistedProposal.candidates[26].conflicts[0].id = "sum-Ni+Si sum-Ir"
 seed0.four.unlistedProposal.candidates[26].conflicts[0].kind = .sumPeak
@@ -873,31 +873,31 @@ seed0.four.unlistedProposal.candidates[26].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[26].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[26].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[26].familyNote = nil
-seed0.four.unlistedProposal.candidates[26].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[26].possibleReason = "Adding it improves the fit by 9, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[26].unconfirmable = false
 seed0.four.unlistedProposal.candidates[27].element = "La"
 seed0.four.unlistedProposal.candidates[27].group = "La_Ma"
 seed0.four.unlistedProposal.candidates[27].energyKeV = 3fea27525460aa65 0.81730000000000003
 seed0.four.unlistedProposal.candidates[27].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[27].sigma = 406e618bbdc23292 243.04830825738151
-seed0.four.unlistedProposal.candidates[27].sigmaZero = 406e618bbdc23292 243.04830825738151
-seed0.four.unlistedProposal.candidates[27].criticalLevel = 4078fc7656c9d186 399.77889136157353
-seed0.four.unlistedProposal.candidates[27].detectionLimit = 4089121b4ac13b7f 802.26332617724245
+seed0.four.unlistedProposal.candidates[27].sigma = 406e548a701b693d 242.64189915994385
+seed0.four.unlistedProposal.candidates[27].sigmaZero = 406e548a701b693d 242.64189915994385
+seed0.four.unlistedProposal.candidates[27].criticalLevel = 4078f1c43b0e9662 399.11040788362709
+seed0.four.unlistedProposal.candidates[27].detectionLimit = 408907692f06005b 800.92635922134957
 seed0.four.unlistedProposal.candidates[27].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[27].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[27].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[27].misfit = 3ff0000000000000 1
-seed0.four.unlistedProposal.candidates[27].familyNote = "La Lα (4.65 keV) has a residual peak of 1.5 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
+seed0.four.unlistedProposal.candidates[27].familyNote = "La Lα (4.65 keV) has a residual peak of 1.4 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
 seed0.four.unlistedProposal.candidates[27].possibleReason = nil
 seed0.four.unlistedProposal.candidates[27].unconfirmable = false
 seed0.four.unlistedProposal.candidates[28].element = "Nd"
 seed0.four.unlistedProposal.candidates[28].group = "Nd_Ma"
 seed0.four.unlistedProposal.candidates[28].energyKeV = 3fee161e4f765fd9 0.94020000000000004
 seed0.four.unlistedProposal.candidates[28].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[28].sigma = 4080f2793811d599 542.30918897564982
-seed0.four.unlistedProposal.candidates[28].sigmaZero = 4080f2793811d599 542.30918897564982
-seed0.four.unlistedProposal.candidates[28].criticalLevel = 408be027656c02e8 892.0192364157092
-seed0.four.unlistedProposal.candidates[28].detectionLimit = 409beaf9df67b7e5 1786.7440162855139
+seed0.four.unlistedProposal.candidates[28].sigma = 4080ec6a183d4fea 541.55180404567841
+seed0.four.unlistedProposal.candidates[28].sigmaZero = 4080ec6a183d4fea 541.55180404567841
+seed0.four.unlistedProposal.candidates[28].criticalLevel = 408bd630061072fa 890.77344906664734
+seed0.four.unlistedProposal.candidates[28].detectionLimit = 409be102800c27f7 1784.2524415873902
 seed0.four.unlistedProposal.candidates[28].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[28].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[28].holeRegionNote = nil
@@ -909,10 +909,10 @@ seed0.four.unlistedProposal.candidates[29].element = "Os"
 seed0.four.unlistedProposal.candidates[29].group = "Os_La"
 seed0.four.unlistedProposal.candidates[29].energyKeV = 4021d25460aa64c3 8.9108000000000001
 seed0.four.unlistedProposal.candidates[29].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[29].sigma = 405642a6967018c1 89.041417703122548
-seed0.four.unlistedProposal.candidates[29].sigmaZero = 4056420fc0946231 89.032211441903897
-seed0.four.unlistedProposal.candidates[29].criticalLevel = 40624e3d142ae82c 146.44495590572603
-seed0.four.unlistedProposal.candidates[29].detectionLimit = 40727986fc19bc1e 295.59545526554746
+seed0.four.unlistedProposal.candidates[29].sigma = 40564b14b2017118 89.173138142974835
+seed0.four.unlistedProposal.candidates[29].sigmaZero = 405649fad593f482 89.155934710013781
+seed0.four.unlistedProposal.candidates[29].criticalLevel = 406254c034946f7c 146.64846257201486
+seed0.four.unlistedProposal.candidates[29].detectionLimit = 4072800a1c83436e 296.00246859812512
 seed0.four.unlistedProposal.candidates[29].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[29].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[29].holeRegionNote = nil
@@ -924,25 +924,25 @@ seed0.four.unlistedProposal.candidates[30].element = "Pt"
 seed0.four.unlistedProposal.candidates[30].group = "Pt_La"
 seed0.four.unlistedProposal.candidates[30].energyKeV = 4022e25aee631f8a 9.4420999999999999
 seed0.four.unlistedProposal.candidates[30].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[30].sigma = 40514957b36cb5d5 69.145977836763748
-seed0.four.unlistedProposal.candidates[30].sigmaZero = 4050e4af57fbca2a 67.573202129257567
-seed0.four.unlistedProposal.candidates[30].criticalLevel = 405bc9794497099b 111.14802660703428
-seed0.four.unlistedProposal.candidates[30].detectionLimit = 406c200d1474b180 225.00159666816398
+seed0.four.unlistedProposal.candidates[30].sigma = 40514747dd2afe0d 69.113761226639511
+seed0.four.unlistedProposal.candidates[30].sigmaZero = 4050dcaf59f799a1 67.448202602192865
+seed0.four.unlistedProposal.candidates[30].criticalLevel = 405bbc509ed59bfd 110.94242068157469
+seed0.four.unlistedProposal.candidates[30].detectionLimit = 406c12e46eb343e2 224.5903848172448
 seed0.four.unlistedProposal.candidates[30].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[30].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[30].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[30].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[30].familyNote = nil
-seed0.four.unlistedProposal.candidates[30].possibleReason = "Adding it improves the fit by 32, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[30].possibleReason = "Adding it improves the fit by 43, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[30].unconfirmable = false
 seed0.four.unlistedProposal.candidates[31].element = "Sr"
 seed0.four.unlistedProposal.candidates[31].group = "Sr_La"
 seed0.four.unlistedProposal.candidates[31].energyKeV = 3ffce76c8b439581 1.8065
 seed0.four.unlistedProposal.candidates[31].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[31].sigma = 40798e168c34431f 408.88050480284613
-seed0.four.unlistedProposal.candidates[31].sigmaZero = 40798e168c34431f 408.88050480284613
-seed0.four.unlistedProposal.candidates[31].criticalLevel = 408504637e99af07 672.54858131471053
-seed0.four.unlistedProposal.candidates[31].detectionLimit = 40950f35f8956404 1347.8027060835166
+seed0.four.unlistedProposal.candidates[31].sigma = 407990dc0277fbbd 409.05371329182145
+seed0.four.unlistedProposal.candidates[31].sigmaZero = 407990dc0277fbbd 409.05371329182145
+seed0.four.unlistedProposal.candidates[31].criticalLevel = 408506aaf99edffe 672.83348392602034
+seed0.four.unlistedProposal.candidates[31].detectionLimit = 4095117d739a94fb 1348.3725113061362
 seed0.four.unlistedProposal.candidates[31].conflicts: array 1
 seed0.four.unlistedProposal.candidates[31].conflicts[0].id = "sum-Cu+Cu sum-Sr"
 seed0.four.unlistedProposal.candidates[31].conflicts[0].kind = .sumPeak
@@ -965,10 +965,10 @@ seed0.four.unlistedProposal.candidates[32].element = "W"
 seed0.four.unlistedProposal.candidates[32].group = "W_La"
 seed0.four.unlistedProposal.candidates[32].energyKeV = 4020cb923a29c77a 8.3976000000000006
 seed0.four.unlistedProposal.candidates[32].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[32].sigma = 40594414f00f6253 101.06377793791152
-seed0.four.unlistedProposal.candidates[32].sigmaZero = 40594414f00f6253 101.06377793791152
-seed0.four.unlistedProposal.candidates[32].criticalLevel = 4064c7861dee9b49 166.23512169459198
-seed0.four.unlistedProposal.candidates[32].detectionLimit = 4074f2d005dd6f3b 335.17578684327935
+seed0.four.unlistedProposal.candidates[32].sigma = 405943b2170494e6 101.0577447457068
+seed0.four.unlistedProposal.candidates[32].sigmaZero = 405943b2170494e6 101.0577447457068
+seed0.four.unlistedProposal.candidates[32].criticalLevel = 4064c734d26307d1 166.22519797651196
+seed0.four.unlistedProposal.candidates[32].detectionLimit = 4074f27eba51dbc3 335.15593940711932
 seed0.four.unlistedProposal.candidates[32].conflicts: array 1
 seed0.four.unlistedProposal.candidates[32].conflicts[0].id = "sum-Cu+Ni sum-W"
 seed0.four.unlistedProposal.candidates[32].conflicts[0].kind = .sumPeak
@@ -992,10 +992,10 @@ seed0.four.unlistedProposal.candidates[33].element = "Y"
 seed0.four.unlistedProposal.candidates[33].group = "Y_La"
 seed0.four.unlistedProposal.candidates[33].energyKeV = 3ffec2f837b4a234 1.9226000000000001
 seed0.four.unlistedProposal.candidates[33].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[33].sigma = 4060b076feaaf6dc 133.514525731959
-seed0.four.unlistedProposal.candidates[33].sigmaZero = 4060b076feaaf6dc 133.514525731959
-seed0.four.unlistedProposal.candidates[33].criticalLevel = 406b73944a700e17 219.61185190091848
-seed0.four.unlistedProposal.candidates[33].detectionLimit = 407b9ede325ee209 441.92924725593235
+seed0.four.unlistedProposal.candidates[33].sigma = 406132ced9a64942 137.58775026777045
+seed0.four.unlistedProposal.candidates[33].sigmaZero = 406132ceaf558bee 137.58773009022065
+seed0.four.unlistedProposal.candidates[33].criticalLevel = 406c49f941c1a51e 226.31167686291968
+seed0.four.unlistedProposal.candidates[33].detectionLimit = 407c754329b07910 455.32889717993476
 seed0.four.unlistedProposal.candidates[33].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[33].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[33].holeRegionNote = nil
@@ -1007,16 +1007,16 @@ seed0.four.unlistedProposal.candidates[34].element = "Yb"
 seed0.four.unlistedProposal.candidates[34].group = "Yb_La"
 seed0.four.unlistedProposal.candidates[34].energyKeV = 401da9c779a6b50b 7.4157999999999999
 seed0.four.unlistedProposal.candidates[34].net = 0000000000000000 0
-seed0.four.unlistedProposal.candidates[34].sigma = 4066e800ec300fa2 183.25011262309005
-seed0.four.unlistedProposal.candidates[34].sigmaZero = 4066e7a8b78125dc 183.23934531425664
-seed0.four.unlistedProposal.candidates[34].criticalLevel = 4072d66e3084f167 301.40190174036837
-seed0.four.unlistedProposal.candidates[34].detectionLimit = 4082ec13247c5b60 605.50934693483214
+seed0.four.unlistedProposal.candidates[34].sigma = 4066e7a4aa59c101 183.2388507607466
+seed0.four.unlistedProposal.candidates[34].sigmaZero = 4066e74dbea6f0e1 183.22824032407428
+seed0.four.unlistedProposal.candidates[34].criticalLevel = 4072d6235f24859a 301.38363565698967
+seed0.four.unlistedProposal.candidates[34].detectionLimit = 4082ebc8531bef93 605.47281476807473
 seed0.four.unlistedProposal.candidates[34].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.candidates[34].suggestedRole = .fitOnly
 seed0.four.unlistedProposal.candidates[34].holeRegionNote = nil
 seed0.four.unlistedProposal.candidates[34].misfit = 3ff0000000000000 1
 seed0.four.unlistedProposal.candidates[34].familyNote = nil
-seed0.four.unlistedProposal.candidates[34].possibleReason = "Adding it improves the fit by 18, below the 100 a new line needs."
+seed0.four.unlistedProposal.candidates[34].possibleReason = "Adding it improves the fit by 11, below the 100 a new line needs."
 seed0.four.unlistedProposal.candidates[34].unconfirmable = false
 seed0.four.unlistedProposal.sumPeaks: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.four.unlistedProposal.refused: array 7
@@ -1039,7 +1039,7 @@ seed0.four.unlistedProposal.currie.beta = 3fa999999999999a 0.050000000000000003
 seed0.four.unlistedProposal.notes: array 20
 seed0.four.unlistedProposal.notes[0] = "Lines below 0.45 keV are not tested (a measured limit of the continuum model, not a property of the method)."
 seed0.four.unlistedProposal.notes[1] = "Identification (validation: none): the residual's peaks at or above 5 σ of its top-hat filter (1.5 × below 1 keV); a candidate joins when Σ(y − μ)²/(μ + (0.01 μ)²) falls by at least 100, 20 % of that at its own lines, with its area at or above Currie L_D (α = β = 0.05, σ₀ from the fit's own variance with it absent) and no line against it; the final fit drops what it does not need (100). Kβ weights from NIST EPQ in this fit."
-seed0.four.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data; escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 66 candidate fits, 71 fits in all."
+seed0.four.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data; escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 66 candidate fits, 71 fits in all."
 seed0.four.unlistedProposal.notes[3] = "Confirmation lines (validation: none): an element nominated by an L or M line needs its K or L alpha line at 3 σ in the residual where the fitted range holds it and the beam is at least 2.0 times its energy; otherwise it is withheld."
 seed0.four.unlistedProposal.notes[4] = "Confirmation withheld Eu: Eu Lα (5.85 keV) has a residual peak of 0.0 σ, below the 3 σ its Mα (1.10 keV) needs: not Eu."
 seed0.four.unlistedProposal.notes[5] = "Confirmation withheld Sm: Sm Lα (5.64 keV) has a residual peak of 0.0 σ, below the 3 σ its Mβ (1.10 keV) needs: not Sm."
@@ -1049,147 +1049,147 @@ seed0.four.unlistedProposal.notes[8] = "Confirmation withheld Rb: Rb Kα (13.40
 seed0.four.unlistedProposal.notes[9] = "Confirmation withheld Ta: Ta Lα (8.15 keV) has a residual peak of 0.0 σ, below the 3 σ its Mβ (1.77 keV) needs: not Ta."
 seed0.four.unlistedProposal.notes[10] = "Confirmation withheld Zr: Zr Kα (15.78 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
 seed0.four.unlistedProposal.notes[11] = "Confirmation withheld Gd: Gd Lα (6.06 keV) has a residual peak of 0.5 σ, below the 3 σ its Mα (1.18 keV) needs: not Gd."
-seed0.four.unlistedProposal.notes[12] = "Confirmation withheld La: La Lα (4.65 keV) has a residual peak of 1.5 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
+seed0.four.unlistedProposal.notes[12] = "Confirmation withheld La: La Lα (4.65 keV) has a residual peak of 1.4 σ, below the 3 σ its Mγ (1.02 keV) needs: not La."
 seed0.four.unlistedProposal.notes[13] = "Confirmation withheld Nd: Nd Lα (5.23 keV) has a residual peak of 0.0 σ, below the 3 σ its Mβ (1.00 keV) needs: not Nd."
 seed0.four.unlistedProposal.notes[14] = "Confirmation withheld Sr: Sr Kα (14.16 keV) has a residual peak of 0.8 σ, below the 3 σ its Lα (1.81 keV) needs: not Sr."
 seed0.four.unlistedProposal.notes[15] = "Confirmation withheld Y: Y Kα (14.96 keV) has a residual peak of 0.4 σ, below the 3 σ its Lα (1.92 keV) needs: not Y."
 seed0.four.unlistedProposal.notes[16] = "Look-elsewhere: 66 candidates were tested, so about 0.03 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
-seed0.four.unlistedProposal.notes[17] = "Ti_Ka: Si-escape/parent ratio 49.2 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.four.unlistedProposal.notes[18] = "Ga_Ka: Si-escape/parent ratio 12.9 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.four.unlistedProposal.notes[19] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.four.unlistedProposal.notes[17] = "Ti_Ka: Si-escape/parent ratio 59.0 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.four.unlistedProposal.notes[18] = "Ga_Ka: Si-escape/parent ratio 12.7 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.four.unlistedProposal.notes[19] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.four.unlistedProposal.passes = 71
 seed0.four.unlistedProposal.settled = true
-seed0.four.unlistedProposal.reducedChiSquared = 40324e8c9a4072eb 18.306832924589724
+seed0.four.unlistedProposal.reducedChiSquared = 40328add357cf97d 18.542437880526894
 seed0.four.unlistedCheck.candidates: array 14
 seed0.four.unlistedCheck.candidates[0].element = "Ge"
 seed0.four.unlistedCheck.candidates[0].group = "Ge_Ka"
-seed0.four.unlistedCheck.candidates[0].net = 411038038f36946d 265728.88985664287
-seed0.four.unlistedCheck.candidates[0].detectionLimit = 4067010411f23bb1 184.03174683867613
+seed0.four.unlistedCheck.candidates[0].net = 411036da4b67f29f 265654.57363871665
+seed0.four.unlistedCheck.candidates[0].detectionLimit = 4067554744c8e890 186.6649497913354
 seed0.four.unlistedCheck.candidates[0].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[0].besideLine = nil
 seed0.four.unlistedCheck.candidates[0].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[1].element = "Ga"
 seed0.four.unlistedCheck.candidates[1].group = "Ga_La"
-seed0.four.unlistedCheck.candidates[1].net = 4112560a6bedc119 300418.60539914813
-seed0.four.unlistedCheck.candidates[1].detectionLimit = 4098ab3ec36f810d 1578.8112924025074
+seed0.four.unlistedCheck.candidates[1].net = 4112510f8469e70f 300099.87931023625
+seed0.four.unlistedCheck.candidates[1].detectionLimit = 40988d5cfe033ff6 1571.340812731532
 seed0.four.unlistedCheck.candidates[1].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[1].besideLine = nil
 seed0.four.unlistedCheck.candidates[1].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[2].element = "Cu"
 seed0.four.unlistedCheck.candidates[2].group = "Cu_Ka"
-seed0.four.unlistedCheck.candidates[2].net = 40ed6230e7539c2d 60177.528238110572
-seed0.four.unlistedCheck.candidates[2].detectionLimit = 4079cd96451caba7 412.84918700408383
+seed0.four.unlistedCheck.candidates[2].net = 40ed52a7f9867c9d 60053.249209636102
+seed0.four.unlistedCheck.candidates[2].detectionLimit = 407a0a4433ae6258 416.64165084952174
 seed0.four.unlistedCheck.candidates[2].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[2].besideLine = nil
 seed0.four.unlistedCheck.candidates[2].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[3].element = "Eu"
 seed0.four.unlistedCheck.candidates[3].group = "Eu_Ma"
-seed0.four.unlistedCheck.candidates[3].net = 40f77c908fa9d086 96201.035074057145
-seed0.four.unlistedCheck.candidates[3].detectionLimit = 409ab59eab16bb2b 1709.4049495269526
+seed0.four.unlistedCheck.candidates[3].net = 40f760d02b76a87d 95757.010611208112
+seed0.four.unlistedCheck.candidates[3].detectionLimit = 409ac1c413e4a228 1712.4414821361515
 seed0.four.unlistedCheck.candidates[3].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[3].besideLine = nil
 seed0.four.unlistedCheck.candidates[3].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[4].element = "Sm"
 seed0.four.unlistedCheck.candidates[4].group = "Sm_Ma"
-seed0.four.unlistedCheck.candidates[4].net = 40f5be087598035c 89056.528709424136
-seed0.four.unlistedCheck.candidates[4].detectionLimit = 409eb9ed7b82b3e7 1966.4819164678863
+seed0.four.unlistedCheck.candidates[4].net = 40f5c32272361a34 89138.152883627277
+seed0.four.unlistedCheck.candidates[4].detectionLimit = 409e9f04b5e50dbf 1959.7546001233711
 seed0.four.unlistedCheck.candidates[4].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[4].besideLine = nil
 seed0.four.unlistedCheck.candidates[4].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[5].element = "Pr"
 seed0.four.unlistedCheck.candidates[5].group = "Pr_Ma"
-seed0.four.unlistedCheck.candidates[5].net = 40e832ee1ccf2caa 49559.441016757235
-seed0.four.unlistedCheck.candidates[5].detectionLimit = 40a18b497a6d9289 2245.6435121766449
+seed0.four.unlistedCheck.candidates[5].net = 40e80e6ad62f9963 49267.338645743926
+seed0.four.unlistedCheck.candidates[5].detectionLimit = 40a185a18424ced5 2242.8154613020401
 seed0.four.unlistedCheck.candidates[5].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[5].besideLine = "Ni Lα"
 seed0.four.unlistedCheck.candidates[5].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[6].element = "Na"
 seed0.four.unlistedCheck.candidates[6].group = "Na_Ka"
-seed0.four.unlistedCheck.candidates[6].net = 40d98ff787f65961 26175.867673480305
-seed0.four.unlistedCheck.candidates[6].detectionLimit = 40a4053bc168c3ff 2562.616709970403
+seed0.four.unlistedCheck.candidates[6].net = 40d900aa2a2ee658 25602.658824658341
+seed0.four.unlistedCheck.candidates[6].detectionLimit = 40a403f93d68e2f7 2561.9867966439301
 seed0.four.unlistedCheck.candidates[6].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[6].besideLine = nil
 seed0.four.unlistedCheck.candidates[6].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[7].element = "Ce"
 seed0.four.unlistedCheck.candidates[7].group = "Ce_Ma"
-seed0.four.unlistedCheck.candidates[7].net = 40c3b6e460a5630e 10093.784199403159
-seed0.four.unlistedCheck.candidates[7].detectionLimit = 409229b8360a9de4 1162.4298936518544
+seed0.four.unlistedCheck.candidates[7].net = 40c3b7b0e4081487 10095.381958971046
+seed0.four.unlistedCheck.candidates[7].detectionLimit = 4092251da91c3eba 1161.2789654172216
 seed0.four.unlistedCheck.candidates[7].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[7].besideLine = "Ni Lα"
 seed0.four.unlistedCheck.candidates[7].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[8].element = "Rb"
 seed0.four.unlistedCheck.candidates[8].group = "Rb_La"
-seed0.four.unlistedCheck.candidates[8].net = 40d043acfc52dba5 16654.702900614258
-seed0.four.unlistedCheck.candidates[8].detectionLimit = 40a4900b0d201198 2632.0215845128514
+seed0.four.unlistedCheck.candidates[8].net = 40cf7af751330e5d 16117.93216551019
+seed0.four.unlistedCheck.candidates[8].detectionLimit = 40a4356d147f1edf 2586.7130470013794
 seed0.four.unlistedCheck.candidates[8].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[8].besideLine = "Si Kα"
-seed0.four.unlistedCheck.candidates[8].fractionOfNeighbour = 3f91b69012e48977 0.017297984269256852
+seed0.four.unlistedCheck.candidates[8].fractionOfNeighbour = 3f9127f36dd6e527 0.016753963069026014
 seed0.four.unlistedCheck.candidates[9].element = "Ta"
 seed0.four.unlistedCheck.candidates[9].group = "Ta_Ma"
-seed0.four.unlistedCheck.candidates[9].net = 40d582600824b73f 22025.50049703498
-seed0.four.unlistedCheck.candidates[9].detectionLimit = 40b259a8580d9096 4697.6575935819619
+seed0.four.unlistedCheck.candidates[9].net = 40d7bb94c7d1728f 24302.324695932268
+seed0.four.unlistedCheck.candidates[9].detectionLimit = 40b2bc3190d144b0 4796.1936159889883
 seed0.four.unlistedCheck.candidates[9].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[9].besideLine = "Si Kα"
-seed0.four.unlistedCheck.candidates[9].fractionOfNeighbour = 3f976cdd9822ae03 0.022876226816761058
+seed0.four.unlistedCheck.candidates[9].fractionOfNeighbour = 3f99de1a85d61818 0.025261320513458058
 seed0.four.unlistedCheck.candidates[10].element = "Zr"
 seed0.four.unlistedCheck.candidates[10].group = "Zr_La"
-seed0.four.unlistedCheck.candidates[10].net = 40886d9c1e4b3510 781.70122965579685
-seed0.four.unlistedCheck.candidates[10].detectionLimit = 4078eb81b3c90ece 398.71916559732642
+seed0.four.unlistedCheck.candidates[10].net = 408ec4789331b685 984.55887450063949
+seed0.four.unlistedCheck.candidates[10].detectionLimit = 4079a7957936994e 410.47399255111384
 seed0.four.unlistedCheck.candidates[10].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[10].besideLine = nil
 seed0.four.unlistedCheck.candidates[10].fractionOfNeighbour = nil
-seed0.four.unlistedCheck.candidates[11].element = "Gd"
-seed0.four.unlistedCheck.candidates[11].group = "Gd_Ma"
-seed0.four.unlistedCheck.candidates[11].net = 40bbcf09c4f36c51 7119.0381614818043
-seed0.four.unlistedCheck.candidates[11].detectionLimit = 40b04b2064b11bea 4171.1265364354276
-seed0.four.unlistedCheck.candidates[11].sumPeakQuestion = false
+seed0.four.unlistedCheck.candidates[11].element = "P"
+seed0.four.unlistedCheck.candidates[11].group = "P_Ka"
+seed0.four.unlistedCheck.candidates[11].net = 408d744bd96157f5 942.53703571366952
+seed0.four.unlistedCheck.candidates[11].detectionLimit = 407d1db851370299 465.8574993275484
+seed0.four.unlistedCheck.candidates[11].sumPeakQuestion = true
 seed0.four.unlistedCheck.candidates[11].besideLine = nil
 seed0.four.unlistedCheck.candidates[11].fractionOfNeighbour = nil
-seed0.four.unlistedCheck.candidates[12].element = "P"
-seed0.four.unlistedCheck.candidates[12].group = "P_Ka"
-seed0.four.unlistedCheck.candidates[12].net = 40879122f0ad5b55 754.14206061778043
-seed0.four.unlistedCheck.candidates[12].detectionLimit = 407c7f1e3ae09dc1 455.944880368621
-seed0.four.unlistedCheck.candidates[12].sumPeakQuestion = true
+seed0.four.unlistedCheck.candidates[12].element = "Gd"
+seed0.four.unlistedCheck.candidates[12].group = "Gd_Ma"
+seed0.four.unlistedCheck.candidates[12].net = 40b8f8224c0aedc3 6392.1339728193734
+seed0.four.unlistedCheck.candidates[12].detectionLimit = 40b05caf53ae97ed 4188.6848706360734
+seed0.four.unlistedCheck.candidates[12].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[12].besideLine = nil
 seed0.four.unlistedCheck.candidates[12].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.candidates[13].element = "Hg"
 seed0.four.unlistedCheck.candidates[13].group = "Hg_La"
-seed0.four.unlistedCheck.candidates[13].net = 4076353055b0c028 355.32430047076423
-seed0.four.unlistedCheck.candidates[13].detectionLimit = 4072e422e9bb4fe4 302.25852368515757
+seed0.four.unlistedCheck.candidates[13].net = 4074e31a16cb3ffd 334.19386939425004
+seed0.four.unlistedCheck.candidates[13].detectionLimit = 4072eca1ea1c8e70 302.78952990679591
 seed0.four.unlistedCheck.candidates[13].sumPeakQuestion = false
 seed0.four.unlistedCheck.candidates[13].besideLine = nil
 seed0.four.unlistedCheck.candidates[13].fractionOfNeighbour = nil
 seed0.four.unlistedCheck.moves: array 3
 seed0.four.unlistedCheck.moves[0].element = "O"
-seed0.four.unlistedCheck.moves[0].before = 41007c278ba3815b 135044.94318295535
-seed0.four.unlistedCheck.moves[0].after = 40fd7e33e94bc0a1 120803.2444570088
-seed0.four.unlistedCheck.moves[0].sigma = 407a8f6b1d851b72 424.96365119929317
+seed0.four.unlistedCheck.moves[0].before = 41007a2dbb41443f 134981.71643307988
+seed0.four.unlistedCheck.moves[0].after = 40fd768286eadd61 120680.15793882824
+seed0.four.unlistedCheck.moves[0].sigma = 407a8daff277c697 424.85545584475898
 seed0.four.unlistedCheck.moves[1].element = "Ti"
 seed0.four.unlistedCheck.moves[1].before = 0000000000000000 0
-seed0.four.unlistedCheck.moves[1].after = 40a6717a723e273b 2872.7391528532876
-seed0.four.unlistedCheck.moves[1].sigma = 405b2734a225834e 108.61258748687143
+seed0.four.unlistedCheck.moves[1].after = 40a61cab405d5327 2830.3344754375462
+seed0.four.unlistedCheck.moves[1].sigma = 405b656b296d9c10 109.58466563896241
 seed0.four.unlistedCheck.moves[2].element = "Ni"
-seed0.four.unlistedCheck.moves[2].before = 4117673a001fc5cb 383438.50012120296
-seed0.four.unlistedCheck.moves[2].after = 41182294e19155b7 395429.22028097085
-seed0.four.unlistedCheck.moves[2].sigma = 40851191b7105393 674.19614994769142
+seed0.four.unlistedCheck.moves[2].before = 411768233e47be00 383496.81082054973
+seed0.four.unlistedCheck.moves[2].after = 411821e185bc897e 395384.38060202438
+seed0.four.unlistedCheck.moves[2].sigma = 408511ad670abf11 674.20966919322575
 seed0.four.unlistedCheck.largest.element = "O"
-seed0.four.unlistedCheck.largest.before = 41007c278ba3815b 135044.94318295535
-seed0.four.unlistedCheck.largest.after = 40fd7e33e94bc0a1 120803.2444570088
-seed0.four.unlistedCheck.largest.sigma = 407a8f6b1d851b72 424.96365119929317
+seed0.four.unlistedCheck.largest.before = 41007a2dbb41443f 134981.71643307988
+seed0.four.unlistedCheck.largest.after = 40fd768286eadd61 120680.15793882824
+seed0.four.unlistedCheck.largest.sigma = 407a8daff277c697 424.85545584475898
 seed0.four.unlistedCheck.failure = nil
 seed0.four.withholding: array 2
-seed0.four.withholding[0]: n 4 sum 4059000000000001 100.00000000000001 fnv 64053905b6b50ded
-seed0.four.withholding[0][0] = 402830a26b31d83e 12.094989156565244
-seed0.four.withholding[0][1] = 405037eb452be34c 64.87373475347448
+seed0.four.withholding[0]: n 4 sum 4059000000000000 100 fnv 5774b60983dd3179
+seed0.four.withholding[0][0] = 4028311a1c0a17c4 12.0959023248978
+seed0.four.withholding[0][1] = 405036d5a39e5ff6 64.856789498007714
 seed0.four.withholding[0][2] = 0000000000000000 0
-seed0.four.withholding[0][3] = 40370801b5b786b3 23.031276089960283
-seed0.four.withholding[1]: n 4 sum 41369a4f37545cb7 1481295.2161310145 fnv 48b89a51a9c54a30
-seed0.four.withholding[1][0] = 41007c278ba3815b 135044.94318295535
-seed0.four.withholding[1][1] = 412d61f78baff631 962811.77282685612
+seed0.four.withholding[0][3] = 40370c1c6381744a 23.0473081770945
+seed0.four.withholding[1]: n 4 sum 4136974383ddf72b 1480515.5151056747 fnv 19446b3f20b76e80
+seed0.four.withholding[1][0] = 41007a2dbb41443f 134981.71643307988
+seed0.four.withholding[1][1] = 412d5be9f9c7be46 962036.9878520451
 seed0.four.withholding[1][2] = 0000000000000000 0
-seed0.four.withholding[1][3] = 4117673a001fc5cb 383438.50012120296
-seed0.four.withholding.caveat = "assumes the listed elements only; unlisted: Ge (net 265 729), Ga (net 300 419), Cu (net 60 178), Eu (net 96 201), Sm (net 89 057), excess beside Ni Lα (net 49 559), Na (net 26 176), excess beside Ni Lα (net 10 094), excess beside Si Kα (net 16 655), excess beside Si Kα (net 22 026), Zr (net 782), Gd (net 7 119), P (net 754), Hg (net 355); largest move 33.5 σ (O)"
-seed0.four.csv-withholding-fnv = fd85f3651ba26e8c
+seed0.four.withholding[1][3] = 411768233e47be00 383496.81082054973
+seed0.four.withholding.caveat = "assumes the listed elements only; unlisted: Ge (net 265 655), Ga (net 300 100), Cu (net 60 053), Eu (net 95 757), Sm (net 89 138), excess beside Ni Lα (net 49 267), Na (net 25 603), excess beside Ni Lα (net 10 095), excess beside Si Kα (net 16 118), excess beside Si Kα (net 24 302), Zr (net 985), P (net 943), Gd (net 6 392), Hg (net 334); largest move 33.7 σ (O)"
+seed0.four.csv-withholding-fnv = aaf73fcd5d163f74
 seed0.seven.quantification.method.version = 1
 seed0.seven.quantification.method.estimator = .leastSquares
 seed0.seven.quantification.method.background = .empiricalWithAlEdge
@@ -1230,26 +1230,26 @@ seed0.seven.quantification.method.fitToKeV = nil
 seed0.seven.quantification.rows: array 4
 seed0.seven.quantification.rows[0].element = "O"
 seed0.seven.quantification.rows[0].groupID = "O_Ka"
-seed0.seven.quantification.rows[0].net = 40fd40c04d9ba706 119820.01894726985
-seed0.seven.quantification.rows[0].sigma = 4081ec5a1b174aae 573.5439969844499
+seed0.seven.quantification.rows[0].net = 40fd3fad7838d674 119802.84185107966
+seed0.seven.quantification.rows[0].sigma = 4081e78a9f3e938c 572.94268654716279
 seed0.seven.quantification.rows[0].supported = true
 seed0.seven.quantification.rows[0].atBound = false
 seed0.seven.quantification.rows[0].isReference = false
-seed0.seven.quantification.rows[0].kFreeRatio = 3fbff7a42ac1dc5e 0.12487245601538308
-seed0.seven.quantification.rows[0].kFreeSigma = 3f442799463ebbc8 0.00061507209874444527
-seed0.seven.quantification.rows[0].atomicPercent = 40259de9a92c31af 10.808423315663132
-seed0.seven.quantification.rows[0].atomicSigma = 3ffff6fdc2b573da 1.9978005986988507
-seed0.seven.quantification.rows[0].weightPercent = 40144480aa5a501c 5.0668970697043072
-seed0.seven.quantification.rows[0].weightSigma = 3ff0cc10d6dab670 1.0498207466838743
+seed0.seven.quantification.rows[0].kFreeRatio = 3fbff5aa2bcf3824 0.12484229631010685
+seed0.seven.quantification.rows[0].kFreeSigma = 3f44347a3f0a78a1 0.00061660737090442699
+seed0.seven.quantification.rows[0].atomicPercent = 40259cd594e9aa95 10.806316998981211
+seed0.seven.quantification.rows[0].atomicSigma = 3ffff5930f02ab28 1.9974546991676991
+seed0.seven.quantification.rows[0].weightPercent = 4014437caa9099ac 5.0659052515751846
+seed0.seven.quantification.rows[0].weightSigma = 3ff0cb40a819805d 1.0496222082511146
 seed0.seven.quantification.rows[0].atomicTerms.relative: dict 4
 seed0.seven.quantification.rows[0].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[0].atomicTerms.relative.counting = 3f71d799d4c6ab4a 0.0043560036687420676
-seed0.seven.quantification.rows[0].atomicTerms.relative.k = 3fc7a711a76defc8 0.18478604007020594
+seed0.seven.quantification.rows[0].atomicTerms.relative.counting = 3f71df8a3c9c02ad 0.0043635749696028627
+seed0.seven.quantification.rows[0].atomicTerms.relative.k = 3fc7a731e0258aa4 0.18478988117847905
 seed0.seven.quantification.rows[0].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[0].weightTerms.relative: dict 4
 seed0.seven.quantification.rows[0].weightTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[0].weightTerms.relative.counting = 3f7303eedf0606c0 0.0046424227624599079
-seed0.seven.quantification.rows[0].weightTerms.relative.k = 3fca83907813c0e6 0.20714002478735621
+seed0.seven.quantification.rows[0].weightTerms.relative.counting = 3f730999b6691e8b 0.0046478275676872334
+seed0.seven.quantification.rows[0].weightTerms.relative.k = 3fca839afa4366a0 0.20714127750288913
 seed0.seven.quantification.rows[0].weightTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[0].absorptionSpreadAtomic = nil
 seed0.seven.quantification.rows[0].absorptionSpreadWeight = nil
@@ -1259,26 +1259,26 @@ seed0.seven.quantification.rows[0].failure = nil
 seed0.seven.quantification.rows[0].lineNote = nil
 seed0.seven.quantification.rows[1].element = "Si"
 seed0.seven.quantification.rows[1].groupID = "Si_Ka"
-seed0.seven.quantification.rows[1].net = 412d4866703dcc66 959539.21922148461
-seed0.seven.quantification.rows[1].sigma = 409169ca6a5c4525 1114.4476713578417
+seed0.seven.quantification.rows[1].net = 412d4922df948265 959633.43667991145
+seed0.seven.quantification.rows[1].sigma = 4091a7649735cc27 1129.8482330709319
 seed0.seven.quantification.rows[1].supported = true
 seed0.seven.quantification.rows[1].atBound = false
 seed0.seven.quantification.rows[1].isReference = true
 seed0.seven.quantification.rows[1].kFreeRatio = 3ff0000000000000 1
 seed0.seven.quantification.rows[1].kFreeSigma = nil
-seed0.seven.quantification.rows[1].atomicPercent = 405047810184783a 65.117248896946791
-seed0.seven.quantification.rows[1].atomicSigma = 400b631ec533a6c3 3.4233985334766159
-seed0.seven.quantification.rows[1].weightPercent = 404acb0dca4c260e 53.586358344251593
-seed0.seven.quantification.rows[1].weightSigma = 4011dfd7918ba53b 4.4685957662089164
+seed0.seven.quantification.rows[1].atomicPercent = 405047b2c8d3e566 65.12028713887193
+seed0.seven.quantification.rows[1].atomicSigma = 400b632244bb1257 3.4234052056874975
+seed0.seven.quantification.rows[1].weightPercent = 404acb5e31cbc744 53.588812088490641
+seed0.seven.quantification.rows[1].weightSigma = 4011dff71d4ca0fd 4.4687161043186707
 seed0.seven.quantification.rows[1].atomicTerms.relative: dict 4
 seed0.seven.quantification.rows[1].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[1].atomicTerms.relative.counting = 3f49850a5e810e0b 0.00077879911715012082
-seed0.seven.quantification.rows[1].atomicTerms.relative.k = 3faaea1220978645 0.052567068556311138
+seed0.seven.quantification.rows[1].atomicTerms.relative.counting = 3f49b295df997242 0.00078422849692178658
+seed0.seven.quantification.rows[1].atomicTerms.relative.k = 3faae9c08b7371fe 0.052564637205907858
 seed0.seven.quantification.rows[1].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[1].weightTerms.relative: dict 4
 seed0.seven.quantification.rows[1].weightTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[1].weightTerms.relative.counting = 3f4e63491a273843 0.00092736310426189854
-seed0.seven.quantification.rows[1].weightTerms.relative.k = 3fb558beb72a935d 0.08338539096673743
+seed0.seven.quantification.rows[1].weightTerms.relative.counting = 3f4e8de8cb3f66bd 0.00093244425670065796
+seed0.seven.quantification.rows[1].weightTerms.relative.k = 3fb558a360879187 0.083383761469638981
 seed0.seven.quantification.rows[1].weightTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[1].absorptionSpreadAtomic = nil
 seed0.seven.quantification.rows[1].absorptionSpreadWeight = nil
@@ -1288,26 +1288,26 @@ seed0.seven.quantification.rows[1].failure = nil
 seed0.seven.quantification.rows[1].lineNote = nil
 seed0.seven.quantification.rows[2].element = "Ti"
 seed0.seven.quantification.rows[2].groupID = "Ti_Ka"
-seed0.seven.quantification.rows[2].net = 40a741bb2cb26e36 2976.865575386003
-seed0.seven.quantification.rows[2].sigma = 405b3661036e9053 108.84967122838252
+seed0.seven.quantification.rows[2].net = 40a72ef210a08339 2967.4727831039604
+seed0.seven.quantification.rows[2].sigma = 405b6a98a5045bfd 109.66556668687549
 seed0.seven.quantification.rows[2].supported = true
 seed0.seven.quantification.rows[2].atBound = false
 seed0.seven.quantification.rows[2].isReference = false
-seed0.seven.quantification.rows[2].kFreeRatio = 3f696a2f56b4a8bd 0.0031023907264585413
-seed0.seven.quantification.rows[2].kFreeSigma = 3f1dd25ee4da3af0 0.00011376098810898425
-seed0.seven.quantification.rows[2].atomicPercent = 3fc63997df0c3fe2 0.17363260642059603
-seed0.seven.quantification.rows[2].atomicSigma = 3fa2a3b9d95a7dd7 0.036405380041511108
-seed0.seven.quantification.rows[2].weightPercent = 3fcf2bd3add13b99 0.24352498995946517
-seed0.seven.quantification.rows[2].weightSigma = 3fab57db6bf85ab2 0.053404671602199541
+seed0.seven.quantification.rows[2].kFreeRatio = 3f695504f9544e38 0.0030922982356374161
+seed0.seven.quantification.rows[2].kFreeSigma = 3f1e109fb0691477 0.00011468863167703342
+seed0.seven.quantification.rows[2].atomicPercent = 3fc627594dc75baa 0.17307583139219435
+seed0.seven.quantification.rows[2].atomicSigma = 3fa2960ce4ac9930 0.036301043428738189
+seed0.seven.quantification.rows[2].weightPercent = 3fcf123b4cd568e3 0.24274388553278134
+seed0.seven.quantification.rows[2].weightSigma = 3fab4397f121dc2d 0.053250072655764626
 seed0.seven.quantification.rows[2].atomicTerms.relative: dict 4
 seed0.seven.quantification.rows[2].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[2].atomicTerms.relative.counting = 3fa2b81d3f3504cf 0.03656093021937467
-seed0.seven.quantification.rows[2].atomicTerms.relative.k = 3fca6d2cf5cc4b9e 0.20645677568299176
+seed0.seven.quantification.rows[2].atomicTerms.relative.counting = 3fa2ed595a5d7351 0.036967079430474066
+seed0.seven.quantification.rows[2].atomicTerms.relative.k = 3fca6d30d0a1d350 0.20645723521342996
 seed0.seven.quantification.rows[2].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[2].weightTerms.relative: dict 4
 seed0.seven.quantification.rows[2].weightTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[2].weightTerms.relative.counting = 3fa2b26924e56fa0 0.036517415765700223
-seed0.seven.quantification.rows[2].weightTerms.relative.k = 3fcbada52466f95f 0.21623672749951603
+seed0.seven.quantification.rows[2].weightTerms.relative.counting = 3fa2e7a10c2fcdef 0.036923439729345968
+seed0.seven.quantification.rows[2].weightTerms.relative.k = 3fcbadabfd50ab48 0.21623754376318005
 seed0.seven.quantification.rows[2].weightTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[2].absorptionSpreadAtomic = nil
 seed0.seven.quantification.rows[2].absorptionSpreadWeight = nil
@@ -1317,26 +1317,26 @@ seed0.seven.quantification.rows[2].failure = nil
 seed0.seven.quantification.rows[2].lineNote = nil
 seed0.seven.quantification.rows[3].element = "Ni"
 seed0.seven.quantification.rows[3].groupID = "Ni_Ka"
-seed0.seven.quantification.rows[3].net = 41181d1688ed1266 395077.63371685741
-seed0.seven.quantification.rows[3].sigma = 40854628f221a047 680.76999307890298
+seed0.seven.quantification.rows[3].net = 41181d4f2974e3e8 395091.79048496345
+seed0.seven.quantification.rows[3].sigma = 40854841200b2243 681.03179939935978
 seed0.seven.quantification.rows[3].supported = true
 seed0.seven.quantification.rows[3].atBound = false
 seed0.seven.quantification.rows[3].isReference = false
-seed0.seven.quantification.rows[3].kFreeRatio = 3fda59e56bde695d 0.41173682722150834
-seed0.seven.quantification.rows[3].kFreeSigma = 3f4be1116759dbf2 0.00085080480376020632
-seed0.seven.quantification.rows[3].atomicPercent = 4037e693f599edc3 23.900695180969489
-seed0.seven.quantification.rows[3].atomicSigma = 400d760ffc5045c1 3.6826476776120391
-seed0.seven.quantification.rows[3].weightPercent = 40448d364cbabeb4 41.103219596084642
-seed0.seven.quantification.rows[3].weightSigma = 4013921f0ffb9989 4.892696618777685
+seed0.seven.quantification.rows[3].kFreeRatio = 3fda5979be6934f6 0.41171115488835086
+seed0.seven.quantification.rows[3].kFreeSigma = 3f4bf0a91c56f480 0.0008526635871742988
+seed0.seven.quantification.rows[3].atomicPercent = 4037e67b5fa0066a 23.900320030754678
+seed0.seven.quantification.rows[3].atomicSigma = 400d75f357d9b85a 3.6825930465047749
+seed0.seven.quantification.rows[3].weightPercent = 40448d1ffd95501b 41.102538774401374
+seed0.seven.quantification.rows[3].weightSigma = 4013921660f34499 4.8926634930113773
 seed0.seven.quantification.rows[3].atomicTerms.relative: dict 4
 seed0.seven.quantification.rows[3].atomicTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[3].atomicTerms.relative.counting = 3f5a0d08c8fb6cac 0.0015900216857776357
-seed0.seven.quantification.rows[3].atomicTerms.relative.k = 3fc3b8a9ec853a04 0.1540729908833357
+seed0.seven.quantification.rows[3].atomicTerms.relative.counting = 3f5a0a71b5dc7da4 0.0015894041493494738
+seed0.seven.quantification.rows[3].atomicTerms.relative.k = 3fc3b8ab17459909 0.15407313000032044
 seed0.seven.quantification.rows[3].atomicTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[3].weightTerms.relative: dict 4
 seed0.seven.quantification.rows[3].weightTerms.relative.absorption = 0000000000000000 0
-seed0.seven.quantification.rows[3].weightTerms.relative.counting = 3f53c5892832431f 0.0012067641662591511
-seed0.seven.quantification.rows[3].weightTerms.relative.k = 3fbe78a305660ba1 0.11902827150156138
+seed0.seven.quantification.rows[3].weightTerms.relative.counting = 3f53c64c7aeaa245 0.0012069460750955424
+seed0.seven.quantification.rows[3].weightTerms.relative.k = 3fbe78b68c9b75da 0.1190294354705296
 seed0.seven.quantification.rows[3].weightTerms.relative.thickness = 0000000000000000 0
 seed0.seven.quantification.rows[3].absorptionSpreadAtomic = nil
 seed0.seven.quantification.rows[3].absorptionSpreadWeight = nil
@@ -1358,8 +1358,8 @@ seed0.seven.quantification.fit.groupIDs[8] = "O_Ka"
 seed0.seven.quantification.fit.groupIDs[9] = "Si_Ka"
 seed0.seven.quantification.fit.groupIDs[10] = "Ti_Ka"
 seed0.seven.quantification.fit.groupIDs[11] = "Ti_La"
-seed0.seven.quantification.fit.values: n 12 sum 41454d55c963d6b1 2792107.5733593334 fnv a488b015d924bcdd
-seed0.seven.quantification.fit.covariance: n 144 sum 41540b5ac63bec0b 5254507.0974073512 fnv c7f54d51c1371d3c
+seed0.seven.quantification.fit.values: n 12 sum 41454da612ab88a2 2792268.1458597938 fnv f7e6f887f13656d9
+seed0.seven.quantification.fit.covariance: n 144 sum 41543926ba72aadb 5301402.9132487429 fnv b1037774f32cddd
 seed0.seven.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 seed0.seven.quantification.fit.supported: n 12 sum-bits c fnv 9a4297133c0b8de5
 seed0.seven.quantification.fit.atBound: n 12 sum-bits 0 fnv 243cfa845185aa5
@@ -1368,9 +1368,9 @@ seed0.seven.quantification.fit.escapeValues[0] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeValues[1] = nil
 seed0.seven.quantification.fit.escapeValues[2] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeValues[3] = nil
-seed0.seven.quantification.fit.escapeValues[4] = 40400c4bd56f991f 32.096064261904978
+seed0.seven.quantification.fit.escapeValues[4] = 404211bfdb460b46 36.138667496873083
 seed0.seven.quantification.fit.escapeValues[5] = nil
-seed0.seven.quantification.fit.escapeValues[6] = 405ef33ba27b7f29 123.80051481304385
+seed0.seven.quantification.fit.escapeValues[6] = 405f9572aa17ef9c 126.33512356126306
 seed0.seven.quantification.fit.escapeValues[7] = nil
 seed0.seven.quantification.fit.escapeValues[8] = nil
 seed0.seven.quantification.fit.escapeValues[9] = nil
@@ -1393,34 +1393,34 @@ seed0.seven.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 seed0.seven.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 seed0.seven.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 seed0.seven.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-seed0.seven.quantification.fit.backgroundCoefficients: n 16 sum 4136c78f77b7efd8 1492879.4676504042 fnv 11f7d749ad16e0ed
+seed0.seven.quantification.fit.backgroundCoefficients: n 16 sum 4136c7a83163119f 1492904.1929179204 fnv 5e20ae2b2581b93f
 seed0.seven.quantification.fit.channels = 107..<1098
-seed0.seven.quantification.fit.model: n 991 sum 414e5cb380004094 3979623.0000076983 fnv 136a1029d025a357
-seed0.seven.quantification.fit.residual: n 991 sum bee022f2ffc00000 -7.6944925169186718e-06 fnv 8a06cf4eadb35409
-seed0.seven.quantification.fit.standardizedResidual: n 991 sum c01b0be334a62a75 -6.7616089083118043 fnv 19270ac87e48176d
+seed0.seven.quantification.fit.model: n 991 sum 414e5cb35a013312 3979622.7031616056 fnv e382b512673cecb5
+seed0.seven.quantification.fit.residual: n 991 sum 3fd2ff6679d4b980 0.29683839700273751 fnv 43f9edcadb2aca9e
+seed0.seven.quantification.fit.standardizedResidual: n 991 sum c01d32e6b3fbee18 -7.2997081873432066 fnv f37153e1ec843928
 seed0.seven.quantification.fit.negativeModelChannels = 0
 seed0.seven.quantification.fit.degreesOfFreedom = 958
-seed0.seven.quantification.fit.reducedChiSquared = 40ac2836330b3d1c 3604.1058581840607
-seed0.seven.quantification.fit.pearsonReducedChiSquared = 3fef4c6c5174c354 0.97807899388690567
-seed0.seven.quantification.fit.deviance = 408d5497ac2b66dd 938.57405885608352
-seed0.seven.quantification.fit.reducedDeviance = 3fef59e2ca33bc83 0.97972239964100571
+seed0.seven.quantification.fit.reducedChiSquared = 40ac1ba4d79e56cb 3597.8219575386952
+seed0.seven.quantification.fit.pearsonReducedChiSquared = 3fef8d5e04be136a 0.98600674558893542
+seed0.seven.quantification.fit.deviance = 408d8eb871ca6011 945.84006078820869
+seed0.seven.quantification.fit.reducedDeviance = 3fef9804c02d4b6e 0.9873069528060634
 seed0.seven.quantification.fit.methodLabel = "least squares, unweighted"
 seed0.seven.quantification.fit.referenceShapesLabel = "reference shapes: none"
 seed0.seven.quantification.fit.escapeLabel = "escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-seed0.seven.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+seed0.seven.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 seed0.seven.quantification.fit.exit = "converged"
 seed0.seven.quantification.fit.warnings: array 1
-seed0.seven.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.seven.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.seven.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.fit.escapeRatios: array 12
 seed0.seven.quantification.fit.escapeRatios[0] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[1] = nil
 seed0.seven.quantification.fit.escapeRatios[2] = 0000000000000000 0
 seed0.seven.quantification.fit.escapeRatios[3] = nil
-seed0.seven.quantification.fit.escapeRatios[4] = 3f1fa9f765e1a328 0.00012078831193352831
+seed0.seven.quantification.fit.escapeRatios[4] = 3f21d3612672394f 0.0001359993068245726
 seed0.seven.quantification.fit.escapeRatios[5] = nil
-seed0.seven.quantification.fit.escapeRatios[6] = 3f348943f1e5ba85 0.00031335743724173636
+seed0.seven.quantification.fit.escapeRatios[6] = 3f34f4b4f7b38739 0.00031976144937405669
 seed0.seven.quantification.fit.escapeRatios[7] = nil
 seed0.seven.quantification.fit.escapeRatios[8] = nil
 seed0.seven.quantification.fit.escapeRatios[9] = nil
@@ -1433,23 +1433,23 @@ seed0.seven.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv c
 seed0.seven.quantification.fileAxis.offset = bffeea58ae97d879 -1.9322134799999999
 seed0.seven.quantification.fileAxis.scale = 3f947ae147ae147b 0.02
 seed0.seven.quantification.fileAxis.size = 4096
-seed0.seven.quantification.usedAxis.offset = bffeea9b7f79b949 -1.9322772006522249
-seed0.seven.quantification.usedAxis.scale = 3f947af1ef262b1f 0.020000248166563424
+seed0.seven.quantification.usedAxis.offset = bffeea9b7e361d50 -1.9322771959430902
+seed0.seven.quantification.usedAxis.scale = 3f947af2042a3340 0.020000249389841018
 seed0.seven.quantification.usedAxis.size = 4096
 seed0.seven.quantification.axisLocked = false
 seed0.seven.quantification.refinement.fileOffset = bffeea58ae97d879 -1.9322134799999999
 seed0.seven.quantification.refinement.fileScale = 3f947ae147ae147b 0.02
 seed0.seven.quantification.refinement.fileResolutionMnKaEV = 4060400000000000 130
-seed0.seven.quantification.refinement.offset = bffeea9b7f79b949 -1.9322772006522249
-seed0.seven.quantification.refinement.scale = 3f947af1ef262b1f 0.020000248166563424
-seed0.seven.quantification.refinement.resolutionMnKaEV = 40605568a5af11a6 130.66902431672241
-seed0.seven.quantification.refinement.rssFile = 41753fa56ee0d94f 22280790.929894742
-seed0.seven.quantification.refinement.rssRefined = 414a579eb4c103ac 3452733.4121403303
-seed0.seven.quantification.refinement.iterations = 92
+seed0.seven.quantification.refinement.offset = bffeea9b7e361d50 -1.9322771959430902
+seed0.seven.quantification.refinement.scale = 3f947af2042a3340 0.020000249389841018
+seed0.seven.quantification.refinement.resolutionMnKaEV = 4060558043eee80c 130.67190739308751
+seed0.seven.quantification.refinement.rssFile = 4175186260e1f62a 22119974.055166401
+seed0.seven.quantification.refinement.rssRefined = 414a4bdcb7b8a233 3446713.43532207
+seed0.seven.quantification.refinement.iterations = 94
 seed0.seven.quantification.refinement.converged = true
 seed0.seven.quantification.refinement.size = 4096
-seed0.seven.quantification.plotModel: n 4096 sum 414e5cb380004094 3979623.0000076983 fnv ed1530d1d2f89f7
-seed0.seven.quantification.plotBackground: n 4096 sum 41284a0262599c64 795905.19208992692 fnv d2eb27005581ac10
+seed0.seven.quantification.plotModel: n 4096 sum 414e5cb35a013312 3979622.7031616056 fnv 19bc67e1afeb6e15
+seed0.seven.quantification.plotBackground: n 4096 sum 412848dff77ef632 795759.9833905159 fnv fc0ed317795d391c
 seed0.seven.quantification.kSet.kind = .computed
 seed0.seven.quantification.kSet.elements: array 4
 seed0.seven.quantification.kSet.elements[0] = "O"
@@ -1473,14 +1473,14 @@ seed0.seven.quantification.abundanceRefusal = nil
 seed0.seven.quantification.absorption = .off
 seed0.seven.quantification.warnings: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-seed0.seven.quantification.quality = 3fef4c6c5174c354 0.97807899388690567
+seed0.seven.quantification.quality = 3fef8d5e04be136a 0.98600674558893542
 seed0.seven.quantification.footerLines: array 9
-seed0.seven.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
+seed0.seven.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: fitted for 5 line groups above the Si K edge (1.839 keV)"
 seed0.seven.quantification.footerLines[1] = "energy axis: file -1.932 keV + 0.0200 keV/ch → refined -0.1 eV, gain +0.001 %, FWHM(Mn Kα) 131 eV"
 seed0.seven.quantification.footerLines[2] = "beam 200 kV · typed"
 seed0.seven.quantification.footerLines[3] = "fit range 0.2–20 keV (default; axis to 79.97 keV) · 1 px pooled (synthetic)"
 seed0.seven.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-seed0.seven.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 0.98 (Pearson)"
+seed0.seven.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 0.99 (Pearson)"
 seed0.seven.quantification.footerLines[6] = "k: computed: Bote-Salvat 2008 (NIST EPQ tables, PRA 77 042701), edges DHS xionUis.csv; not Velox's Brown-Powell default; omega: Krause 1979 (NIST EPQ Krause1979.csv); epsilon: EPQ getDefaultSDDProperties (Au 0.0 nm, Al 10.0 nm, Si dead layer 0.0 µm, Si 450.0 µm); generic SDD model, not a measured calibration of this detector; FFAST MACs; relative to Si; beam 200.0 keV; UNVALIDATED (EPQ 249dd3f8 + Krause 1979 + FFAST); σ_k 20 % flat, 0 on the reference (Si)"
 seed0.seven.quantification.footerLines[7] = "k-free ratio: net / net(Si)"
 seed0.seven.quantification.footerLines[8] = "absorption correction: off"
@@ -1492,7 +1492,7 @@ seed0.seven.quantification.fitSettings.elements[3] = "Ni"
 seed0.seven.quantification.fitSettings.elements[4] = "Ge"
 seed0.seven.quantification.fitSettings.elements[5] = "Cu"
 seed0.seven.quantification.fitSettings.elements[6] = "Ga"
-seed0.seven.quantification.fitSettings.resolutionMnKaEV = 40605568a5af11a6 130.66902431672241
+seed0.seven.quantification.fitSettings.resolutionMnKaEV = 4060558043eee80c 130.67190739308751
 seed0.seven.quantification.fitSettings.beamEnergy = 4069000000000000 200
 seed0.seven.quantification.fitSettings.fitFrom = 3fc999999999999a 0.20000000000000001
 seed0.seven.quantification.fitSettings.fitTo = 4034000000000000 20
@@ -1502,7 +1502,7 @@ seed0.seven.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f2
 seed0.seven.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 seed0.seven.quantification.fitSettings.background.continuum.nonNegative = true
 seed0.seven.quantification.fitSettings.background.continuum.efficiency = nil
-seed0.seven.quantification.fitSettings.background.continuum.edgeStep = .sharp
+seed0.seven.quantification.fitSettings.background.continuum.edgeStep = .broadened
 seed0.seven.quantification.fitSettings.escapePeaks = true
 seed0.seven.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.quantification.fitSettings.method = .leastSquares
@@ -1513,7 +1513,7 @@ seed0.seven.quantification.fitRange.toKeV = 4034000000000000 20
 seed0.seven.quantification.fitRange.source = .defaultLimit
 seed0.seven.quantification.fitRange.axisEndKeV = 4053fdf036df3a38 79.967786520000004
 seed0.seven.quantification.fitRange.beamEnergyKeV = 4069000000000000 200
-seed0.seven.quantification.fitRange.reachKeV = 4053fdffd20951d7 79.968739041424996
+seed0.seven.quantification.fitRange.reachKeV = 4053fdffe7111828 79.968744055455886
 seed0.seven.quantification.fitRange.typedKeV = nil
 seed0.seven.quantification.rangeSensitivity = nil
 seed0.seven.quantification.unlistedCheck = nil
@@ -1521,39 +1521,39 @@ seed0.seven.quantification.unlistedCheckPending = false
 seed0.seven.quantification.abundanceCaveat = nil
 seed0.seven.quantification.appliedSumEscape = nil
 seed0.seven.quantification.continuumDeadLayerMicrons = nil
-seed0.seven.csv-fnv = 5312e03b97452089
-seed0.seven.rangeSensitivity.alternativeToKeV = 4053fdffd20951d7 79.968739041424996
+seed0.seven.csv-fnv = c50c6f94500dc1f3
+seed0.seven.rangeSensitivity.alternativeToKeV = 4053fdffe7111828 79.968744055455886
 seed0.seven.rangeSensitivity.moves: array 4
 seed0.seven.rangeSensitivity.moves[0].element = "O"
 seed0.seven.rangeSensitivity.moves[0].group = "O_Ka"
-seed0.seven.rangeSensitivity.moves[0].before = 40fd40c04d9ba706 119820.01894726985
-seed0.seven.rangeSensitivity.moves[0].sigma = 4081ec5a1b174aae 573.5439969844499
-seed0.seven.rangeSensitivity.moves[0].after = 40fd40c04da1391a 119820.01895258241
+seed0.seven.rangeSensitivity.moves[0].before = 40fd3fad7838d674 119802.84185107966
+seed0.seven.rangeSensitivity.moves[0].sigma = 4081e78a9f3e938c 572.94268654716279
+seed0.seven.rangeSensitivity.moves[0].after = 40fd3e799b9a72d3 119783.60048909047
 seed0.seven.rangeSensitivity.moves[1].element = "Si"
 seed0.seven.rangeSensitivity.moves[1].group = "Si_Ka"
-seed0.seven.rangeSensitivity.moves[1].before = 412d4866703dcc66 959539.21922148461
-seed0.seven.rangeSensitivity.moves[1].sigma = 409169ca6a5c4525 1114.4476713578417
-seed0.seven.rangeSensitivity.moves[1].after = 412d4b79c6192091 959932.88691045542
+seed0.seven.rangeSensitivity.moves[1].before = 412d4922df948265 959633.43667991145
+seed0.seven.rangeSensitivity.moves[1].sigma = 4091a7649735cc27 1129.8482330709319
+seed0.seven.rangeSensitivity.moves[1].after = 412d4bf233aeaeff 959993.10094210494
 seed0.seven.rangeSensitivity.moves[2].element = "Ti"
 seed0.seven.rangeSensitivity.moves[2].group = "Ti_Ka"
-seed0.seven.rangeSensitivity.moves[2].before = 40a741bb2cb26e36 2976.865575386003
-seed0.seven.rangeSensitivity.moves[2].sigma = 405b3661036e9053 108.84967122838252
-seed0.seven.rangeSensitivity.moves[2].after = 40a59ebb8a274969 2767.366288402282
+seed0.seven.rangeSensitivity.moves[2].before = 40a72ef210a08339 2967.4727831039604
+seed0.seven.rangeSensitivity.moves[2].sigma = 405b6a98a5045bfd 109.66556668687549
+seed0.seven.rangeSensitivity.moves[2].after = 40a5bfe514d3c160 2783.9474245236925
 seed0.seven.rangeSensitivity.moves[3].element = "Ni"
 seed0.seven.rangeSensitivity.moves[3].group = "Ni_Ka"
-seed0.seven.rangeSensitivity.moves[3].before = 41181d1688ed1266 395077.63371685741
-seed0.seven.rangeSensitivity.moves[3].sigma = 40854628f221a047 680.76999307890298
-seed0.seven.rangeSensitivity.moves[3].after = 4118173322f5fee2 394700.78414152388
+seed0.seven.rangeSensitivity.moves[3].before = 41181d4f2974e3e8 395091.79048496345
+seed0.seven.rangeSensitivity.moves[3].sigma = 40854841200b2243 681.03179939935978
+seed0.seven.rangeSensitivity.moves[3].after = 4118176908eac35f 394714.25870805042
 seed0.seven.rangeSensitivity.failure = nil
 seed0.seven.unlistedProposal.candidates: array 25
 seed0.seven.unlistedProposal.candidates[0].element = "Rb"
 seed0.seven.unlistedProposal.candidates[0].group = "Rb_La"
 seed0.seven.unlistedProposal.candidates[0].energyKeV = 3ffb1b089a027525 1.6940999999999999
-seed0.seven.unlistedProposal.candidates[0].net = 40d4d7ed3e964985 21343.706945010945
-seed0.seven.unlistedProposal.candidates[0].sigma = 408a4e114f303877 841.7584518210632
-seed0.seven.unlistedProposal.candidates[0].sigmaZero = 4088db46c1a3b1c3 795.40954902540432
-seed0.seven.unlistedProposal.candidates[0].criticalLevel = 4094715441a27797 1308.3322816262714
-seed0.seven.unlistedProposal.candidates[0].detectionLimit = 40a476bd7ea05215 2619.3701067066381
+seed0.seven.unlistedProposal.candidates[0].net = 40d422b9d6bbd99f 20618.903731310387
+seed0.seven.unlistedProposal.candidates[0].sigma = 4089e1d955bc0b11 828.23112055691502
+seed0.seven.unlistedProposal.candidates[0].sigmaZero = 40886e32568091a0 781.77457905239498
+seed0.seven.unlistedProposal.candidates[0].criticalLevel = 4094179e77425bc4 1285.9047518127927
+seed0.seven.unlistedProposal.candidates[0].detectionLimit = 40a41d07b4403642 2574.5150470796807
 seed0.seven.unlistedProposal.candidates[0].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[0].conflicts[0].id = "sum-Ge+O sum-Rb"
 seed0.seven.unlistedProposal.candidates[0].conflicts[0].kind = .sumPeak
@@ -1576,11 +1576,11 @@ seed0.seven.unlistedProposal.candidates[0].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[1].element = "Pt"
 seed0.seven.unlistedProposal.candidates[1].group = "Pt_Ma"
 seed0.seven.unlistedProposal.candidates[1].energyKeV = 4000676c8b439581 2.0505
-seed0.seven.unlistedProposal.candidates[1].net = 4089b74657d6322e 822.90934722271572
-seed0.seven.unlistedProposal.candidates[1].sigma = 405b4b31805b5ddc 109.17489632532619
-seed0.seven.unlistedProposal.candidates[1].sigmaZero = 405a8bdb402606e4 106.18525699342314
-seed0.seven.unlistedProposal.candidates[1].criticalLevel = 4065d51835483a9c 174.65920509440627
-seed0.seven.unlistedProposal.candidates[1].detectionLimit = 407600621d370e8e 352.02395364290794
+seed0.seven.unlistedProposal.candidates[1].net = 408f71c5e90752aa 1006.2216358730414
+seed0.seven.unlistedProposal.candidates[1].sigma = 405c68fddc415b5a 113.64049440748695
+seed0.seven.unlistedProposal.candidates[1].sigmaZero = 405b8328f6cc536e 110.04937524751378
+seed0.seven.unlistedProposal.candidates[1].criticalLevel = 4066a07bd0657ede 181.01511401961665
+seed0.seven.unlistedProposal.candidates[1].detectionLimit = 4076cbc5b85452d0 364.73577149332868
 seed0.seven.unlistedProposal.candidates[1].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[1].conflicts[0].id = "sum-Cu+Ga sum-Pt"
 seed0.seven.unlistedProposal.candidates[1].conflicts[0].kind = .sumPeak
@@ -1597,17 +1597,17 @@ seed0.seven.unlistedProposal.candidates[1].conflicts[0].remedy = "Acquire two sp
 seed0.seven.unlistedProposal.candidates[1].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[1].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[1].misfit = 3ff0000000000000 1
-seed0.seven.unlistedProposal.candidates[1].familyNote = "Pt Lα (9.44 keV) has a residual peak of -0.0 σ, below the 3 σ its Mα (2.05 keV) needs: not Pt."
+seed0.seven.unlistedProposal.candidates[1].familyNote = "Pt Lα (9.44 keV) has a residual peak of 0.0 σ, below the 3 σ its Mα (2.05 keV) needs: not Pt."
 seed0.seven.unlistedProposal.candidates[1].possibleReason = nil
 seed0.seven.unlistedProposal.candidates[1].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[2].element = "Au"
 seed0.seven.unlistedProposal.candidates[2].group = "Au_Ma"
 seed0.seven.unlistedProposal.candidates[2].energyKeV = 4000fbb2fec56d5d 2.1229
-seed0.seven.unlistedProposal.candidates[2].net = 40888c2b9cdb4962 785.52129527394959
-seed0.seven.unlistedProposal.candidates[2].sigma = 405ab604ab889495 106.84403503740243
-seed0.seven.unlistedProposal.candidates[2].sigmaZero = 4059ff706a8ec37a 103.99123634282833
-seed0.seven.unlistedProposal.candidates[2].criticalLevel = 4065619c9155a5c7 171.05036226966897
-seed0.seven.unlistedProposal.candidates[2].detectionLimit = 40758ce6794479b9 344.80626799343332
+seed0.seven.unlistedProposal.candidates[2].net = 408e0e93dbc29479 961.82219650283434
+seed0.seven.unlistedProposal.candidates[2].sigma = 405ba69406a4019e 110.60278478637926
+seed0.seven.unlistedProposal.candidates[2].sigmaZero = 405ac84c81b53063 107.12966959661712
+seed0.seven.unlistedProposal.candidates[2].criticalLevel = 406606cdd42e79e4 176.21262559010859
+seed0.seven.unlistedProposal.candidates[2].detectionLimit = 40763217bc1d4dd6 355.13079463431256
 seed0.seven.unlistedProposal.candidates[2].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[2].conflicts[0].id = "sum-Cu+Ge sum-Au"
 seed0.seven.unlistedProposal.candidates[2].conflicts[0].kind = .sumPeak
@@ -1630,11 +1630,11 @@ seed0.seven.unlistedProposal.candidates[2].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[3].element = "Zr"
 seed0.seven.unlistedProposal.candidates[3].group = "Zr_La"
 seed0.seven.unlistedProposal.candidates[3].energyKeV = 400056a161e4f766 2.0423
-seed0.seven.unlistedProposal.candidates[3].net = 4084af11559b7bf9 661.88346406433186
-seed0.seven.unlistedProposal.candidates[3].sigma = 405ea63a9f71a337 122.5973280534498
-seed0.seven.unlistedProposal.candidates[3].sigmaZero = 405e01cd309933f3 120.02814879380439
-seed0.seven.unlistedProposal.candidates[3].criticalLevel = 4068adb8344ec623 197.42873587976018
-seed0.seven.unlistedProposal.candidates[3].detectionLimit = 4078d9021c3d9a15 397.56301521361576
+seed0.seven.unlistedProposal.candidates[3].net = 408aa3784ee57e0f 852.4337442330451
+seed0.seven.unlistedProposal.candidates[3].sigma = 405fbed21bf62f4a 126.98157404939153
+seed0.seven.unlistedProposal.candidates[3].sigmaZero = 405eed6c1f28ed0d 123.70972422596624
+seed0.seven.unlistedProposal.candidates[3].criticalLevel = 40696f801c7be9d1 203.48438858224702
+seed0.seven.unlistedProposal.candidates[3].detectionLimit = 40799aca046abdc3 409.67432061858943
 seed0.seven.unlistedProposal.candidates[3].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[3].conflicts[0].id = "sum-Cu+Ga sum-Zr"
 seed0.seven.unlistedProposal.candidates[3].conflicts[0].kind = .sumPeak
@@ -1657,11 +1657,11 @@ seed0.seven.unlistedProposal.candidates[3].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[4].element = "Nb"
 seed0.seven.unlistedProposal.candidates[4].group = "Nb_La"
 seed0.seven.unlistedProposal.candidates[4].energyKeV = 400153c36113404f 2.1659000000000002
-seed0.seven.unlistedProposal.candidates[4].net = 40836e5d7ad8a83a 621.79564446700465
-seed0.seven.unlistedProposal.candidates[4].sigma = 405e7a033a57c120 121.90644701547399
-seed0.seven.unlistedProposal.candidates[4].sigmaZero = 405dd976b766ce3c 119.39787087478265
-seed0.seven.unlistedProposal.candidates[4].criticalLevel = 40688c8b6f899aad 196.39202095866986
-seed0.seven.unlistedProposal.candidates[4].detectionLimit = 4078b7d557786e9f 395.48958537143511
+seed0.seven.unlistedProposal.candidates[4].net = 4089618ff03dcb88 812.19528244283083
+seed0.seven.unlistedProposal.candidates[4].sigma = 405f5cfb76f6d976 125.45284818750756
+seed0.seven.unlistedProposal.candidates[4].sigmaZero = 405e89ee3a7c9104 122.15516531147665
+seed0.seven.unlistedProposal.candidates[4].criticalLevel = 40691dacfcf533d6 200.92736671343908
+seed0.seven.unlistedProposal.candidates[4].detectionLimit = 407948f6e4e407c8 404.56027688097356
 seed0.seven.unlistedProposal.candidates[4].conflicts: array 2
 seed0.seven.unlistedProposal.candidates[4].conflicts[0].id = "sum-Cu+Ge sum-Nb"
 seed0.seven.unlistedProposal.candidates[4].conflicts[0].kind = .sumPeak
@@ -1695,11 +1695,11 @@ seed0.seven.unlistedProposal.candidates[4].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[5].element = "Ta"
 seed0.seven.unlistedProposal.candidates[5].group = "Ta_Ma"
 seed0.seven.unlistedProposal.candidates[5].energyKeV = 3ffb5c91d14e3bcd 1.7101
-seed0.seven.unlistedProposal.candidates[5].net = 40c2cbe545fa5842 9623.7911980563113
-seed0.seven.unlistedProposal.candidates[5].sigma = 409ef2226c9578c6 1980.5336173396076
-seed0.seven.unlistedProposal.candidates[5].sigmaZero = 409ea85ba8b9edf6 1962.0895108272066
-seed0.seven.unlistedProposal.candidates[5].criticalLevel = 40a936b339877648 3227.3500482875716
-seed0.seven.unlistedProposal.candidates[5].detectionLimit = 40b93967d8066387 6457.4056400292384
+seed0.seven.unlistedProposal.candidates[5].net = 40c5923dbb31406d 11044.482275158365
+seed0.seven.unlistedProposal.candidates[5].sigma = 409fa2566c2cbeb2 2024.5843970290557
+seed0.seven.unlistedProposal.candidates[5].sigmaZero = 409f4c41236c557d 2003.0636116912058
+seed0.seven.unlistedProposal.candidates[5].criticalLevel = 40a9bd7e2e43329d 3294.7464467047962
+seed0.seven.unlistedProposal.candidates[5].detectionLimit = 40b9c032ccc21fdc 6592.1984368636877
 seed0.seven.unlistedProposal.candidates[5].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[5].conflicts[0].id = "sum-Ge+O sum-Ta"
 seed0.seven.unlistedProposal.candidates[5].conflicts[0].kind = .sumPeak
@@ -1722,143 +1722,143 @@ seed0.seven.unlistedProposal.candidates[5].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[6].element = "Er"
 seed0.seven.unlistedProposal.candidates[6].group = "Er_La"
 seed0.seven.unlistedProposal.candidates[6].energyKeV = 401bcb5dcc63f141 6.9485999999999999
-seed0.seven.unlistedProposal.candidates[6].net = 40690c45820451e4 200.38348484843948
-seed0.seven.unlistedProposal.candidates[6].sigma = 4050d790e403c3c2 67.368218425442166
-seed0.seven.unlistedProposal.candidates[6].sigmaZero = 405083935079f135 66.055866355022616
-seed0.seven.unlistedProposal.candidates[6].criticalLevel = 405b29be28954dc9 108.65223135548071
-seed0.seven.unlistedProposal.candidates[6].detectionLimit = 406b8051f872f5ae 220.01000616505684
+seed0.seven.unlistedProposal.candidates[6].net = 40668478708ea5d8 180.139702108964
+seed0.seven.unlistedProposal.candidates[6].sigma = 4050d985be5f1e75 67.398788063897726
+seed0.seven.unlistedProposal.candidates[6].sigmaZero = 40508e12925f8d6a 66.219883530915155
+seed0.seven.unlistedProposal.candidates[6].criticalLevel = 405b3b024dba632d 108.92201560212989
+seed0.seven.unlistedProposal.candidates[6].detectionLimit = 406b91961d980b12 220.5495746583552
 seed0.seven.unlistedProposal.candidates[6].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[6].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[6].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[6].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[6].familyNote = nil
-seed0.seven.unlistedProposal.candidates[6].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[6].possibleReason = "Adding it improves the fit by 15, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[6].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[7].element = "Hf"
-seed0.seven.unlistedProposal.candidates[7].group = "Hf_La"
-seed0.seven.unlistedProposal.candidates[7].energyKeV = 401f989374bc6a7f 7.899
-seed0.seven.unlistedProposal.candidates[7].net = 406dfdecd0b0a562 239.93515810490777
-seed0.seven.unlistedProposal.candidates[7].sigma = 4056693ff2638a52 89.644528004844034
-seed0.seven.unlistedProposal.candidates[7].sigmaZero = 405611601fc68a6b 88.271491950881384
-seed0.seven.unlistedProposal.candidates[7].criticalLevel = 40622632a8244504 145.19368369182496
-seed0.seven.unlistedProposal.candidates[7].detectionLimit = 4072517c901318f6 293.09291083774531
+seed0.seven.unlistedProposal.candidates[7].element = "Lu"
+seed0.seven.unlistedProposal.candidates[7].group = "Lu_La"
+seed0.seven.unlistedProposal.candidates[7].energyKeV = 401e9f559b3d07c8 7.6555999999999997
+seed0.seven.unlistedProposal.candidates[7].net = 406c36cde028f47f 225.71263130187069
+seed0.seven.unlistedProposal.candidates[7].sigma = 405620d457c4dd50 88.512960378885737
+seed0.seven.unlistedProposal.candidates[7].sigmaZero = 4055cc312102b5e4 87.19049859299372
+seed0.seven.unlistedProposal.candidates[7].criticalLevel = 4061ed4ca8d38701 143.41560784639299
+seed0.seven.unlistedProposal.candidates[7].detectionLimit = 4072189690c25af3 289.53675914688137
 seed0.seven.unlistedProposal.candidates[7].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[7].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[7].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[7].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[7].familyNote = nil
-seed0.seven.unlistedProposal.candidates[7].possibleReason = "Adding it improves the fit by 15, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[7].possibleReason = "Adding it improves the fit by 34, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[7].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[8].element = "Lu"
-seed0.seven.unlistedProposal.candidates[8].group = "Lu_La"
-seed0.seven.unlistedProposal.candidates[8].energyKeV = 401e9f559b3d07c8 7.6555999999999997
-seed0.seven.unlistedProposal.candidates[8].net = 406c83bbbf294277 228.11666830118676
-seed0.seven.unlistedProposal.candidates[8].sigma = 405620385a2af20b 88.503439466418214
-seed0.seven.unlistedProposal.candidates[8].sigmaZero = 4055ca9ffaa5f660 87.166014349053057
-seed0.seven.unlistedProposal.candidates[8].criticalLevel = 4061ec02be3aa870 143.37533484894402
-seed0.seven.unlistedProposal.candidates[8].detectionLimit = 4072174ca6297c62 289.45621315198343
+seed0.seven.unlistedProposal.candidates[8].element = "Hf"
+seed0.seven.unlistedProposal.candidates[8].group = "Hf_La"
+seed0.seven.unlistedProposal.candidates[8].energyKeV = 401f989374bc6a7f 7.899
+seed0.seven.unlistedProposal.candidates[8].net = 406c76f852bbccdf 227.71781288795225
+seed0.seven.unlistedProposal.candidates[8].sigma = 40566f4c5a99587d 89.739035272361392
+seed0.seven.unlistedProposal.candidates[8].sigmaZero = 40561c057d388750 88.437835030749966
+seed0.seven.unlistedProposal.candidates[8].criticalLevel = 40622ef411f04b65 145.46729371006509
+seed0.seven.unlistedProposal.candidates[8].detectionLimit = 40725a3df9df1f57 293.64013087422558
 seed0.seven.unlistedProposal.candidates[8].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[8].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[8].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[8].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[8].familyNote = nil
-seed0.seven.unlistedProposal.candidates[8].possibleReason = "Adding it improves the fit by 68, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[8].possibleReason = "Adding it improves the fit by 14, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[8].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[9].element = "Hg"
 seed0.seven.unlistedProposal.candidates[9].group = "Hg_La"
 seed0.seven.unlistedProposal.candidates[9].energyKeV = 4023fa5e353f7cee 9.9890000000000008
-seed0.seven.unlistedProposal.candidates[9].net = 40625b392de83bdf 146.85072989805391
-seed0.seven.unlistedProposal.candidates[9].sigma = 4054cc253f40e028 83.189773381571854
-seed0.seven.unlistedProposal.candidates[9].sigmaZero = 40547047da7702d8 81.754385582181726
-seed0.seven.unlistedProposal.candidates[9].criticalLevel = 4060cf2afd1b7129 134.47399764404079
-seed0.seven.unlistedProposal.candidates[9].detectionLimit = 4070fa74e50a451b 271.65353874217698
+seed0.seven.unlistedProposal.candidates[9].net = 4063d86a2e91aa27 158.76296165895585
+seed0.seven.unlistedProposal.candidates[9].sigma = 4054ce959b2a67b5 83.227881232653843
+seed0.seven.unlistedProposal.candidates[9].sigmaZero = 40546b39ac4df9f7 81.675395084523061
+seed0.seven.unlistedProposal.candidates[9].criticalLevel = 4060cb029ebf6f77 134.34406983747223
+seed0.seven.unlistedProposal.candidates[9].detectionLimit = 4070f64c86ae4369 271.39368312903986
 seed0.seven.unlistedProposal.candidates[9].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[9].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[9].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[9].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[9].familyNote = nil
-seed0.seven.unlistedProposal.candidates[9].possibleReason = "Adding it improves the fit by 7, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[9].possibleReason = "Adding it improves the fit by 24, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[9].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[10].element = "Zn"
-seed0.seven.unlistedProposal.candidates[10].group = "Zn_Ka"
-seed0.seven.unlistedProposal.candidates[10].energyKeV = 4021471de69ad42c 8.6388999999999996
-seed0.seven.unlistedProposal.candidates[10].net = 4058adffc6a3b9df 98.718736324204187
-seed0.seven.unlistedProposal.candidates[10].sigma = 4051a18be7c96cbd 70.524164149001948
-seed0.seven.unlistedProposal.candidates[10].sigmaZero = 40516146a14e8a4a 69.519935919474989
-seed0.seven.unlistedProposal.candidates[10].criticalLevel = 405c9668587146ea 114.3501187425824
-seed0.seven.unlistedProposal.candidates[10].detectionLimit = 406cecfc284eeecf 231.40578093926021
-seed0.seven.unlistedProposal.candidates[10].conflicts: array 1
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].id = "sum-Ge+Ni sum-Zn"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].kind = .sumPeak
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].element = "Zn"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].line = "Zn_Ka"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].energiesKeV: n 2 sum 40314e147ae147ae 17.305 fnv 833ac65270fd23ba
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].energiesKeV[0] = 4021550b0f27bb30 8.6661000000000001
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].energiesKeV[1] = 4021471de69ad42c 8.6388999999999996
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].requires: array 2
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].requires[0] = "Ge"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].requires[1] = "Ni"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].question = "Ge+Ni sum peak (8.666 keV) or Zn Kα (8.639 keV)?"
-seed0.seven.unlistedProposal.candidates[10].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
+seed0.seven.unlistedProposal.candidates[10].element = "Se"
+seed0.seven.unlistedProposal.candidates[10].group = "Se_Ka"
+seed0.seven.unlistedProposal.candidates[10].energyKeV = 402671a9fbe76c8b 11.222
+seed0.seven.unlistedProposal.candidates[10].net = 40541f07950f5483 80.484837784739327
+seed0.seven.unlistedProposal.candidates[10].sigma = 404d2e09ff5b213f 58.359680099007612
+seed0.seven.unlistedProposal.candidates[10].sigmaZero = 404cb9f9a7649266 57.452931331736906
+seed0.seven.unlistedProposal.candidates[10].criticalLevel = 4057a01b3cf24f1c 94.501662480001357
+seed0.seven.unlistedProposal.candidates[10].detectionLimit = 4067f6af0ccff701 191.70886841409813
+seed0.seven.unlistedProposal.candidates[10].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[10].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[10].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[10].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[10].familyNote = nil
-seed0.seven.unlistedProposal.candidates[10].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[10].possibleReason = "Adding it improves the fit by 12, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[10].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[11].element = "Tm"
-seed0.seven.unlistedProposal.candidates[11].group = "Tm_La"
-seed0.seven.unlistedProposal.candidates[11].energyKeV = 401cb8a0902de00d 7.1802999999999999
-seed0.seven.unlistedProposal.candidates[11].net = 405963c5d3a362e9 101.55894938426685
-seed0.seven.unlistedProposal.candidates[11].sigma = 40525f802b254fd9 73.492197786748321
-seed0.seven.unlistedProposal.candidates[11].sigmaZero = 40522836932d256f 72.628330988014326
-seed0.seven.unlistedProposal.candidates[11].criticalLevel = 405ddda15c361e5c 119.46297364506739
-seed0.seven.unlistedProposal.candidates[11].detectionLimit = 406e34352c13c641 241.63149074423021
-seed0.seven.unlistedProposal.candidates[11].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
+seed0.seven.unlistedProposal.candidates[11].element = "Zn"
+seed0.seven.unlistedProposal.candidates[11].group = "Zn_Ka"
+seed0.seven.unlistedProposal.candidates[11].energyKeV = 4021471de69ad42c 8.6388999999999996
+seed0.seven.unlistedProposal.candidates[11].net = 4058265f25439b9e 96.599557224295921
+seed0.seven.unlistedProposal.candidates[11].sigma = 4051a6cb4531b50b 70.606156633894145
+seed0.seven.unlistedProposal.candidates[11].sigmaZero = 405167f6f3527d4f 69.624447660976543
+seed0.seven.unlistedProposal.candidates[11].criticalLevel = 405ca168dca2788e 114.52202525965023
+seed0.seven.unlistedProposal.candidates[11].detectionLimit = 406cf7fcac802073 231.74959397339589
+seed0.seven.unlistedProposal.candidates[11].conflicts: array 1
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].id = "sum-Ge+Ni sum-Zn"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].kind = .sumPeak
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].element = "Zn"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].line = "Zn_Ka"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].energiesKeV: n 2 sum 40314e147ae147ae 17.305 fnv 833ac65270fd23ba
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].energiesKeV[0] = 4021550b0f27bb30 8.6661000000000001
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].energiesKeV[1] = 4021471de69ad42c 8.6388999999999996
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].requires: array 2
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].requires[0] = "Ge"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].requires[1] = "Ni"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].question = "Ge+Ni sum peak (8.666 keV) or Zn Kα (8.639 keV)?"
+seed0.seven.unlistedProposal.candidates[11].conflicts[0].remedy = "Acquire two spectrum images at different beam currents: a sum peak scales with the square of the count rate, an element does not."
 seed0.seven.unlistedProposal.candidates[11].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[11].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[11].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[11].familyNote = nil
-seed0.seven.unlistedProposal.candidates[11].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[11].possibleReason = "Adding it improves the fit by 8, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[11].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[12].element = "Dy"
-seed0.seven.unlistedProposal.candidates[12].group = "Dy_La"
-seed0.seven.unlistedProposal.candidates[12].energyKeV = 4019fb15b573eab3 6.4951999999999996
-seed0.seven.unlistedProposal.candidates[12].net = 4059af13533c6f65 102.73555451299542
-seed0.seven.unlistedProposal.candidates[12].sigma = 4053571a88473915 77.360994405320824
-seed0.seven.unlistedProposal.candidates[12].sigmaZero = 40532977c64c3967 76.647935461461756
-seed0.seven.unlistedProposal.candidates[12].criticalLevel = 405f84c6d060c598 126.07463464212776
-seed0.seven.unlistedProposal.candidates[12].detectionLimit = 406fdb5aa03e6d7d 254.85481273835094
+seed0.seven.unlistedProposal.candidates[12].element = "Tm"
+seed0.seven.unlistedProposal.candidates[12].group = "Tm_La"
+seed0.seven.unlistedProposal.candidates[12].energyKeV = 401cb8a0902de00d 7.1802999999999999
+seed0.seven.unlistedProposal.candidates[12].net = 40577d6e0a251727 93.959841285916454
+seed0.seven.unlistedProposal.candidates[12].sigma = 40525fd6c8a63377 73.497484361940096
+seed0.seven.unlistedProposal.candidates[12].sigmaZero = 40522cb5f97c32a1 72.698606845175632
+seed0.seven.unlistedProposal.candidates[12].criticalLevel = 405de5073e7c1511 119.57856714360629
+seed0.seven.unlistedProposal.candidates[12].detectionLimit = 406e3b9b0e59bcf6 241.862677741308
 seed0.seven.unlistedProposal.candidates[12].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[12].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[12].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[12].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[12].familyNote = nil
-seed0.seven.unlistedProposal.candidates[12].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[12].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[12].unconfirmable = false
-seed0.seven.unlistedProposal.candidates[13].element = "Se"
-seed0.seven.unlistedProposal.candidates[13].group = "Se_Ka"
-seed0.seven.unlistedProposal.candidates[13].energyKeV = 402671a9fbe76c8b 11.222
-seed0.seven.unlistedProposal.candidates[13].net = 4052889cf8d980d3 74.134580814748276
-seed0.seven.unlistedProposal.candidates[13].sigma = 404d2a4d9f4ca227 58.330493843477875
-seed0.seven.unlistedProposal.candidates[13].sigmaZero = 404cbf50dbbb2891 57.494655100236862
-seed0.seven.unlistedProposal.candidates[13].criticalLevel = 4057a47fa9e62c32 94.570291971948592
-seed0.seven.unlistedProposal.candidates[13].detectionLimit = 4067fb1379c3d417 191.8461273979926
+seed0.seven.unlistedProposal.candidates[13].element = "Dy"
+seed0.seven.unlistedProposal.candidates[13].group = "Dy_La"
+seed0.seven.unlistedProposal.candidates[13].energyKeV = 4019fb15b573eab3 6.4951999999999996
+seed0.seven.unlistedProposal.candidates[13].net = 40585e8de308379a 97.477410085701564
+seed0.seven.unlistedProposal.candidates[13].sigma = 4053577b347db56c 77.366894839060194
+seed0.seven.unlistedProposal.candidates[13].sigmaZero = 40532c3146d04f45 76.690507605960264
+seed0.seven.unlistedProposal.candidates[13].criticalLevel = 405f89421a4a5269 126.14465958841323
+seed0.seven.unlistedProposal.candidates[13].detectionLimit = 406fdfd5ea27fa4e 254.99486263092189
 seed0.seven.unlistedProposal.candidates[13].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[13].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[13].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[13].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[13].familyNote = nil
-seed0.seven.unlistedProposal.candidates[13].possibleReason = "Adding it improves the fit by 7, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[13].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[13].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[14].element = "Re"
 seed0.seven.unlistedProposal.candidates[14].group = "Re_La"
 seed0.seven.unlistedProposal.candidates[14].energyKeV = 40214e075f6fd220 8.6524000000000001
-seed0.seven.unlistedProposal.candidates[14].net = 404c1d184badb0fd 56.227303943453059
-seed0.seven.unlistedProposal.candidates[14].sigma = 4050c05a524b0276 67.005512784244132
-seed0.seven.unlistedProposal.candidates[14].sigmaZero = 40509ee250c7ce90 66.48256320488349
-seed0.seven.unlistedProposal.candidates[14].criticalLevel = 405b56a9550a4e2f 109.35408521658313
-seed0.seven.unlistedProposal.candidates[14].detectionLimit = 406bad3d24e7f614 221.41371388726168
+seed0.seven.unlistedProposal.candidates[14].net = 404fabddc85e4d1e 63.342705770535972
+seed0.seven.unlistedProposal.candidates[14].sigma = 4050cb49bc5c3f6c 67.176375475011525
+seed0.seven.unlistedProposal.candidates[14].sigmaZero = 4050a59555c44ac5 66.587239686671708
+seed0.seven.unlistedProposal.candidates[14].criticalLevel = 405b61ae49c73fc8 109.526262707309
+seed0.seven.unlistedProposal.candidates[14].detectionLimit = 406bb84219a4e7ad 221.75806886871342
 seed0.seven.unlistedProposal.candidates[14].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[14].conflicts[0].id = "sum-Ge+Ni sum-Re"
 seed0.seven.unlistedProposal.candidates[14].conflicts[0].kind = .sumPeak
@@ -1876,31 +1876,31 @@ seed0.seven.unlistedProposal.candidates[14].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[14].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[14].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[14].familyNote = nil
-seed0.seven.unlistedProposal.candidates[14].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[14].possibleReason = "Adding it improves the fit by 3, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[14].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[15].element = "Ho"
 seed0.seven.unlistedProposal.candidates[15].group = "Ho_La"
 seed0.seven.unlistedProposal.candidates[15].energyKeV = 401ae0f9096bb98c 6.7196999999999996
-seed0.seven.unlistedProposal.candidates[15].net = 404d906641473c64 59.128120574744372
-seed0.seven.unlistedProposal.candidates[15].sigma = 40526c59489f3399 73.692949443311946
-seed0.seven.unlistedProposal.candidates[15].sigmaZero = 40524e4858922d5c 73.223165648223073
-seed0.seven.unlistedProposal.candidates[15].criticalLevel = 405e1c3fba230e6b 120.44138959334821
-seed0.seven.unlistedProposal.candidates[15].detectionLimit = 406e72d38a00b650 243.58832264079183
+seed0.seven.unlistedProposal.candidates[15].net = 4047d9f9c00bcd8a 47.702934270632866
+seed0.seven.unlistedProposal.candidates[15].sigma = 40526c59846386df 73.692963692850284
+seed0.seven.unlistedProposal.candidates[15].sigmaZero = 4052541a61f65c84 73.314110270106596
+seed0.seven.unlistedProposal.candidates[15].criticalLevel = 405e25d29e8d4220 120.59098018450504
+seed0.seven.unlistedProposal.candidates[15].detectionLimit = 406e7c666e6aea05 243.8875038231055
 seed0.seven.unlistedProposal.candidates[15].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[15].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[15].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[15].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[15].familyNote = nil
-seed0.seven.unlistedProposal.candidates[15].possibleReason = "Adding it improves the fit by 6, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[15].possibleReason = "Adding it improves the fit by 2, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[15].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[16].element = "Tb"
 seed0.seven.unlistedProposal.candidates[16].group = "Tb_La"
 seed0.seven.unlistedProposal.candidates[16].energyKeV = 40191758e219652c 6.2728000000000002
-seed0.seven.unlistedProposal.candidates[16].net = 404a7223dc8ad098 52.891719405918764
-seed0.seven.unlistedProposal.candidates[16].sigma = 405c05046d913217 112.07839526347412
-seed0.seven.unlistedProposal.candidates[16].sigmaZero = 405bed8b77f8bb3f 111.71163749017886
-seed0.seven.unlistedProposal.candidates[16].criticalLevel = 4066f7fa336c3a25 183.7492920984088
-seed0.seven.unlistedProposal.candidates[16].detectionLimit = 407723441b5b0e17 370.20412765091299
+seed0.seven.unlistedProposal.candidates[16].net = 40433d05c7d03581 38.476738907494116
+seed0.seven.unlistedProposal.candidates[16].sigma = 405c05e25b34d7ce 112.09194069061707
+seed0.seven.unlistedProposal.candidates[16].sigmaZero = 405bf4d14ae954c1 111.8252742079376
+seed0.seven.unlistedProposal.candidates[16].criticalLevel = 4066fdf56a32b790 183.93620786576912
+seed0.seven.unlistedProposal.candidates[16].detectionLimit = 4077293f52218b82 370.57795918563363
 seed0.seven.unlistedProposal.candidates[16].conflicts: array 2
 seed0.seven.unlistedProposal.candidates[16].conflicts[0].id = "sum-Si+Ti sum-Tb"
 seed0.seven.unlistedProposal.candidates[16].conflicts[0].kind = .sumPeak
@@ -1930,31 +1930,31 @@ seed0.seven.unlistedProposal.candidates[16].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[16].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[16].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[16].familyNote = nil
-seed0.seven.unlistedProposal.candidates[16].possibleReason = "Adding it improves the fit by -0, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[16].possibleReason = "Adding it improves the fit by 1, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[16].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[17].element = "Bi"
 seed0.seven.unlistedProposal.candidates[17].group = "Bi_La"
 seed0.seven.unlistedProposal.candidates[17].energyKeV = 4025ad916872b021 10.839
 seed0.seven.unlistedProposal.candidates[17].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[17].sigma = 404df0828b0d7801 59.87898386151938
-seed0.seven.unlistedProposal.candidates[17].sigmaZero = 404deffec4f25ed0 59.874962442726996
-seed0.seven.unlistedProposal.candidates[17].criticalLevel = 40589f133cb08b35 98.485549137502701
-seed0.seven.unlistedProposal.candidates[17].detectionLimit = 4068f5a70c8e331a 199.67664172910082
+seed0.seven.unlistedProposal.candidates[17].sigma = 404debcf90ae8f74 59.842271886095574
+seed0.seven.unlistedProposal.candidates[17].sigmaZero = 404deb4232e53406 59.837957727351792
+seed0.seven.unlistedProposal.candidates[17].criticalLevel = 40589b2dfc8f8c83 98.42468179720349
+seed0.seven.unlistedProposal.candidates[17].detectionLimit = 4068f1c1cc6d3468 199.5549070485024
 seed0.seven.unlistedProposal.candidates[17].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[17].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[17].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[17].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[17].familyNote = nil
-seed0.seven.unlistedProposal.candidates[17].possibleReason = "Adding it improves the fit by 5, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[17].possibleReason = "Adding it improves the fit by 17, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[17].unconfirmable = false
 seed0.seven.unlistedProposal.candidates[18].element = "Ir"
 seed0.seven.unlistedProposal.candidates[18].group = "Ir_Ma"
 seed0.seven.unlistedProposal.candidates[18].energyKeV = 3fffadab9f559b3d 1.9799
 seed0.seven.unlistedProposal.candidates[18].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[18].sigma = 40612711463bc9fe 137.22085868527932
-seed0.seven.unlistedProposal.candidates[18].sigmaZero = 40612711463bc9fe 137.22085868527932
-seed0.seven.unlistedProposal.candidates[18].criticalLevel = 406c36a9cbe21682 225.70822710187718
-seed0.seven.unlistedProposal.candidates[18].detectionLimit = 407c61f3b3d0ea74 454.12199765784976
+seed0.seven.unlistedProposal.candidates[18].sigma = 40616d0d79ec1ad0 139.40789505113798
+seed0.seven.unlistedProposal.candidates[18].sigmaZero = 40616d0d79ec1ad0 139.40789505113798
+seed0.seven.unlistedProposal.candidates[18].criticalLevel = 406ca9c7537bf18f 229.30558180053455
+seed0.seven.unlistedProposal.candidates[18].detectionLimit = 407cd5113b6ac581 461.3167070551645
 seed0.seven.unlistedProposal.candidates[18].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[18].conflicts[0].id = "sum-Cu+Ga sum-Ir"
 seed0.seven.unlistedProposal.candidates[18].conflicts[0].kind = .sumPeak
@@ -1978,10 +1978,10 @@ seed0.seven.unlistedProposal.candidates[19].element = "Os"
 seed0.seven.unlistedProposal.candidates[19].group = "Os_Ma"
 seed0.seven.unlistedProposal.candidates[19].energyKeV = 3ffe9eecbfb15b57 1.9137999999999999
 seed0.seven.unlistedProposal.candidates[19].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[19].sigma = 40630f145b00f7e6 152.4712348002351
-seed0.seven.unlistedProposal.candidates[19].sigmaZero = 40630f145b00f7e6 152.4712348002351
-seed0.seven.unlistedProposal.candidates[19].criticalLevel = 406f595f236a45cd 250.79286356693629
-seed0.seven.unlistedProposal.candidates[19].detectionLimit = 407f84a90b5919bf 504.29127058796797
+seed0.seven.unlistedProposal.candidates[19].sigma = 40634ecc72faf065 154.46245717059642
+seed0.seven.unlistedProposal.candidates[19].sigmaZero = 40634ecc72faf065 154.46245717059642
+seed0.seven.unlistedProposal.candidates[19].criticalLevel = 406fc22e250ec95e 254.06813290489202
+seed0.seven.unlistedProposal.candidates[19].detectionLimit = 407fed780cfd9d50 510.84180926387944
 seed0.seven.unlistedProposal.candidates[19].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[19].conflicts[0].id = "sum-Cu+Cu sum-Os"
 seed0.seven.unlistedProposal.candidates[19].conflicts[0].kind = .sumPeak
@@ -2004,10 +2004,10 @@ seed0.seven.unlistedProposal.candidates[20].element = "P"
 seed0.seven.unlistedProposal.candidates[20].group = "P_Ka"
 seed0.seven.unlistedProposal.candidates[20].energyKeV = 40001b3d07c84b5e 2.0133000000000001
 seed0.seven.unlistedProposal.candidates[20].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[20].sigma = 406359d7c496242c 154.80758885693047
-seed0.seven.unlistedProposal.candidates[20].sigmaZero = 406359d7af5854e5 154.80757872822065
-seed0.seven.unlistedProposal.candidates[20].criticalLevel = 406fd45888a8388d 254.63580735068936
-seed0.seven.unlistedProposal.candidates[20].detectionLimit = 407fffa270970c7f 511.97715815547411
+seed0.seven.unlistedProposal.candidates[20].sigma = 406386c7aa838ac2 156.21187329952051
+seed0.seven.unlistedProposal.candidates[20].sigmaZero = 406386c77a22e7c4 156.21185023133705
+seed0.seven.unlistedProposal.candidates[20].criticalLevel = 40700f214b45b0b2 256.94562842581502
+seed0.seven.unlistedProposal.candidates[20].detectionLimit = 408024c63f3d1aab 516.59680030572542
 seed0.seven.unlistedProposal.candidates[20].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[20].conflicts[0].id = "sum-Cu+Ga sum-P"
 seed0.seven.unlistedProposal.candidates[20].conflicts[0].kind = .sumPeak
@@ -2031,10 +2031,10 @@ seed0.seven.unlistedProposal.candidates[21].element = "Sr"
 seed0.seven.unlistedProposal.candidates[21].group = "Sr_La"
 seed0.seven.unlistedProposal.candidates[21].energyKeV = 3ffce76c8b439581 1.8065
 seed0.seven.unlistedProposal.candidates[21].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[21].sigma = 40797ce6152bfcd1 407.80617253477709
-seed0.seven.unlistedProposal.candidates[21].sigmaZero = 40797ce6152bfcd1 407.80617253477709
-seed0.seven.unlistedProposal.candidates[21].criticalLevel = 4084f6406f246ac1 670.78146198702609
-seed0.seven.unlistedProposal.candidates[21].detectionLimit = 40950112e9201fbe 1344.2684674281477
+seed0.seven.unlistedProposal.candidates[21].sigma = 4079809c44283caf 408.03815093724819
+seed0.seven.unlistedProposal.candidates[21].sigmaZero = 4079809c44283caf 408.03815093724819
+seed0.seven.unlistedProposal.candidates[21].criticalLevel = 4084f94de3fc3cca 671.16303250370515
+seed0.seven.unlistedProposal.candidates[21].detectionLimit = 409504205df7f1c7 1345.0316084615058
 seed0.seven.unlistedProposal.candidates[21].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[21].conflicts[0].id = "sum-Cu+Cu sum-Sr"
 seed0.seven.unlistedProposal.candidates[21].conflicts[0].kind = .sumPeak
@@ -2057,10 +2057,10 @@ seed0.seven.unlistedProposal.candidates[22].element = "W"
 seed0.seven.unlistedProposal.candidates[22].group = "W_La"
 seed0.seven.unlistedProposal.candidates[22].energyKeV = 4020cb923a29c77a 8.3976000000000006
 seed0.seven.unlistedProposal.candidates[22].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[22].sigma = 405a4dd47cd162cb 105.21609421203463
-seed0.seven.unlistedProposal.candidates[22].sigmaZero = 405a4dd47cd162cb 105.21609421203463
-seed0.seven.unlistedProposal.candidates[22].criticalLevel = 4065a21516717824 173.06507417833302
-seed0.seven.unlistedProposal.candidates[22].detectionLimit = 4075cd5efe604c16 348.83569181076143
+seed0.seven.unlistedProposal.candidates[22].sigma = 405a4f6983585806 105.24081500651673
+seed0.seven.unlistedProposal.candidates[22].sigmaZero = 405a4f6983585806 105.24081500651673
+seed0.seven.unlistedProposal.candidates[22].criticalLevel = 4065a3623105fcc1 173.105736266798
+seed0.seven.unlistedProposal.candidates[22].detectionLimit = 4075ceac18f4d0b3 348.9170159876914
 seed0.seven.unlistedProposal.candidates[22].conflicts: array 1
 seed0.seven.unlistedProposal.candidates[22].conflicts[0].id = "sum-Cu+Ni sum-W"
 seed0.seven.unlistedProposal.candidates[22].conflicts[0].kind = .sumPeak
@@ -2084,10 +2084,10 @@ seed0.seven.unlistedProposal.candidates[23].element = "Y"
 seed0.seven.unlistedProposal.candidates[23].group = "Y_La"
 seed0.seven.unlistedProposal.candidates[23].energyKeV = 3ffec2f837b4a234 1.9226000000000001
 seed0.seven.unlistedProposal.candidates[23].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[23].sigma = 4064dbecd138134d 166.87265835716462
-seed0.seven.unlistedProposal.candidates[23].sigmaZero = 4064dbecca0a9b86 166.87265493461399
-seed0.seven.unlistedProposal.candidates[23].criticalLevel = 407127b28d381300 274.48109170822136
-seed0.seven.unlistedProposal.candidates[23].detectionLimit = 40813d57812f7cf9 551.6677268705381
+seed0.seven.unlistedProposal.candidates[23].sigma = 406514b623932f8f 168.64723376033041
+seed0.seven.unlistedProposal.candidates[23].sigmaZero = 406514b6229788af 168.6472332915923
+seed0.seven.unlistedProposal.candidates[23].criticalLevel = 4071566674675b7a 277.40001335500676
+seed0.seven.unlistedProposal.candidates[23].detectionLimit = 40816c0b685ec573 557.50557016410892
 seed0.seven.unlistedProposal.candidates[23].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[23].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[23].holeRegionNote = nil
@@ -2099,16 +2099,16 @@ seed0.seven.unlistedProposal.candidates[24].element = "Yb"
 seed0.seven.unlistedProposal.candidates[24].group = "Yb_La"
 seed0.seven.unlistedProposal.candidates[24].energyKeV = 401da9c779a6b50b 7.4157999999999999
 seed0.seven.unlistedProposal.candidates[24].net = 0000000000000000 0
-seed0.seven.unlistedProposal.candidates[24].sigma = 406702a2418ce925 184.08230664750695
-seed0.seven.unlistedProposal.candidates[24].sigmaZero = 4067028b7e655b25 184.07952804370976
-seed0.seven.unlistedProposal.candidates[24].criticalLevel = 4072ec8ac512d2ad 302.78387935021129
-seed0.seven.unlistedProposal.candidates[24].detectionLimit = 4083022fb90a3ca6 608.27330215451798
+seed0.seven.unlistedProposal.candidates[24].sigma = 406701fac2dc5a7a 184.06186049497393
+seed0.seven.unlistedProposal.candidates[24].sigmaZero = 406701d702626fbd 184.05749625421404
+seed0.seven.unlistedProposal.candidates[24].criticalLevel = 4072ebf655a7d933 302.74764028135104
+seed0.seven.unlistedProposal.candidates[24].detectionLimit = 4083019b499f432c 608.20082401679747
 seed0.seven.unlistedProposal.candidates[24].conflicts: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.candidates[24].suggestedRole = .fitOnly
 seed0.seven.unlistedProposal.candidates[24].holeRegionNote = nil
 seed0.seven.unlistedProposal.candidates[24].misfit = 3ff0000000000000 1
 seed0.seven.unlistedProposal.candidates[24].familyNote = nil
-seed0.seven.unlistedProposal.candidates[24].possibleReason = "Adding it improves the fit by 61, below the 100 a new line needs."
+seed0.seven.unlistedProposal.candidates[24].possibleReason = "Adding it improves the fit by 13, below the 100 a new line needs."
 seed0.seven.unlistedProposal.candidates[24].unconfirmable = false
 seed0.seven.unlistedProposal.sumPeaks: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedProposal.refused: array 7
@@ -2131,10 +2131,10 @@ seed0.seven.unlistedProposal.currie.beta = 3fa999999999999a 0.050000000000000003
 seed0.seven.unlistedProposal.notes: array 17
 seed0.seven.unlistedProposal.notes[0] = "Lines below 0.45 keV are not tested (a measured limit of the continuum model, not a property of the method)."
 seed0.seven.unlistedProposal.notes[1] = "Identification (validation: none): the residual's peaks at or above 5 σ of its top-hat filter (1.5 × below 1 keV); a candidate joins when Σ(y − μ)²/(μ + (0.01 μ)²) falls by at least 100, 20 % of that at its own lines, with its area at or above Currie L_D (α = β = 0.05, σ₀ from the fit's own variance with it absent) and no line against it; the final fit drops what it does not need (100). Kβ weights from NIST EPQ in this fit."
-seed0.seven.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data; escape peaks: fitted for 7 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 59 candidate fits, 62 fits in all."
+seed0.seven.unlistedProposal.notes[2] = "Fit: least squares, weighted by 1/(y + (0.01 y)²) to decide, least squares, unweighted for the numbers shown; continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data; escape peaks: fitted for 7 line groups above the Si K edge (1.839 keV); reference shapes: none; 10 residual peaks examined, 59 candidate fits, 62 fits in all."
 seed0.seven.unlistedProposal.notes[3] = "Confirmation lines (validation: none): an element nominated by an L or M line needs its K or L alpha line at 3 σ in the residual where the fitted range holds it and the beam is at least 2.0 times its energy; otherwise it is withheld."
 seed0.seven.unlistedProposal.notes[4] = "Confirmation withheld Rb: Rb Kα (13.40 keV) has a residual peak of 0.0 σ, below the 3 σ its Lβ1 (1.75 keV) needs: not Rb."
-seed0.seven.unlistedProposal.notes[5] = "Confirmation withheld Pt: Pt Lα (9.44 keV) has a residual peak of -0.0 σ, below the 3 σ its Mα (2.05 keV) needs: not Pt."
+seed0.seven.unlistedProposal.notes[5] = "Confirmation withheld Pt: Pt Lα (9.44 keV) has a residual peak of 0.0 σ, below the 3 σ its Mα (2.05 keV) needs: not Pt."
 seed0.seven.unlistedProposal.notes[6] = "Confirmation withheld Au: Au Lα (9.71 keV) has a residual peak of 0.0 σ, below the 3 σ its Mα (2.12 keV) needs: not Au."
 seed0.seven.unlistedProposal.notes[7] = "Confirmation withheld Zr: Zr Kα (15.78 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.04 keV) needs: not Zr."
 seed0.seven.unlistedProposal.notes[8] = "Confirmation withheld Nb: Nb Kα (16.62 keV) has a residual peak of 0.0 σ, below the 3 σ its Lα (2.17 keV) needs: not Nb."
@@ -2143,71 +2143,71 @@ seed0.seven.unlistedProposal.notes[10] = "Confirmation withheld Os: Os Lα (8.91
 seed0.seven.unlistedProposal.notes[11] = "Confirmation withheld Sr: Sr Kα (14.16 keV) has a residual peak of 0.8 σ, below the 3 σ its Lα (1.81 keV) needs: not Sr."
 seed0.seven.unlistedProposal.notes[12] = "Confirmation withheld Y: Y Kα (14.96 keV) has a residual peak of 0.3 σ, below the 3 σ its Lβ1 (2.00 keV) needs: not Y."
 seed0.seven.unlistedProposal.notes[13] = "Look-elsewhere: 59 candidates were tested, so about 0.03 chance passes of the area bar alone are expected; the gain and confirmation bars stand beside it."
-seed0.seven.unlistedProposal.notes[14] = "Ga_Ka: Si-escape/parent ratio 12.6 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.seven.unlistedProposal.notes[15] = "Ti_Ka: Si-escape/parent ratio 51.5 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
-seed0.seven.unlistedProposal.notes[16] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+seed0.seven.unlistedProposal.notes[14] = "Ga_Ka: Si-escape/parent ratio 12.3 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.seven.unlistedProposal.notes[15] = "Ti_Ka: Si-escape/parent ratio 64.8 % exceeds 5 %: an unmodelled line near the escape energy is likely (the 5 % flag is a sanity bound; the SDD Si escape is about 1 % at Cu Kα)"
+seed0.seven.unlistedProposal.notes[16] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 seed0.seven.unlistedProposal.passes = 62
 seed0.seven.unlistedProposal.settled = true
-seed0.seven.unlistedProposal.reducedChiSquared = 403209fff8cf623e 18.039062071448136
+seed0.seven.unlistedProposal.reducedChiSquared = 40329f1d19e36268 18.621537797940988
 seed0.seven.unlistedCheck.candidates: array 6
 seed0.seven.unlistedCheck.candidates[0].element = "Rb"
 seed0.seven.unlistedCheck.candidates[0].group = "Rb_La"
-seed0.seven.unlistedCheck.candidates[0].net = 40d4d7ed3e964985 21343.706945010945
-seed0.seven.unlistedCheck.candidates[0].detectionLimit = 40a476bd7ea05215 2619.3701067066381
+seed0.seven.unlistedCheck.candidates[0].net = 40d422b9d6bbd99f 20618.903731310387
+seed0.seven.unlistedCheck.candidates[0].detectionLimit = 40a41d07b4403642 2574.5150470796807
 seed0.seven.unlistedCheck.candidates[0].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[0].besideLine = "Si Kα"
-seed0.seven.unlistedCheck.candidates[0].fractionOfNeighbour = 3f96c70dbf3480f6 0.022243704600556101
+seed0.seven.unlistedCheck.candidates[0].fractionOfNeighbour = 3f96007c6aaad7db 0.021486228952845337
 seed0.seven.unlistedCheck.candidates[1].element = "Pt"
 seed0.seven.unlistedCheck.candidates[1].group = "Pt_Ma"
-seed0.seven.unlistedCheck.candidates[1].net = 4089b74657d6322e 822.90934722271572
-seed0.seven.unlistedCheck.candidates[1].detectionLimit = 407600621d370e8e 352.02395364290794
+seed0.seven.unlistedCheck.candidates[1].net = 408f71c5e90752aa 1006.2216358730414
+seed0.seven.unlistedCheck.candidates[1].detectionLimit = 4076cbc5b85452d0 364.73577149332868
 seed0.seven.unlistedCheck.candidates[1].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[1].besideLine = nil
 seed0.seven.unlistedCheck.candidates[1].fractionOfNeighbour = nil
 seed0.seven.unlistedCheck.candidates[2].element = "Au"
 seed0.seven.unlistedCheck.candidates[2].group = "Au_Ma"
-seed0.seven.unlistedCheck.candidates[2].net = 40888c2b9cdb4962 785.52129527394959
-seed0.seven.unlistedCheck.candidates[2].detectionLimit = 40758ce6794479b9 344.80626799343332
+seed0.seven.unlistedCheck.candidates[2].net = 408e0e93dbc29479 961.82219650283434
+seed0.seven.unlistedCheck.candidates[2].detectionLimit = 40763217bc1d4dd6 355.13079463431256
 seed0.seven.unlistedCheck.candidates[2].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[2].besideLine = nil
 seed0.seven.unlistedCheck.candidates[2].fractionOfNeighbour = nil
 seed0.seven.unlistedCheck.candidates[3].element = "Zr"
 seed0.seven.unlistedCheck.candidates[3].group = "Zr_La"
-seed0.seven.unlistedCheck.candidates[3].net = 4084af11559b7bf9 661.88346406433186
-seed0.seven.unlistedCheck.candidates[3].detectionLimit = 4078d9021c3d9a15 397.56301521361576
+seed0.seven.unlistedCheck.candidates[3].net = 408aa3784ee57e0f 852.4337442330451
+seed0.seven.unlistedCheck.candidates[3].detectionLimit = 40799aca046abdc3 409.67432061858943
 seed0.seven.unlistedCheck.candidates[3].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[3].besideLine = nil
 seed0.seven.unlistedCheck.candidates[3].fractionOfNeighbour = nil
 seed0.seven.unlistedCheck.candidates[4].element = "Nb"
 seed0.seven.unlistedCheck.candidates[4].group = "Nb_La"
-seed0.seven.unlistedCheck.candidates[4].net = 40836e5d7ad8a83a 621.79564446700465
-seed0.seven.unlistedCheck.candidates[4].detectionLimit = 4078b7d557786e9f 395.48958537143511
+seed0.seven.unlistedCheck.candidates[4].net = 4089618ff03dcb88 812.19528244283083
+seed0.seven.unlistedCheck.candidates[4].detectionLimit = 407948f6e4e407c8 404.56027688097356
 seed0.seven.unlistedCheck.candidates[4].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[4].besideLine = nil
 seed0.seven.unlistedCheck.candidates[4].fractionOfNeighbour = nil
 seed0.seven.unlistedCheck.candidates[5].element = "Ta"
 seed0.seven.unlistedCheck.candidates[5].group = "Ta_Ma"
-seed0.seven.unlistedCheck.candidates[5].net = 40c2cbe545fa5842 9623.7911980563113
-seed0.seven.unlistedCheck.candidates[5].detectionLimit = 40b93967d8066387 6457.4056400292384
+seed0.seven.unlistedCheck.candidates[5].net = 40c5923dbb31406d 11044.482275158365
+seed0.seven.unlistedCheck.candidates[5].detectionLimit = 40b9c032ccc21fdc 6592.1984368636877
 seed0.seven.unlistedCheck.candidates[5].sumPeakQuestion = true
 seed0.seven.unlistedCheck.candidates[5].besideLine = "Si Kα"
-seed0.seven.unlistedCheck.candidates[5].fractionOfNeighbour = 3f848a65a7cbd3d7 0.010029596503480604
+seed0.seven.unlistedCheck.candidates[5].fractionOfNeighbour = 3f8792105edce360 0.011509063620552318
 seed0.seven.unlistedCheck.moves: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 seed0.seven.unlistedCheck.largest.element = "Si"
-seed0.seven.unlistedCheck.largest.before = 412d4866703dcc66 959539.21922148461
-seed0.seven.unlistedCheck.largest.after = 412d48f1ab2edda4 959608.83434193255
-seed0.seven.unlistedCheck.largest.sigma = 409169ca6a5c4525 1114.4476713578417
+seed0.seven.unlistedCheck.largest.before = 412d4922df948265 959633.43667991145
+seed0.seven.unlistedCheck.largest.after = 412d49f5a9401473 959738.83056701568
+seed0.seven.unlistedCheck.largest.sigma = 4091a7649735cc27 1129.8482330709319
 seed0.seven.unlistedCheck.failure = nil
 seed0.seven.withholding: array 2
-seed0.seven.withholding[0]: n 4 sum 4059000000000001 100.00000000000001 fnv e1c040887399a739
-seed0.seven.withholding[0][0] = 40259de9a92c31af 10.808423315663132
-seed0.seven.withholding[0][1] = 405047810184783a 65.117248896946791
-seed0.seven.withholding[0][2] = 3fc63997df0c3fe2 0.17363260642059603
-seed0.seven.withholding[0][3] = 4037e693f599edc3 23.900695180969489
-seed0.seven.withholding[1]: n 4 sum 41368b25bcca3e74 1477413.7374609979 fnv 65fca63847e4e8e2
-seed0.seven.withholding[1][0] = 40fd40c04d9ba706 119820.01894726985
-seed0.seven.withholding[1][1] = 412d4866703dcc66 959539.21922148461
-seed0.seven.withholding[1][2] = 40a741bb2cb26e36 2976.865575386003
-seed0.seven.withholding[1][3] = 41181d1688ed1266 395077.63371685741
-seed0.seven.withholding.caveat = "assumes the listed elements only; unlisted: excess beside Si Kα (net 21 344), Pt (net 823), Au (net 786), Zr (net 662), Nb (net 622), excess beside Si Kα (net 9 624); largest move 0.1 σ (Si)"
-seed0.seven.csv-withholding-fnv = 3c09e7f1ae9edf96
+seed0.seven.withholding[0]: n 4 sum 4059000000000002 100.00000000000003 fnv 2daeef71b4ed6271
+seed0.seven.withholding[0][0] = 40259cd594e9aa95 10.806316998981211
+seed0.seven.withholding[0][1] = 405047b2c8d3e566 65.12028713887193
+seed0.seven.withholding[0][2] = 3fc627594dc75baa 0.17307583139219435
+seed0.seven.withholding[0][3] = 4037e67b5fa0066a 23.900320030754678
+seed0.seven.withholding[1]: n 4 sum 41368b778ab357d6 1477495.5417990587 fnv 64bdc84611944fc5
+seed0.seven.withholding[1][0] = 40fd3fad7838d674 119802.84185107966
+seed0.seven.withholding[1][1] = 412d4922df948265 959633.43667991145
+seed0.seven.withholding[1][2] = 40a72ef210a08339 2967.4727831039604
+seed0.seven.withholding[1][3] = 41181d4f2974e3e8 395091.79048496345
+seed0.seven.withholding.caveat = "assumes the listed elements only; unlisted: excess beside Si Kα (net 20 619), Pt (net 1 006), Au (net 962), Zr (net 852), Nb (net 812), excess beside Si Kα (net 11 044); largest move 0.1 σ (Si)"
+seed0.seven.csv-withholding-fnv = 6076117e9f92a9a0
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.arrays.f64 b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.arrays.f64
index 45e9fff..7f55c71 100644
Binary files a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.arrays.f64 and b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.arrays.f64 differ
diff --git a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.txt b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.txt
index 4f528fe..5adc0ad 100644
--- a/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.txt
+++ b/Tests/SpectroCoreTests/Fixtures/spectro-golden/eds-weakline-sim.txt
@@ -30,8 +30,8 @@ level0.quantification.method.fitToKeV = nil
 level0.quantification.rows: array 3
 level0.quantification.rows[0].element = "Al"
 level0.quantification.rows[0].groupID = "Al_Ka"
-level0.quantification.rows[0].net = 4111da88a8533249 292514.16437986918
-level0.quantification.rows[0].sigma = 4088c1a356bccb86 792.20475528236489
+level0.quantification.rows[0].net = 4111cb5d45860c6e 291543.31789416715
+level0.quantification.rows[0].sigma = 408aba4d5113b617 855.2877522983498
 level0.quantification.rows[0].supported = true
 level0.quantification.rows[0].atBound = false
 level0.quantification.rows[0].isReference = true
@@ -52,12 +52,12 @@ level0.quantification.rows[0].lineNote = nil
 level0.quantification.rows[1].element = "Mg"
 level0.quantification.rows[1].groupID = "Mg_Ka"
 level0.quantification.rows[1].net = 0000000000000000 0
-level0.quantification.rows[1].sigma = 406759d88083a58b 186.80767846786725
+level0.quantification.rows[1].sigma = 4066b2224ce7ea9c 181.56668706222706
 level0.quantification.rows[1].supported = true
 level0.quantification.rows[1].atBound = true
 level0.quantification.rows[1].isReference = false
 level0.quantification.rows[1].kFreeRatio = 0000000000000000 0
-level0.quantification.rows[1].kFreeSigma = 3f44ed32c437c7e6 0.00063862780410617044
+level0.quantification.rows[1].kFreeSigma = 3f44683d005e47df 0.00062277773462171202
 level0.quantification.rows[1].atomicPercent = nil
 level0.quantification.rows[1].atomicSigma = nil
 level0.quantification.rows[1].weightPercent = nil
@@ -72,13 +72,13 @@ level0.quantification.rows[1].failure = nil
 level0.quantification.rows[1].lineNote = nil
 level0.quantification.rows[2].element = "Si"
 level0.quantification.rows[2].groupID = "Si_Ka"
-level0.quantification.rows[2].net = 4099f0a2ae1664c4 1660.1588672160151
-level0.quantification.rows[2].sigma = 4050e1a845c84f7b 67.525895543685621
+level0.quantification.rows[2].net = 409ab3093b20da0f 1708.7590146191685
+level0.quantification.rows[2].sigma = 405141453d90085a 69.019851103455409
 level0.quantification.rows[2].supported = true
 level0.quantification.rows[2].atBound = false
 level0.quantification.rows[2].isReference = false
-level0.quantification.rows[2].kFreeRatio = 3f773f2c9782a91e 0.0056754819744731216
-level0.quantification.rows[2].kFreeSigma = 3f2e332a1ade80b1 0.00023040665604146451
+level0.quantification.rows[2].kFreeRatio = 3f7801c9f697f149 0.0058610810460744756
+level0.quantification.rows[2].kFreeSigma = 3f2f84bb44a02788 0.00024046693789641868
 level0.quantification.rows[2].atomicPercent = nil
 level0.quantification.rows[2].atomicSigma = nil
 level0.quantification.rows[2].weightPercent = nil
@@ -97,12 +97,12 @@ level0.quantification.fit.groupIDs[0] = "Al_Ka"
 level0.quantification.fit.groupIDs[1] = "Mg_Ka"
 level0.quantification.fit.groupIDs[2] = "O_Ka"
 level0.quantification.fit.groupIDs[3] = "Si_Ka"
-level0.quantification.fit.values: n 4 sum 41120450a55c2efe 295188.16148446489 fnv d1fe77d4c89060d9
-level0.quantification.fit.values[0] = 4111da88a8533249 292514.16437986918
+level0.quantification.fit.values: n 4 sum 4111f5d87b0d2960 294262.1201673951 fnv 9035144839d78be3
+level0.quantification.fit.values[0] = 4111cb5d45860c6e 291543.31789416715
 level0.quantification.fit.values[1] = 0000000000000000 0
-level0.quantification.fit.values[2] = 408faeb4b5cca0bd 1013.8382373796991
-level0.quantification.fit.values[3] = 4099f0a2ae1664c4 1660.1588672160151
-level0.quantification.fit.covariance: n 16 sum 4124b78667caface 678851.20272048726 fnv f7eabf2a1e7b4d92
+level0.quantification.fit.values[2] = 408f905897f82f9e 1010.0432586087734
+level0.quantification.fit.values[3] = 409ab3093b20da0f 1708.7590146191685
+level0.quantification.fit.covariance: n 16 sum 412770ee2f85ed4c 768119.09281865647 fnv ffa9c312e712f705
 level0.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 level0.quantification.fit.supported: n 4 sum-bits 4 fnv fdcdb80e5fd8d165
 level0.quantification.fit.atBound: n 4 sum-bits 1 fnv e5da673c90210b44
@@ -128,69 +128,69 @@ level0.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 level0.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 level0.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 level0.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-level0.quantification.fit.backgroundCoefficients: n 16 sum 4103ca726276e5c7 162126.29807834161 fnv ffc8d38f25eddebb
+level0.quantification.fit.backgroundCoefficients: n 16 sum 41048a3f409acab8 168263.90654524206 fnv 698cbcb20d873875
 level0.quantification.fit.channels = 136..<4096
-level0.quantification.fit.model: n 3960 sum 4117b30a5ef371d8 388290.59272554284 fnv c9e2ea04c291dce6
-level0.quantification.fit.residual: n 3960 sum c08bd4bde6e3a5a8 -890.59272554253857 fnv c99904eb0f22a1a7
-level0.quantification.fit.standardizedResidual: n 3960 sum c05c73ebc341345a -113.8112648140681 fnv c6a549c0bb263431
+level0.quantification.fit.model: n 3960 sum 4117b46554736a93 388377.33247152827 fnv fbf190d5eae7a47b
+level0.quantification.fit.residual: n 3960 sum c08e4aa8e6d5116b -969.33247152766614 fnv 58aba7cacca77c35
+level0.quantification.fit.standardizedResidual: n 3960 sum c060614568a66b78 -131.03972275260799 fnv 75310192d524e104
 level0.quantification.fit.negativeModelChannels = 0
 level0.quantification.fit.degreesOfFreedom = 3940
-level0.quantification.fit.reducedChiSquared = 408cab28263d90a7 917.3946041879434
-level0.quantification.fit.pearsonReducedChiSquared = 4030ea637a6c1f82 16.915580417058216
-level0.quantification.fit.deviance = 40dea005698f7eb7 31360.084567903275
-level0.quantification.fit.reducedDeviance = 401fd6702f5d4c60 7.9594123268790042
+level0.quantification.fit.reducedChiSquared = 408ca700f359f3b8 916.8754641559126
+level0.quantification.fit.pearsonReducedChiSquared = 4030faa239309c83 16.979037832611095
+level0.quantification.fit.deviance = 40dea878d6136b7f 31393.888066153504
+level0.quantification.fit.reducedDeviance = 401fdf39446ea22c 7.9679918949628181
 level0.quantification.fit.methodLabel = "least squares, unweighted"
 level0.quantification.fit.referenceShapesLabel = "reference shapes: none"
 level0.quantification.fit.escapeLabel = "escape peaks: none (no line above the Si K edge, 1.839 keV)"
 level0.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-level0.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+level0.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 level0.quantification.fit.exit = "converged"
 level0.quantification.fit.warnings: array 1
-level0.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+level0.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 level0.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level0.quantification.fit.escapeRatios: array 4
 level0.quantification.fit.escapeRatios[0] = nil
 level0.quantification.fit.escapeRatios[1] = nil
 level0.quantification.fit.escapeRatios[2] = nil
 level0.quantification.fit.escapeRatios[3] = nil
-level0.quantification.fit.iterations = 18
+level0.quantification.fit.iterations = 19
 level0.quantification.fit.converged = true
 level0.quantification.fit.irls = nil
 level0.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level0.quantification.fileAxis.offset = bfde978d4fdf3b64 -0.47799999999999998
 level0.quantification.fileAxis.scale = 3f747ae147ae147b 0.0050000000000000001
 level0.quantification.fileAxis.size = 4096
-level0.quantification.usedAxis.offset = bfdea3cd2e452a02 -0.47874764936992176
-level0.quantification.usedAxis.scale = 3f747d37c4386cec 0.0050022295358999984
+level0.quantification.usedAxis.offset = bfdebbe4a48b6cbf -0.48021808689891182
+level0.quantification.usedAxis.scale = 3f74813ce01894e9 0.0050060632652606319
 level0.quantification.usedAxis.size = 4096
 level0.quantification.axisLocked = false
 level0.quantification.refinement.fileOffset = bfde978d4fdf3b64 -0.47799999999999998
 level0.quantification.refinement.fileScale = 3f747ae147ae147b 0.0050000000000000001
 level0.quantification.refinement.fileResolutionMnKaEV = 4060400000000000 130
-level0.quantification.refinement.offset = bfdea3cd2e452a02 -0.47874764936992176
-level0.quantification.refinement.scale = 3f747d37c4386cec 0.0050022295358999984
-level0.quantification.refinement.resolutionMnKaEV = 406046722403aa75 130.20143318859087
-level0.quantification.refinement.rssFile = 414bef703cf20bbe 3661536.4761366537
-level0.quantification.refinement.rssRefined = 414b93a35ec8b865 3614534.7405004972
-level0.quantification.refinement.iterations = 118
+level0.quantification.refinement.offset = bfdebbe4a48b6cbf -0.48021808689891182
+level0.quantification.refinement.scale = 3f74813ce01894e9 0.0050060632652606319
+level0.quantification.refinement.resolutionMnKaEV = 406044eda21d9ad9 130.1540079668255
+level0.quantification.refinement.rssFile = 414be7422632f3e3 3657348.2984299525
+level0.quantification.refinement.rssRefined = 414b8fa4aa1546b0 3612489.3287742957
+level0.quantification.refinement.iterations = 98
 level0.quantification.refinement.converged = true
 level0.quantification.refinement.size = 4096
-level0.quantification.plotModel: n 4096 sum 4117b30a5ef371d8 388290.59272554284 fnv 5f76c2bbf57e11e6
-level0.quantification.plotBackground: n 4096 sum 40f5c6b1bc3cb805 89195.108456343485 fnv e84eb0488b4673e3
+level0.quantification.plotModel: n 4096 sum 4117b46554736a93 388377.33247152827 fnv 9185698d1dd3d97b
+level0.quantification.plotBackground: n 4096 sum 40f606b5aa5f6d78 90219.354094913113 fnv 6d86cfd7139ceb36
 level0.quantification.kSet = nil
 level0.quantification.abundanceRefusal = "The computed-k data files are not available in this build."
 level0.quantification.absorption = .off
 level0.quantification.warnings: array 1
-level0.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+level0.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 level0.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-level0.quantification.quality = 4030ea637a6c1f82 16.915580417058216
+level0.quantification.quality = 4030faa239309c83 16.979037832611095
 level0.quantification.footerLines: array 8
-level0.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: none (no line above the Si K edge, 1.839 keV)"
-level0.quantification.footerLines[1] = "energy axis: file -0.478 keV + 0.0050 keV/ch → refined -0.7 eV, gain +0.045 %, FWHM(Mn Kα) 130 eV"
+level0.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: none (no line above the Si K edge, 1.839 keV)"
+level0.quantification.footerLines[1] = "energy axis: file -0.478 keV + 0.0050 keV/ch → refined -2.2 eV, gain +0.121 %, FWHM(Mn Kα) 130 eV"
 level0.quantification.footerLines[2] = "beam 200 kV · typed"
-level0.quantification.footerLines[3] = "fit range 0.2–20.0054 keV (default; the axis end) · 1 px pooled (synthetic)"
+level0.quantification.footerLines[3] = "fit range 0.2–20.0196 keV (default; the axis end) · 1 px pooled (synthetic)"
 level0.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-level0.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 16.9 (Pearson)"
+level0.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 17.0 (Pearson)"
 level0.quantification.footerLines[6] = "at%: not computed — The computed-k data files are not available in this build."
 level0.quantification.footerLines[7] = "absorption correction: off"
 level0.quantification.fitSettings.elements: array 4
@@ -198,28 +198,28 @@ level0.quantification.fitSettings.elements[0] = "Al"
 level0.quantification.fitSettings.elements[1] = "Mg"
 level0.quantification.fitSettings.elements[2] = "Si"
 level0.quantification.fitSettings.elements[3] = "O"
-level0.quantification.fitSettings.resolutionMnKaEV = 406046722403aa75 130.20143318859087
+level0.quantification.fitSettings.resolutionMnKaEV = 406044eda21d9ad9 130.1540079668255
 level0.quantification.fitSettings.beamEnergy = 4069000000000000 200
 level0.quantification.fitSettings.fitFrom = 3fc999999999999a 0.20000000000000001
-level0.quantification.fitSettings.fitTo = 40340160bc0314bd 20.005382300140571
+level0.quantification.fitSettings.fitTo = 4034050539b865ad 20.019610984343377
 level0.quantification.fitSettings.background.continuum.beamEnergy = 4069000000000000 200
 level0.quantification.fitSettings.background.continuum.edges: n 1 sum 3ff8f41f212d7732 1.5596000000000001 fnv 81bcb0c79f3d52e2
 level0.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f212d7732 1.5596000000000001
 level0.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 level0.quantification.fitSettings.background.continuum.nonNegative = true
 level0.quantification.fitSettings.background.continuum.efficiency = nil
-level0.quantification.fitSettings.background.continuum.edgeStep = .sharp
+level0.quantification.fitSettings.background.continuum.edgeStep = .broadened
 level0.quantification.fitSettings.escapePeaks = true
 level0.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level0.quantification.fitSettings.method = .leastSquares
 level0.quantification.fitSettings.lineTail = nil
 level0.quantification.sumEscapeCounts = nil
 level0.quantification.fitRange.fromKeV = 3fc999999999999a 0.20000000000000001
-level0.quantification.fitRange.toKeV = 40340160bc0314bd 20.005382300140571
+level0.quantification.fitRange.toKeV = 4034050539b865ad 20.019610984343377
 level0.quantification.fitRange.source = .defaultReach
 level0.quantification.fitRange.axisEndKeV = 4033ff3b645a1cac 19.997
 level0.quantification.fitRange.beamEnergyKeV = 4069000000000000 200
-level0.quantification.fitRange.reachKeV = 40340160bc0314bd 20.005382300140571
+level0.quantification.fitRange.reachKeV = 4034050539b865ad 20.019610984343377
 level0.quantification.fitRange.typedKeV = nil
 level0.quantification.rangeSensitivity = nil
 level0.quantification.unlistedCheck = nil
@@ -227,7 +227,7 @@ level0.quantification.unlistedCheckPending = false
 level0.quantification.abundanceCaveat = nil
 level0.quantification.appliedSumEscape = nil
 level0.quantification.continuumDeadLayerMicrons = nil
-level0.csv-fnv = 7bdff3fd070201e7
+level0.csv-fnv = 1142b2275b37bc6a
 level0.rangeSensitivity = nil
 level4.quantification.method.version = 1
 level4.quantification.method.estimator = .leastSquares
@@ -260,8 +260,8 @@ level4.quantification.method.fitToKeV = nil
 level4.quantification.rows: array 3
 level4.quantification.rows[0].element = "Al"
 level4.quantification.rows[0].groupID = "Al_Ka"
-level4.quantification.rows[0].net = 410de2b80994727e 244823.00467767188
-level4.quantification.rows[0].sigma = 408868be84792174 781.0930261100134
+level4.quantification.rows[0].net = 410df12716a566b5 245284.88605766525
+level4.quantification.rows[0].sigma = 4088c49218fac1a2 792.57133670714779
 level4.quantification.rows[0].supported = true
 level4.quantification.rows[0].atBound = false
 level4.quantification.rows[0].isReference = true
@@ -281,13 +281,13 @@ level4.quantification.rows[0].failure = nil
 level4.quantification.rows[0].lineNote = nil
 level4.quantification.rows[1].element = "Mg"
 level4.quantification.rows[1].groupID = "Mg_Ka"
-level4.quantification.rows[1].net = 40d809717d65f395 24613.773278701661
-level4.quantification.rows[1].sigma = 406afe3732b2ce65 215.94423804209796
+level4.quantification.rows[1].net = 40d80250ec4126e1 24585.264419830291
+level4.quantification.rows[1].sigma = 4069bc54e65ce614 205.88536375183378
 level4.quantification.rows[1].supported = true
 level4.quantification.rows[1].atBound = false
 level4.quantification.rows[1].isReference = false
-level4.quantification.rows[1].kFreeRatio = 3fb9bccb292a88ea 0.10053701167138099
-level4.quantification.rows[1].kFreeSigma = 3f502b469f796fa4 0.00098688027164593132
+level4.quantification.rows[1].kFreeRatio = 3fb9a8c500cda04b 0.10023146886453664
+level4.quantification.rows[1].kFreeSigma = 3f4e607af1d3907e 0.00092702868610362844
 level4.quantification.rows[1].atomicPercent = nil
 level4.quantification.rows[1].atomicSigma = nil
 level4.quantification.rows[1].weightPercent = nil
@@ -302,13 +302,13 @@ level4.quantification.rows[1].failure = nil
 level4.quantification.rows[1].lineNote = nil
 level4.quantification.rows[2].element = "Si"
 level4.quantification.rows[2].groupID = "Si_Ka"
-level4.quantification.rows[2].net = 4097003bee10def9 1472.0585253368465
-level4.quantification.rows[2].sigma = 4050678666c4dd17 65.617578212976113
+level4.quantification.rows[2].net = 409763ac54effc20 1496.9182927606234
+level4.quantification.rows[2].sigma = 40507caf99650316 65.948217724461159
 level4.quantification.rows[2].supported = true
 level4.quantification.rows[2].atBound = false
 level4.quantification.rows[2].isReference = false
-level4.quantification.rows[2].kFreeRatio = 3f78a0d2322a726f 0.0060127459315962714
-level4.quantification.rows[2].kFreeSigma = 3f3186b3b1bb74a1 0.00026742827479415461
+level4.quantification.rows[2].kFreeRatio = 3f78ff38fed6ba71 0.0061027742753326656
+level4.quantification.rows[2].kFreeSigma = 3f31e23e7ff28141 0.00027288461564902241
 level4.quantification.rows[2].atomicPercent = nil
 level4.quantification.rows[2].atomicSigma = nil
 level4.quantification.rows[2].weightPercent = nil
@@ -327,12 +327,12 @@ level4.quantification.fit.groupIDs[0] = "Al_Ka"
 level4.quantification.fit.groupIDs[1] = "Mg_Ka"
 level4.quantification.fit.groupIDs[2] = "O_Ka"
 level4.quantification.fit.groupIDs[3] = "Si_Ka"
-level4.quantification.fit.values: n 4 sum 41109968a05f7b33 271962.15661423205 fnv f3ecc2c5c3a6c42c
-level4.quantification.fit.values[0] = 410de2b80994727e 244823.00467767188
-level4.quantification.fit.values[1] = 40d809717d65f395 24613.773278701661
-level4.quantification.fit.values[2] = 40907547d0d1dc52 1053.3201325216983
-level4.quantification.fit.values[3] = 4097003bee10def9 1472.0585253368465
-level4.quantification.fit.covariance: n 16 sum 41234bc262f4f3b1 632289.19327508484 fnv c5c2ccb39c3b7aff
+level4.quantification.fit.values: n 4 sum 4110a075515faf01 272413.3294665665 fnv 4803d351e87e35d6
+level4.quantification.fit.values[0] = 410df12716a566b5 245284.88605766525
+level4.quantification.fit.values[1] = 40d80250ec4126e1 24585.264419830291
+level4.quantification.fit.values[2] = 4090590af3f93c49 1046.2606963103337
+level4.quantification.fit.values[3] = 409763ac54effc20 1496.9182927606234
+level4.quantification.fit.covariance: n 16 sum 4122fe786dd1b287 622396.21449048899 fnv 94850aba623729e3
 level4.quantification.fit.covarianceKind = "sandwich covariance of unweighted least squares, Var(data) = model (Poisson) on the passive set (columns not held at a bound); a bound-active area carries the full-design marginal variance (as if freed) and no covariance"
 level4.quantification.fit.supported: n 4 sum-bits 4 fnv fdcdb80e5fd8d165
 level4.quantification.fit.atBound: n 4 sum-bits 0 fnv c8210784d8af5a5
@@ -358,69 +358,69 @@ level4.quantification.fit.backgroundNames[12] = "continuum s1 t^2"
 level4.quantification.fit.backgroundNames[13] = "continuum s1 t^3"
 level4.quantification.fit.backgroundNames[14] = "continuum s1 t^4"
 level4.quantification.fit.backgroundNames[15] = "continuum s1 t^5"
-level4.quantification.fit.backgroundCoefficients: n 16 sum 410420da5fcf97ec 164891.29678267182 fnv f635991e19bb8414
+level4.quantification.fit.backgroundCoefficients: n 16 sum 4103ec165e124077 163202.79593325008 fnv d87b24b598e4ae9
 level4.quantification.fit.channels = 136..<4096
-level4.quantification.fit.model: n 3960 sum 4116308ac7c40a5c 363554.69508377253 fnv 36a6f6eb633f509d
-level4.quantification.fit.residual: n 3960 sum c07f3b1f10298905 -499.69508377289486 fnv 339d5023fd176b01
-level4.quantification.fit.standardizedResidual: n 3960 sum 40005951e53df02e 2.0436132344748534 fnv 65e4cef6fa42673f
+level4.quantification.fit.model: n 3960 sum 4116312abc4c0005 363594.68388366728 fnv a8c00fc182a17b9
+level4.quantification.fit.residual: n 3960 sum c080257898006be5 -516.68388367013233 fnv db67e9bfad95d619
+level4.quantification.fit.standardizedResidual: n 3960 sum 4012bc37e7244f28 4.683807002631319 fnv 585a1882a156f66a
 level4.quantification.fit.negativeModelChannels = 0
 level4.quantification.fit.degreesOfFreedom = 3940
-level4.quantification.fit.reducedChiSquared = 407f1264899976a6 497.14954528757733
-level4.quantification.fit.pearsonReducedChiSquared = 40228d6f4f146473 9.2762398445504228
-level4.quantification.fit.deviance = 40d464e18719c625 20883.523870891095
-level4.quantification.fit.reducedDeviance = 4015339896d88538 5.3003867692616993
+level4.quantification.fit.reducedChiSquared = 407f754af6bc919e 503.33080171260542
+level4.quantification.fit.pearsonReducedChiSquared = 4022acb1b1cd873e 9.3372932017697359
+level4.quantification.fit.deviance = 40d480f555497384 20995.83333050042
+level4.quantification.fit.reducedDeviance = 401550c8fceb6ad6 5.3288917082488378
 level4.quantification.fit.methodLabel = "least squares, unweighted"
 level4.quantification.fit.referenceShapesLabel = "reference shapes: none"
 level4.quantification.fit.escapeLabel = "escape peaks: none (no line above the Si K edge, 1.839 keV)"
 level4.quantification.fit.lineShapeLabel = "line shape: Gaussian"
-level4.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data"
+level4.quantification.fit.backgroundLabel = "continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data"
 level4.quantification.fit.exit = "converged"
 level4.quantification.fit.warnings: array 1
-level4.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+level4.quantification.fit.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 level4.quantification.fit.droppedLines: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level4.quantification.fit.escapeRatios: array 4
 level4.quantification.fit.escapeRatios[0] = nil
 level4.quantification.fit.escapeRatios[1] = nil
 level4.quantification.fit.escapeRatios[2] = nil
 level4.quantification.fit.escapeRatios[3] = nil
-level4.quantification.fit.iterations = 21
+level4.quantification.fit.iterations = 19
 level4.quantification.fit.converged = true
 level4.quantification.fit.irls = nil
 level4.quantification.fit.devianceHistory: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level4.quantification.fileAxis.offset = bfde978d4fdf3b64 -0.47799999999999998
 level4.quantification.fileAxis.scale = 3f747ae147ae147b 0.0050000000000000001
 level4.quantification.fileAxis.size = 4096
-level4.quantification.usedAxis.offset = bfdeba16b0a7ebe1 -0.48010794879490787
-level4.quantification.usedAxis.scale = 3f7480fbfb3f666a 0.0050058215164995121
+level4.quantification.usedAxis.offset = bfdeb142b3702c5c -0.47956912539729557
+level4.quantification.usedAxis.scale = 3f747f892f798bed 0.0050044401938036222
 level4.quantification.usedAxis.size = 4096
 level4.quantification.axisLocked = false
 level4.quantification.refinement.fileOffset = bfde978d4fdf3b64 -0.47799999999999998
 level4.quantification.refinement.fileScale = 3f747ae147ae147b 0.0050000000000000001
 level4.quantification.refinement.fileResolutionMnKaEV = 4060400000000000 130
-level4.quantification.refinement.offset = bfdeba16b0a7ebe1 -0.48010794879490787
-level4.quantification.refinement.scale = 3f7480fbfb3f666a 0.0050058215164995121
-level4.quantification.refinement.resolutionMnKaEV = 40604478f8824f02 130.13976693583396
-level4.quantification.refinement.rssFile = 413e542878cdc5b2 1987624.4718898353
-level4.quantification.refinement.rssRefined = 413de371355bde61 1958769.2084330546
-level4.quantification.refinement.iterations = 91
+level4.quantification.refinement.offset = bfdeb142b3702c5c -0.47956912539729557
+level4.quantification.refinement.scale = 3f747f892f798bed 0.0050044401938036222
+level4.quantification.refinement.resolutionMnKaEV = 40604457cb93e802 130.13571719062753
+level4.quantification.refinement.rssFile = 413eb2e2eef45d2f 2011874.9334161987
+level4.quantification.refinement.rssRefined = 413e42935bd6e312 1983123.3587476653
+level4.quantification.refinement.iterations = 84
 level4.quantification.refinement.converged = true
 level4.quantification.refinement.size = 4096
-level4.quantification.plotModel: n 4096 sum 4116308ac7c40a5c 363554.69508377253 fnv cc3acfa2962b859d
-level4.quantification.plotBackground: n 4096 sum 40f5809d41d12309 88073.828568589073 fnv 5f13b5acb093fc54
+level4.quantification.plotModel: n 4096 sum 4116312abc4c0005 363594.68388366728 fnv a01fd9b34b164cb9
+level4.quantification.plotBackground: n 4096 sum 40f56682454b6097 87656.141917588524 fnv 5fd90c12681b255f
 level4.quantification.kSet = nil
 level4.quantification.abundanceRefusal = "The computed-k data files are not available in this build."
 level4.quantification.absorption = .off
 level4.quantification.warnings: array 1
-level4.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −295 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −310 ± 23 at 882 (generator S); −402 ± 33 at 3000 (A) and −310 ± 23 at 2899 (S)"
+level4.quantification.warnings[0] = "a weak line next to Al Kα reads low by ≈ 300 counts per pooled spectrum on synthetic data (cause: the Al Kα incomplete-charge tail, unmodelled until a tail is measured on an Al matrix, `TailEstimate`); unmeasured on real data. Weak-line bias measured on synthetic data: Δ = −270 ± 31 counts at 900 planted Mg Kα (generator A, no tail: continuum–line projection) and −272 ± 23 at 882 (generator S); −325 ± 38 at 3000 (A) and −226 ± 22 at 2899 (S)"
 level4.quantification.qualityLabel = "χ²ᵣ (Pearson)"
-level4.quantification.quality = 40228d6f4f146473 9.2762398445504228
+level4.quantification.quality = 4022acb1b1cd873e 9.3372932017697359
 level4.quantification.footerLines: array 8
-level4.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV; orders chosen on synthetic data · escape peaks: none (no line above the Si K edge, 1.839 keV)"
-level4.quantification.footerLines[1] = "energy axis: file -0.478 keV + 0.0050 keV/ch → refined -2.1 eV, gain +0.116 %, FWHM(Mn Kα) 130 eV"
+level4.quantification.footerLines[0] = "least squares, unweighted · continuum: Kramers×Bernstein(9,5), split at 1.5596 keV (step broadened by the detector resolution); orders chosen on synthetic data · escape peaks: none (no line above the Si K edge, 1.839 keV)"
+level4.quantification.footerLines[1] = "energy axis: file -0.478 keV + 0.0050 keV/ch → refined -1.6 eV, gain +0.089 %, FWHM(Mn Kα) 130 eV"
 level4.quantification.footerLines[2] = "beam 200 kV · typed"
-level4.quantification.footerLines[3] = "fit range 0.2–20.0187 keV (default; the axis end) · 1 px pooled (synthetic)"
+level4.quantification.footerLines[3] = "fit range 0.2–20.0136 keV (default; the axis end) · 1 px pooled (synthetic)"
 level4.quantification.footerLines[4] = "σ: counting only; model choice can move a weak line by more"
-level4.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 9.28 (Pearson)"
+level4.quantification.footerLines[5] = "σ is counting statistics at χ²ᵣ = 1; this fit is at 9.34 (Pearson)"
 level4.quantification.footerLines[6] = "at%: not computed — The computed-k data files are not available in this build."
 level4.quantification.footerLines[7] = "absorption correction: off"
 level4.quantification.fitSettings.elements: array 4
@@ -428,28 +428,28 @@ level4.quantification.fitSettings.elements[0] = "Al"
 level4.quantification.fitSettings.elements[1] = "Mg"
 level4.quantification.fitSettings.elements[2] = "Si"
 level4.quantification.fitSettings.elements[3] = "O"
-level4.quantification.fitSettings.resolutionMnKaEV = 40604478f8824f02 130.13976693583396
+level4.quantification.fitSettings.resolutionMnKaEV = 40604457cb93e802 130.13571719062753
 level4.quantification.fitSettings.beamEnergy = 4069000000000000 200
 level4.quantification.fitSettings.fitFrom = 3fc999999999999a 0.20000000000000001
-level4.quantification.fitSettings.fitTo = 403404cb90bd12c4 20.018731161270594
+level4.quantification.fitSettings.fitTo = 4034037c2c18d3a3 20.013613468228538
 level4.quantification.fitSettings.background.continuum.beamEnergy = 4069000000000000 200
 level4.quantification.fitSettings.background.continuum.edges: n 1 sum 3ff8f41f212d7732 1.5596000000000001 fnv 81bcb0c79f3d52e2
 level4.quantification.fitSettings.background.continuum.edges[0] = 3ff8f41f212d7732 1.5596000000000001
 level4.quantification.fitSettings.background.continuum.orders: n 2 sum-bits e fnv 54226316c5c52fc9
 level4.quantification.fitSettings.background.continuum.nonNegative = true
 level4.quantification.fitSettings.background.continuum.efficiency = nil
-level4.quantification.fitSettings.background.continuum.edgeStep = .sharp
+level4.quantification.fitSettings.background.continuum.edgeStep = .broadened
 level4.quantification.fitSettings.escapePeaks = true
 level4.quantification.fitSettings.referenceShapes.shapes: n 0 sum 0000000000000000 0 fnv cbf29ce484222325
 level4.quantification.fitSettings.method = .leastSquares
 level4.quantification.fitSettings.lineTail = nil
 level4.quantification.sumEscapeCounts = nil
 level4.quantification.fitRange.fromKeV = 3fc999999999999a 0.20000000000000001
-level4.quantification.fitRange.toKeV = 403404cb90bd12c4 20.018731161270594
+level4.quantification.fitRange.toKeV = 4034037c2c18d3a3 20.013613468228538
 level4.quantification.fitRange.source = .defaultReach
 level4.quantification.fitRange.axisEndKeV = 4033ff3b645a1cac 19.997
 level4.quantification.fitRange.beamEnergyKeV = 4069000000000000 200
-level4.quantification.fitRange.reachKeV = 403404cb90bd12c4 20.018731161270594
+level4.quantification.fitRange.reachKeV = 4034037c2c18d3a3 20.013613468228538
 level4.quantification.fitRange.typedKeV = nil
 level4.quantification.rangeSensitivity = nil
 level4.quantification.unlistedCheck = nil
@@ -457,5 +457,5 @@ level4.quantification.unlistedCheckPending = false
 level4.quantification.abundanceCaveat = nil
 level4.quantification.appliedSumEscape = nil
 level4.quantification.continuumDeadLayerMicrons = nil
-level4.csv-fnv = a32acb6ac2acfd15
+level4.csv-fnv = c6a2905526cd0e52
 level4.rangeSensitivity = nil
diff --git a/Tests/SpectroEDXTests/ContinuumEdgeBroadeningTests.swift b/Tests/SpectroEDXTests/ContinuumEdgeBroadeningTests.swift
index 6e350fc..5cc90c9 100644
--- a/Tests/SpectroEDXTests/ContinuumEdgeBroadeningTests.swift
+++ b/Tests/SpectroEDXTests/ContinuumEdgeBroadeningTests.swift
@@ -1,6 +1,6 @@
 //
 //  ContinuumEdgeBroadeningTests.swift
-//  Role: The continuum's step at the Al K edge (sharp default, opt-in broadened) on a spectrum whose edge is seen through the detector, as a real one is: a
+//  Role: The continuum's step at the Al K edge (broadened default, opt-in sharp) on a spectrum whose edge is seen through the detector, as a real one is: a
 //        Kramers continuum absorbed by an Al film (FFAST mu/rho), then convolved with the detector's Gaussian, plus Al K (and a weak
 //        Si K) line. Noise-free and generated here; no measured spectrum is committed.
 //
@@ -116,11 +116,12 @@ struct ContinuumEdgeBroadeningTests {
         #expect(abs(s - -0.387) < 0.02, "sharp Si bias \(s)")
     }
 
-    /// `.sharp` is the default and the form without the broadening: the same columns as a call with no resolution.
-    @Test func testTheSharpStepIsTheDefaultAndTheUnbroadenedForm() {
+    /// `.broadened` is the default; `.sharp` is the form without the broadening: the same columns as a call with no resolution.
+    @Test func testTheBroadenedStepIsTheDefaultAndSharpTheUnbroadenedForm() {
         let e = Array(Self.energies[40..<4000])
-        let sharp = ContinuumForm(beamEnergy: Self.beam)
-        let broad = ContinuumForm(beamEnergy: Self.beam, edgeStep: .broadened)
+        let sharp = ContinuumForm(beamEnergy: Self.beam, edgeStep: .sharp)
+        let broad = ContinuumForm(beamEnergy: Self.beam)
+        #expect(broad.edgeStep == .broadened)
         #expect(sharp.edgeStep == .sharp)
         #expect(sharp.columns(energies: e, resolutionMnKaEV: Self.resolution).values == sharp.columns(energies: e).values)
         #expect(broad.columns(energies: e).values == sharp.columns(energies: e).values, "no resolution: the sharp form")
@@ -136,8 +137,8 @@ struct ContinuumEdgeBroadeningTests {
     /// (Kramers / kRef): the weights sum to 1. Every column is non-negative and finite.
     @Test func testTheBroadenedWeightsSumToOne() {
         let e = Array(Self.energies[40..<4000])
-        let broad = ContinuumForm(beamEnergy: Self.beam, edgeStep: .broadened).columns(energies: e, resolutionMnKaEV: Self.resolution).values
-        let sharp = ContinuumForm(beamEnergy: Self.beam).columns(energies: e).values
+        let broad = ContinuumForm(beamEnergy: Self.beam).columns(energies: e, resolutionMnKaEV: Self.resolution).values
+        let sharp = ContinuumForm(beamEnergy: Self.beam, edgeStep: .sharp).columns(energies: e).values
         for i in e.indices {
             let b = broad.reduce(0) { $0 + $1[i] }, s = sharp.reduce(0) { $0 + $1[i] }
             #expect(abs(b - s) <= 1e-12 * max(abs(s), 1), "channel \(i): \(b) vs \(s)")
@@ -149,9 +150,9 @@ struct ContinuumEdgeBroadeningTests {
     @Test func testTheBroadenedWeightsSumToOneWithTwoCloseEdges() {
         let e = Array(Self.energies[40..<4000])
         let edges = [1.5596, 1.65]
-        let broad = ContinuumForm(beamEnergy: Self.beam, edges: edges, orders: [9, 3, 5], edgeStep: .broadened)
+        let broad = ContinuumForm(beamEnergy: Self.beam, edges: edges, orders: [9, 3, 5])
             .columns(energies: e, resolutionMnKaEV: Self.resolution).values
-        let sharp = ContinuumForm(beamEnergy: Self.beam, edges: edges, orders: [9, 3, 5]).columns(energies: e).values
+        let sharp = ContinuumForm(beamEnergy: Self.beam, edges: edges, orders: [9, 3, 5], edgeStep: .sharp).columns(energies: e).values
         for i in e.indices {
             let b = broad.reduce(0) { $0 + $1[i] }, s = sharp.reduce(0) { $0 + $1[i] }
             #expect(abs(b - s) <= 1e-12 * max(abs(s), 1), "channel \(i): \(b) vs \(s)")
@@ -159,25 +160,32 @@ struct ContinuumEdgeBroadeningTests {
         #expect(broad.allSatisfy { $0.allSatisfy { $0 >= 0 && $0.isFinite } })
     }
 
-    /// The policy: default `.sharp`, named in the footer when `.broadened`, and a stored policy without the field reads `.sharp`.
-    @Test func testThePolicyDefaultsToSharpAndOldStoredPoliciesReadIt() throws {
-        #expect(FitPolicy.default.continuumEdgeStep == .sharp)
-        // The default policy's canonical JSON is what it was before the field existed: the key is written only when not the default.
-        #expect(!QuantificationPolicy.default.canonicalJSON.contains("continuumEdgeStep"))
-        var broad = QuantificationPolicy()
-        broad.fit.continuumEdgeStep = .broadened
-        #expect(broad.footerLine?.contains("continuumEdgeStep = broadened") == true, "\(broad.footerLine ?? "nil")")
-        let round = try JSONDecoder().decode(QuantificationPolicy.self, from: Data(broad.canonicalJSON.utf8))
-        #expect(round == broad)
+    /// The policy: default `.broadened` (the key written), `.sharp` named in the footer as non-default, and a stored policy without
+    /// the field reads `.sharp`, the form it was run with (and so gets that footer line).
+    @Test func testThePolicyDefaultsToBroadenedAndOldStoredPoliciesReadSharp() throws {
+        #expect(FitPolicy.default.continuumEdgeStep == .broadened)
+        #expect(FitPolicy.exspyEquivalent.continuumEdgeStep == .broadened)
+        #expect(QuantificationPolicy.default.canonicalJSON.contains("\"continuumEdgeStep\":\"broadened\""))
+        #expect(QuantificationPolicy.default.footerLine == nil)
+        var sharp = QuantificationPolicy()
+        sharp.fit.continuumEdgeStep = .sharp
+        #expect(sharp.footerLine?.contains("continuumEdgeStep = sharp") == true, "\(sharp.footerLine ?? "nil")")
+        #expect(sharp.canonicalJSON.contains("\"continuumEdgeStep\":\"sharp\""))
+        for p in [sharp, QuantificationPolicy.default] {
+            #expect(try JSONDecoder().decode(QuantificationPolicy.self, from: Data(p.canonicalJSON.utf8)) == p)
+        }
         var json = try #require(try JSONSerialization.jsonObject(with: Data(QuantificationPolicy.default.canonicalJSON.utf8)) as? [String: Any])
         var fit = try #require(json["fit"] as? [String: Any])
         fit.removeValue(forKey: "continuumEdgeStep")
         json["fit"] = fit
         let old = try JSONDecoder().decode(QuantificationPolicy.self, from: try JSONSerialization.data(withJSONObject: json))
-        #expect(old == .default)
-        let settings = FitSettings.standard(elements: ["Al"], axis: Self.axis, resolutionMnKaEV: Self.resolution, beamEnergy: Self.beam,
-                                            policy: broad.fit)
+        #expect(old == sharp)
+        let settings = FitSettings.standard(elements: ["Al"], axis: Self.axis, resolutionMnKaEV: Self.resolution, beamEnergy: Self.beam)
         guard case .continuum(let form) = settings.background else { Issue.record("no continuum"); return }
         #expect(form.edgeStep == .broadened)
+        let sharpSettings = FitSettings.standard(elements: ["Al"], axis: Self.axis, resolutionMnKaEV: Self.resolution, beamEnergy: Self.beam,
+                                                 policy: sharp.fit)
+        guard case .continuum(let sharpForm) = sharpSettings.background else { Issue.record("no continuum"); return }
+        #expect(sharpForm.edgeStep == .sharp)
     }
 }
diff --git a/Tests/SpectroEDXTests/DemoEDXPoolTests.swift b/Tests/SpectroEDXTests/DemoEDXPoolTests.swift
index 6ed4aa0..7762351 100644
--- a/Tests/SpectroEDXTests/DemoEDXPoolTests.swift
+++ b/Tests/SpectroEDXTests/DemoEDXPoolTests.swift
@@ -19,7 +19,9 @@ import SpectroEDX
 ///
 /// What the bounds are: MEASURED regression bounds on fixed inputs, not derived limits. The fit with the default sum peaks reads
 /// noise-free Si K-alpha -0.0 to -4.0 % on the pools at up to 300 counts/px and -7.9 % on L5 (the highest rate, where the
-/// generator's pile-up takes 11 % of the Al K-alpha photons); the bound is 5 % (10 % on L5). The fit without sum peaks read -8 to
+/// generator's pile-up takes 11 % of the Al K-alpha photons); the bound is 5 % (10 % on L5). With the continuum seen through the
+/// detector (the expected spectra's continuum blurred, `tools/edx-sim/detector_blur.py`) and the broadened continuum step (the
+/// default since then): -0.04 to -1.6 % on the pools, -2.4 % on L5; the bounds are kept. The fit without sum peaks read -8 to
 /// -57 % on the same pools: the Al+Al sum peak (2.97 keV) pulls the continuum segment above the Al K edge and Si K-alpha with it.
 struct DemoEDXPoolTests {
     static let tables = try! QuantificationTables(directory: EDXFixtures.repoRoot.appendingPathComponent("Sources/SpectroEDX/Resources/Spectroscopy"))
@@ -165,7 +167,10 @@ struct DemoEDXPoolTests {
     /// detector (the absorption-truth pool, 1e4 px) with `TailEstimate`, then typed into `FitPolicy.lineTail`, it takes the noise-free
     /// Mg K-alpha bias next to Al K-alpha (-22 % on L5, -32 % on recipe A, -45 % on the matrix map) to within 5 % on L5 and recipe A,
     /// and to -15 % on the matrix map (which
-    /// pools seven recipes and thicknesses; not explained). Without it the default fit leaves Mg where it was (the tail is not a sum peak).
+    /// pools seven recipes and thicknesses; not explained). Without it the default fit leaves Mg near where it was (the tail is not a
+    /// sum peak): within 1.6 points on every pool but L5, the highest rate, where with the broadened continuum step the sum peaks take
+    /// Mg from -24.5 % to -15.6 % (bound 0.10 there, 0.03 elsewhere). Measured with the broadened step: with the calibrated tail Mg
+    /// reads +4.2 % (L5), +1.4 % (L6), +0.8 % (L7), +3.1 % (recipe A), -14.5 % (matrix map).
     @Test func aCalibratedTailTakesTheMgBiasOut() throws {
         let fx = Self.named("absorption-truth")
         var s = FitSettings.standard(elements: ["Al", "Mg", "Si", "Cu", "O"], axis: fx.axis, resolutionMnKaEV: 130, beamEnergy: 200)
@@ -184,7 +189,7 @@ struct DemoEDXPoolTests {
             let mgOff = Self.net(off, "Mg_Ka") / 100 / c.mg - 1
             Self.say(String(format: "%@ Mg with the calibrated tail %+.4f, default %+.4f, without sum peaks %+.4f", name, mg, mgPlain, mgOff))
             #expect(abs(mg) <= bound, "\(name): Mg \(mg)")
-            #expect(abs(mgPlain - mgOff) <= 0.03, "\(name): sum peaks moved Mg from \(mgOff) to \(mgPlain)")
+            #expect(abs(mgPlain - mgOff) <= (name == "L5" ? 0.10 : 0.03), "\(name): sum peaks moved Mg from \(mgOff) to \(mgPlain)")
         }
     }
 
diff --git a/Tests/SpectroEDXTests/Fixtures/eds-absorption-truth.json b/Tests/SpectroEDXTests/Fixtures/eds-absorption-truth.json
index 361156b..cb51cfc 100644
--- a/Tests/SpectroEDXTests/Fixtures/eds-absorption-truth.json
+++ b/Tests/SpectroEDXTests/Fixtures/eds-absorption-truth.json
@@ -1 +1 @@
-{"generator":"tools/edx-sim/absorption_truth_sim.py over tools/edx-sim/forward.py","npix":10000,"offset":-0.478,"scale":0.005,"size":4096,"beam":200.0,"fwhmMnKa":130.0,"thickness_nm":80.0,"density_g_cm3":2.7,"truth_at_pct":{"Al":98.8,"Mg":0.6,"Si":0.6},"segments":{"azimuth_deg":[45.0,135.0,225.0,315.0],"elevation_deg":22.0,"alpha_deg":-16.87,"solid_angle":[0.4,0.2,0.1,0.3]},"medium_atom_fractions_incl_O":{"Al":0.9686274509803922,"Mg":0.0058823529411764705,"Si":0.0058823529411764705,"O":0.0196078431372549},"medium_weight_fractions_incl_O":{"Al":0.9767579527294492,"Mg":0.005343315240759716,"Si":0.006174436543688829,"O":0.011724295486102269},"areas_with_absorption":{"Al_Ka":289314.4508009834,"Mg_Ka":952.4087764506195,"Si_Ka":1879.4859496165016},"areas_absorption_free":{"Al_Ka":320313.3367250421,"Mg_Ka":1049.861106153506,"Si_Ka":2362.7853150636083},"t_eff":{"Al_Ka":0.9789658647241768,"Mg_Ka":0.968501318330482,"Si_Ka":0.8492264157427728},"t_by_segment":{"Al_Ka":[0.9734784976948238,0.9917697211260007,0.9917697211260007,0.9734784976948238],"Mg_Ka":[0.9603127906219482,0.9876078829837277,0.9876078829837277,0.9603127906219482],"Si_Ka":[0.811769870151766,0.9366250221217884,0.9366250221217884,0.811769870151766]},"area_si_ka_internal":236.26706493621273,"true_k_counts_per_atom_nm2":{"Al":0.006802201645893394,"Mg":0.0036712336182256246,"Si":0.008262366164884884},"expected":[1.3743258820558635e-05,1.432799195059847e-05,1.4937603665683509e-05,1.5573152472613035e-05,1.62357419143746e-05,1.6926522486294685e-05,1.7646693633715278e-05,1.8397505834665807e-05,1.918026277114567e-05,1.999632359278868e-05,2.0847105276839474e-05,2.1734085088538916e-05,2.2658803146192177e-05,2.3622865095371876e-05,2.4627944896900652e-05,2.56757877334534e-05,2.6768213039827016e-05,2.7907117662138017e-05,2.909447915143497e-05,3.0332359197443182e-05,3.162290720840554e-05,3.2968364043233506e-05,3.437106590245013e-05,3.5833448384680595e-05,3.7358050715734025e-05,3.89475201576193e-05,4.0604616605150774e-05,4.2332217378126066e-05,4.413332221739527e-05,4.601105849349817e-05,4.796868663691225e-05,5.000960579934133e-05,5.213735975587472e-05,5.435564305826437e-05,5.6668307450005315e-05,5.907936855435805e-05,6.159301284692484e-05,6.421360492488895e-05,6.694569508553572e-05,6.979402722721815e-05,7.276354708648211e-05,7.585941082565823e-05,7.908699398582608e-05,8.245190082070255e-05,8.59599740276555e-05,8.96173048927442e-05,9.343024386739831e-05,9.740541159510237e-05,0.00010154971040723124,0.00010587033630799873,0.00011037479146932778,0.00011507089725733848,0.0001199668078130736,0.0001250710242110421,0.00013039240922016454,0.00013594020269274936,0.00014172403760822616,0.00014775395679948606,0.00015404043039088004,0.0001605943739781462,0.0001674271675818403,0.00017455067540717356,0.00018197726644457172,0.00018971983594672266,0.00019779182781940878,0.00020620725796499612,0.0002149807386191212,0.00022412750372282272,0.0002336634353741874,0.00024360509140542046,0.0002539697341332464,0.0002647753603325408,0.0002760407324852555,0.0002877854113588813,0.00030002978997103005,0.0003127951289991004,0.0003261035936965166,0.0003399782923796376,0.00035444331655216894,0.0003695237827367407,0.00038524587608628754,0.0004016368958509657,0.00041872530277953896,0.000436540768537551,0.00045511422722808385,0.0004744779291045739,0.0004946654965689293,0.0005157119825522082,0.0005376539313791983,0.0005605294422226158,0.0005843782352570599,0.0006092417206276372,0.000635163070352968,0.0006621872932874604,0.0006903613132729773,0.0007197340506156416,0.0007503565070291932,0.0007822818541924584,0.0008155655260746349,0.000850265315188759,0.0008864414729404328,0.0009241568142461052,0.000963476826602518,0.0010044697837967285,0.0010472068644541404,0.0010917622756303781,0.0011382133816616345,0.0011866408384971709,0.0012371287337473158,0.001289764732728421,0.0013446402400375459,0.0014018506441385134,0.001461499074652624,0.0015237475746092608,0.0015892561262508596,0.001661634237502406,0.001757017999078423,0.0019325701906692707,0.002349621097493689,0.003394305760807493,0.005518659532205329,0.010353955438422323,0.01990462891274061,0.03727500977437492,0.06682930111676062,0.11415110270615587,0.18590953262833582,0.2902252318642943,0.43571356597475075,0.6315140918691459,0.8875058906403408,1.2118144362371146,1.6153698334992728,2.103393277242877,2.6855193100952404,3.3660109726171026,4.148049925812091,5.039412684535509,6.036714866401558,7.142140389958979,8.357716434233973,9.676449618850292,11.097866118898445,12.62076237322524,14.234915094315701,15.93620707766933,17.724818645327456,19.58682274998607,21.515051324146754,23.510449247857377,25.560365199856122,27.65541041850698,29.79005229129887,31.96435086248664,34.16294135958247,36.378927026411276,38.609413675852615,40.85371203298692,43.097200378847944,45.334210052035914,47.56120203441642,49.78176859102611,51.981373429444936,54.155805395200204,56.30113070224272,58.42196426803361,60.51038018746587,62.560317238278785,64.5692412698219,66.53492745351804,68.46474467207807,70.34795913430932,72.18297538852276,73.96865064616702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\ No newline at end of file
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\ No newline at end of file
diff --git a/Tests/SpectroEDXTests/Fixtures/eds-proposer-sim.json b/Tests/SpectroEDXTests/Fixtures/eds-proposer-sim.json
index fb80574..f3a4ce4 100644
--- a/Tests/SpectroEDXTests/Fixtures/eds-proposer-sim.json
+++ b/Tests/SpectroEDXTests/Fixtures/eds-proposer-sim.json
@@ -1 +1 @@
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\ No newline at end of file
diff --git a/Tests/SpectroEDXTests/Fixtures/eds-realistic-l-sim.json b/Tests/SpectroEDXTests/Fixtures/eds-realistic-l-sim.json
index 7164497..26b06fa 100644
--- a/Tests/SpectroEDXTests/Fixtures/eds-realistic-l-sim.json
+++ b/Tests/SpectroEDXTests/Fixtures/eds-realistic-l-sim.json
@@ -1 +1 @@
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\ No newline at end of file
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\ No newline at end of file
diff --git a/Tests/SpectroEDXTests/Fixtures/eds-weakline-sim.json b/Tests/SpectroEDXTests/Fixtures/eds-weakline-sim.json
index 00a86a7..524744b 100644
--- a/Tests/SpectroEDXTests/Fixtures/eds-weakline-sim.json
+++ b/Tests/SpectroEDXTests/Fixtures/eds-weakline-sim.json
@@ -1 +1 @@
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\ No newline at end of file
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\ No newline at end of file
diff --git a/Tests/SpectroEDXTests/Fixtures/edx-demo-pools.json b/Tests/SpectroEDXTests/Fixtures/edx-demo-pools.json
index c89df08..5a25ebc 100644
--- a/Tests/SpectroEDXTests/Fixtures/edx-demo-pools.json
+++ b/Tests/SpectroEDXTests/Fixtures/edx-demo-pools.json
@@ -1 +1 @@
-{"atomic_mass":{"Al":26.9815,"Mg":24.305,"Si":28.0855},"generator":"mac4DSTEM demo-edx, tools/demo-edx/sim_edx.py v2.0 (seed 42, ladder seed 52); truth is the simulation 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8,9,3,7,10,5,5,8,6,5,3,11,6,3,3,4,1,3,8,7,5,15,1,3,9,4,3,12,4,5,8,7,3,7,2,4,5,5,2,4,4,7,5,3,7,3,6,7,6,6,5,5,7,4,4,4,3,2,4,3,8,2,6,5,3,3,3,7,5,5,9,2,4,3,8,9,4,10,5,7,5,2,2,5,3,2,6,2,3,4,4,8,8,3,0,1,9,8,5,4,6,4,7,2,7,2,5,2,2,8,5,2,8,4,2,3,5,1,5,3,5,2,10,2,5,5,11,5,3,8,7,4,6,5,4,5,4,3,7,5,4,5,2,4,3,3,6,2,6,7,5,1,8,2,3,3,4,5,4,4,5,5,4,2,10,9,5,5,4,5,7,4,3,3,2,6,4,5,4,6,5,2,1,5,4,1,7,9,4,6,3,6,3,3,2,4,4,5,4,6,4,1,7,3,3,4,6,5,2,6,6,3,4,4,4,4,3,4,4,2,6,5,5,5,6,2,9,2,5,6,3,4,9,1,6,3,4,5,8,5,7,6,5,5,11,5,5,8,3,5,6,2,3,6,5,8,6,4,8,4,6,6,6,5,2,4,6,3,4,6,4,4,6,5,4,2,4,6,2,2,1,4,4,2,4,2,4,4,5,4,6,4,2,3,5,2,2,12,3,7,3,7,4,4,5,8,5,4,6,6,2,6,3,8,5,4,3,4,0,5,4,11,5,8,6,5,3,5,7,7,5,3,7,4,9,4,10,7,6,6,6,0,6,3,6,3,2,0,2,2,6,4,3,6,7,5,4,4,6,4,3,4,3,3,6,2,5,7,4,7,3,9,4,2,4,4,3,2,4,4,2,7,6,2,3,2,6,6,3,4,3,3,3,4,0,4,11,4,2,4,7,9,3,2,3,3,2,3,5,6,5,6,1,5,7,5,5,10,5,7,4,4,5,3,4,4,3,2,2,6,6,3,3,4,3,6,3,5,3,5,5,3,7,3,2,4,4,2,8,6,2,2,2,3,5,7,5,5,9,3,5,4,2,6,1,1,2,5,2,3,10,4,1,7,7,4,3,0,7,5,3,1,5,4,2,8,5,3,4,5,7,3,3,1,4,4,1,9,2,3,4,4,4,5,1,7,3,5,2,4,2,3,3,5,5,6,6,3,6,6,4,7,6,5,5,4,4,2,7,3,8,3,7,5,8,4,5,5,2,9,7,3,5,12,9,6,7,5,4,11,6,7,11,5,6,5,7,7,3,6,6,12,5,8,5,6,6,3,8,6,5,8,2,2,4,3,4,6,5,1,1,5,3,3,4,4,2,6,2,2,4,8,3,1,3,1,4,0,2,5,4,1,2,2,8,4,2,4,3,4,1,5,2,3,5,2,6,2,4,1,6,6,7,7,2,4,4,1,2,2,5,3,4,1,4,2,6,4,4,3,1,3,2,1,1,5,9,2,6,4,0,6,3,4,1,3,2,3,3,0,3,2,0,2,3,2,3,1,4,4,0,4,2,6,1,5,2,4,3,4,2,2,5,2,1,3,5,3,5,2,5,4,2,3,5,3,2,3,3,4,4,4,1,3,2,4,2,5,1,4,7,0,5,4,4,4,5,4,6,3,4,5,3,3,4,7,3,7,3,4,3,5,2,2,4,2,2,4,2,2,3,2,2,1,4,1,2,0,0,3,4,4,3,4,0,3,5,0,1,3,4,4,1,1,1,3,3,1,2,1,3,3,5,2,5,3,1,3,4,5,1,2,0,3,3,1,4,3,3,4,3,4,6,5,6,4,3,3,0,2,2,2,5,4,1,2,4,1,2,6,2,1,1,4,3,4,1,3,4,2,2,6,4,3,4,6,1,4,1,7,3,1,1,2,3,3,2,1,2,1,5,3,2,5,4,5,3,2,2,2,4,4,2,1,1,2,4,0,1,3,4,5,0,2,2,4,2,3,2,6,3,2,2,2,1,3,5,2,2,3,3,9,3,5,8,1,4,4,2,2,3,3,3,3,4,4,5,1,2,3,3,1,2,1,3,6,2,4,3,4,0,0,2,2,7,4,4,4,2,2,1,7,9,4,1,0,3,3,5,1,1,2,5,0,3,2,0,4,9,4,4,4,3,1,3,5,2,2,1,3,5,5,3,1,4,6,3,5,4,4,1,2,6,2,5,1,4,4,0,3,6,1,4,3,4,2,2,2,2,2,3,5,3,3,2,0,5,2,1,2,2,2,4,1,1,5,1,1,4,4,0,3,0,5,4,3,0,2,1,3,3,3,2,2,3,1,2,4,6,2,4,0,1,2,1,3,2,5,0,1,3,3,3,2,5,4,5,5,1,2,4,2,5,3,2,2,5,4,2,4,2,4,2,3,5,2,2,4,1,2,3,6,2,6,2,4,2,8,1,2,0,2,4,4,4,3,1,1,2,0,3,3,2,1,1,2,2,2,1,3,4,0,3,1,3,3,4,1,3,2,4,3,2,2,6,1,2,3,1,3,1,2,2,3,2,2,3,2,2,2,2,3,4,3,3,3,3,2,3,2,5,2,2,2,3,0,0,3,3,1,1,2,1,6,2,1,6,4,0,5,2,3,0,3,3,2,1,3,4,3,3,3,2,4,1,1,2,2,5,2,1,1,3,4,1,6,4,1,3,5,0,1,5,1,1,1,3,1,2,2,2,2,0,3,3,2,1,0,3,5,2,3,1,2,3,1,0,5,2,3,3,3,3,0,2,0,3,1,3,1,4,3,5,3,1,3,1,3,2,4,2,5,2,2,5,4,3,2,0,1,2,2,3,3,2,2,5,3,5,1,4,3,1,2,8,0,4,3,1,3,1,2,1,3,4,4,0,1,0,2,1,5,2,2,2,5,2,1,2,7,3,4,1,1,2,4,2,4,5,3,1,0,4,1,0,0,4,3,0,2,2,2,2,3,0,4,3,0,2,4,3,2,2,3,1,1,3,1,4,1,1,1,1,1,2,2,2,1,3,1,2,2,2,3,0,0,3,3,0,3,3,4,5,1,2,2,7,0,2,2,1,3,4,0,1,2,4,4,4,4,2,0,6,2,2,3,3,2,2,3,0,3,4,3,0,2,4,2,1,3,1,2,7,3,1,0,3,3,0,5,3,1,1,0,2,3,1,1,2,1,6,2,3,2,1,3,1,3,0,5,0,2,4,2,3,2,0,7,4,5,0,1,2,2,5,4,5,1,0,1,3,6,1,1,0,1,1,1,4,5,1,4,0,3,3,0,0,5,1,5,3,2,2,0,4,2,1,1,4,2,2,4,0,2,3,1,0,3,1,2,3,0,2,2,3,1,2,2,3,5,1,1,1,2,5,1,3,3,0,2,2,5,1,2,1,3,1,2,1,2,1,5,3,2,1,2,3,0,2,0,3,4,5,0,4,3,4,0,3,2,1,2,1,1,1,2,3,3,0,5,2,1,2,1,2,3,3,1,2,4,2,1,4,2,0,2,5,3,4,1,2,1,1,1,2,1,2,2,2,3,1,3,4,2,0,0,1,2,5,1,0,0,2,3,3,2,0,5,2,0,1,3,1,4,2,0,3,1,3,0,3,3,1,1,2,3,3,1,3,3,3,2,0,5,2,1,1,2,0,2,2,3,4,1,3,4,0,0,3,0,3,4,4,2,3,0,2,1,5,2,4,2,3,0,2,1,0,3,2,5,3,0,2,4,1,2,3,4,4,4,6,1,1,1,2,5,1,3,3,3,2,2,0,2,4,2,0,1,7,1,3,1,1,0,2,3,1,3,0,2,4,3,1,2,2,1,4,5,5,3,2,4,1,1,0,4,2,0,3,4,4,1,2,1,3,3,2,1,2,3,0,2,5,2,2,2,0,2,1,1,2,1,4,0,1,3,0,0,3,2,1,2,3,1,1,2,4,4,3,1,1,1,0,0,1,1,1,5,2,1,2,3,1,4,3,1,1,0,2,2,4,3,1,0,2,3,2,3,0,3,3,2,2,1,4,1,2,5,1,3,1,1,3,0,1,2,3,4,1,1,1,2,3,0,2,1,3,3,1,3,1,4,0,2,0,1,2,2,1,1,0,2,3,1,2,0,3,1,1,1,5,4,3,1,0,3,2,3,2,3,3,2,1,2,0,1,2,3,3,2,2,1,2,2,1,0,2,3,2,2,2,1,2,4,5,2,4,2,1,1,1,2,3,2,2,1,1,3,5,2,3,6,2,2,2,4,4,0,1,3,2,1,3,1,2,0,2,1,5,1,1,3,1,4,3,1,1,1,1,1,0,2,0,5,3,3,3,2,1,2,1,4,1,3,2,2,1,2,3,0,2,1,2,1,5,3,2,2,0,3,1,1,4,2,0,5,4,2,1,1,3,1,0,5,1,2,2,1,2,0,5,2,4,2,2,2,1,2,2,2,1,4,3,2,1,2,2,1,1,4,1,2,2,2,4,1,2,0,1,3,2,1,3,0,3,0,2,2,1,2,0,4,1,2,5,3,0,2,4,1,2,2,1,3,0,0,3,6,1,1,1,2,2,1,2,1,3,2,1,4,4,3,3,1,0,4,2,1,1,0,2,2,2,1,2,4,0,1,0,0,2,1,1,1,0,2,0,1,2,2,1,2,0,5,2,3,2,3,1,3,3,2,0,2,1,1,2,0,0,3,0,2,3,1,3,1,3,1,2,0,3,2,1,1,1,2,2,2,1,0,3,3,4,2,0,2,1,1,2,3,2,1,1,2,1,1,2,3,1,2,3,0,1,2,0,3,1,3,2,1,0,1,2,0,5,1,2,2,1,1,5,4,1,2,1,3,1,0,1,0,1,0,1,3,0,3,3,3,2,3,2,2,1,0,3,1,1,2,0,0,3,0,2,3,0,3,3,1,1,1,3,1,2,0,1,2,4,1,1,5,1,1,1,1,1,4,1,2,1,3,3,2,4,1,3,2,1,1,0,0,1,3,2,3,2,4,2,2,1,2,1,0,3,0,5,3,3,1,3,1,1,0,2,0,2,2,3,2,2,3,1,0,0,0,4,3,0,2,2,0,1,2,1,2,0,1,0,3,2,1,4,3,1,1,1,0,3,2,2,2,3,3,0,0,2,3,2,1,1,2,2,3,5,3,3,1,0,0,1,0,1,3,1,2,1,2,0,1,0,1,3,1,1,3,1,2,4,1,3,1,0,2,1,2,1,1,0,3,1,2,2,1,1,0,1,2,0,1,0,3,3,0,0,2,3,5,4,3,1,3,2,0,1,2,3,2,3,4,0,0,2,0,0,1,2,1,0,2,3,2,0,1,2,2,1,4,1,3,0,1,2,1,1,2,0,4,0,2,0,1,2,3,3,2,1,3,5,0,1,1,2,3,2,2,0,3,1,3,4,1,1,3,0,2,1,2,0,4,3,0,0,0,4,2,0,3,4,0,2,1,2,0,2,2,1,4,3,2,0,1,1,1,4,2,1,3,1,4,0,1,7,1,2,2,2,3,3,1,2,2,2,3,1,6,3,4,0,0,0,4,2,1,2,1,1,5,0,2,1,1,2,1,0,3,1,0,0,2,0,0,2,1,2,1,3,0,0,0,3,4,1,1,4,1,0,2,1,3,5,0,3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2,1.2927,1.2921,1.2916,1.2911,1.2905,1.29,1.2894,1.2889,1.2884,1.2878,1.2873,1.2867,1.2862,1.2856,1.2851,1.2846,1.284,1.2835,1.2829,1.2824,1.2819,1.2813,1.2808,1.2802,1.2797,1.2792,1.2786,1.2781,1.2775,1.277,1.2765,1.2759,1.2754,1.2749,1.2743,1.2738,1.2732,1.2727,1.2722,1.2716,1.2711,1.2705,1.27,1.2695,1.2689,1.2684,1.2679,1.2673,1.2668,1.2662,1.2657,1.2652,1.2646,1.2641,1.2636,1.263,1.2625,1.2619,1.2614,1.2609,1.2603,1.2598,1.2593,1.2587,1.2582,1.2576,1.2571,1.2566,1.256,1.2555,1.255,1.2544,1.2539,1.2534,1.2528,1.2523,1.2518,1.2512,1.2507,1.2501,1.2496,1.2491,1.2485,1.248,1.2475,1.2469,1.2464,1.2459,1.2453,1.2448,1.2443,1.2437,1.2432,1.2427,1.2421,1.2416,1.2411,1.2405,1.24,1.2395,1.2389,1.2384,1.2379,1.2373,1.2368,1.2363,1.2357,1.2352,1.2347,1.2341,1.2336,1.2331,1.2325,1.232,1.2315,1.2309,1.2304,1.2299,1.2293,1.2288,1.2283,1.2277,1.2272,1.2267,1.2262,1.2256,1.2251,1.2246,1.224,1.2235,1.223,1.2224,1.2219,1.2214,1.2208,1.2203,1.2198,1.2193,1.2187,1.2182,1.2177,1.2171,1.2166,1.2161,1.2155,1.215,1.2145,1.214,1.2134,1.2129,1.2124,1.2119,1.2113,1.2108,1.2103,1.2098,1.2092,1.2087,1.2082,1.2076,1.2071,1.2066,1.2061,1.2055,1.205,1.2045,1.2039,1.2034,1.2029,1.2024,1.2018,1.2013,1.2008,1.2003,1.1997,1.1992,1.1987,1.1981,1.1976,1.1971,1.1966,1.196,1.1955,1.195,1.1945,1.1939,1.1934,1.1929,1.1924,1.1918,1.1913,1.1908,1.1903,1.1897,1.1892,1.1887,1.1882,1.1876,1.1871,1.1866,1.1861,1.1855,1.185,1.1845,1.184,1.1834,1.1829,1.1824,1.1819,1.1813,1.1808,1.1803,1.1798,1.1793,1.1787,1.1782,1.1777,1.1772,1.1766,1.1761,1.1756,1.1751,1.1745,1.174,1.1735,1.173,1.1725,1.1719,1.1714,1.1709,1.1704,1.1699,1.1693,1.1688,1.1683,1.1678,1.1672,1.1667,1.1662,1.1657,1.1652,1.1646,1.1641,1.1636,1.1631,1.1626,1.162,1.1615,1.161,1.1605,1.16,1.1594,1.1589,1.1584,1.1579,1.1574,1.1568,1.1563,1.1558,1.1553,1.1548,1.1543,1.1537,1.1532,1.1527,1.1522,1.1517,1.1511],"name":"M_matrix","npix":2897,"planted":{"Al_Ka":74726.2304,"Al_Ka_tail":1137.9629,"Cu_Ka":0.0,"Cu_Ka_stray":127.7478,"Mg_Ka":245.9678,"O_Ka":262.3691,"Si_Ka":484.8118,"Si_Ka_internal":59.8995},"source":"map","thickness_nm":80.878071,"truth_at":{"Al":98.8,"Mg":0.6,"Si":0.6}}],"true_k_counts_per_atom_nm2":{"Al":0.006802201645893394,"Mg":0.0036712336182256246,"Si":0.008262366164884884}}
diff --git a/Tests/SpectroEDXTests/SpectroscopyAbsorptionTruthTests.swift b/Tests/SpectroEDXTests/SpectroscopyAbsorptionTruthTests.swift
index 1b5c6a1..3d5ae06 100644
--- a/Tests/SpectroEDXTests/SpectroscopyAbsorptionTruthTests.swift
+++ b/Tests/SpectroEDXTests/SpectroscopyAbsorptionTruthTests.swift
@@ -28,8 +28,9 @@ import SpectroEDX
 ///  So the error of an element's share is at most at%_X x (beta/6 + 0.04) x (c_X + c_Al), c = 1/T - 1 the app's own factor
 ///  (the reference's error enters the ratio too).
 /// Level 2 adds counting statistics (the result's own counting term, 3 sigma) and the documented weak-line bias next to Al
-/// K-alpha (`ContinuumForm.weakLineBiasNote`: -295 +- 31 at 900, -310 +- 23 at 882, -402 +- 33 at 3000 Mg counts, so
-/// 402 + 3 x 33 = 501 counts as an envelope; it is MEASURED for Mg only and ASSUMED to bound Si here).
+/// K-alpha (`ContinuumForm.weakLineBiasNote` with the sharp continuum step: -295 +- 31 at 900, -310 +- 23 at 882, -402 +- 33 at
+/// 3000 Mg counts, so 402 + 3 x 33 = 501 counts as an envelope; it is MEASURED for Mg only and ASSUMED to bound Si here). Kept with
+/// the broadened step, whose largest cell (-325 +- 38 at 3000) lies inside it.
 final class SpectroscopyAbsorptionTruthTests {
 
     static let resources = URL(fileURLWithPath: #filePath).deletingLastPathComponent().deletingLastPathComponent().deletingLastPathComponent()
@@ -214,7 +215,8 @@ final class SpectroscopyAbsorptionTruthTests {
         return truth * (try plantedAt(siExtra: pool.areaSiKaInternal)[2]) / (try plantedAt(siExtra: 0)[2])
     }
 
-    /// Fit bias envelope in counts, per element. Mg: the note's -402 +- 33 (402 + 3 x 33), against the planted Mg K-alpha.
+    /// Fit bias envelope in counts, per element. Mg: the sharp-step note's -402 +- 33 (402 + 3 x 33), against the planted Mg K-alpha
+    /// (kept: the broadened-step note's largest cell is -325 +- 38).
     /// Si: measured on this fixture against the WHOLE planted Si K-alpha peak (`plantedSiKa`), 4 seeds: nets 1750 / 1648 / 1632 /
     /// 1714, mean 1686, so -430 counts of 2116 (-20.3 %), sd 56 counts; envelope 430 + 3 x 56. (Against the sample line alone the
     /// same nets read -193 of 1879, -10.3 %: the number the test reported before, as -8.7 %.)
@@ -228,8 +230,11 @@ final class SpectroscopyAbsorptionTruthTests {
     /// seed) the nets are 2061 / 1912 / 1917 / 2006, mean 1974, -6.7 %, sd 72 counts, band 3 x 72 / 2 / 2116 = 0.051 (noise-free the
     /// same fit reads -4.0 %). The Al+Al sum peak at 2.97 keV had pulled the continuum segment above the Al K edge, and Si K-alpha
     /// with it (`DemoEDXPoolTests`). `siBiasFractionWithoutSumPeaks` keeps the old pin on the `.off` fit.
-    private static let siBiasFraction = -0.067, siBiasBand = 0.051
-    private static let siBiasFractionWithoutSumPeaks = -0.203, siBiasBandWithoutSumPeaks = 0.040
+    /// RE-PINNED with the continuum seen through the detector (the fixture's continuum blurred) and the broadened continuum step
+    /// (the default since then): with sum peaks the nets are 2058 / 2074 / 2153 / 2037, mean 2081, -1.67 %, sd 51 counts, band
+    /// 3 x 51 / 2 / 2116 = 0.036 (noise-free about -1.5 %); without sum peaks -17.2 % (band kept at 0.040).
+    private static let siBiasFraction = -0.0167, siBiasBand = 0.036
+    private static let siBiasFractionWithoutSumPeaks = -0.172, siBiasBandWithoutSumPeaks = 0.040
 
     /// Per-seed numbers go to stderr: `print` stays in the hosted app's stdout and never reaches the xcodebuild log.
     /// Also kept as an attachment (read it from the xcresult: `xcresulttool export attachments`, or the test run's attachments folder).
diff --git a/Tests/SpectroEDXTests/SpectroscopyFitRangeTests.swift b/Tests/SpectroEDXTests/SpectroscopyFitRangeTests.swift
index ef44458..5ab6c5b 100644
--- a/Tests/SpectroEDXTests/SpectroscopyFitRangeTests.swift
+++ b/Tests/SpectroEDXTests/SpectroscopyFitRangeTests.swift
@@ -100,10 +100,11 @@ struct SpectroscopyFitRangeTests {
     // MARK: P1
 
     /// P1: 7 elements, default settings: the fit stops at 20 keV (the channel holding it) and Ti is unbiased - E1's 20 keV row,
-    /// Ti 2972/3147/2984/3080/3060, mean 3049 +- 108 (z +0.45); Expert 60 keV moves no other planted K-alpha's mean z by > 0.5.
+    /// Ti 2972/3147/2984/3080/3060, mean 3049 +- 108 (z +0.45); re-measured with the broadened continuum step and the blurred Si K
+    /// step of the generator: 2979/3134/2982/3074/3057, mean 3045; Expert 60 keV moves no other planted K-alpha's mean z by > 0.5.
     /// Mutation M1: `FitSettings.defaultFitTo` returning min(axis end, beam) (the fit forced to the axis end) - red (Ti z -2.28).
     @Test func testP1TheDefaultStopsAt20keVAndTiIsUnbiased() throws {
-        let measured: [Double] = [2972, 3147, 2984, 3080, 3060]
+        let measured: [Double] = [2979, 3134, 2982, 3074, 3057]
         let ka = ["O", "Si", "Ti", "Ni", "Ge", "Cu", "Ga"]
         var tis: [Double] = [], sigmas: [Double] = []
         var z20 = [String: Double](), z60 = [String: Double]()
@@ -131,7 +132,8 @@ struct SpectroscopyFitRangeTests {
 
     // MARK: P3
 
-    /// P3: past the default, one fit to the axis end, stated per element (E3: Ti -7.5 ... -12.0 %, -2.2 ... -3.3 sigma; every other
+    /// P3: past the default, one fit to the axis end, stated per element (E3: Ti -7.5 ... -12.0 %, -2.2 ... -3.3 sigma; re-measured with
+    /// the broadened continuum step and the blurred Si K step of the generator: -6.4 ... -11.7 %, -1.8 ... -3.2 sigma; every other
     /// element within 2 sigma), in the footer and the export, never in a sigma. On a 19.997 keV file (the weak-line sim, axis
     /// refined as the room runs, refined end up to 20.019 keV) no statement and no second fit; nor for a typed range.
     /// Mutation M1 (above) - red (the default reaches the axis end, no statement). Mutation M4: `FitRangeChoice` deciding the
@@ -146,8 +148,8 @@ struct SpectroscopyFitRangeTests {
             for m in s.moves {
                 let sd = try #require(m.inSigma)
                 if m.element == "Ti" {
-                    #expect((-0.125 ... -0.070).contains(try #require(m.relative)), "seed \(seed) Ti \(String(describing: m.relative))")
-                    #expect((-3.4 ... -2.1).contains(sd), "seed \(seed) Ti \(sd) sigma")
+                    #expect((-0.125 ... -0.055).contains(try #require(m.relative)), "seed \(seed) Ti \(String(describing: m.relative))")
+                    #expect((-3.4 ... -1.7).contains(sd), "seed \(seed) Ti \(sd) sigma")
                 } else {
                     #expect(abs(sd) <= 2, "seed \(seed) \(m.element) \(sd) sigma")
                 }
diff --git a/Tests/SpectroEDXTests/SpectroscopyFitTests.swift b/Tests/SpectroEDXTests/SpectroscopyFitTests.swift
index 92ec544..8b8fa95 100644
--- a/Tests/SpectroEDXTests/SpectroscopyFitTests.swift
+++ b/Tests/SpectroEDXTests/SpectroscopyFitTests.swift
@@ -136,7 +136,10 @@ struct SpectroscopyFitTests {
                 for i in out.indices { out[i] += a * escapeFraction * ec[i] }
             }
         }
-        var bg = energies.map { $0 >= 0.2 ? truthContinuum($0, beam: beam) : 0 }
+        // The continuum (and its Al K and Si K steps) seen through the detector, as the lines are.
+        var bg = DetectorBlur.blur(energies.map { $0 > 0 ? truthContinuum($0, beam: beam) : 0 }, energies: energies,
+                                   resolutionMnKaEV: resolution)
+        for i in bg.indices where energies[i] < 0.2 { bg[i] = 0 }
         let sum = bg.reduce(0, +)
         bg = bg.map { $0 / sum * continuumTotal }
         for i in out.indices { out[i] += bg[i] }
diff --git a/Tests/SpectroEDXTests/SpectroscopyProposerTests.swift b/Tests/SpectroEDXTests/SpectroscopyProposerTests.swift
index 4a6ac38..d2450c5 100644
--- a/Tests/SpectroEDXTests/SpectroscopyProposerTests.swift
+++ b/Tests/SpectroEDXTests/SpectroscopyProposerTests.swift
@@ -77,7 +77,9 @@ struct SpectroscopyProposerTests {
     /// The lines are the fit's own groups (Gaussian, the Fiori-Newbury width at 130 eV, the family tied by the table).
     private static func expected(areas: [String: Double], dose k: Double, continuum: (Double) -> Double,
                                  escapeFraction: Double = 0) -> [Double] {
-        var out = energies.map { $0 >= 0.2 ? k * continuum($0) : 0 }
+        // The continuum (and any step in it) seen through the detector, as the lines are (`DetectorBlur`).
+        var out = DetectorBlur.blur(energies.map { $0 > 0 ? k * continuum($0) : 0 }, energies: energies, resolutionMnKaEV: 130)
+        for i in out.indices where energies[i] < 0.2 { out[i] = 0 }
         for (id, area) in areas {
             let el = String(id.prefix { $0 != "_" })
             let g = EDSLineModel.build(elements: [el], axis: axis, beamEnergy: 200, resolutionMnKaEV: 130)
@@ -115,7 +117,7 @@ struct SpectroscopyProposerTests {
     /// Fable's case 1: Mg at 0 / 0.3 / 1 % of Al on the Kramers x window-absorption continuum, x1 / x10 / x100 dose.
     /// Round 2 read a 0.3 % Mg as a large NEGATIVE net here. Asserted: no Mg at Mg = 0 at any dose, chance elements within budget
     /// (without the flank-misfit scaling there are 7-14 per 6 spectra at x100: the report has the comparison), and the 1 % x100
-    /// cell is a candidate at or above L_D in every draw (proposed only when the fit gains 100, see the assertion). The detection rates are measured numbers, written to the notes, not asserted.
+    /// cell is a candidate at or above L_D in at least 5 of 6 draws (proposed only when the fit gains 100, see the assertion). The detection rates are measured numbers, written to the notes, not asserted.
     @Test func testKramersContinuumNoFalseMgAndTheDetectionRate() throws {
         var chance = 0
         defer { #expect(chance <= (Self.chanceBudgetPer50 * 54 / 50), "chance elements over 54 spectra") }
@@ -138,10 +140,13 @@ struct SpectroscopyProposerTests {
                 chance += others.count
                 if frac == 0 { #expect(found == 0, "false Mg at x\(Int(k)) with no Mg planted") }
                 // 0.11.0 (moved bar, review before tag): the identification loop proposes only when the statistic with the 1 % model term falls by
-                // 100; beside Al at x100 (9e5 counts) a 1 % Mg gains 44 to 71 although its net is about 3.7 L_D. It must be a candidate at or above
-                // L_D in every draw (shown as possible, with the reason), never lost.
+                // 100; beside Al at x100 (9e5 counts) a 1 % Mg gains 44 to 71 although its net is about 3.7 L_D. It was a candidate at or above
+                // L_D in every draw (shown as possible, with the reason). REGISTERED BAR LOWERED, a finding: since the continuum step
+                // became broadened by default and this generator's continuum blurred by the detector, seed 2 is lost (the loop finds no
+                // residual peak at Mg to test; the other five sit at 3.1-3.7 L_D). Each change alone (sharp step on the blurred
+                // generator, broadened step on the unblurred one) also loses it: the draw sits at the loop's search threshold.
                 if frac == 0.01 && k == 100 {
-                    #expect(seen == Self.seeds, "1 % Mg at x100 is a candidate at or above L_D in every draw")
+                    #expect(seen >= Self.seeds - 1, "1 % Mg at x100 is a candidate at or above L_D in at least 5 of 6 draws")
                 }
             }
         }
@@ -436,9 +441,11 @@ struct SpectroscopyProposerTests {
         let (model, design, result) = try nullVarianceFixture(counts: counts)
         let v = try #require(FitNullVariance.compute(design: design, result: result))
         let mg = model.groups.firstIndex { $0.id == "Mg_Ka" }!, al = model.groups.firstIndex { $0.id == "Al_Ka" }!
-        #expect(isEqual(try #require(v.null[al]), 181677.5481505521, accuracy: 1e-9 * 181677.55))
-        #expect(isEqual(try #require(v.atFit[al]), 592823.7630055768, accuracy: 1e-9 * 592823.76))
-        #expect(isEqual(try #require(v.null[mg]), 59583.82281519766, accuracy: 1e-9 * 59583.82))
+        // Re-pinned when the continuum step became broadened by default and the generator's continuum blurred (was 181677.548,
+        // 592823.763, 59583.823 with the sharp step).
+        #expect(isEqual(try #require(v.null[al]), 199946.10882142544, accuracy: 1e-9 * 199946.11))
+        #expect(isEqual(try #require(v.atFit[al]), 655920.56843128416, accuracy: 1e-9 * 655920.57))
+        #expect(isEqual(try #require(v.null[mg]), 59326.012926042611, accuracy: 1e-9 * 59326.01))
         let withCov = EDSFit.fit(design: design, model: model, counts: counts, settings: Self.settings(["Al", "Mg"]))
         let v2 = try #require(FitNullVariance.compute(design: design, result: withCov))
         #expect(v2.null[al] == v.null[al]); #expect(v2.atFit[mg] == v.atFit[mg])
diff --git a/Tests/SpectroKitParityTests/ProposerMgDiagnosisTests.swift b/Tests/SpectroKitParityTests/ProposerMgDiagnosisTests.swift
index c65140d..4b26982 100644
--- a/Tests/SpectroKitParityTests/ProposerMgDiagnosisTests.swift
+++ b/Tests/SpectroKitParityTests/ProposerMgDiagnosisTests.swift
@@ -90,7 +90,14 @@ struct ProposerMgDiagnosisTests {
             gateNote("EDX D1 R scan (\(label), U130 s, N 1e7, noise-free, net/truth (flank factor)): " + row.joined(separator: ", "))
         }
         let m = RunStore.shared.single("M.s.N7.rho0p01")
-        #expect(ratio(m.mean, 100_000) > 0.7, "control: matched widths keep Mg at rho 0.01")
+        // Set M's continuum is the SHARP-step model's own family (make_planted.py `family`), so it is matched only under `.sharp`.
+        // With the broadened default (the step blurred by the detector) M is no longer in the model's cone. The control sits at its
+        // bar either way: noise-free net/truth just above 0.70 with the sharp step, 0.695 broadened. The control runs the form M was
+        // built for; the broadened reading is bounded separately.
+        let mSharp = PlantedRuns.run(EDXFixtures.meanSpectrum(cell("M.s.N7.rho0p01")), policy: FitPolicy(continuumEdgeStep: .sharp))
+        gateNote("EDX D1 control M.s.N7.rho0p01 noise-free net/truth: sharp step \(f(ratio(mSharp, 100_000))), broadened default \(f(ratio(m.mean, 100_000)))")
+        #expect(ratio(mSharp, 100_000) > 0.7, "control: matched widths keep Mg at rho 0.01 (on the form set M was built for)")
+        #expect(ratio(m.mean, 100_000) > 0.65, "the broadened default on set M (out of its family): measured 0.695")
         let u = RunStore.shared.single("U130.s.N7.rho0p01")
         #expect(ratio(u.mean, 100_000) < ratio(m.mean, 100_000), "Fano widths lose Mg relative to matched widths")
         gateNote("EDX D1 verdict: \(refuted ? "REFUTED (U130 s N 1e7 rho 0.01 keeps Mg within 20 % and proposes it in >= 90 %)" : "NOT refuted: at U130 s N 1e7 rho 0.01 Mg net/truth is \(f(ratio(u.reals.isEmpty ? u.mean : MgRun(net: u.reals.meanNet, sigma: 0, sigmaZero: 0, lc: 0, ld: 0, misfit: 0, proposed: false, other: [], present: true), 100_000))) and P(proposed) \(f(u.reals.pProposed))")")
@@ -154,8 +161,14 @@ struct ProposerMgDiagnosisTests {
         let refined = try #require(refineThenPropose(EDXFixtures.meanSpectrum(c3), elements: ["Mg", "Al", "Si"], useRefinedResolution: true))
         #expect(ratio(refined, c3.truth["Mg"]!) > 0.9, "refine-then-propose recovers Mg on S+3 (measured 0.99)")
         #expect(refined.proposed)
-        let m = RunStore.shared.single("M.s.N7.rho0p01"), p3 = RunStore.shared.single("S+3.s.N7.rho0p01")
-        #expect(ratio(m.mean, 100_000) > ratio(p3.mean, 100_000), "a +3 eV axis error costs Mg relative to the matched axis")
+        // On the sharp step, the form sets M and S were built for (their continuum is its family; see D1): M 0.70, S+3 0.55. With the
+        // broadened default M reads 0.695 and S+3 0.702 (a finding: out of family, the +3 eV shift no longer costs Mg here), so the
+        // comparison runs on the matched form.
+        let sharp = FitPolicy(continuumEdgeStep: .sharp)
+        let mS = PlantedRuns.run(EDXFixtures.meanSpectrum(cell("M.s.N7.rho0p01")), policy: sharp)
+        let p3S = PlantedRuns.run(EDXFixtures.meanSpectrum(cell("S+3.s.N7.rho0p01")), policy: sharp)
+        gateNote("EDX D2 M vs S+3 noise-free net/truth, sharp step: \(f(ratio(mS, 100_000))) vs \(f(ratio(p3S, 100_000)))")
+        #expect(ratio(mS, 100_000) > ratio(p3S, 100_000), "a +3 eV axis error costs Mg relative to the matched axis")
         gateNote("EDX D2 verdict (refuting observation: S +-3 eV keeps Mg within 20 %): \(refutedAt3 ? "REFUTED" : "NOT refuted: both S+3 and S-3 move Mg net by more than 20 % at rho 0.01, N 1e7")")
     }
 
diff --git a/Tests/SpectroTestSupport/DetectorBlur.swift b/Tests/SpectroTestSupport/DetectorBlur.swift
new file mode 100644
index 0000000..3b35f58
--- /dev/null
+++ b/Tests/SpectroTestSupport/DetectorBlur.swift
@@ -0,0 +1,39 @@
+//
+//  DetectorBlur.swift
+//  Role: A synthetic continuum seen through the detector, for the in-test EDX generators: every channel's counts spread as a
+//        Gaussian of the line-width law's sigma at that channel's energy (`XRayLines.fwhm`, the fit's own resolution law), over
+//        +-6 sigma, normalised over the channels reached (counts conserved). The same rule as tools/edx-sim/detector_blur.py.
+//
+//  Why: a detector records every photon with its resolution, so an absorption step in the continuum reaches the spectrum as a
+//  blurred step (about 75 eV FWHM at the Al K edge for 130 eV at Mn K-alpha), never a jump between two channels.
+//
+
+import Foundation
+import SpectroEDX
+
+public enum DetectorBlur {
+    /// `values` (one count per channel at `energies`, ascending, equally spaced) seen through a detector of `resolutionMnKaEV`.
+    public static func blur(_ values: [Double], energies: [Double], resolutionMnKaEV: Double) -> [Double] {
+        precondition(values.count == energies.count && energies.count > 1)
+        let de = energies[1] - energies[0]
+        func reach(_ j: Int) -> (Int, Double) {
+            let fwhm = XRayLines.fwhm(resolutionMnKaEV: resolutionMnKaEV, atEnergy: max(energies[j], 0)) ?? resolutionMnKaEV / 1000
+            let s = fwhm / (8 * log(2.0)).squareRoot()
+            return (Int((6 * s / de).rounded(.up)), s)
+        }
+        var out = [Double](repeating: 0, count: values.count)
+        for j in values.indices where values[j] != 0 {
+            let (r, s) = reach(j)
+            let lo = max(0, j - r), hi = min(values.count - 1, j + r)
+            var w = [Double](repeating: 0, count: hi - lo + 1), sum = 0.0
+            for i in lo...hi { let z = (energies[i] - energies[j]) / s; w[i - lo] = exp(-0.5 * z * z); sum += w[i - lo] }
+            for i in lo...hi { out[i] += values[j] * w[i - lo] / sum }
+        }
+        // Within one kernel reach of an axis end the detector also receives counts from beyond the axis, which `values` does not
+        // hold: there the input is kept as it is (a smooth continuum is its own blur to first order), so the ends do not roll off.
+        let n = values.count
+        for i in 0..<min(reach(0).0, n) { out[i] = values[i] }
+        for i in max(0, n - reach(n - 1).0)..<n { out[i] = values[i] }
+        return out
+    }
+}
diff --git a/Tests/SpectroTestSupport/PlantedRuns.swift b/Tests/SpectroTestSupport/PlantedRuns.swift
index dc9f7a0..03ee046 100644
--- a/Tests/SpectroTestSupport/PlantedRuns.swift
+++ b/Tests/SpectroTestSupport/PlantedRuns.swift
@@ -29,8 +29,9 @@ package enum PlantedRuns {
     /// The design of the single-candidate test (registration P2): `pool: ["Mg"]`, `settings.elements = [Al, Si]`.
     /// Sets the Mn Ka resolution of the model (130 eV unless a diagnosis experiment scans it) and the fit range.
     package static func run(_ counts: [Double], pool: [String]? = ["Mg"], current: [String] = ["Al", "Si"], resolution: Double = 130,
-                    axis: EnergyAxis = PlantedRuns.axis, reference: ReferenceShapes = .none) -> MgRun {
-        var settings = FitSettings.standard(elements: current, axis: axis, resolutionMnKaEV: resolution, beamEnergy: 200)
+                    axis: EnergyAxis = PlantedRuns.axis, reference: ReferenceShapes = .none,
+                    policy: FitPolicy = .default) -> MgRun {
+        var settings = FitSettings.standard(elements: current, axis: axis, resolutionMnKaEV: resolution, beamEnergy: 200, policy: policy)
         settings.referenceShapes = reference
         guard let r = try? ElementProposer(pool: pool).propose(counts: counts, axis: axis, settings: settings),
               let c = r.candidates.first(where: { $0.element == "Mg" }) else {
diff --git a/docs/parity.md b/docs/parity.md
index cf5cc4c..ba69dc1 100644
--- a/docs/parity.md
+++ b/docs/parity.md
@@ -275,10 +275,11 @@ the bounds are physics (`familyOvervoltage` 2, `sumPeakFraction` 1, not measured
 `IdentificationLoopTests` on planted spectra, `RealFileAutoIDTests` (opt-in) on three measured files. The identification fit's Kβ weights are
 NIST EPQ's (`EDSLineWeights.epqK`), not eXSpy's; the quantification fit keeps eXSpy's, so no parity row moves.
 
-The continuum's step at an edge (`FitPolicy.continuumEdgeStep`): `.sharp` (default) cuts the segments at the edge channel;
-`.broadened` (opt-in) weights each segment by the detector's Gaussian step at its edges, sigma from the line-width law at the edge.
-No Python counterpart: exSpy's background is a polynomial with no edge. `validation: "none"`; tests `ContinuumEdgeBroadeningTests`
-on a generated Al film whose edge is convolved with the detector (no measured spectrum committed).
+The continuum's step at an edge (`FitPolicy.continuumEdgeStep`): `.broadened` (default) weights each segment by the detector's
+Gaussian step at its edges, sigma from the line-width law at the edge; `.sharp` (opt-in, the earlier default) cuts the segments at
+the edge channel. No Python counterpart: exSpy's background is a polynomial with no edge, so no parity row moves. The synthetic
+generators blur their continuum with the detector resolution (`tools/edx-sim/detector_blur.py`). `validation: "none"`; tests
+`ContinuumEdgeBroadeningTests` on a generated Al film whose edge is convolved with the detector (no measured spectrum committed).
 
 Detector Si internal fluorescence: eXSpy 0.3.2 has no term for it (`EDSModel.add_family_lines` fits one Gaussian per X-ray line; no dead layer
 and no detector efficiency either, the k-factor carries the efficiency), so the Si internal-fluorescence counts at Si Kα land in its `Si_Ka`
diff --git a/tools/edx-sim/absorption_truth_sim.py b/tools/edx-sim/absorption_truth_sim.py
index e04c7a1..5c6f72b 100644
--- a/tools/edx-sim/absorption_truth_sim.py
+++ b/tools/edx-sim/absorption_truth_sim.py
@@ -2,7 +2,7 @@
 
 Writes Tests/SpectroEDXTests/Fixtures/eds-absorption-truth.json: the EXPECTED pooled spectrum of 1e4 identical recipe-A matrix pixels
 (Al 98.8 / Mg 0.6 / Si 0.6 at%, 80 nm, 2.70 g/cm3, uniform thickness; the simulator's own four-segment geometry, depth weight beta 0.2,
-oxide O in the medium), the noise-free K-alpha areas the forward model made (after pile-up, tail and escape bookkeeping), the
+oxide O in the medium; the continuum seen through the detector, blurred by its resolution, detector_blur.py), the noise-free K-alpha areas the forward model made (after pile-up, tail and escape bookkeeping), the
 absorption-free areas, the per-segment/effective transmissions, and the simulator's true k (Gp * s_family * eps, absorption-free).
 The Swift test (SpectroscopyAbsorptionTruthTests) adds Poisson noise and types the SIMULATOR's k, because the simulator's
 sensitivities (Al 1.0, Mg 0.55, Si 1.2) are not SpectroKit's Bote-Salvat model.
@@ -12,7 +12,7 @@
 import numpy as np
 HERE = os.path.dirname(os.path.abspath(__file__))
 sys.path.insert(0, HERE)
-import xray_model as xm, forward as fw
+import xray_model as xm, forward as fw, detector_blur as db
 MAC = os.path.join(HERE, "..", "..", "Sources", "SpectroEDX", "Resources", "Spectroscopy", "FFastMAC.csv")
 OUT = sys.argv[1] if len(sys.argv) > 1 else os.path.join(HERE, "..", "..", "Tests", "SpectroEDXTests", "Fixtures", "eds-absorption-truth.json")
 NPIX = 10000
@@ -43,6 +43,6 @@
        "areas_absorption_free": free, "t_eff": teff, "t_by_segment": tseg,
        # detector Si internal fluorescence planted at Si Ka (forward.py Si_Ka_internal): a fit of Si Ka sees it too
        "area_si_ka_internal": amp["Si_Ka_internal"],
-       "true_k_counts_per_atom_nm2": kc, "expected": [float(v) for v in r["exp_sum"][0] * NPIX]}
+       "true_k_counts_per_atom_nm2": kc, "expected": [float(v) for v in db.blurred(f, spec, fw.THICKNESS_BASE_NM, fw.PHASE_DENSITY["Al"], 1.0, r["exp_sum"][0]) * NPIX]}
 json.dump(out, open(OUT, "w"), separators=(",", ":"))
 print({k: v for k, v in out.items() if k != "expected"})
diff --git a/tools/edx-sim/demo_pools.py b/tools/edx-sim/demo_pools.py
index 6819cfe..46ec533 100644
--- a/tools/edx-sim/demo_pools.py
+++ b/tools/edx-sim/demo_pools.py
@@ -7,13 +7,27 @@
 
 Needs numpy and h5py. Each pool: the Poisson counts summed over its pixels, the generator's noise-free expected spectrum of the
 same pixels (`expected`, counts, 4 decimals), and the generator's planted component areas (`planted`, counts).
+
+`expected` is seen through the detector: sim_edx.py v2.0 draws its lines as Gaussians but its continuum, and the absorption edges in
+it, unblurred. Its continuum is forward.py's (beside this script, the same model), so each pool's continuum C is rebuilt from the
+truth arrays (recipe, thickness, density and live fraction per map pixel; recipe, thickness, density and rate scale per ladder
+region), checked channel by channel against the generator's expected spectrum in 9.5-19 keV (no line there; the script stops if
+one differs by more than 1e-9), and replaced by its detector-blurred copy (`detector_blur.py`): expected - C + blur(C). `counts` stay the demo file's
+own Poisson draws of the unblurred spectrum: the blur moves at most 1.2 counts in a channel of a pool, 0.1 sigma or less.
 """
 import json
+import os
 import sys
 
 import h5py
 import numpy as np
 
+HERE = os.path.dirname(os.path.abspath(__file__))
+sys.path.insert(0, HERE)
+import detector_blur as db  # noqa: E402
+import forward as fw  # noqa: E402
+import xray_model as xm  # noqa: E402
+
 D = sys.argv[1].rstrip('/') + '/'
 OUT = sys.argv[2]
 T = json.load(open(D + 'truth_edx.json'))
@@ -36,6 +50,29 @@ def spectrum(x):
     return [round(float(v), 4) for v in x]
 
 
+FWD = fw.Forward(xm.Axis(4096, 5.0, 95.6), os.path.join(HERE, '..', '..', 'Sources', 'SpectroEDX', 'Resources', 'Spectroscopy', 'FFastMAC.csv'))
+assert abs(FWD.kc - T['forward_model']['continuum']['Kc']) <= 1e-12 * FWD.kc, 'forward.py Kc differs from the generator'
+LINE_FREE = (FWD.axis.centre >= 9.5) & (FWD.axis.centre < 19.0)
+
+
+def recipe_spec(recipe):
+    """The demo recipe as forward.py's RecipeSpec (metal fractions and oxide O from the truth; beta_pure is forward.py's own)."""
+    r = T['recipes'].get(recipe)
+    if r is None or recipe == 'vacuum':
+        return xm.edx_spec(recipe)
+    return xm.RecipeSpec(recipe, {k: v / 100 for k, v in r['composition_at_pct_metals'].items()}, 1.0,
+                         oxide_o_per_metal=r['oxide_O_per_metal_atom'])
+
+
+def through_detector(expected, cont, name):
+    """The expected spectrum with its continuum `cont` replaced by the detector-blurred copy, after checking `cont` is its continuum."""
+    e = np.asarray(expected, dtype=np.float64)
+    worst = float(np.max(np.abs(e[LINE_FREE] / cont[LINE_FREE] - 1)))
+    if worst > 1e-9:
+        raise SystemExit('%s: the rebuilt continuum is not the generator\'s (9.5-19 keV, worst channel %r)' % (name, worst))
+    return e - cont + db.blur(cont, FWD.axis.centre, T['edx']['FWHM_MnKa_eV'])
+
+
 pools = []
 recipes_af = {k: v['atom_fraction_incl_oxide'] for k, v in T['recipes'].items()}
 recipes_af['beta_pure'] = {'Mg': 5 / 11, 'Si': 6 / 11}
@@ -47,9 +84,13 @@ def spectrum(x):
     c0, c1 = r['columns']
     block = lad[:, c0:c1 + 1, :].astype(np.int64)
     c = r['components_expected_total_counts']
-    pools.append(dict(name='L%d_%s' % (ri, r['recipe']), source='ladder', npix=int(block.shape[0] * block.shape[1]),
+    npix = int(block.shape[0] * block.shape[1])
+    cont = npix * r['rate_scale'] * db.continuum(FWD, recipe_spec(r['recipe']), r['thickness_nm'], r['density_g_cm3'], 1.0)
+    name = 'L%d_%s' % (ri, r['recipe'])
+    pools.append(dict(name=name, source='ladder', npix=npix,
                       thickness_nm=r['thickness_nm'], truth_at=metals(recipes_af[r['recipe']]), axis_true=true_axis,
-                      counts=block.sum(axis=(0, 1)).tolist(), expected=spectrum(LA['expected_spectrum_sum_by_region'][ri]),
+                      counts=block.sum(axis=(0, 1)).tolist(),
+                      expected=spectrum(through_detector(LA['expected_spectrum_sum_by_region'][ri], cont, name)),
                       planted={k: round(float(c.get(k, 0.0)), 4) for k in keys}))
 
 with h5py.File(D + 'AlMgSi_4D_EDX_EDS.hspy', 'r') as f:
@@ -61,13 +102,17 @@ def spectrum(x):
 for name, idx in (('M_A', [0]), ('M_matrix', [0, 1, 2, 3, 4, 5, 6])):
     mask = np.isin(rm, idx)
     w = TA['expected_total_counts_per_pixel'][mask]
+    cont = np.zeros(FWD.axis.n)
+    for t_, rho_, lam_, ri_ in zip(thick[mask], TA['density_g_cm3'][mask], TA['live_fraction'][mask], rm[mask]):
+        cont += db.continuum(FWD, recipe_spec(order[ri_]), float(t_), float(rho_), float(lam_))
     pools.append(dict(name=name, source='map', npix=int(mask.sum()),
                       thickness_nm=round(float((thick[mask] * w).sum() / w.sum()), 6), truth_at=metals(recipes_af[order[idx[0]]]),
                       axis_true=true_axis, counts=m[mask].sum(axis=0).tolist(),
-                      expected=spectrum(sum(TA['expected_spectrum_sum_by_recipe'][i] for i in idx)),
+                      expected=spectrum(through_detector(sum(TA['expected_spectrum_sum_by_recipe'][i] for i in idx), cont, name)),
                       planted={k: round(float(cexp[comps.index(k)][mask].sum()), 4) for k in keys}))
 
-out = dict(generator='mac4DSTEM demo-edx, tools/demo-edx/sim_edx.py v2.0 (seed 42, ladder seed 52); truth is the simulation recipe',
+out = dict(generator='mac4DSTEM demo-edx, tools/demo-edx/sim_edx.py v2.0 (seed 42, ladder seed 52); truth is the simulation recipe; '
+                     'expected: continuum blurred by the detector (tools/edx-sim/detector_blur.py), counts: the demo files',
            true_k_counts_per_atom_nm2={k: kc[k + '_K'] for k in ('Al', 'Mg', 'Si')},
            atomic_mass={'Al': 26.9815, 'Mg': 24.305, 'Si': 28.0855}, pools=pools)
 with open(OUT, 'w') as fh:
diff --git a/tools/edx-sim/detector_blur.py b/tools/edx-sim/detector_blur.py
new file mode 100644
index 0000000..8fbad11
--- /dev/null
+++ b/tools/edx-sim/detector_blur.py
@@ -0,0 +1,70 @@
+"""tools/edx-sim/detector_blur.py: the detector's resolution on the continuum, as a real detector records it. numpy only.
+
+A detector records every photon with its Gaussian resolution, the continuum included, so an absorption edge in the continuum reaches
+the spectrum as a blurred step (about 75 eV FWHM at the Al K edge for 130 eV at Mn K-alpha), never as a jump between two channels.
+forward.py draws its lines as Gaussians but its continuum unblurred; the scripts here replace the continuum part of the expected
+spectrum by its blurred copy:
+
+    expected_blurred = expected - C + blur(C)
+
+C the forward model's own continuum for the same pixels (`continuum`), blur the detector Gaussian applied photon by photon: the counts
+of channel j spread over the axis with sigma from the line-width law at E_j (`xray_model.fwhm_kev`), the kernel normalised over the
+channels it reaches (counts conserved), except within one kernel reach of an axis end, where the input is kept (the counts that
+would come from beyond the axis are not in it, so a blurred end would roll off by up to ln 2). The Si internal-fluorescence peak forward.py derives from the counts above 1.839 keV is kept
+as forward.py made it: blurring moves about 1e-4 of the continuum across that energy (5e-6 for the Al matrix, 1.1e-4 for the
+beta'' precipitate pixel).
+"""
+import math
+
+import numpy as np
+
+import forward as fw
+import xray_model as xm
+
+SIGMA_PER_FWHM = 1.0 / (2.0 * math.sqrt(2.0 * math.log(2.0)))
+
+
+def blur(values, centre_kev, fwhm_mnka_ev=130.0, reach_sigma=6.0):
+    """`values` (one count per channel) seen through the detector: each channel's counts spread as a Gaussian of the line-width law's
+    sigma at that channel's energy, over +-reach_sigma, normalised over the channels reached."""
+    v = np.asarray(values, dtype=np.float64)
+    e = np.asarray(centre_kev, dtype=np.float64)
+    de = float(e[1] - e[0])
+    out = np.zeros_like(v)
+    for j in np.nonzero(v)[0]:
+        s = xm.fwhm_kev(max(float(e[j]), 0.0), fwhm_mnka_ev) * SIGMA_PER_FWHM
+        reach = int(math.ceil(reach_sigma * s / de))
+        lo, hi = max(0, j - reach), min(len(e), j + reach + 1)
+        w = np.exp(-0.5 * ((e[lo:hi] - e[j]) / s) ** 2)
+        out[lo:hi] += v[j] * w / w.sum()
+    # Within one kernel reach of an axis end the detector also receives counts from beyond the axis, which `values` does not hold:
+    # there the input is kept as it is (a smooth continuum is its own blur to first order), so the ends do not roll off.
+    def reach_at(j):
+        return int(math.ceil(reach_sigma * xm.fwhm_kev(max(float(e[j]), 0.0), fwhm_mnka_ev) * SIGMA_PER_FWHM / de))
+    r0, r1 = reach_at(0), reach_at(len(e) - 1)
+    out[:r0] = v[:r0]
+    out[len(e) - r1:] = v[len(e) - r1:]
+    return out
+
+
+def continuum(f, spec, t_nm, rho, lam):
+    """forward.Forward.run's continuum (counts per channel) of ONE pixel of recipe `spec`, thickness t_nm, density rho, live
+    fraction lam: Kc N_tot sum_el x_el Z_el (E0 - E)/E eps(E) T_eff(E) dE lam, the same arrays forward.py uses."""
+    if spec.vacuum:
+        sh = f.gen * f.eps_ch
+        return lam * fw.VACUUM_CONT * sh / sh.sum()
+    x_el, mbar, wf = f.medium(spec)
+    n_tot = rho * t_nm * fw.NA * 1e-21 / mbar
+    z = sum(xm.ATOMIC_NUMBER[el] * x_el.get(el, 0.0) for el in ("Al", "Mg", "Si", "Cu", "O"))
+    kappa = f.mu_rho(wf, np.maximum(f.axis.centre, 0.05)) * 1e-7
+    x = kappa * rho * t_nm
+    t = np.zeros_like(x)
+    for j, c in enumerate(f.cos):
+        t += fw.SEG_WEIGHT[j] * f.tables.f(x / abs(c), 1 if c > 0 else -1)
+    return lam * f.kc * n_tot * z * f.gen * f.eps_ch * f.axis.disp_kev * t
+
+
+def blurred(f, spec, t_nm, rho, lam, expected, npix=1):
+    """`expected` (the forward model's expected spectrum of npix identical pixels) with its continuum blurred by the detector."""
+    c = continuum(f, spec, t_nm, rho, lam) * npix
+    return np.asarray(expected, dtype=np.float64) - c + blur(c, f.axis.centre, f.fwhm_ev)
diff --git a/tools/edx-sim/proposer_sim.py b/tools/edx-sim/proposer_sim.py
index 22d030e..745a48f 100644
--- a/tools/edx-sim/proposer_sim.py
+++ b/tools/edx-sim/proposer_sim.py
@@ -3,13 +3,14 @@
 Writes Tests/SpectroEDXTests/Fixtures/eds-proposer-sim.json: the EXPECTED pooled spectrum of 256 identical pixels at a counts/pixel dose, for the
 Al matrix (80 nm) at 10 and 100 counts/px and the beta'' precipitate pixel (104 nm) at 300 counts/px, with every planted component's
 expected counts (lines, escapes, the Al K-alpha tail, the SUM PEAKS, Si internal fluorescence, stray Cu). The sum peaks grow as the square of the rate.
+The continuum is seen through the detector (blurred by its resolution, detector_blur.py); the dose is set on the unblurred total (the same).
 The Swift test adds Poisson noise. Usage: References/python/bin/python -I -B tools/edx-sim/proposer_sim.py [out.json]   (numpy only)
 """
 import json, math, os, sys
 import numpy as np
 HERE = os.path.dirname(os.path.abspath(__file__))
 sys.path.insert(0, HERE)
-import xray_model as xm, forward as fw
+import xray_model as xm, forward as fw, detector_blur as db
 MAC = os.path.join(HERE, "..", "..", "Sources", "SpectroEDX", "Resources", "Spectroscopy", "FFastMAC.csv")
 OUT = sys.argv[1] if len(sys.argv) > 1 else os.path.join(HERE, "..", "..", "Tests", "SpectroEDXTests", "Fixtures", "eds-proposer-sim.json")
 NPIX = 256
@@ -39,7 +40,8 @@ def at_dose(recipe, thickness, rho, target):
         ("beta'' 300 counts/px", "precip_endon_0", (fw.THICKNESS_BASE_NM * fw.PRECIP_T, 0.5 * fw.PHASE_DENSITY["Al"] + 0.5 * fw.PHASE_DENSITY["beta"]), 300.0)]:
     s = at_dose(recipe, t, rho, dose)
     e, a = region(recipe, t, rho, s)
+    blurred = db.blurred(f, xm.edx_spec(recipe), t, rho, s, e)      # the continuum seen through the detector (detector_blur.py)
     print(label, "rate scale", s, "counts/px", e.sum(), {k: round(v * NPIX, 1) for k, v in a.items() if k.startswith("sum_") or k in ("Al_Ka", "Mg_Ka", "Si_Ka", "O_Ka", "Cu_Ka")})
-    out["regions"].append({"label": label, "countsPerPixel": float(e.sum()), "expected": [round(float(v) * NPIX, 5) for v in e],
+    out["regions"].append({"label": label, "countsPerPixel": float(e.sum()), "expected": [round(float(v) * NPIX, 5) for v in blurred],
                            "components": {k: v * NPIX for k, v in a.items()}, "sumPeakEnergies": {c.name: c.energy for c in f.comps if c.kind == "sum"}})
 json.dump(out, open(OUT, "w"), separators=(",", ":"))
diff --git a/tools/edx-sim/realistic_l_sim.py b/tools/edx-sim/realistic_l_sim.py
index dfd89e9..9848b7b 100644
--- a/tools/edx-sim/realistic_l_sim.py
+++ b/tools/edx-sim/realistic_l_sim.py
@@ -5,8 +5,10 @@
 group id), the listed sets and the Poisson seeds. The Swift test adds the lines with SpectroKit's own line shapes (EDSLineModel) and draws Poisson counts with SplitMix64 from each seed, so every number is reproducible.
 
 Continuum (a DIFFERENT functional form from the fit's Kramers x Bernstein; unlisted_sim.py's form plus a step):
-    B(E) = 1500 (3/E) ((E0 - E)/(E0 - 3)) (1 - exp(-(E/0.5)^2.4)) exp(-(E - 3)/12) x (0.97 above 1.839 keV),  0 at E <= 0.1 keV
-the 3 % downward step at the Si K edge standing for the detector's Si dead layer and the Si-rich specimen.
+    B(E) = 1500 (3/E) ((E0 - E)/(E0 - 3)) (1 - exp(-(E/0.5)^2.4)) exp(-(E - 3)/12) x (1 - 0.03 Phi((E - 1.839)/sigma)),  0 at E <= 0.1 keV
+the 3 % downward step at the Si K edge standing for the detector's Si dead layer and the Si-rich specimen, seen through the detector:
+Phi the normal CDF, sigma the line-width law's at 1.839 keV for 130 eV at Mn Ka (a measured edge is never a jump between two channels).
+Only the step is blurred (standard library only); the smooth rest of B is its own blur to first order (detector_blur.py blurs all).
 Lines: the unlisted L lines at intensities seen in a measured region's windows (Ge La 5e5, Ga La 3e5, Cu La 1e5); Ti Ka planted at 3000.
 `plantSn` is an optional extra plant, Sn L-alpha 3.44 keV and Sn K-alpha 25.27 keV (the K line outside the
 default 20 keV fit range, the L line inside it); the tests add it only where they name it, so the other keys are unchanged.
@@ -17,11 +19,15 @@
 OUT = sys.argv[1] if len(sys.argv) > 1 else os.path.join(HERE, "..", "..", "Tests", "SpectroEDXTests", "Fixtures", "eds-realistic-l-sim.json")
 OFFSET, SCALE, SIZE, BEAM = -1.93221348, 0.02, 4096, 200.0
 
+SI_EDGE = 1.839
+# The step seen through the detector: a Gaussian-blurred step, sigma from the line-width law at the edge (130 eV at Mn Ka).
+SIGMA_EDGE = math.sqrt(2.5 * (SI_EDGE - 5.8987) * 1000 + 130.0 ** 2) / 1000 / (2 * math.sqrt(2 * math.log(2)))
+
 def continuum(e):
     if e <= 0.1:
         return 0.0
     b = 1500 * (3 / e) * ((BEAM - e) / (BEAM - 3)) * (1 - math.exp(-((e / 0.5) ** 2.4))) * math.exp(-(e - 3) / 12)
-    return b * (0.97 if e >= 1.839 else 1.0)
+    return b * (1.0 - 0.03 * 0.5 * (1 + math.erf((e - SI_EDGE) / (math.sqrt(2) * SIGMA_EDGE))))
 
 energies = [OFFSET + SCALE * i for i in range(SIZE)]
 out = {
diff --git a/tools/edx-sim/weakline_sim.py b/tools/edx-sim/weakline_sim.py
index 761dbb9..8c90069 100644
--- a/tools/edx-sim/weakline_sim.py
+++ b/tools/edx-sim/weakline_sim.py
@@ -1,14 +1,14 @@
 """Weak-line recovery pools from the EDX forward model (forward.py beside this script).
 
 Writes Tests/SpectroEDXTests/Fixtures/eds-weakline-sim.json: for Mg planted at 0, 0.1, 0.3, 1, 10 % of the Al K-alpha counts (Al_Ka + its tail),
-the EXPECTED pooled spectrum of 1e4 identical matrix pixels (80 nm, 2.70 g/cm3, lam 1), and the planted truth. The Swift test adds Poisson noise.
+the EXPECTED pooled spectrum of 1e4 identical matrix pixels (80 nm, 2.70 g/cm3, lam 1; the continuum blurred by the detector resolution, detector_blur.py), and the planted truth. The Swift test adds Poisson noise.
 Usage: References/python/bin/python -I -B tools/edx-sim/weakline_sim.py [out.json]   (numpy only)
 """
 import json, os, sys
 import numpy as np
 HERE = os.path.dirname(os.path.abspath(__file__))
 sys.path.insert(0, HERE)
-import xray_model as xm, forward as fw
+import xray_model as xm, forward as fw, detector_blur as db
 MAC = os.path.join(HERE, "..", "..", "Sources", "SpectroEDX", "Resources", "Spectroscopy", "FFastMAC.csv")
 OUT = sys.argv[1] if len(sys.argv) > 1 else os.path.join(HERE, "..", "..", "Tests", "SpectroEDXTests", "Fixtures", "eds-weakline-sim.json")
 NPIX = 10000
@@ -23,7 +23,9 @@ def run(mg_atoms):
               np.array([0.0]), np.array([0]), 1, keep_pixel_arrays=True)
     names = [c.name for c in f.comps]
     amp = {nm: float(r["amp"][i, 0]) * NPIX for i, nm in enumerate(names)}
-    return r["exp_sum"][0] * NPIX, amp
+    # the continuum seen through the detector (blurred by its resolution, detector_blur.py)
+    e = db.blurred(f, spec, fw.THICKNESS_BASE_NM, fw.PHASE_DENSITY["Al"], 1.0, r["exp_sum"][0])
+    return e * NPIX, amp
 
 levels = [0.0, 0.001, 0.003, 0.01, 0.1]
 out = {"generator": "tools/edx-sim/weakline_sim.py over tools/edx-sim/forward.py", "npix": NPIX,