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Defect Chemistry and Structural Disorder in IGZO

Computational investigation of indium gallium zinc oxide (IGZO), with a focus on oxygen vacancies, structural disorder, and their influence on electronic properties.

Research Question

How does local structural disorder influence oxygen-vacancy formation and electronic structure in crystalline and amorphous IGZO?

Objectives

  1. Establish a reproducible computational reference for crystalline IGZO.
  2. Investigate oxygen-vacancy formation energies and charge states.
  3. Determine how local In/Ga/Zn coordination affects vacancy energetics and electronic structure.
  4. Generate and characterise amorphous IGZO structures.
  5. Compare defect chemistry between crystalline and amorphous IGZO.
  6. Develop and validate a MACE interatomic potential for larger-scale atomistic sampling.
  7. Build reproducible workflows using AiiDA, Python, ASE and pymatgen.

Computational Methods

  • VASP — crystalline reference calculations and electronic structure.
  • CP2K — DFT molecular dynamics, amorphisation and amorphous-structure calculations.
  • LAMMPS — large-scale molecular dynamics using validated potentials.
  • MACE — machine-learning interatomic potential development.
  • AiiDA — workflow automation, provenance and reproducibility.
  • ASE / pymatgen — structure generation and analysis.
  • Python — data processing, statistics and visualisation.

Project Status

🟡 Research project initiated

Completed

  • Define initial research direction
  • Establish repository structure

In Progress

  • Literature review
  • Identify and validate crystalline IGZO structure
  • DFT convergence testing
  • Pristine crystalline IGZO calculations

Planned

  • Oxygen-vacancy calculations
  • Amorphous IGZO generation
  • Amorphous structural analysis
  • MACE dataset generation
  • MACE training and validation
  • Large-scale atomistic sampling
  • Defect statistics

Repository Structure

igzo-defect-modelling/
├── docs/
├── structures/
├── calculations/
├── mace/
├── notebooks/
├── src/
├── reports/
├── workflows/
├── README.md
├── LICENSE
└── requirements.txt

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Computational investigation of defect chemistry and structural disorder in IGZO, a transparent conducting oxide and amorphous oxide semiconductor, using DFT, molecular dynamics and machine-learning potentials.

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