diff --git a/crates/lib-dialects/src/ansi.rs b/crates/lib-dialects/src/ansi.rs
index 6e9044029..c3913a637 100644
--- a/crates/lib-dialects/src/ansi.rs
+++ b/crates/lib-dialects/src/ansi.rs
@@ -3953,7 +3953,11 @@ pub fn raw_dialect() -> Dialect {
                                 ];
                             })
                             .to_matchable(),
-                        Ref::new("ElseClauseSegment").optional().to_matchable(),
+                        Ref::new("ElseClauseSegment")
+                            .optional()
+                            .reset_terminators()
+                            .terminators(vec![Ref::keyword("END").to_matchable()])
+                            .to_matchable(),
                         MetaSegment::dedent().to_matchable(),
                         Ref::keyword("END").to_matchable(),
                     ])
@@ -3971,7 +3975,11 @@ pub fn raw_dialect() -> Dialect {
                                 ];
                             })
                             .to_matchable(),
-                        Ref::new("ElseClauseSegment").optional().to_matchable(),
+                        Ref::new("ElseClauseSegment")
+                            .optional()
+                            .reset_terminators()
+                            .terminators(vec![Ref::keyword("END").to_matchable()])
+                            .to_matchable(),
                         MetaSegment::dedent().to_matchable(),
                         Ref::keyword("END").to_matchable(),
                     ])
diff --git a/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.sql b/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.sql
new file mode 100644
index 000000000..6336718f8
--- /dev/null
+++ b/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.sql
@@ -0,0 +1,6 @@
+select case
+      when a = 1 then 'one'
+      when a = 2 then 'two'
+  else 'other' || 's'
+    end as b
+from test;
diff --git a/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.yml b/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.yml
new file mode 100644
index 000000000..58043d07e
--- /dev/null
+++ b/crates/lib-dialects/test/fixtures/dialects/postgres/sqruff/case_else_concat.yml
@@ -0,0 +1,51 @@
+file:
+- statement:
+  - select_statement:
+    - select_clause:
+      - keyword: select
+      - select_clause_element:
+        - expression:
+          - case_expression:
+            - keyword: case
+            - when_clause:
+              - keyword: when
+              - expression:
+                - column_reference:
+                  - naked_identifier: a
+                - comparison_operator:
+                  - raw_comparison_operator: =
+                - numeric_literal: '1'
+              - keyword: then
+              - expression:
+                - quoted_literal: '''one'''
+            - when_clause:
+              - keyword: when
+              - expression:
+                - column_reference:
+                  - naked_identifier: a
+                - comparison_operator:
+                  - raw_comparison_operator: =
+                - numeric_literal: '2'
+              - keyword: then
+              - expression:
+                - quoted_literal: '''two'''
+            - else_clause:
+              - keyword: else
+              - expression:
+                - quoted_literal: '''other'''
+                - binary_operator:
+                  - pipe: '|'
+                  - pipe: '|'
+                - quoted_literal: '''s'''
+            - keyword: end
+        - alias_expression:
+          - keyword: as
+          - naked_identifier: b
+    - from_clause:
+      - keyword: from
+      - from_expression:
+        - from_expression_element:
+          - table_expression:
+            - table_reference:
+              - naked_identifier: test
+- statement_terminator: ;
diff --git a/crates/lib/src/core/linter/core.rs b/crates/lib/src/core/linter/core.rs
index b3a805ee7..94913201c 100644
--- a/crates/lib/src/core/linter/core.rs
+++ b/crates/lib/src/core/linter/core.rs
@@ -864,6 +864,19 @@ mod tests {
     use crate::core::config::FluffConfig;
     use crate::core::linter::core::Linter;
 
+    fn postgres_all_rules_linter() -> Linter {
+        let config = FluffConfig::from_source(
+            r#"
+[sqruff]
+dialect = postgres
+rules = all
+"#,
+            None,
+        );
+
+        Linter::new(config, None, None, true).unwrap()
+    }
+
     fn normalise_paths(paths: Vec<String>) -> Vec<String> {
         paths
             .into_iter()
@@ -1082,4 +1095,88 @@ mod tests {
             "Should not have LT01 false positives on template syntax"
         );
     }
+
+    #[test]
+    fn test_postgres_case_else_concat_does_not_raise_lt01_and_fixes_cleanly() {
+        let sql = r#"select case
+      when a = 1 then 'one'
+      when a = 2 then 'two'
+  else 'other' || 's'
+    end as b
+from test;
+"#;
+        let expected = r#"select
+    case
+        when a = 1 then 'one'
+        when a = 2 then 'two'
+        else 'other' || 's'
+    end as b
+from test;
+"#;
+
+        let mut linter = postgres_all_rules_linter();
+        let linted = linter.lint_string_wrapped(sql, false).unwrap();
+        let violations = linted.violations();
+
+        assert!(
+            !violations.iter().any(|v| v.rule_code() == "LT01"),
+            "Expected no LT01 violations, got: {:?}",
+            violations
+                .iter()
+                .map(|v| (v.rule_code(), v.desc().to_string()))
+                .collect::<Vec<_>>()
+        );
+        assert!(
+            violations.iter().all(|v| v.rule_code() == "LT02"),
+            "Expected only LT02 violations, got: {:?}",
+            violations
+                .iter()
+                .map(|v| (v.rule_code(), v.desc().to_string()))
+                .collect::<Vec<_>>()
+        );
+
+        let fixed = postgres_all_rules_linter()
+            .lint_string_wrapped(sql, true)
+            .unwrap()
+            .fix_string();
+
+        assert_eq!(fixed, expected);
+    }
+
+    #[test]
+    fn test_postgres_case_else_binary_operator_spacing_still_triggers_lt01() {
+        let sql = r#"select case
+      when a = 1 then 'one'
+  else 1+2
+    end as b
+from test;
+"#;
+        let expected = r#"select
+    case
+        when a = 1 then 'one'
+        else 1 + 2
+    end as b
+from test;
+"#;
+
+        let mut linter = postgres_all_rules_linter();
+        let linted = linter.lint_string_wrapped(sql, false).unwrap();
+        let violations = linted.violations();
+
+        assert!(
+            violations.iter().any(|v| v.rule_code() == "LT01"),
+            "Expected LT01 violations, got: {:?}",
+            violations
+                .iter()
+                .map(|v| (v.rule_code(), v.desc().to_string()))
+                .collect::<Vec<_>>()
+        );
+
+        let fixed = postgres_all_rules_linter()
+            .lint_string_wrapped(sql, true)
+            .unwrap()
+            .fix_string();
+
+        assert_eq!(fixed, expected);
+    }
 }
diff --git a/crates/lib/test/fixtures/rules/std_rule_cases/LT01-operators.yml b/crates/lib/test/fixtures/rules/std_rule_cases/LT01-operators.yml
index 47167eec6..d968c8790 100644
--- a/crates/lib/test/fixtures/rules/std_rule_cases/LT01-operators.yml
+++ b/crates/lib/test/fixtures/rules/std_rule_cases/LT01-operators.yml
@@ -90,6 +90,35 @@ pass_tsql_assignment_operator:
 pass_concat_string:
   pass_str: SELECT 'barry' || 'pollard'
 
+pass_postgres_case_else_concat_string:
+  pass_str: |
+    select case
+          when a = 1 then 'one'
+          when a = 2 then 'two'
+      else 'other' || 's'
+        end as b
+    from test;
+  configs:
+    core:
+      dialect: postgres
+
+fail_postgres_case_else_binary_operator_spacing:
+  fail_str: |
+    select case
+          when a = 1 then 'one'
+      else 1+2
+        end as b
+    from test;
+  fix_str: |
+    select case
+          when a = 1 then 'one'
+      else 1 + 2
+        end as b
+    from test;
+  configs:
+    core:
+      dialect: postgres
+
 test_pass_placeholder_spacing:
   # Test for spacing issues around placeholders
   # https://github.com/sqlfluff/sqlfluff/issues/4253