# hook-example1.hook
[Trigger]
Operation = Upgrade
Operation = Install
Operation = Remove
Type = Package
Target = *
[Action]
Description = Cleaning pacman cache...
When = PostTransaction
Exec = /usr/bin/paccache -r
# hook-example2.hook
[Trigger]
Operation = Remove
Operation = Install
Operation = Upgrade
Type = Package
Target = *
[Action]
Description = Keep the last cache and the currently installed.
When = PostTransaction
Exec = /usr/bin/paccache -rvk2
man alpm-hooks(5)provides all the possible options